KR927003515A - 아미노카르복실산 염의 제조방법 - Google Patents

아미노카르복실산 염의 제조방법 Download PDF

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Publication number
KR927003515A
KR927003515A KR1019920701507A KR920701507A KR927003515A KR 927003515 A KR927003515 A KR 927003515A KR 1019920701507 A KR1019920701507 A KR 1019920701507A KR 920701507 A KR920701507 A KR 920701507A KR 927003515 A KR927003515 A KR 927003515A
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KR
South Korea
Prior art keywords
reaction
acid salt
aminocarboxylic acid
copper
carbon atoms
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KR1019920701507A
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English (en)
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KR950006892B1 (ko
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요시아끼 우라노
유끼오 가도노
다까끼요 고또
Original Assignee
다나까 쇼오소
가부시끼가이샤 닛뽕 쇼꾸바이
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Publication of KR927003515A publication Critical patent/KR927003515A/ko
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Publication of KR950006892B1 publication Critical patent/KR950006892B1/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

아미노카르복실산 염의 제조방법
[도면의 간단한 설명]
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 알칼리 금속 하이드록사이드 및/또는 알킬리 토금속 하이드록사이드, 구리-함유 촉매 및 물의 존재하에 하기 일반식(1)로 나타내는 아미노 알코올을 산화적 탈수소화 반응시켜 아미노카르복실산염을 제조하는 방법에 있어서, 상기 반응계에 알루미늄 금속 및/또는 알루미늄 화합물을 첨가하여 반응을 수행함을 특징으로 하는 방법.
    (상기식에서, R1및 R2는 각각 독립적으로 수소원자, 히드록시에틸기, 탄소 1∼18의 알킬기, 또는 탄소수 2∼3의 아미노알킬기를 나타낸다).
  2. 제1항에 있어서, 아미노 알코올 중량을 기준으로 알루미늄 원자로 0.001중량%이상의 알루미늄 금속 및/또는 알루미늄 화합물을 반응계에 첨가함을 특징으로 하는 방법.
  3. 제1항 또는 2항에 있어서, 반응에 사용한후 구리-함유 촉매를 회수하여 다음 반응에 재사용함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920701507A 1990-10-23 1991-10-21 아미노카르복실산 염의 제조방법 KR950006892B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP90-286670 1990-10-23
JP28667090 1990-10-23
PCT/JP1991/001440 WO1992006949A1 (fr) 1990-10-23 1991-10-21 Procede de production de sels d'acide aminocarboxylique

Publications (2)

Publication Number Publication Date
KR927003515A true KR927003515A (ko) 1992-12-18
KR950006892B1 KR950006892B1 (ko) 1995-06-26

Family

ID=17707441

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920701507A KR950006892B1 (ko) 1990-10-23 1991-10-21 아미노카르복실산 염의 제조방법

Country Status (11)

Country Link
US (1) US5220055A (ko)
EP (1) EP0506973B1 (ko)
JP (1) JP2916256B2 (ko)
KR (1) KR950006892B1 (ko)
AU (1) AU636803B2 (ko)
CA (1) CA2071999C (ko)
DE (1) DE69115883T2 (ko)
DK (1) DK0506973T3 (ko)
ES (1) ES2081497T3 (ko)
MX (1) MX9101721A (ko)
WO (1) WO1992006949A1 (ko)

