KR830006339A - 알파-올레핀의 중합용촉매제 및 그 제조방법 - Google Patents
알파-올레핀의 중합용촉매제 및 그 제조방법 Download PDFInfo
- Publication number
- KR830006339A KR830006339A KR1019810002203A KR810002203A KR830006339A KR 830006339 A KR830006339 A KR 830006339A KR 1019810002203 A KR1019810002203 A KR 1019810002203A KR 810002203 A KR810002203 A KR 810002203A KR 830006339 A KR830006339 A KR 830006339A
- Authority
- KR
- South Korea
- Prior art keywords
- alpha
- polymerization
- catalyst
- producing
- same
- Prior art date
Links
- 239000004711 α-olefin Substances 0.000 title claims 16
- 238000000034 method Methods 0.000 title claims 4
- 239000002685 polymerization catalyst Substances 0.000 title claims 3
- 238000004519 manufacturing process Methods 0.000 claims 11
- 238000006116 polymerization reaction Methods 0.000 claims 11
- 239000003054 catalyst Substances 0.000 claims 10
- 239000010936 titanium Substances 0.000 claims 9
- 229910052719 titanium Inorganic materials 0.000 claims 9
- -1 titanium halide Chemical class 0.000 claims 7
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 3
- 150000002681 magnesium compounds Chemical class 0.000 claims 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000000047 product Substances 0.000 claims 2
- 108091006149 Electron carriers Proteins 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- 본문에 상술한 바와 같이, (a) 유기알루미늄 함유 화합물과 (b) 할로겐화티타늄 함유 성분으로 이루어지며, 상기 할로겐화티타늄 함유성분은 (i) 할로겐함유 마그네슘화합물을 유기 포스파이트와 반응시킴에 의하여 반응생성물을 생성하고, (ii) 상기 반응생성물을 할로겐화 티타늄 화합물 및 여전자체 화합물의 복합체와 공분쇄함에 의하여 공분쇄된 생성물을 생성하고, (iii) 상기 공분쇄된 생성물을 할로겐화 티타늄 화합물과 반응시킴으로써 이루어지는 알파-올레핀의 중합용촉 매제 및 그 제조방법.
- 할로겐함유 마그네슘 화합물이 MgCl2인 특허청구의 범위 1기재의 알파-올레핀의 중합용촉매제 및 그 제조방법.
- 유기 포스파이트의 사용량은 마그네슘 화합물의 몰당 약 0.01~10몰의 포스파이트로 이루어지는 특허청구의 범위 1기재의 알파-올레핀의 중합용촉매제 및 그 제조방법.
- 유기 포스파이트는 구조식,(식중, R1, R2및 R3은 1~20개의 탄소원자를 가진 알킬, 아릴 및 아릴치환기가 6~18개의 탄소원자를 가지며 알킬치환기는 1~20개의 탄소원자로 되어 있는 알킬 치환 아릴이다)으로 표시되는 특허청구의 범위 1기재의 알파-올레핀의 중합용촉매제 및 그 제조방법.
- 유기포스파이트가 트리아릴 포스파이트인 특허청구의 범위 1기재의 알파-올레핀의 중합용 촉매제 및 그 제조방법.
- 복합체는 TiCl4. 에틸 벤조에이트 복합체인 특허청구의 범위 1기재의 알파-올레핀의 중합용촉매제 및 그 제조방법.
- 반응단계(iii)에서 사용되는 할로겐화티타늄 화합물의 3염화티타늄 물질인 특허청구의 범위 1기재의 알파-올레핀의 중합용촉매제 및 그 제조방법.
- 반응단계(iii)에서 사용되는 할로겐화티타늄 화합물이 4염화티타늄 물질인 특허청구의 범위 1기재의 알파-올레핀의 중합용촉매제 및 그 제조방법.
- 할로겐화티타늄 함유 성분내에 존재하는 티타늄의 양이, 티타늄 금속으로서, 약 0.1-10중량%의 양으로 이루어지는 특허청구의 범위 1기재의 알파-올레핀의 중합용촉매제 및 그 제조방법.
- 유기 알루미늄 함유성분은 유기 알루미늄화합물 및 카르복실산의 에스테르로 구성되는 그루우프에서 선택된 여전자체로 이루어지는 특허청구의 범위 1기재의 알파-올레핀의 중합용촉매제 및 그 제조방법.
