LV10116B - Method of polimerisation of epoxy compounds - Google Patents
Method of polimerisation of epoxy compounds Download PDFInfo
- Publication number
- LV10116B LV10116B LVP-92-135A LV920135A LV10116B LV 10116 B LV10116 B LV 10116B LV 920135 A LV920135 A LV 920135A LV 10116 B LV10116 B LV 10116B
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- metal complex
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- 238000000034 method Methods 0.000 title claims abstract description 9
- 150000001875 compounds Chemical class 0.000 title claims 8
- 239000004593 Epoxy Substances 0.000 title claims 6
- 239000002879 Lewis base Substances 0.000 claims abstract description 17
- 150000007527 lewis bases Chemical class 0.000 claims abstract description 17
- -1 epoxide compound Chemical class 0.000 claims abstract description 13
- 239000003446 ligand Substances 0.000 claims abstract description 10
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 7
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 claims description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 3
- 150000003568 thioethers Chemical class 0.000 claims description 3
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 2
- 229910001437 manganese ion Inorganic materials 0.000 claims description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 2
- 229910021645 metal ion Inorganic materials 0.000 claims 2
- 230000000737 periodic effect Effects 0.000 claims 2
- 150000002989 phenols Chemical class 0.000 claims 2
- YRAJNWYBUCUFBD-UHFFFAOYSA-N 2,2,6,6-tetramethylheptane-3,5-dione Chemical compound CC(C)(C)C(=O)CC(=O)C(C)(C)C YRAJNWYBUCUFBD-UHFFFAOYSA-N 0.000 claims 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000013466 adhesive and sealant Substances 0.000 claims 1
- 238000004870 electrical engineering Methods 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000010907 mechanical stirring Methods 0.000 claims 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 125000004076 pyridyl group Chemical group 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 7
- 238000006116 polymerization reaction Methods 0.000 abstract description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 2
- 150000001455 metallic ions Chemical class 0.000 abstract 2
- 229940106691 bisphenol a Drugs 0.000 abstract 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 4
- CVBUKMMMRLOKQR-UHFFFAOYSA-N 1-phenylbutane-1,3-dione Chemical compound CC(=O)CC(=O)C1=CC=CC=C1 CVBUKMMMRLOKQR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 125000005594 diketone group Chemical group 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 150000002924 oxiranes Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 125000005595 acetylacetonate group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- ZASKXVBJDUIFPP-UHFFFAOYSA-N 1h-imidazole;2-methyl-1h-imidazole Chemical compound C1=CNC=N1.CC1=NC=CN1 ZASKXVBJDUIFPP-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000219495 Betulaceae Species 0.000 description 1
- 235000005940 Centaurea cyanus Nutrition 0.000 description 1
- 240000004385 Centaurea cyanus Species 0.000 description 1
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 241000402754 Erythranthe moschata Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 241000283903 Ovis aries Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- MJSNUBOCVAKFIJ-LNTINUHCSA-N chromium;(z)-4-oxoniumylidenepent-2-en-2-olate Chemical compound [Cr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MJSNUBOCVAKFIJ-LNTINUHCSA-N 0.000 description 1
- 239000000039 congener Substances 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 101150061972 zur gene Proteins 0.000 description 1
Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/70—Chelates
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
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- C07K5/00—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof
- C07K5/02—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing at least one abnormal peptide link
