KR900003388A - 전이금속 회수방법 - Google Patents

전이금속 회수방법 Download PDF

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KR900003388A
KR900003388A KR1019890012041A KR890012041A KR900003388A KR 900003388 A KR900003388 A KR 900003388A KR 1019890012041 A KR1019890012041 A KR 1019890012041A KR 890012041 A KR890012041 A KR 890012041A KR 900003388 A KR900003388 A KR 900003388A
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조오지 아바치오글로우 안토니
로버트 브라이언트 데이비드
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티모시 엔. 비숍
유니온 카바이드 케미칼즈 앤드 플라스틱 캄파니 인코포레이티드
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Abstract

내용 없음

Description

전이금속 회수방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 전이금속(예, 로듐) 회수방법의 플로우 시트(flow sheet)를 도시한 것이다.

Claims (29)

  1. 전이금속-함유 액체를 유기인 리간드가 이온 결합된 이온-교환 수지에 접촉시킴을 특징으로 하여, 상기 액체로부터 VIII족 전이금속을 회수하는 방법.
  2. 전이금속-함유 액체를 이온성 유기인 리간드-교환된 이온-교환 수지에 접촉시킴을 특징으로 하여, 상기 액체로부터 VIII족 전이금속을 회수하는 방법.
  3. 제1항에 있어서, 전이금속이 로듐인 방법.
  4. 제3항에 있어서, 액체가 2ppm 이하의 로듐이 함유된 하이드로포밀화 공정의 알데히드 생성물을 함유하는 방법.
  5. 제1항에 있어서, 이온- 교환 수지가 유기인 리간드가 이온 결함된 음이온-교환 수지인 방법.
  6. 제5항에 있어서, 음이온-교환 수지가 거대망상(macroreticular)의 강염기 음이온-교환 수지인 방법.
  7. 제7항에 있어서, 수지에 이온 결합된 유기인 리간드가 이온성 오르가노포스핀인 방법.
  8. 제1항에 있어서,이온성 오르가노포스핀이 하기 일반식(1) 및 (2)의 화합물중에서 선택되는 방법.
    상기식에서,R1,R2,R3,R4,R5,R6및 R7은 각각 독립적으로 알킬, 아릴, 알카릴, 아르알킬, 및 사이클로알킬 라디칼중에서 선택된 탄소수 1 내지 30의 탄화수소 라디칼이고, Q는 이가(divalent) 유기 브리징(bridging)그룹이며, Y1,Y2,Y3,Y4,Y5,Y6및 Y7은 탄화수소 라디칼상에 치환되고 각각 독립적으로, -SO3M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다), -PO3M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다), -NR3X'(여기서, R은 알킬, 아릴, 알카릴, 아르알킬, 및 사이클로알킬 라디칼중에서 선택된 탄소수 1 내지 30의 탄화수소 라디칼이고, X'은 무기 또는 유기 음이온 원자 또는 라디칼이다), 및 -CO2M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다.)중에서 선택된 총 중성 전하의 이온성 라디칼이며, m1,m2,m3,m4,m5,m6및 m7은 동일하거나, 상이할 수 있고 0 내지 5의 정수이며, m1,m2및 m3중 적어도 하나, 및 m4,m5,m6및 m7중 적어도 하나는 1 이상이다.
  9. 제8항에 있어서, M이 양이온 수소원자인 방법.
  10. 제8항에 있어서, 이온성 오르가노포스핀 리간드가 이온성 트리아릴포스핀인 방법.
  11. 제10항에 있어서, 이온성 트리아릴포스핀이 설폰화 트리페닐포스핀 또는 이의 염인 방법.
  12. 제1항에 있어서, 수지에 이온결합된 유기인 리간드가 이온성 유기아인산염 리간드인 방법.