- 유기 알루미늄 함유 성분은 트리에틸 알루미늄과 에틸 아니스에이트 또는 에틸 벤조 에이트로 이루어지는 특허청구의 범위 1기재의 알파-올레핀의 중합용촉매제 및 그 제조방법.
- 특허청구의 범위 1기재의 촉매제를 사용하는 알파-올레핀의 중합방법.
- 알파-올레핀은 구조식, R-CH=CH2(식중, R은 1~8개의 탄소원자를 가진 알킬기(基) 및 수소이다)으로 표시되는 특허청구의 범위 12기재의 알파-올레핀의 중합방법.
- 알파-올레핀이 프로필렌인 특허청구의 범위 기재의 알파-올레핀의 중합방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/170,262 US4325836A (en) | 1980-07-18 | 1980-07-18 | Novel titanium halide containing catalyst |
US170,262 | 1980-07-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830006339A true KR830006339A (ko) | 1983-09-24 |
KR840001831B1 KR840001831B1 (ko) | 1984-10-22 |
Family
ID=22619197
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019810002203A KR840001831B1 (ko) | 1980-07-18 | 1981-06-17 | 알파-올레핀의 중합용 할로겐화 티타늄 함유촉매제 |
Country Status (16)
Country | Link |
---|---|
US (1) | US4325836A (ko) |
EP (1) | EP0044445A3 (ko) |
JP (1) | JPS5755904A (ko) |
KR (1) | KR840001831B1 (ko) |
AU (1) | AU7133981A (ko) |
BR (1) | BR8104176A (ko) |
CA (1) | CA1159044A (ko) |
CS (1) | CS225839B2 (ko) |
DD (1) | DD202443A5 (ko) |
ES (1) | ES504073A0 (ko) |
NO (1) | NO812459L (ko) |
PT (1) | PT73326B (ko) |
RO (1) | RO82690B (ko) |
SU (1) | SU1217245A3 (ko) |
YU (1) | YU177981A (ko) |
ZA (1) | ZA813733B (ko) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4680350A (en) * | 1981-09-10 | 1987-07-14 | Stauffer Chemical Company | Purified catalyst support |
US4384984A (en) * | 1981-09-30 | 1983-05-24 | Stauffer Chemical Company | Titanium catalyst for polymerizing olefins |
US4451688A (en) * | 1981-12-03 | 1984-05-29 | Nippon Oil Company, Limited | Process for preparing polyolefins |
US4431571A (en) * | 1982-05-14 | 1984-02-14 | Standard Oil Company (Indiana) | Retreating comminuted olefin polymerization catalyst with a titanium(IV) compound, a haloalkylchlorosilane and an ester |
US4431572A (en) * | 1982-05-14 | 1984-02-14 | Standard Oil Company (Indiana) | Retreating comminuted olefin polymerization catalyst with a titanium (IV) compound, a chlorocarbon and an ester |
US4431570A (en) * | 1982-05-14 | 1984-02-14 | Standard Oil Company (Indiana) | Retreating comminuted olefin polymerization catalyst with a titanium (IV) compound and an ester |
US4981928A (en) * | 1983-08-04 | 1991-01-01 | Exxon Research And Engineering Company | Supported polyolefin catalyst for polymerization of ethylene under high temperatures |
IT1197320B (it) * | 1986-10-02 | 1988-11-30 | Ausimont Spa | Catalizzatori per la preparazione di copolimeri olefinici elastomerici,saturi ed insaturi,e vopolimeri con essi ottenuti |
US5248737A (en) * | 1987-05-08 | 1993-09-28 | Aristech Chemical Corporation | Method of making amine/propylene copolymers |
US5270410A (en) * | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
US5270276A (en) * | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
US4971936A (en) * | 1989-07-10 | 1990-11-20 | Shell Oil Company | Catalyst component for making primarily isotactic elastomeric polypropylene or polybutene |
US5118767A (en) * | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for producing mildly elastomeric primarily isotatic polypropylene and poly-1-butene |
US5089573A (en) * | 1990-02-26 | 1992-02-18 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
US5118649A (en) * | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for the production of elastomeric primarily isotactic polyolefins and catalysts for use in said process |