- C07K5/0205—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing at least one abnormal peptide link containing the structure -NH-(X)3-C(=0)-, e.g. statine or derivatives thereof
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- C07K5/0207—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing at least one abnormal peptide link containing the structure -NH-(X)4-C(=0), e.g. 'isosters', replacing two amino acids
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- C07K5/06—Dipeptides
- C07K5/06008—Dipeptides with the first amino acid being neutral
- C07K5/06017—Dipeptides with the first amino acid being neutral and aliphatic
- C07K5/06034—Dipeptides with the first amino acid being neutral and aliphatic the side chain containing 2 to 4 carbon atoms
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- C07K5/06—Dipeptides
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- C07K5/08—Tripeptides
- C07K5/0802—Tripeptides with the first amino acid being neutral
- C07K5/0804—Tripeptides with the first amino acid being neutral and aliphatic
- C07K5/0808—Tripeptides with the first amino acid being neutral and aliphatic the side chain containing 2 to 4 carbon atoms, e.g. Val, Ile, Leu
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- C07K—PEPTIDES
- C07K5/00—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof
- C07K5/04—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing only normal peptide links
- C07K5/08—Tripeptides
- C07K5/0819—Tripeptides with the first amino acid being acidic
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- C—CHEMISTRY; METALLURGY
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
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- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
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- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
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- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
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- Genetics & Genomics (AREA)
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- Heart & Thoracic Surgery (AREA)
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- Crystallography & Structural Chemistry (AREA)
- Pulmonology (AREA)
- Reproductive Health (AREA)
- Endocrinology (AREA)
- Vascular Medicine (AREA)
- Epoxy Resins (AREA)
- Polyethers (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD90338525A DD293126A5 (de) | 1990-03-09 | 1990-03-09 | Verfahren zur polymerisation von epoxidischen verbindungen |
| DD90338526A DD292468A5 (de) | 1990-03-09 | 1990-03-09 | Verfahren zur polymerisation von epoxidverbindungen |
| PCT/EP1991/000419 WO1991013925A1 (de) | 1990-03-09 | 1991-03-06 | Verfahren zur polymerisation von epoxidverbindungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| LV10116A LV10116A (lv) | 1994-05-10 |
| LV10116B true LV10116B (en) | 1995-02-20 |
Family
ID=25748335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LVP-92-135A LV10116B (en) | 1990-03-09 | 1992-09-29 | Method of polimerisation of epoxy compounds |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0518908B1 (ja) |
| JP (1) | JP3215106B2 (ja) |
| KR (1) | KR970001539B1 (ja) |
| AT (1) | ATE119174T1 (ja) |
| BR (1) | BR9104778A (ja) |
| CA (1) | CA2054212C (ja) |
| DE (1) | DE59104812D1 (ja) |
| ES (1) | ES2036162T3 (ja) |
| GR (1) | GR920300130T1 (ja) |
| LV (1) | LV10116B (ja) |
| WO (1) | WO1991013925A1 (ja) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4207258A1 (de) * | 1992-03-07 | 1993-09-09 | Ruetgerswerke Ag | Schleifmittel |
| DE4208518A1 (de) * | 1992-03-17 | 1993-09-23 | Ruetgerswerke Ag | Hochtemperaturbestaendige elektro-laminate, verfahren zu ihrer herstellung und verwendung |
| DE4303824A1 (de) * | 1993-02-10 | 1994-08-11 | Ruetgerswerke Ag | Epoxidharzsystem |
| DE4408865C2 (de) * | 1994-03-16 | 2001-05-17 | Raymond A & Cie | Verwendung einer einkomponentigen, adhäsiven Beschichtungsmasse zum Ausrüsten der Oberflächen von Befestigungselementen mit einer reaktiven Klebschicht |