  13. 제12항에 있어서, 이온성 유기아인산염이 (i) 일반식(I)의 다(poly)-아인산염, (ii) 일반식(II)의 이(di) 유기아인산염, 및 (iii) 일반식(III)의 개-구(open-ended) 비스-아인산염중에서 선택되는 방법.
    상기실에서, Ar은 동일하거나 상이한 아릴 라디칼이고, X는 알킬렌, 알킬렌-옥시-알킬렌, 아릴, 및 아릴-(CH2)y-(Q)n-(CH2)y- 아릴중에서 선택된 m-가 탄화수소 라디칼이며, y는 독립적으로 0 또는 1이고, Q는 독립적으로 -CR1R2- -O-, -S-, -NR3-, -SiR4R5-, 및 -CO- 중에서 이가 브리징 그룹이며, R1및 R2는 각각 독립적으로 수소, 탄소수 1 내지 12의 알킬, 페닐, 톨릴 및 아니실중에서 선택된 라디칼이고, R3,R4및 R5는 각각 독립적으로 -H 또는 -CH3이며, n은 각각 독립적으로 0 내지 1이고, m은 2 내지 6이며, T는 일가 탄화수소 라디칼이고, 일반식(III)에서는 각각 동일하거나 상이할 수 있으며, D는 알킬렌, 알킬렌-옥시-알킬렌, 아릴, 및 아릴-(CH2)y-Qn-(CH2)y- 아릴중에서 선택된 이가 브리징 그룹이고, 하기 그룹, 즉, -SO3M (여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다), -PO3M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다), -NR3X1(여기서, R은 알킬, 아릴, 알카릴, 아르알킬, 및 사이클로 알킬 라디칼중에서 선택된 탄소수 1 내지 30의 탄화수소 라디칼이며, X'은 무기 또는 유기 음이온 원자 또는 라디칼이다), 및 -CO2M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다)중에서 선택된 총 중성 전하의 이온성 라디칼이, 일반식((I)의 다-아인산염에서는 Ar 또는 W의 아릴 잔기상에 하나 이상 치환되며, 일반식(II)의 이유기아인산염에서는 Ar 또는 T의 아릴 잔기상에 하나이상 치환되며 일반식(III) 개-구 비스-아인산염에서는 Ar, D 또는 T의 아릴 잔기상에 하나 이상 치환된다.
  14. (i) 전이금속-함유 액체를 제1유기인 리간드가 이온결합된 이온-교환 수지에 접촉시켜 전이금속을 액체로부터 제거하고 수지에 결합시킨 후, (ii) 이 수지를 충분한 양의 제2유기인 리간드가 함유된 액체와 접촉시켜 전이금속을 수지로부터 제거시킴을 특징으로 하여, 전기금속-함유 액체로부터 VIII족 전이금속을 회수하는 방법.
  15. 제14항에 있어서, 전이금속이 로듐인 방법.
  16. 제15항에 있어서, 로듐-함유 액체가 2ppm 이하의 로듐이 함유된 하이드로포밀화 공정의 알데히드 생성물을 함유하는 방법.
  17. 제14항에 있엇, 이온-교환 수지가 유기인 리간드와 이온결합된 음이온-교환 수지인 방법.
  18. 제17항에 있어서, 음이온-교환수지가 거대망상의 강염기 음이온-교환 수지인 방법.
  19. 제14항에 있어서, 제1 및 제2유기인 리간드가 동일한 방법.
  20. 제19항에 있어서, 제2리간드-함유 액체가 극성 액체인 방법.
  21. 제20항에 있어서, 극성 액체가 메탄올인 방법.
  22. 제19항에 있어서, 유기인 리간드가 이온성 오르가노포스핀인 방법.
  23. 제22항에 있어서, 이온성 오르가노포스핀이 하기 일반식(1) 및 (2)의 화합물중에서 선택되는 방법.
    상기식에서, R1,R2,R3,R4,R5,R6및 R7은 각각 독립적으로 알킬, 아릴, 알카릴, 아르알킬, 및 사이클로 알킬 라디칼중에서 선택된 탄소수 1 내지 30의 탄화수소 라디칼이고, Q는 이가 유기 브리징 그룹이며, Y1,Y2,Y3,Y4,Y5,Y6및 Y7은 탄화수소 라디칼상에 치환되고 각각 독립적으로, -SO3M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다), -PO3M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다), -NR3X'(여기서, R은 알킬, 아릴, 알카릴, 아르알킬, 및 사이클로알킬 라디칼중에서 선택된 탄소수 1 내지 30의 탄화수소 라디칼이고, X'은 무기 또는 유기 임이온 원자 또는 라디칼이다), 및 -CO2M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다.)중에서 선택된 총 중성 전하의 이온성 라디킬이며, m1,m2,m3,m4,m5,m6및 m7은 동일하거나, 상이할 수 있고 0 내지 5의 정수이며, m1,m2및 m3중 적어도 하나, 및 m4,m5,m6및 m7중 적어도 하나는 1 이상이다.