US5118768A (en) * | 1990-05-11 | 1992-06-02 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
US5164352A (en) * | 1990-05-11 | 1992-11-17 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3549717A (en) * | 1968-02-28 | 1970-12-22 | Gosei Chem Ind Co Ltd | Process for the production of 1,5,9-cyclododecatriene |
CA920299A (en) * | 1968-08-01 | 1973-01-30 | Mitsui Petrochemical Industries | Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier |
US3670043A (en) * | 1970-03-23 | 1972-06-13 | Donald H Kubicek | OLEFIN CONVERSION PROCESS USING COMPLEXES OF Ti, Zr AND Hf WITH ORGANOALUMINUM AS OLEFIN REACTION CATALYSTS |
NL160286C (ko) * | 1971-06-25 | |||
US4107414A (en) * | 1971-06-25 | 1978-08-15 | Montecatini Edison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
US4013823A (en) * | 1972-06-09 | 1977-03-22 | The B. F. Goodrich Company | Process for preparing elastomeric copolymers of ethylene and higher alpha-olefins |
US3953414A (en) * | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
JPS52104593A (en) * | 1976-03-01 | 1977-09-02 | Mitsui Petrochem Ind Ltd | Polymerization of olefins |
DE2744559A1 (de) * | 1976-10-07 | 1978-04-13 | Mitsubishi Petrochemical Co | Verfahren zur herstellung von katalysatorkomponenten fuer die olefinpolymerisation |
US4148756A (en) * | 1977-04-25 | 1979-04-10 | Exxon Research & Engineering Co. | Novel trialkyl aluminum cocatalyst |
US4130503A (en) * | 1977-12-23 | 1978-12-19 | Phillips Petroleum Company | Phosphite in MgX2 supported TiX3 /AlCl3 catalyst system |
US4243552A (en) * | 1978-12-11 | 1981-01-06 | Phillips Petroleum Company | Polymerization catalyst and process |
-
1980
- 1980-07-18 US US06/170,262 patent/US4325836A/en not_active Expired - Lifetime
-
1981
- 1981-06-02 CA CA000378829A patent/CA1159044A/en not_active Expired
- 1981-06-04 AU AU71339/81A patent/AU7133981A/en not_active Abandoned
- 1981-06-04 ZA ZA00813733A patent/ZA813733B/xx unknown
- 1981-06-08 CS CS814265A patent/CS225839B2/cs unknown
- 1981-06-17 KR KR1019810002203A patent/KR840001831B1/ko active IP Right Grant
- 1981-06-24 JP JP56098160A patent/JPS5755904A/ja active Pending
- 1981-06-29 EP EP81105040A patent/EP0044445A3/en not_active Ceased
- 1981-06-30 BR BR8104176A patent/BR8104176A/pt unknown
- 1981-07-07 PT PT73326A patent/PT73326B/pt unknown
- 1981-07-15 DD DD81231804A patent/DD202443A5/de unknown
- 1981-07-17 YU YU01779/81A patent/YU177981A/xx unknown
- 1981-07-17 NO NO812459A patent/NO812459L/no unknown
- 1981-07-17 ES ES504073A patent/ES504073A0/es active Granted
- 1981-07-17 RO RO104910A patent/RO82690B/ro unknown
- 1981-07-17 SU SU813310348A patent/SU1217245A3/ru active
Also Published As
Publication number | Publication date |
---|---|
EP0044445A3 (en) | 1982-02-03 |
DD202443A5 (de) | 1983-09-14 |
KR840001831B1 (ko) | 1984-10-22 |
CS225839B2 (en) | 1984-02-13 |
ES8205134A1 (es) | 1982-06-01 |
SU1217245A3 (ru) | 1986-03-07 |
JPS5755904A (en) | 1982-04-03 |
AU7133981A (en) | 1982-01-21 |
RO82690A (ro) | 1984-01-14 |
US4325836A (en) | 1982-04-20 |
PT73326A (en) | 1981-08-01 |
EP0044445A2 (en) | 1982-01-27 |
NO812459L (no) | 1982-01-19 |
YU177981A (en) | 1984-02-29 |
ZA813733B (en) | 1982-06-30 |
CA1159044A (en) | 1983-12-20 |
RO82690B (ro) | 1984-01-30 |
ES504073A0 (es) | 1982-06-01 |
PT73326B (en) | 1982-07-30 |
BR8104176A (pt) | 1982-03-16 |
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