KR920703200A - 아미노카르복실산염의 제조방법 - Google Patents

아미노카르복실산염의 제조방법

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Publication number
KR920703200A
KR920703200A KR1019920701772A KR920701772A KR920703200A KR 920703200 A KR920703200 A KR 920703200A KR 1019920701772 A KR1019920701772 A KR 1019920701772A KR 920701772 A KR920701772 A KR 920701772A KR 920703200 A KR920703200 A KR 920703200A
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South Korea
Prior art keywords
reaction
carried out
copper
containing catalyst
nickel
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KR1019920701772A
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English (en)
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KR970009569B1 (ko
Inventor
요시아끼 우라노
유끼오 가도노
다까끼요 고또
Original Assignee
다나까 쇼오소
닛뽕쇼꾸바이가가꾸고오교 가부시끼가이샤
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Application filed by 다나까 쇼오소, 닛뽕쇼꾸바이가가꾸고오교 가부시끼가이샤 filed Critical 다나까 쇼오소
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
    • C07C229/08—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
    • C07C229/10—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C07C229/12—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of acyclic carbon skeletons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
    • C07C229/10—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C07C229/16—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of hydrocarbon radicals substituted by amino or carboxyl groups, e.g. ethylenediamine-tetra-acetic acid, iminodiacetic acids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

아미노카르복실산염의 제조방법
[도면의 간단한 설명]
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 알칼리금속 수산화물 및/ 또는 알칼리토금속 수산화물, 구리 함유 촉매 및 물의 공존하에서 아미노알콜을 산화적 탈수소 반응시켜 하기 일반식(1)로 표시되는 아미노 알콜로부터 아미노카르복실산염을 제조하는 방법에 있어서, 반응 혼합물중의 니켈의 농도를 40ppm미만으로 유지하면서 반응을 수행하는 것을 특징으로 하는 방법.
    [식중 R1및 R2는 각기 수소원자, 히드록시에틸기, 탄소수 1∼18의 알킬기 또는 탄소수 2∼3의 아미노알킬기이다.]
  2. 제1항에 있어서, 반응을 0.3중량%미만의 농도로 니켈을 함유하는 구리-함유 촉매를 사용하여 수행하는 방법.
  3. 제1항에 있어서, 반응을 상기 일반식(1)로 표시되는 아미노알콜에 대하여 5∼50중량%의 양으로 구리-함유 촉매를 사용하여 수행하는 방법.
  4. 제1항에 있어서, 반응을 반응 혼합물의 1m3당 0.1∼1.5kw범위인 교반력을 사용하여 수행하는 방법.
  5. 제1항에 있어서, 내부벽 재료가 니켈을 함유하지 않는 반응기를 사용하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920701772A 1990-11-27 1991-11-26 아미노카르복실산염의 제조방법 KR970009569B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP90-326251 1990-11-27
JP32625190 1990-11-27
JP90-408770 1990-12-28
JP40877090 1990-12-28
JP11328991 1991-05-17
JP91-113289 1991-05-17
PCT/JP1991/001616 WO1992009559A1 (en) 1990-11-27 1991-11-26 Process for producing amino carboxylic acid salt

Publications (2)

Publication Number Publication Date
KR920703200A true KR920703200A (ko) 1992-12-17
KR970009569B1 KR970009569B1 (ko) 1997-06-14

Family

ID=27312472

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920701772A KR970009569B1 (ko) 1990-11-27 1991-11-26 아미노카르복실산염의 제조방법

Country Status (10)