| DE59510429D1 (de) * | 1994-05-10 | 2002-11-28 | Vantico Ag | Metallkomplexkatalysatoren enthaltende Epoxidharzgemische |
| DE4421623A1 (de) * | 1994-06-21 | 1996-01-04 | Thera Ges Fuer Patente | Mehrkomponentige, kationisch härtende Epoxidmassen und deren Verwendung sowie Verfahren zur Herstellung gehärteter Massen |
| DE19905448A1 (de) | 1999-02-09 | 2000-08-10 | Bakelite Ag | Cyanatharze und Epoxidverbindungen enthaltende härtbare Mischungen |
| DE19910711A1 (de) * | 1999-03-10 | 2000-09-14 | Bakelite Ag | Imprägniervergußmassen, ihre Verwendung sowie ein Verfahren zur Imprägnierung von Zündspulen |
| DE10113940A1 (de) * | 2001-03-22 | 2002-09-26 | Bakelite Ag | Verfahren zur Herstellung von mit Harz behandelten Verstärkungs- oder Kaschiermaterialien |
| GB2397859B (en) * | 2001-11-05 | 2006-02-22 | Fiberspar Corp | Spoolable composite tubing with a catalytically cured matrix |
| CA2641492C (en) | 2007-10-23 | 2016-07-05 | Fiberspar Corporation | Heated pipe and methods of transporting viscous fluid |
| US9127546B2 (en) | 2009-01-23 | 2015-09-08 | Fiberspar Coproation | Downhole fluid separation |
| US8955599B2 (en) | 2009-12-15 | 2015-02-17 | Fiberspar Corporation | System and methods for removing fluids from a subterranean well |
| CN102803646B (zh) | 2009-12-15 | 2016-04-20 | 菲伯斯公司 | 用于从地下井去除流体的系统和方法 |
| MX358020B (es) | 2012-08-10 | 2018-08-02 | Nat Oilwell Varco Lp | Conectores de tuberia continua compuesta. |
| DE102014102455A1 (de) * | 2014-02-25 | 2015-08-27 | Seho Systemtechnik Gmbh | Verfahren zum Polymerisieren von einem Kunstharz |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3310602A (en) * | 1962-07-26 | 1967-03-21 | Borden Co | Curing epoxide resins with aromatic amine-aldehyde coordination complexes |
| US3367913A (en) * | 1966-09-09 | 1968-02-06 | Interchem Corp | Thermosetting epoxy resin composition containing a zinc chelate |
| US3677978A (en) * | 1971-08-23 | 1972-07-18 | Ppg Industries Inc | Metal salt complexes of imidazoles as curing agents for one-part epoxy resins |
| GB1435540A (en) * | 1972-07-06 | 1976-05-12 | Mccall Corp | Curable solventless composition |
| CH629230A5 (de) * | 1977-11-04 | 1982-04-15 | Ciba Geigy Ag | Verfahren zur herstellung von metallsalz-aminkomplexen und ihre verwendung. |
| GB8304581D0 (en) * | 1983-02-18 | 1983-03-23 | Secr Defence | Curing agents for epoxy resins |
| US4473674A (en) * | 1983-11-03 | 1984-09-25 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Process for improving mechanical properties of epoxy resins by addition of cobalt ions |
-
1991
- 1991-03-06 WO PCT/EP1991/000419 patent/WO1991013925A1/de active IP Right Grant
- 1991-03-06 DE DE59104812T patent/DE59104812D1/de not_active Expired - Lifetime
- 1991-03-06 BR BR919104778A patent/BR9104778A/pt not_active Application Discontinuation
- 1991-03-06 JP JP50518291A patent/JP3215106B2/ja not_active Expired - Fee Related
- 1991-03-06 EP EP91905067A patent/EP0518908B1/de not_active Expired - Lifetime
- 1991-03-06 AT AT91905067T patent/ATE119174T1/de not_active IP Right Cessation
- 1991-03-06 ES ES91905067T patent/ES2036162T3/es not_active Expired - Lifetime
- 1991-03-06 KR KR1019910701562A patent/KR970001539B1/ko not_active IP Right Cessation
- 1991-03-06 CA CA002054212A patent/CA2054212C/en not_active Expired - Fee Related
-
1992
- 1992-09-29 LV LVP-92-135A patent/LV10116B/lv unknown
-
1993
- 1993-03-16 GR GR920300130T patent/GR920300130T1/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR970001539B1 (ko) | 1997-02-11 |
| CA2054212A1 (en) | 1991-09-10 |
| ATE119174T1 (de) | 1995-03-15 |
| WO1991013925A1 (de) | 1991-09-19 |
| ES2036162T1 (es) | 1993-05-16 |
| EP0518908A1 (de) | 1992-12-23 |
| CA2054212C (en) | 1997-02-11 |
| DE59104812D1 (de) | 1995-04-06 |
| EP0518908B1 (de) | 1995-03-01 |
| BR9104778A (pt) | 1992-03-24 |
| KR920701297A (ko) | 1992-08-11 |
| JP3215106B2 (ja) | 2001-10-02 |
| GR920300130T1 (en) | 1993-03-16 |
| LV10116A (lv) | 1994-05-10 |
| ES2036162T3 (es) | 1995-05-16 |
| JPH05504593A (ja) | 1993-07-15 |
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