KR870008819A - 올레핀의 삼량체화 방법 - Google Patents

올레핀의 삼량체화 방법 Download PDF

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KR870008819A
KR870008819A KR870002250A KR870002250A KR870008819A KR 870008819 A KR870008819 A KR 870008819A KR 870002250 A KR870002250 A KR 870002250A KR 870002250 A KR870002250 A KR 870002250A KR 870008819 A KR870008819 A KR 870008819A
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South Korea
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chromium
aluminum
hydrocarbyl
ligand
molar ratio
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KR870002250A
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로버트 브리크스 존
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티모시 엔. 비숍
유니온 카바이드 코포레이션
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Publication of KR870008819A publication Critical patent/KR870008819A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

올레핀의 삼량체화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. (ⅰ) 삼량체와 조건하에서 활성촉매류를 제공하는 크롬화합물, (ⅱ) 알루미늄 화합물 몰당 약 0.8 내지 약 1.1몰의 물로 가수분해된 하이드로카빌 알루미늄 및 (ⅲ) 하이드로카빌 이소니트릴, 아민 및 에테르로 구성된 그룹 중에서 선택된 공여체 리간드(donor ligand)의 반응생성물을 포함하는 촉매와 접촉되게 에틸렌, 프로필렌, 1-부텐 및 그의 혼합물로 구성된 그룹 중에서 선택된 올레핀을 통과시키며, 여기에서 알루미늄 대 코롬의 몰비는 약 200 이하 대 1의 범위이고 리간드 대 크롬의 몰비는 약 100 이하대 1의 범위임을 포함하는 상기 올레핀을 삼량체화 하는 방법.
  2. 제 1 항에 있어서, 각각의 리간드가 1 내지 20개의 탄소원자를 갖는 방법.
  3. 제 1 항에 있어서, 알루미늄 대크롬의 몰비가 약 1대 1 내지 약 100대 1의 범위인 방법.
  4. 제 1 항에 있어서, 리간드 대 크롬의 몰비가 약 1대 1 내지 약 100대 1의 범위인 방법.
  5. 제 1 항에 있어서, 리간드 대 크롬의 몰비가 약 1대 1 내지 약 40대 1의 범위인 방법.
  6. 제 1 항에 있어서, 올레핀이 에틸렌이며, 공여체 리간드가 CH3O(CH2CH2O)|nCH3이며, n이 1,2 또는 3인 방법.
  7. 제 1 항에 있어서, 올레핀이 에틸렌이고, 공여체 리간드가 3급-부틸이소니트릴인 방법.
  8. 제 1 항에 있어서, 공여체 리간드가 하이드로카빌 알루미늄 구조내로 혼합되는 방법.
  9. 제 1 항에 있어서, 1-헥센을 포함하는 용매 중에서 방법을 수행하는 방법.
  10. 제 1 항에 있어서, 올레핀이 에틸렌인 방법.
  11. (ⅰ) 삼량체화 조건하에서 활성촉매류를 제공하는 크롬화합물, (ⅱ) 알루미늄화합물 몰당 약 0.8 내지 약 1.1몰의 물로 가수분해된 하이드로카빌 알루미늄 및 (ⅲ) 하이드로카빌 이소니트릴, 아민 및 에테르로 구성된 그룹 중에서 선택된 공여체 리간드의 반응 생성물을 포함하며, 여기에서 알루미늄 대 크롬의 몰비가 약 200 이하 대 1의 범위이고, 리간드 대 크롬의 몰비가 약 100 이하 대 1의 범위인 촉매.
  12. 제11항에 있어서, (ⅰ) 상기 크롬 화합물 중의 크롬의 산화상태는 (Ⅱ),(Ⅲ) 및 (Ⅳ) 중에서 선택되고 ; (ⅱ) 하이드로카빌 알루미늄은 일반식 R3Al로 나타내며, 여기에서 R은 각각 알킬, 사이클로알킬 또는 하이라이드 라디칼이고, 적어도 하나의 R은 하이드로카빌 라디칼이며, 둘 또는 세개의 R 라디칼은 환상라디칼 내에 결합될 수 있고, 각각의 R은 서로 같거나 또는 다를 수 있으며, 하이드로카빌 라디칼인 R은 각각 1 내지 20개의 탄소원자를 가지며, (ⅲ) 상기 리간드의 하이드로카빌 부분은 1 내지 20개의 탄소원자를 가지며, 직쇄 또는 측쇄 알킬, 사이클로 알킬, 또는 방향족, 또는 그의 혼합물일 수 있는 촉매.
  13. 제12항에 있어서, 상기 크롬화합물의 비금속 부분이 알콕시, 에스테르 또는 케톤 라디칼이고, 상기 하이드로카빌 알루미늄이 알루미늄 트리알킬 또 트리아릴이며, 상기 리간드가 CH3O(CH2CH2O)nCH3(여기에서 n은 1,2 또는 3이다), 3급-부틸 이소니트릴, 테트라하이드로푸란 및 C6H4(OCH3)2로 구성된 그룹중에서 선택된 촉매.
  14. 제11항에 있어서, 상기 공여체 리간드가 하이드로카빌 알루미늄 구조내로 혼입된 촉매.
  15. (ⅰ) 삼량체화 조건하에서 활성 촉매류를 제공하는 크롬화합물, (ⅱ) 알루미늄 화합물 몰당 약 0.8 내지 약 1.1몰의 물로 가수분해된 하이드로카빌 알루미늄 및 (ⅲ) 하이드로카빌 이소니트릴, 아민 및 에테르로 구성된 그룹중에서 선택된 공여체 리간드를 약 200 이하 대 1 범위의 알루미늄 대 크롬몰비 및 약 100 이하 대 1 범위의 리간드 대 크롬의 몰비를 제공하기에 충분한 양으로 반응시킴을 포함하는 촉매의 제조방법.
  16. 제 1 항에 있어서, 삼량체화를 적어도 약 70℃의 온도에서 수행하는 방법.
  17. 제15항에 있어서, 상기 크롬화합물이 크롬(Ⅱ) 카복실레이트인 방법.
  18. 제17항에 있어서, 상기 크롬(Ⅱ)카복실레이트가 불활성유기 용매 중에서 염화크롬(Ⅱ), 카복실산 및 트리에틸아민의 반응에 의해 제조되는 방법.
  19. 제15항에 있어서, 공여체리간드가 하이드로카빌 알루미늄 구조내로 혼입되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870002250A 1986-03-14 1987-03-13 올레핀의 삼량체화 방법 KR870008819A (ko)