Country Link
US (1) US5220054A (ko)
EP (1) EP0513396B1 (ko)
JP (1) JP2939335B2 (ko)
KR (1) KR970009569B1 (ko)
AU (1) AU634918B2 (ko)
CA (1) CA2074486C (ko)
DE (1) DE69120660T2 (ko)
DK (1) DK0513396T3 (ko)
ES (1) ES2089493T3 (ko)
WO (1) WO1992009559A1 (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2022044A6 (es) * 1990-09-25 1991-11-16 Ercros Sa Procedimiento para la obtencion de derivados del acido acetico.
CA2159828C (en) * 1993-04-12 2004-08-31 Yukio Kadono Process to prepare amino-carboxylic acid salts
DE69407082T2 (de) * 1993-04-12 1998-07-02 Monsanto Co Verfahren zur Herstellung von Carbonsäuren
US5689000A (en) * 1994-07-01 1997-11-18 Monsanto Company Process for preparing carboxylic acid salts and catalysts useful in such process
BR9711410A (pt) * 1996-09-26 1999-08-17 Akzo Nobel Nv Catalisador para a desidrogena-Æo de lcoois aminados a cidos aminocarboxilicos ou de (derivados) de etileno glicol a cidos oxicarboxilicos processo para sua prepara-Æo e utilizacao do catalisador
ITTO980249A1 (it) * 1998-03-23 1999-09-23 Finchimica Srl Procedimento per la preparazione di sali di acidi carbossilici
AR043078A1 (es) 1998-09-14 2005-07-20 Dow Agrosciences Llc Procesos para preparar acidos carboxilicos
EP1173406B1 (en) 1999-05-03 2006-10-18 Monsanto Technology LLC Process for the preparation of carboxylic acid salts from primary alcohols
ATE249419T1 (de) * 1999-07-05 2003-09-15 Atanor S A Verfahren zur herstellung von amino-, imino-, und nitrilocarbonsäuren und für das verfahren mit silber aktivierter kupferkatalysator
US6376708B1 (en) * 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
CN100376326C (zh) * 2006-03-30 2008-03-26 上海工程技术大学 负载型纳米铜镍催化剂制备方法及用于醇胺氧化脱氢反应
DE102006016227A1 (de) * 2006-04-06 2007-10-11 Degussa Gmbh Verfahren zur Herstellung von Kreatin, Kreatin-Monohydrat oder Guanidinoessigsäure
JP2012184213A (ja) * 2010-04-06 2012-09-27 Sumitomo Chemical Co Ltd 含硫アミノ酸の製造方法
RU2452565C1 (ru) * 2011-02-16 2012-06-10 Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН Катализатор, способ его приготовления и способ получения динатриевой соли иминодиуксусной кислоты
JP6553988B2 (ja) * 2015-08-28 2019-07-31 株式会社日本触媒 アミノカルボン酸塩の製造方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3833650A (en) * 1971-08-19 1974-09-03 Jefferson Chem Co Inc Preparation of nitrilotriacetic acid
US3842081A (en) * 1971-08-19 1974-10-15 Jefferson Chem Co Inc Preparation of aminocarboxylic acids from aminoalcohols
JPS6041645A (ja) * 1983-08-17 1985-03-05 Nippon Shokubai Kagaku Kogyo Co Ltd グリシン塩の製造方法
JPS6041644A (ja) * 1983-08-17 1985-03-05 Nippon Shokubai Kagaku Kogyo Co Ltd グリシン塩の製造方法
JPS6097945A (ja) * 1983-11-01 1985-05-31 Nippon Shokubai Kagaku Kogyo Co Ltd ニトリロトリ酢酸塩の製造方法
JPS60100545A (ja) * 1983-11-08 1985-06-04 Nippon Shokubai Kagaku Kogyo Co Ltd ニトリロトリ酢酸塩の製造方法
GB2148287B (en) * 1983-10-05 1987-04-15 Nippon Catalytic Chem Ind Preparation of aminocarboxylic acid salts from amino alcohols
JPS6078948A (ja) * 1983-10-05 1985-05-04 Nippon Shokubai Kagaku Kogyo Co Ltd イミノジ酢酸塩の製造方法
ES2022044A6 (es) * 1990-09-25 1991-11-16 Ercros Sa Procedimiento para la obtencion de derivados del acido acetico.
ES2031412A6 (es) * 1990-10-04 1992-12-01 Ercros Sa Perfeccionamientos introducidos en un procedimiento de obtencion de derivados de acido acetico.

Also Published As

Publication number Publication date
JP2939335B2 (ja) 1999-08-25
DK0513396T3 (da) 1996-07-29
WO1992009559A1 (en) 1992-06-11
EP0513396A1 (en) 1992-11-19
CA2074486C (en) 2002-04-02
AU634918B2 (en) 1993-03-04
CA2074486A1 (en) 1992-05-28
DE69120660T2 (de) 1996-10-31
DE69120660D1 (de) 1996-08-08
AU8913091A (en) 1992-06-25
EP0513396A4 (ko) 1994-02-23
EP0513396B1 (en) 1996-07-03
KR970009569B1 (ko) 1997-06-14
US5220054A (en) 1993-06-15
ES2089493T3 (es) 1996-10-01

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