KR900004661A - 3-아릴이소부틸알코올의 제조방법 - Google Patents

3-아릴이소부틸알코올의 제조방법 Download PDF

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Publication number
KR900004661A
KR900004661A KR1019890012715A KR890012715A KR900004661A KR 900004661 A KR900004661 A KR 900004661A KR 1019890012715 A KR1019890012715 A KR 1019890012715A KR 890012715 A KR890012715 A KR 890012715A KR 900004661 A KR900004661 A KR 900004661A
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KR
South Korea
Prior art keywords
arylcarbinol
propanol
formula
reacted
reaction
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KR1019890012715A
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English (en)
Inventor
보트 카스파르
호프만 헤르비크
샤이드마이어 발터
Original Assignee
하우프터, 라이싱어
바스프 악티엔게젤샤프트
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Application filed by 하우프터, 라이싱어, 바스프 악티엔게젤샤프트 filed Critical 하우프터, 라이싱어
Publication of KR900004661A publication Critical patent/KR900004661A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/18—Monohydroxylic alcohols containing only six-membered aromatic rings as cyclic part
    • C07C33/20—Monohydroxylic alcohols containing only six-membered aromatic rings as cyclic part monocyclic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

3-아릴이소부틸알코올의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 밀폐된 반응용기내에서 250 내지 350℃로 수산화알칼리금속 또는 알칼리금속 알코올레이트의 촉매적양의 존재하에 다음식(Ⅱ)의 아릴카르비놀과 n-프로판올을 반응시킴을 특징으로 하는 다음식(I)의 3-아릴이소부틸알코올의 제조방법:
    상기식에서, R1및 R2는 각각 수소 또는 C8이하의 알킬 또는 시클로알킬기이다.
    상기식에서, R1및 R2는 상기에 정의한 바와같다.
  2. 제1항에 있어서, 식(Ⅱ)의 아릴카르비놀은 반응혼합물에 대해 0.5 내지 2중량%의 NaOH 또는 NOH의 존재하에 n-프로판올과 반응함을 특징으로 하는 방법.
  3. 제1항에 있어서, 식(Ⅱ)의 아릴카르비놀은 약 1:1의 몰비로 n-프로판올과 반응함을 특징으로 하는 방법.
  4. 제1항에 있어서, 식(Ⅱ)의 아릴카르비놀이 n-프로판올과 반응함을 특징으로 하는 방법.
    상기식에서, R1이 메틸, 이소프로필 또는 3차-부틸이고, R2는 수소이다.
  5. 제1항에 있어서, 식(Ⅱ)의 아릴카르비놀이 탈수소 촉매의 부재하에 n-프로판올과 반응함을 특징으로 하는 방법.
  6. 제1항에 있어서, 반응동안에 형성된 반응수가 식(Ⅱ)의 아릴카르비놀과 n-프로판올과 반응중에 증류제거되지 않음을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890012715A 1988-09-03 1989-09-02 3-아릴이소부틸알코올의 제조방법 KR900004661A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3830019A DE3830019A1 (de) 1988-09-03 1988-09-03 Verfahren zur herstellung von 3-aryl-isobutylalkoholen
DEP3830019.2 1988-09-03

Publications (1)

Publication Number Publication Date
KR900004661A true KR900004661A (ko) 1990-04-12

Family

ID=6362253

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890012715A KR900004661A (ko) 1988-09-03 1989-09-02 3-아릴이소부틸알코올의 제조방법

Country Status (7)

Country Link
US (1) US4987270A (ko)
EP (1) EP0358088B1 (ko)
JP (1) JPH02115137A (ko)
KR (1) KR900004661A (ko)
DE (2) DE3830019A1 (ko)
ES (1) ES2055768T3 (ko)
HU (1) HU203713B (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4447361A1 (de) * 1994-12-21 1996-06-27 Schuelke & Mayr Gmbh Biozide Alkohole, ihre Herstellung und ihre Verwendung
JP5854345B2 (ja) * 2010-03-05 2016-02-09 国立大学法人名古屋大学 二量体の製造方法
BR102019024934B1 (pt) 2019-11-26 2022-02-22 Petróleo Brasileiro S.A. - Petrobras Processo para obtenção de compostos, dentre os quais o triptano por reação de acoplamento de álcoois

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2457866A (en) * 1945-05-26 1949-01-04 Carbide & Carbon Chem Corp Condensation of alcohols
US2645667A (en) * 1951-10-01 1953-07-14 Phillips Petroleum Co Condensation of alcohols in the presence of calcium hydroxide
US3119880A (en) * 1961-05-29 1964-01-28 Gulf Research Development Co Condensation of alcohols
US3328470A (en) * 1963-10-03 1967-06-27 Continental Oil Co Greater selectivity in the guerbet reaction
NL6706692A (ko) * 1966-05-18 1967-11-20
NL6709801A (ko) * 1966-07-21 1968-01-22
DE2124589C3 (de) * 1971-05-18 1975-06-05 Basf Ag, 6700 Ludwigshafen Anthrapyrimidin-Farbstoffe und Verfahren zu ihrer Herstellung
US3860664A (en) * 1973-06-06 1975-01-14 Continental Oil Co Process for condensation of alcohols
DE3520185A1 (de) * 1985-06-05 1986-12-11 Henkel KGaA, 4000 Düsseldorf 2-benzylalkanol-1-polyglykolether sowie verfahren zu ihrer herstellung
DE3546016A1 (de) * 1985-12-24 1987-06-25 Basf Ag Verfahren zur herstellung von in 1-stellung durch aromatische oder heterocyclische reste substituierten alkanolen
DE3712873A1 (de) * 1987-04-15 1988-11-03 Consortium Elektrochem Ind 2-methyl- oder 2-methoxyphenylgruppen enthaltende alkohole und deren verwendung als duftstoffe

Also Published As

Publication number Publication date
HU203713B (en) 1991-09-30
EP0358088B1 (de) 1993-06-23
HUT51588A (en) 1990-05-28
ES2055768T3 (es) 1994-09-01
JPH02115137A (ja) 1990-04-27
DE58904784D1 (de) 1993-07-29
US4987270A (en) 1991-01-22
EP0358088A3 (en) 1990-05-23
EP0358088A2 (de) 1990-03-14
DE3830019A1 (de) 1990-03-15

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