KR960701014A - 2-메틸-1, 5-디아미노펜탄의 촉매고리화에 의한 3-메틸피페리딘 및 3-메틸피리딘의 제조 방법[rpocess for preparing 3-methylpiperidine and 3-methylpyridine by catalytic cyclisation of 2-methyl-1,5-diaminopentane] - Google Patents

2-메틸-1, 5-디아미노펜탄의 촉매고리화에 의한 3-메틸피페리딘 및 3-메틸피리딘의 제조 방법[rpocess for preparing 3-methylpiperidine and 3-methylpyridine by catalytic cyclisation of 2-methyl-1,5-diaminopentane] Download PDF

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Publication number
KR960701014A
KR960701014A KR1019950704170A KR19950704170A KR960701014A KR 960701014 A KR960701014 A KR 960701014A KR 1019950704170 A KR1019950704170 A KR 1019950704170A KR 19950704170 A KR19950704170 A KR 19950704170A KR 960701014 A KR960701014 A KR 960701014A
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South Korea
Prior art keywords
methyl
methylpiperidine
diaminopentane
methylpyridine
catalyst
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KR1019950704170A
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English (en)
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KR100276748B1 (ko
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헤벨링 요제프
아름부루스터 에리히
지크리스트 발터
Original Assignee
베아트 라우버·가비 쉴링어
론자 아게
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Priority claimed from CH3794A external-priority patent/CH686135A5/de
Application filed by 베아트 라우버·가비 쉴링어, 론자 아게 filed Critical 베아트 라우버·가비 쉴링어
Publication of KR960701014A publication Critical patent/KR960701014A/ko
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Publication of KR100276748B1 publication Critical patent/KR100276748B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C07D213/08—Preparation by ring-closure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/10—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms
    • C07D211/12—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms with only hydrogen atoms attached to the ring nitrogen atom

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Hydrogenated Pyridines (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

기상으로 2-메틸-1.5-디아노펜탄으로부터 3- 메틸피페리딘 또는 3-메틸피리딘을 제조하는 방법에 있어서, 최초의 생성물을 촉매상을 통과하게 한다. 첫번째 단계에서, 3-메틸피페리딘을 제조하고, 원한다면 두번째 단계에서 3-메틸피리딘을 제조한다.

Description

2-메틸-1.5-디아미노펜탄의 촉매고리화에 의한 3-메틸피페리딘 및 3-메틸피리딘의 제조방법[RPOCESS FOR PREPARING 3-METHYLPIPERIDINE AND 3-METHYLPYRIDINE BY CATALYTIC CYCLISATION OF 2-METHYL -1.5- DIAMINOPENTANE]
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 기상으로 2-메틸-1.5-디아노펜탄으로부터 3-메틸피페리딘을 제조하는 방법에 있어서, 300∼400℃의 온도 및 대기압보다 0내지 10바아 이상인 압력에서, 활성 성분으로 원소 Al 및 /또는 Si의 1종 이상의 산화물을 함유하고, 표면상에서의 염기성 및 산성 센터의 비율이 2이상이며, 40㎡/g 이상의 비표면적을 갖는 촉매를 통해 2-메틸-1.5-디아미노펜탄 기체를 통과시키는 것을 특징으로 하는 방법.
  2. 제1항에 있어서, 사용하는 촉매가 활성화 AL2O3또는 알류미늄/규소 혼합 산화물인 것을 특징으로 하는 방법.
  3. 제1항에 있어서, 사용하는 촉매가 천연 또는 합성 제올라이트인 것을 특징으로 하는 방법.
  4. 300∼400℃의 온ㄴ도 및 대기압보다 0 내지 10바아 이상인 압력에서, 활성 성분으로 Al 및/또는 Si의 1종이상의 산화물을 함유하고, 표면상에서의 염기성 및 산성 센터의 비율이 2 이상이며, 40㎡/g 이상의 비표면적을 갖는 촉매를 통해 출발 물질을 통과시켜 기상으로 2-메틸-1.5-디아미노펜탄으로부터의 최초의 3-메틸피페리딘을 제조하고, 이어서 생성된 3-메틸피페리딘을 바람직하게는 220∼400℃에서, 탈수소 촉매를 통해 통과시키는 것을 특징으로 하는 3-메틸피리딘의 제조방법.
  5. 제4항에 있어서, 사용하는 탈수소 촉매가 지지체상의 귀금속인 것을 특징으로 하는 방법.
  6. 제5항에 있어서, 사용하는 귀금속이 파라듐 또는 플라티늄인 것을 특징으로 하는 방법.
  7. 제6항에 있어서, 사용하는 탈수소 촉매가 가용성 팔라듐착물로 이온 교환하여 제조한 비정질 규소/알루미늄 산화물상의 팔라듐인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950704170A 1993-04-02 1994-03-30 2-메틸-1,5-디아미노펜탄의 촉매고리화에 의한 3-메틸피페리딘 및 3-메틸피리딘의 제조방법 KR100276748B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CH1014/93-0 1993-04-02
CH101493 1993-04-02
CH37/94-3 1994-01-06
CH3794A CH686135A5 (de) 1994-01-06 1994-01-06 Verfahren zur Herstellung von 3-Methylpiperidin und 3-Methylpyridin.
PCT/EP1994/001005 WO1994022824A1 (de) 1993-04-02 1994-03-30 Verfahren zur herstellung von 3-methylpiperidin und 3-methylpyridin durch katalytische cyclisierung von 2-methyl-1, 5-diaminopentan

Publications (2)

Publication Number Publication Date
KR960701014A true KR960701014A (ko) 1996-02-24
KR100276748B1 KR100276748B1 (ko) 2001-01-15

