KR920701103A - 개선된 비닐에테르 제조방법 - Google Patents

개선된 비닐에테르 제조방법

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KR920701103A
KR920701103A KR1019910700729A KR910700729A KR920701103A KR 920701103 A KR920701103 A KR 920701103A KR 1019910700729 A KR1019910700729 A KR 1019910700729A KR 910700729 A KR910700729 A KR 910700729A KR 920701103 A KR920701103 A KR 920701103A
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titanium
metal
reducing agent
aryl
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KR950001678B1 (ko
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아더 폴 스캅
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원본미기재
보오드 오브 거버너즈 오브 와이언 스테이트 유니버시티
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Abstract

내용 없음

Description

개선된 비닐에테르 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 유기용매속에서 다음 구조식(Ⅱ)으로 표현되는 카르보닐 함유 화합물을 역시 다음 구조식(Ⅲ)의 에스테르 화합물과 반응시켜서 아연금속, 티타늄염과 아민염기 존재하에 다음 구조식(Ⅰ)의 화합물을 제조하는 방법.
    여기서 A와 R은 수동적 유기그룹이고 ArOY는 히드록시기와 또한 P가 보호기일때 OP중에서 선택된 치환물인 OY로 치환된 아릴고리를 갖춘 아릴기이다.
  2. 제1항에 있어서, 금속형 환원제는 아연인 것을 특징으로 하는 방법.
  3. 제2항에 있어서, 티타늄은 3염화티타늄과 4염화티타늄 중에서 선택하는 것으로된 방법.
  4. 제3항에 있어서, 아민염기는 트리에릴아민이고 유기용매는 테트라히드로퓨란인 것으로된 방법.
  5. 제1항에 있어서, OY를 트리알킬실리옥시, 디알킬아릴 실리옥시, 디아릴알킬실리옥시와 트리아릴실리옥시 중에서 선택하여된 방법.
  6. 제1항에 있어서, OY가 히드록실기인 것으로된 방법.
  7. 유기용매속에서 다음구조식(Ⅴ)으로 표현되는 카르보닐 함유 화합물을 역시 다음 구조식(Ⅵ)의 에스테르 화합물과 반응시켜서 금속형 환원제, 티타늄금속염 또한 아민염기 존재하에 다음 구조식(Ⅳ)의 비닐에테르를 제조하는 방법에 대한 것이다.
    여기에 R1은 1내지 20 탄소원자를 함유한 알킬, 아릴 또한 아랄킬이고 때로는 산소, 황, 질소, 인 및 할로겐을 함유하며, R2는 아릴, 비아릴 및 치환 혹은 비치환된 융해고리 다중고리형 아릴기중에서 선택된 것이고 또한 R1과 R2는 탄소, 산소 및 질소함유기중에서 선택된 성분으로 함께 결합될 수 있고, R3C-는 6내지 30탄소원자를 함유한 다중고리형 알킬기중에서 선택하고, OY는 히드록시기와 또한 P가 보호기일때의 OP기중에서 선택된 치환물이다.
  8. 제7항에 있어서, 금속형 환원제는 아연인 것을 특징으로 하는 방법.
  9. 제8항에 있어서, 티타늄염은 3염화티타늄과 4염화티타늄중에서 선택하는 것으로된 방법.
  10. 제9항에 있어서, 아민염기는 트리에틸아민과 유기용매는 테트라히드로퓨란인 것으로된 방법.
  11. 제7항에 있어서, OY를 트리알킬실리옥시, 디알킬 아릴실리옥시, 디아릴알킬실리옥시와 트리아릴실리옥시중에서 선택하여된 방법.
  12. 제7항에 있어서, OY는 히드록실기인 것으로된 방법.
  13. 제7항에 있어서, 비닐에테르속의 Y가 OX기를 제공하는 또다른기로 대체되는 것을 특징으로 하는 방법.
  14. 제7항에 있어서, OX기를 무기 산소산염, 인산염, 산소-피라노시드, 아릴 및 알킬 카르복실 에스테르중에서 선택하여된 방법.
  15. 제1항에 있어서, 카르보닐 함유 화합물과 에스테르 화합물의 반응에 앞서서 금속형 환원제와 티타늄염 혼합물에 아민을 서서히 첨가하는 것으로된 방법.
  16. 제15항에 있어서, 티타늄염이 염화물인 것으로된 방법.
  17. 제16항에 있어서, 금속형 환원제는 미세하게 분쇄한 것인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910700729A 1989-12-14 1990-12-12 개선된 비닐에테르 제조방법 KR950001678B1 (ko)

