MA46875A - Tôle d'acier laminée à chaud et revêtue pour estampage à chaud, pièce en acier revêtue estampée à chaud et procédés de fabrication correspondants - Google Patents

Tôle d'acier laminée à chaud et revêtue pour estampage à chaud, pièce en acier revêtue estampée à chaud et procédés de fabrication correspondants

Info

Publication number
MA46875A
MA46875A MA046875A MA46875A MA46875A MA 46875 A MA46875 A MA 46875A MA 046875 A MA046875 A MA 046875A MA 46875 A MA46875 A MA 46875A MA 46875 A MA46875 A MA 46875A
Authority
MA
Morocco
Prior art keywords
hot
coated
steel sheet
rolled steel
rolled
Prior art date
Application number
MA046875A
Other languages
English (en)
Other versions
MA46875B1 (fr
Inventor
Martin Beauvais
Thomas Henrion
Ronan Jacolot
Original Assignee
Arcelormittal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arcelormittal filed Critical Arcelormittal
Publication of MA46875A publication Critical patent/MA46875A/fr
Publication of MA46875B1 publication Critical patent/MA46875B1/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02Stamping using rigid devices or tools
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02Stamping using rigid devices or tools
    • B21D22/022Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/012Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of aluminium or an aluminium alloy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/013Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/016Layered products comprising a layer of metal all layers being exclusively metallic all layers being formed of aluminium or aluminium alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/62Quenching devices
    • C21D1/673Quenching devices for die quenching
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/13Modifying the physical properties of iron or steel by deformation by hot working
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0278Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
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    • C21METALLURGY OF IRON
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    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0068Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
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    • C21METALLURGY OF IRON
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    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C21D9/48Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals deep-drawing sheets
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
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    • C22C21/10Alloys based on aluminium with zinc as the next major constituent
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    • C22C33/04Making ferrous alloys by melting
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    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
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    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
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    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
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    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
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    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • C23C28/025Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only with at least one zinc-based layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/02Iron or ferrous alloys
    • B23K2103/04Steel or steel alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/001Austenite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)
  • Coating With Molten Metal (AREA)
  • Heat Treatment Of Articles (AREA)
  • Shaping Metal By Deep-Drawing, Or The Like (AREA)

Abstract

L'invention concerne un procédé de fabrication d'une tôle d'acier laminée à chaud et revêtue ayant une épaisseur comprise entre 1,8 mm et 5 mm, comprenant la fourniture d'un semi-produit ayant une composition comprenant : 0,04 % ≤ c ≤ 0,38 %, 0,40 % ≤ mn ≤ 3 %, 0,005 % ≤ si ≤ 0,70 %, 0,005 % ≤ al ≤ 0,1 %, 0,001 % ≤ cr ≤ 2 %, 0,001 % ≤ ni ≤ 2 %, 0,001 % ≤ ti ≤ 0,2 %, nb ≤ 0,1 %, b ≤ 0,010 %, 0,0005 % ≤ n ≤ 0,010 %, 0,0001 % ≤ s ≤ 0,05 %, 0,0001 % ≤ p ≤ 0,1 %, mo ≤ 0,65 %, w ≤ 0,30 %, ca ≤ 0,006 %, le laminage à chaud à une température de laminage finale frt, pour obtenir un produit en acier laminé à chaud ayant une épaisseur comprise entre 1,8 mm et 5 mm, puis le refroidissement jusqu'à une température d'enroulement tbobine satisfaisant : 450 °c ≤ tbobine ≤ tbobinemax avec tbobinemax = 650 - 140 xfγ, tbobinemax étant exprimée en degrés celsius et fγ désignant la fraction d'austénite juste avant l'enroulement, et l'enroulement pour obtenir un substrat d'acier laminé à chaud, le décapage et le revêtement du substrat d'acier laminé à chaud avec de l'al ou un alliage d'al par immersion à chaud continue dans un bain, pour obtenir une tôle d'acier laminée à chaud et revêtue comprenant une tôle d'acier laminée à chaud et un revêtement d'al ou d'alliage d'al, ayant une épaisseur comprise entre 10 et 33 µm, de chaque côté de la tôle d'acier laminée à chaud.
MA46875A 2016-11-24 2017-11-23 Tôle d'acier laminée à chaud et revêtue pour estampage à chaud, pièce en acier revêtue estampée à chaud et procédés de fabrication correspondants MA46875B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PCT/IB2016/057100 WO2018096387A1 (fr) 2016-11-24 2016-11-24 Tôle d'acier laminé à chaud et revêtu pour estampage à chaud, pièce d'acier revêtu estampé à chaud, et ses procédés de fabrication
PCT/IB2017/057370 WO2018096487A1 (fr) 2016-11-24 2017-11-23 Tôle d'acier laminée à chaud et revêtue pour estampage à chaud, pièce en acier revêtue estampée à chaud et procédés de fabrication correspondants