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US5602279A (en) * 1986-04-15 1997-02-11 Exxon Research And Engineering Company Primary hindered aminoacids for promoted acid gas scrubbing process
US5739390A (en) * 1993-04-12 1998-04-14 Monsanto Company Process to prepare amino carboxylic acid salts
US5292936A (en) * 1993-04-12 1994-03-08 Monsanto Company Process to prepare amino carboxylic acid salts
US5606512A (en) * 1994-07-27 1997-02-25 The Dow Chemical Company Determining the biodegradability of iminodiacetic acid derivatives
DE69515671T3 (de) * 1994-07-27 2004-06-17 The Dow Chemical Co., Midland Bestimmung der biodegradabilität von asparaginsäurederivaten, abbaubare chelatbildner, verwendungen und zusammensetzungen davon
TR199900699T2 (xx) * 1996-09-26 1999-07-21 Akzo Nobel N.V. Amino alkolleri aminokarboksilik asitlere veya etilen glikol� (t�revlerini) oksikarboksilik asitlere dehidrojene etmek i�in kataliz�r, bunu haz�rlamak i�in y�ntem ve bunun uygulamalar�.
ITTO980249A1 (it) 1998-03-23 1999-09-23 Finchimica Srl Procedimento per la preparazione di sali di acidi carbossilici
AR043078A1 (es) 1998-09-14 2005-07-20 Dow Agrosciences Llc Procesos para preparar acidos carboxilicos
IL143139A0 (en) 1998-12-01 2002-04-21 Syngenta Participations Ag Process for the preparation of aminocarboxylic acids
CA2370621A1 (en) 1999-05-03 2000-11-09 Monsanto Technology Llc Process for the preparation of carboxylic acid salts from primary alcohols
US20020038051A1 (en) 2000-02-18 2002-03-28 Degussa-Huls Ag Raney copper
EP1382388A1 (de) 2000-02-18 2004-01-21 Degussa AG Festbettraney-Kupferkatalysator zur Dehydrierung von Alkoholen
US6376708B1 (en) 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
CA2463776A1 (en) 2001-10-18 2003-04-24 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
MXPA05004061A (es) * 2002-10-18 2005-06-08 Monsanto Technology Llc Uso de catalizadores de cobre con soporte metalico para la reformacion de alcoholes.
ES2426165T3 (es) 2010-03-18 2013-10-21 Basf Se Procedimiento para la obtención de aminocarboxilatos pobres en productos secundarios
US8785685B2 (en) 2011-04-12 2014-07-22 Basf Se Process for preparing aminopolycarboxylates proceeding from amino acids
CN103459367B (zh) * 2011-04-12 2015-05-27 巴斯夫欧洲公司 由氨基酸制备氨基多羧酸盐的方法
KR20140024006A (ko) 2011-05-23 2014-02-27 바스프 에스이 아미노폴리카르복실레이트의 제조 방법
US8609894B2 (en) 2011-05-23 2013-12-17 Basf Se Process for preparing aminopolycarboxylates

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US3842081A (en) * 1971-08-19 1974-10-15 Jefferson Chem Co Inc Preparation of aminocarboxylic acids from aminoalcohols
US3833650A (en) * 1971-08-19 1974-09-03 Jefferson Chem Co Inc Preparation of nitrilotriacetic acid
JPS6041645A (ja) * 1983-08-17 1985-03-05 Nippon Shokubai Kagaku Kogyo Co Ltd グリシン塩の製造方法
JPS6078948A (ja) * 1983-10-05 1985-05-04 Nippon Shokubai Kagaku Kogyo Co Ltd イミノジ酢酸塩の製造方法
JPS6097945A (ja) * 1983-11-01 1985-05-31 Nippon Shokubai Kagaku Kogyo Co Ltd ニトリロトリ酢酸塩の製造方法
GB2148287B (en) * 1983-10-05 1987-04-15 Nippon Catalytic Chem Ind Preparation of aminocarboxylic acid salts from amino alcohols
JPS60100545A (ja) * 1983-11-08 1985-06-04 Nippon Shokubai Kagaku Kogyo Co Ltd ニトリロトリ酢酸塩の製造方法
JPS6165840A (ja) * 1984-09-07 1986-04-04 Nippon Shokubai Kagaku Kogyo Co Ltd ジグリコ−ル酸塩の製造方法
ES2022044A6 (es) * 1990-09-25 1991-11-16 Ercros Sa Procedimiento para la obtencion de derivados del acido acetico.
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JPH06165840A (ja) * 1992-10-29 1994-06-14 Matsushita Electric Ind Co Ltd クロロフロロカーボンの回収方法及びその再生方法

Also Published As

Publication number Publication date
AU8711791A (en) 1992-05-20
EP0506973B1 (en) 1995-12-27
DE69115883T2 (de) 1996-06-05
WO1992006949A1 (fr) 1992-04-30
DE69115883D1 (de) 1996-02-08
KR950006892B1 (ko) 1995-06-26
AU636803B2 (en) 1993-05-06
EP0506973A1 (en) 1992-10-07
MX9101721A (es) 1992-06-05
CA2071999A1 (en) 1992-04-24
EP0506973A4 (ko) 1994-02-23
ES2081497T3 (es) 1996-03-16
CA2071999C (en) 1995-11-21
JP2916256B2 (ja) 1999-07-05
DK0506973T3 (da) 1996-01-29
US5220055A (en) 1993-06-15

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