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Application Number Priority Date Filing Date Title
US839638 1986-03-14
US06/839,638 US4668838A (en) 1986-03-14 1986-03-14 Process for trimerization

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KR870008819A true KR870008819A (ko) 1987-10-21

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US (1) US4668838A (ko)
EP (1) EP0237079B1 (ko)
JP (1) JPS62265237A (ko)
KR (1) KR870008819A (ko)
CN (2) CN1045712A (ko)
AR (1) AR241012A1 (ko)
AT (1) ATE54439T1 (ko)
AU (1) AU594749B2 (ko)
BR (1) BR8701145A (ko)
CA (1) CA1273018A (ko)
DE (1) DE3763603D1 (ko)
ES (1) ES2017474B3 (ko)
FI (1) FI871125A (ko)
GR (1) GR3000913T3 (ko)
HU (1) HU201785B (ko)
IL (1) IL81821A (ko)
IN (1) IN168364B (ko)
MA (1) MA20901A1 (ko)
MY (1) MY101166A (ko)
NO (1) NO167454C (ko)
NZ (1) NZ219617A (ko)
PH (2) PH23205A (ko)
PT (1) PT84481B (ko)
TR (1) TR23720A (ko)
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AU6989387A (en) 1987-09-17
PH23205A (en) 1989-06-06
MY101166A (en) 1991-07-31
FI871125A (fi) 1987-09-15
EP0237079B1 (en) 1990-07-11
AR241012A1 (es) 1991-04-30
GR3000913T3 (en) 1991-12-10
NO871054L (no) 1987-09-15
NO167454B (no) 1991-07-29
NO871054D0 (no) 1987-03-13
JPH0466457B2 (ko) 1992-10-23
HU201785B (en) 1990-12-28
ATE54439T1 (de) 1990-07-15
CN1011693B (zh) 1991-02-20
PT84481A (en) 1987-04-01
BR8701145A (pt) 1988-01-05
IL81821A0 (en) 1987-10-20
HUT44049A (en) 1988-01-28
EP0237079A1 (en) 1987-09-16
US4668838A (en) 1987-05-26
MA20901A1 (fr) 1987-10-01
IL81821A (en) 1990-09-17
AU594749B2 (en) 1990-03-15
ES2017474B3 (es) 1991-02-16
IN168364B (ko) 1991-03-23
CA1273018A (en) 1990-08-21
PT84481B (pt) 1989-11-10
CN1045712A (zh) 1990-10-03
NZ219617A (en) 1989-04-26
PH24154A (en) 1990-03-22
TR23720A (tr) 1990-07-17
NO167454C (no) 1991-11-06
JPS62265237A (ja) 1987-11-18
ZA871859B (en) 1988-04-27
FI871125A0 (fi) 1987-03-13
DE3763603D1 (de) 1990-08-16
CN87101861A (zh) 1987-09-23
AR241012A2 (es) 1991-04-30

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