  24. 제19항에 있어서, 유기인 리간드가 이온성 유기아인산염인 방법.
  25. 제24항에 있어서, 이온성 유기아인산염이 (i) 일반식(I)의 다-아인산염, (ii) 일반식(II)의 이유기아인산염, 및 (iii) 일반식(III)의 개-구 비스-아인산염중에서 선택되는 방법.
    상기식에서, Ar은 동일하거나 상이한 이릴 라디칼이고, X는 알킬렌, 알킬렌-옥시-알킬렌, 아릴, 및 아릴-(CH2)y-(Q)n-(CH2)y- 아릴중에서 선택된 m-가 탄화수소 라디칼이며, y는 독립적으로 0 또는 1이고, Q는 독립적으로 CR1R2- -O-, -S-, -NR3-, -SiR4R5-, 및 -CO- 중에서 선택된 이가 브리징 그룹이며, R1및 R2는 각각 독립적으로 수소, 탄소수 1 내지 12의 알킬, 페닐, 톨릴 및 아니실중에서 선택된 라디칼이고, R3,R4및 R5는 각각 독립적으로 -H 또는 -CH3이며, n은 각각 독립적으로 0 내지 1이고, m은 2 내지 6이며, T는 일가 탄화수소 라디칼이고, 일반식(III)에서는 각각 동일하거나 상이할 수 있으며, D는 알킬렌, 알킬렌-옥시-알킬렌, 아릴, 및 아릴-(CH2)y-Qn-(CH2)y- 아릴중에서 선택된 이가 브리징 그룹이고, 하기 그룹, 즉, -SO3M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다), -PO3M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다), -NR3X'(여기서, R은 알킬, 아릴, 알카릴, 아르알킬, 및 사이클로 알킬 라디칼중에서 선택된 탄소수 1 내지 30의 탄화수소 라디칼이며, X'은 무기 또는 유기 음이온 원자 또는 라디칼이다), 및 -CO2M(여기서, M은 무기 또는 유기 양이온 원자 또는 라디칼이다)중에서 선택된 총 중성 전하의 이온성 라디칼이, 일반식(I)의 다-아인산염에서는 Ar 또는 X의 아릴잔기상에 하나 이상 치환되고, 일반식(II)의 이유기아인산염에서는 Ar 또는 T의 이릴 잔기상에 하나 이상 치환되며, 일반식(III)의 개-구 비스-아인산염에서는 Ar, D 또는 T의 아릴 잔기상에 하나 이상 치환된다.
  26. 유기인 리간드가 이온결합된 이온-교환 수지.
  27. 제26항에 있어서, 유기인 리간드가 이온성 오르가노포스핀인 이온-교환 수지.
  28. 제26항에 있어서, 유기인 리간드가 이온성 유기아인산염인 이온-교환 수지.
  29. (i) 2ppm 이하의 로듐을 함유한 하이드로포밀화 공정의 알데히드 생성물을 유기인 리간드가 이온결합된 이온교환 수지에 접촉시켜 액체로부터 로듐을 제거시키고 수지에 결합시킨 후, (ii) 이 수지를 재사용하기 위한 수지를 재생성시키기에 충분한 양의 상기 이온성 유기인 리간드가 함유된 액체와 접촉시켜 수지로부터 로듐을 제거시킴을 특징으로 하여, 상기 알데히드 생성물로부터 로듐을 회수하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890012041A 1988-08-25 1989-08-24 전이금속 회수방법 KR940004628B1 (ko)

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US5114473A (en) 1992-05-19
CN1021657C (zh) 1993-07-21
BR8904259A (pt) 1990-04-10
AU4019889A (en) 1990-03-01
PL166018B1 (pl) 1995-03-31
RU2004499C1 (ru) 1993-12-15
EP0355837A2 (en) 1990-02-28
CN1040826A (zh) 1990-03-28
JPH02160627A (ja) 1990-06-20
EP0355837A3 (en) 1990-05-16
AU621396B2 (en) 1992-03-12
MX166329B (es) 1992-12-29
JPH0829946B2 (ja) 1996-03-27

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