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MA46875A true MA46875A (fr) 2019-10-02
MA46875B1 MA46875B1 (fr) 2021-04-30

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MA054573A MA54573A (fr) 2016-11-24 2017-11-23 Tôle d'acier laminée à chaud et revêtue pour estampage à chaud, pièce en acier revêtue estampée à chaud et procédés de fabrication correspondants
MA49658A MA49658B1 (fr) 2016-11-24 2017-11-23 Feuille d'acier laminée à chaud et revêtue pour formage à chaud, pièce d'acier formée à chaud et revêtue et leurs procédés de fabrication
MA46875A MA46875B1 (fr) 2016-11-24 2017-11-23 Tôle d'acier laminée à chaud et revêtue pour estampage à chaud, pièce en acier revêtue estampée à chaud et procédés de fabrication correspondants
MA49659A MA49659B1 (fr) 2016-11-24 2017-11-23 Tôle d'acier laminée à chaud et revêtue pour estampage à chaud, pièce en acier revêtue estampée à chaud et procédés de fabrication correspondants

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MA49658A MA49658B1 (fr) 2016-11-24 2017-11-23 Feuille d'acier laminée à chaud et revêtue pour formage à chaud, pièce d'acier formée à chaud et revêtue et leurs procédés de fabrication

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MA (4) MA54573A (fr)
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MA54573A (fr) 2021-10-27
JP7130816B2 (ja) 2022-09-05
CN113046645B (zh) 2022-09-27
MA49658B1 (fr) 2021-08-31
KR20190073462A (ko) 2019-06-26
RU2726165C1 (ru) 2020-07-09
HUE056759T2 (hu) 2022-03-28
ES2886340T3 (es) 2021-12-17
CA3217629A1 (fr) 2018-05-31
KR102308581B1 (ko) 2021-10-05
WO2018096387A1 (fr) 2018-05-31
EP4417724A2 (fr) 2024-08-21
CN113046633B (zh) 2022-08-02
EP3656552B1 (fr) 2021-07-21
US20200224297A1 (en) 2020-07-16
MA49659B1 (fr) 2021-09-30
PL3656888T3 (pl) 2021-12-13
EP3656888A1 (fr) 2020-05-27
WO2018096487A1 (fr) 2018-05-31
JP6998955B2 (ja) 2022-01-18
CA3156703C (fr) 2023-10-17
JP2021152217A (ja) 2021-09-30
HUE056344T2 (hu) 2022-02-28
UA127668C2 (uk) 2023-11-22
CA3156200A1 (fr) 2018-05-31
ES2903368T3 (es) 2022-04-01
MA46875B1 (fr) 2021-04-30
CN113046645A (zh) 2021-06-29
CN109982839B (zh) 2021-03-19
CA3044772C (fr) 2022-07-19
CA3044772A1 (fr) 2018-05-31
EP3901321A1 (fr) 2021-10-27
JP7433386B2 (ja) 2024-02-19
JP2020509160A (ja) 2020-03-26
CN113046633A (zh) 2021-06-29
EP3901321B1 (fr) 2024-10-02
EP3656888B1 (fr) 2021-07-21
BR122023000524B1 (pt) 2023-10-10
EP3544808B1 (fr) 2021-04-14
ZA201903061B (en) 2020-01-29
ES2868828T3 (es) 2021-10-22
KR102272870B1 (ko) 2021-07-06
JP2022169693A (ja) 2022-11-09
US20230167557A1 (en) 2023-06-01
MA49659A (fr) 2021-03-31
MA49658A (fr) 2021-03-24
CA3156200C (fr) 2024-01-02
HUE055027T2 (hu) 2021-10-28
EP3544808A1 (fr) 2019-10-02
MX2019006106A (es) 2019-08-21
UA127366C2 (uk) 2023-07-26
BR112019009708A2 (pt) 2019-08-13
UA124973C2 (uk) 2021-12-22
PL3656552T3 (pl) 2021-12-20
PL3544808T3 (pl) 2021-10-04
KR20210074405A (ko) 2021-06-21
EP3656552A1 (fr) 2020-05-27
CA3156703A1 (fr) 2018-05-31
CN109982839A (zh) 2019-07-05
UA127669C2 (uk) 2023-11-22

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