KR940021496A - 말단 이중 결합을 갖는 올레핀의 제조방법 - Google Patents

말단 이중 결합을 갖는 올레핀의 제조방법 Download PDF

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KR940021496A
KR940021496A KR1019940004581A KR19940004581A KR940021496A KR 940021496 A KR940021496 A KR 940021496A KR 1019940004581 A KR1019940004581 A KR 1019940004581A KR 19940004581 A KR19940004581 A KR 19940004581A KR 940021496 A KR940021496 A KR 940021496A
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component
components
pyrrole ring
ring unit
chromium
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KR100284063B1 (ko
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미쓰히사 다무라
겐시 우찌다
요시아끼 이또오
기요시 이와나가
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고오사이 아끼오
스미또모가가꾸고오교 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 하기 성분들로부터 제조된 생성물을 함유하는 촉매를 사용함을 특징으로 하는, 에틸렌, 프로필렌 및 1-부텐으로 구성된 군으로부터 선택된 하나 이상의 단량체의 삼원화 반응에 의한 말단 이중 결합을 갖는 올레핀의 제조방법에 관한 것이다 :
(1) 성분(A) : 하기식[1]로 표시되는 크롬 화합물 :
CrXmYn [1]
(식중, X은 카르복실산 잔기, 1, 3-디케톤 잔기. 할로겐원자 또는 알콕시기를 나타내고; Y은 아민, 포스핀, 산화 포스핀, 니트로실기 또는 에테르를 나타내고; m은 2 내지 4의 정수를 의미하고; n은 0 내지 4의 정수를 의미한다.)
성분(B) : 피롤 고리 단위 또는 아미다졸 고리 단위를 갖는 헤테로시클릭화합물, 및 성분(C) : 하기 일반식[2]로 표시되는 알루미늄 화합물 :
AlRkZ3-k [2]
(식중, R은 수소원자 또는 탄소수 1 내지 10의 알킬기를 나타내고; Z은 할로겐원자를 나타내고; k은 0 내지 3의 실수를 의미한다.) 또는
(2) 성분(A) 및 성분(B′) : 피롤 고리 단위 또는 이미다졸 고리 단위를 갖고 또한 피롤 고리 또는 이미다졸 고리내의 알루미늄 및 질소사이의 결합을 갖는 헤테로시클릭 화합물.
본 발명에 있어서, 1-헥센과 같은 말단 이중 결합을 갖는 올레핀은 본 발명의 방법으로 효과적이고 편리하게 수득될 수 있고, 상기 방법은 또한 산업상 이용성 면에서도 양호하다.

Description

말단 이중 결합을 갖는 올레핀의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 하기 성분들로부터 제조된 생성물을 함유하는 촉매를 사용함을 특징으로 하는, 에틸렌, 프로필렌 및 1-부텐으로 구성된 군으로부터 선택된 하나 이상의 단량체의 삼원화 반응에 의한 말단 이중 결합을 갖는 올레핀의 제조방법 :
    (1) 성분(A) : 하기식[1]로 표시되는 크롬 화합물 :
    CrXmYn [1]
    (식중, X은 카르복실산 잔기, 1, 3-디케톤 잔기. 할로겐원자 또는 알콕시기를 나타내고; Y은 아민, 포스핀, 산화 포스핀, 니트로실기 또는 에테르를 나타내고; m은 2 내지 4의 정수를 의미하고; n은 0 내지 4의 정수를 의미한다.)
    성분(B) : 피롤 고리 단위 또는 아미다졸 고리 단위를 갖는 헤테로시클릭화합물, 및 성분(C) : 하기 일반식[2]로 표시되는 알루미늄 화합물 :
    AlRkZ3-k [2]
    (식중, R은 수소원자 또는 탄소수 1 내지 10의 알킬기를 나타내고; Z은 할로겐원자를 나타내고; k은 0 내지 3의 실수를 의미한다.) 또는
    (2) 성분(A) 및 성분(B′) : 피롤 고리 단위 또는 이미다졸 고리 단위를 갖고 또한 피롤 고리 또는 이미다졸 고리내의 알루미늄 및 질소사이의 결합을 갖는 헤테로시클릭 화합물.
  2. 제1항에 있어서, 상기 생성물이 성분(A), (B) 및 (C) 또는 성분(A) 및 (B′)이외에 성분(D) : 물, 알코올, 페놀 또는 그의 유도체로부터 또한 제조되는 방법.
  3. 제1항에 있어서, 상기 생성물이 성분(A), (B) 및 (C) 또는 성분(A) 및 (B′)이외에 성분(E) : 산 또는 에스테르로부터 또한 제조되는 방법.
  4. 제1항에 있어서, 생성물이 성분(A), (B) 및 (C) 또는 성분(A) 및 (B′)이외에 성분(F) :디엔으로부터 또한 제조되는 방법.
  5. 제1항에 있어서, 상기 단량체가 에틸렌인 방법.
  6. 제1항에 있어서, 성분(B)가 피롤 고리 단위를 갖는 방법.
  7. 제1항에 있어서, 성분(B′)가 피롤 고리 단위를 갖는 방법.
  8. 제1항에 있어서, 성분(C)가 트리알킬알루미늄 또는 수소화알킬알루미늄인 방법.
  9. 제1항에 있어서, 상기 생성물이 성분(A) 및 (B′)이외에 성분(C)로부터 또한 제조되는 방법.
  10. 제9항에 있어서, 성분(A)의 X는 할로겐원자이고, 성분(A)의 Y는 아민 및/또는 에테르이고, 성분(B′)는 피롤 고리 단위를 갖고, 성분(C)는 트리알킬알루미늄인 방법.
  11. 제10항에 있어서, Y가 피리딘 또는 테트라히드로푸란인 방법.
  12. 제11항에 있어서, 성분(A)는 트리클로로트리피리딘 크롬(Ⅲ), 트리클로로트리(4-에틸피리딘) 크롬(Ⅲ), 트리클로로트리(4-이소프로필피리딘) 크롬(Ⅲ), 크리클로로트리(4-페닐피리딘) 크롬(Ⅲ) 또는 트리클로로트리(테트라히드로푸란) 크롬(Ⅲ)이고, 성분(B)는 디이소부틸알루미늄 2,5-디메틸피롤리드이고, 성분(C)는 트리에틸알루미늄인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940004581A 1993-03-12 1994-03-09 말단 이중 결합을 갖는 올레핀의 제조 방법 KR100284063B1 (ko)

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JP27536993 1993-11-04
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US (1) US5731487A (ko)
EP (1) EP0614865B1 (ko)
KR (1) KR100284063B1 (ko)
CA (1) CA2118665A1 (ko)
DE (1) DE69406158T2 (ko)
TW (1) TW279167B (ko)

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TW279167B (ko) 1996-06-21
US5731487A (en) 1998-03-24
EP0614865A1 (en) 1994-09-14
EP0614865B1 (en) 1997-10-15
CA2118665A1 (en) 1994-09-13
DE69406158T2 (de) 1998-03-12
DE69406158D1 (de) 1997-11-20
KR100284063B1 (ko) 2001-03-02

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