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US450459 1989-12-14
US450,459 1989-12-14
US07/450,459 US4983779A (en) 1986-07-17 1989-12-14 Process for the preparation of vinyl ethers
PCT/US1990/007372 WO1991009002A1 (en) 1989-12-14 1990-12-12 Process for the preparation of vinyl ethers

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JPH0731201B2 (ja) 1987-12-31 1995-04-10 トロピックス・インコーポレーテッド 化学発光による測定法
US5582980A (en) * 1989-07-17 1996-12-10 Tropix, Inc. Chemiluminescent 1,2-dioxetanes
US6022964A (en) 1989-07-17 2000-02-08 Tropix, Inc. Chemiluminescent 1,2-dioxetanes
US5326882A (en) * 1989-07-17 1994-07-05 Tropix, Inc. Chemiluminescent 3-(substituted Adamant-2'-Ylidene) 1,2-dioxetanes
ATE174914T1 (de) * 1990-08-30 1999-01-15 Tropix Inc Chemolumineszente 3-(substituierte adamant-2'- ylidene)1,2-dioxetane
DE4210759A1 (de) * 1992-04-01 1993-10-07 Boehringer Mannheim Gmbh Substituierte Thiazolin-Dioxetan-Substrate, Verfahren zur Herstellung und Verwendung
AU1518195A (en) * 1993-12-23 1995-07-10 Tropix, Inc. Chemiluminescent energy transfer assays
US5773628A (en) * 1994-11-14 1998-06-30 Tropix, Inc. 1,2-dioxetane compounds with haloalkoxy groups, methods preparation and use
US5721370A (en) * 1995-07-31 1998-02-24 Lumigen Inc. Water soluble tri-substituted 1,2-dioxetane compounds and assay compositions having increased storage stability
CN101496917B (zh) 2003-05-21 2013-07-31 株式会社Jms 细胞培养的血清调制装置和血清调制方法及细胞培养方法
CN100525906C (zh) * 2007-02-09 2009-08-12 上海华谊丙烯酸有限公司 缩醛气相分解催化剂及其制备方法
CN102030779A (zh) * 2010-11-17 2011-04-27 云南瑞亘生物科技有限公司 一种免疫分析用化学发光物amppd的制备方法
CA3011328A1 (en) * 2016-01-26 2017-08-03 Ramot At Tel-Aviv University Ltd. Chemiluminescent probes for diagnostics and in vivo imaging
US11857674B2 (en) 2016-05-18 2024-01-02 Reoxcyn, Llc Lubricant formulations
US9474768B1 (en) * 2016-05-18 2016-10-25 Reoxcyn Discoveries Group, Inc. Lubricant formulations

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US4983779A (en) 1991-01-08
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CA2045553C (en) 1999-04-13
DE69022582T2 (de) 1996-03-07
CN1020893C (zh) 1993-05-26
JPH03504815A (ja) 1991-10-24
JPH0825941B2 (ja) 1996-03-13
WO1991009002A1 (en) 1991-06-27
CA2045553A1 (en) 1991-06-15
EP0458965A1 (en) 1991-12-04
DK0458965T3 (da) 1996-01-15
JPH04505458A (ja) 1992-09-24
AU637194B2 (en) 1993-05-20
ATE128110T1 (de) 1995-10-15
DE69022582D1 (de) 1995-10-26
CN1052478A (zh) 1991-06-26
AU7183391A (en) 1991-07-18
GR3018174T3 (en) 1996-02-29
KR950001678B1 (ko) 1995-02-28

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