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KR1019950704170A KR100276748B1 (ko) 1993-04-02 1994-03-30 2-메틸-1,5-디아미노펜탄의 촉매고리화에 의한 3-메틸피페리딘 및 3-메틸피리딘의 제조방법

Country Status (27)

Country Link
US (1) US5714610A (ko)
EP (1) EP0691955B1 (ko)
JP (1) JP3520519B2 (ko)
KR (1) KR100276748B1 (ko)
AT (1) ATE153658T1 (ko)
BG (1) BG62767B1 (ko)
BR (1) BR9405915A (ko)
CA (1) CA2159586C (ko)
CZ (1) CZ287321B6 (ko)
DE (1) DE59402925D1 (ko)
DK (1) DK0691955T3 (ko)
EE (1) EE03176B1 (ko)
ES (1) ES2104377T3 (ko)
FI (1) FI112473B (ko)
GE (1) GEP20012441B (ko)
GR (1) GR3024294T3 (ko)
HR (1) HRP940211B1 (ko)
IL (1) IL109173A (ko)
LV (1) LV12129B (ko)
NO (1) NO303937B1 (ko)
PL (1) PL177347B1 (ko)
RO (2) RO117914B1 (ko)
RU (1) RU2127726C1 (ko)
SK (1) SK281702B6 (ko)
TW (1) TW239129B (ko)
UA (1) UA42717C2 (ko)
WO (1) WO1994022824A1 (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GEP20012441B (en) * 1993-04-02 2001-05-25 Lonza Ag Process for Preparing 3-Methylpiperidine and 3-Methylpyridine
CH689831A5 (de) * 1995-11-07 1999-12-15 Eprova Ag Stabile kristalline Tetrahydrofolsaeure-Salze.
ZA968485B (en) 1995-11-01 1997-05-20 Lonza Ag Process for preparing nicotinamide
DE10144631A1 (de) * 2001-09-11 2003-03-27 Basf Ag Verfahren zur Herstellung von Pyrrol und Pyridin
US6995112B2 (en) * 2002-11-08 2006-02-07 Chevron U.S.A. Inc. Highly homogeneous amorphous silica-alumina catalyst composition
WO2010034616A1 (en) * 2008-09-26 2010-04-01 Dsm Ip Assets B.V. Method for the preparation of 3-methylpyridine
US8530664B2 (en) * 2009-10-16 2013-09-10 Lonza Ltd. Catalysts for the preparation of methylpyridine
EP2322273A1 (en) * 2009-10-16 2011-05-18 Lonza Ltd. Catalysts for the preparation of methylpyridine
RU2474473C1 (ru) * 2011-09-16 2013-02-10 Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации КАТАЛИЗАТОР, СПОСОБ ЕГО ПРИГОТОВЛЕНИЯ И СПОСОБ ПОЛУЧЕНИЯ β-ПИКОЛИНА
CN103044317B (zh) * 2013-01-07 2015-07-29 清华大学 制备3-甲基吡啶的方法和系统
CN104841475B (zh) * 2014-02-17 2018-09-11 凯赛（金乡）生物材料有限公司 一种用于制备哌啶的改性分子筛催化剂及其制备方法和应用
CN112010802B (zh) * 2020-08-13 2022-03-29 浙江新和成股份有限公司 3-甲基吡啶的连续制备方法

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FR1115492A (fr) * 1953-12-16 1956-04-25 Ici Ltd Fabrication de la pipéridine et de la pyridine
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FR2503156A1 (fr) * 1981-04-01 1982-10-08 Rhone Poulenc Spec Chim Procede de preparation de pyridine et de pyridines substituees
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Also Published As

Publication number Publication date
SK281702B6 (sk) 2001-07-10
BG100095A (bg) 1996-05-31
EE03176B1 (et) 1999-04-15
FI954660A (fi) 1995-09-29
LV12129B (lv) 1998-12-20
HRP940211B1 (en) 2000-06-30
ES2104377T3 (es) 1997-10-01
NO953896D0 (no) 1995-09-29
CA2159586C (en) 2003-11-18
PL311006A1 (en) 1996-01-22
CZ254295A3 (en) 1996-03-13
JP3520519B2 (ja) 2004-04-19
ATE153658T1 (de) 1997-06-15
TW239129B (ko) 1995-01-21
FI954660A0 (fi) 1995-09-29
KR100276748B1 (ko) 2001-01-15
BG62767B1 (bg) 2000-07-31
JPH08510447A (ja) 1996-11-05
NO303937B1 (no) 1998-09-28
BR9405915A (pt) 1995-12-12
LV12129A (lv) 1998-09-20
FI112473B (fi) 2003-12-15
CA2159586A1 (en) 1994-10-13
AU6537694A (en) 1994-10-24
RU2127726C1 (ru) 1999-03-20
GR3024294T3 (en) 1997-10-31
DE59402925D1 (de) 1997-07-03
CZ287321B6 (en) 2000-10-11
DK0691955T3 (da) 1997-06-16
HRP940211A2 (en) 1997-06-30
EP0691955A1 (de) 1996-01-17
SK122695A3 (en) 1996-02-07
RO117914B1 (ro) 2002-09-30
RO121267B1 (ro) 2007-02-28
IL109173A (en) 1999-03-12
NO953896L (no) 1995-09-29
PL177347B1 (pl) 1999-10-29
IL109173A0 (en) 1994-06-24
AU678232B2 (en) 1997-05-22
WO1994022824A1 (de) 1994-10-13
GEP20012441B (en) 2001-05-25
UA42717C2 (uk) 2001-11-15
US5714610A (en) 1998-02-03
EP0691955B1 (de) 1997-05-28

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