KR880011248A - 공반응성 광개시제 - Google Patents

공반응성 광개시제 Download PDF

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KR880011248A
KR880011248A KR1019880001709A KR880001709A KR880011248A KR 880011248 A KR880011248 A KR 880011248A KR 1019880001709 A KR1019880001709 A KR 1019880001709A KR 880001709 A KR880001709 A KR 880001709A KR 880011248 A KR880011248 A KR 880011248A
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hydroxy
phenyl
compound
thioxanthone
propyl ketone
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KR960015191B1 (ko
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쾌흘러 만프레트
온게마하 외르그
포에취 아이케
아이덴슁크 루돌프
그레버 게르하르트
도르취 디이터
도르프너 콘라트
루드비그 이르슈 안스
겔하우스 위르겐
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브리지테노우만 위르겐 헤우만
메르크 파텐트 게젤사프트 비트 베쉬랭크터 하프퉁
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    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/031—Organic compounds not covered by group G03F7/029
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71—Monoisocyanates or monoisothiocyanates
    • C08G18/711—Monoisocyanates or monoisothiocyanates containing oxygen in addition to isocyanate oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S522/904—Monomer or polymer contains initiating group

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Abstract

내용없음

Description

공반응성 광개시제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 에틸렌적으로 치환된 화합물을 함유한 계의 광중합용 공반응성 광개시제로서, 일반식(Ⅰ)의 화합물의 용도.
    RG-A-IN
    상기 식에서, IN은 광개시제 기본 구조이다. 여기에서 R은 -CR3R4R5또는이고 R1은 H, C1-12-알킬, 할로겐 또는 RG-A- 그룹 또는 카보닐 그룹에 대해 오르토 위치에 존재하는 두 개의 R1라디칼은 함께 이와 달리 -S이고, R2는, H, 할로겐, C1-12-알킬 또는 C1-12-알콜시 또는 RG-A- 그룹이고, R3,R|4는 상호 독립적으로 H, C1-12-알킬, C1-12-알켄일, C1-12-알콕시 또는 페닐, 또는 함께 C2-6-알킬렌이고 R5는 ORw, N(R7)또는 SO2RW이고, R6는 각각 할로겐, C1-6-알킬 또는 C1-6-알콕시에 의해 임의적으로 치환된 C1-6-알킬, C1-6-알카노일, 페닐 또는 벤조일이고, R7는 H, C1-6-알킬 또는 C1-6-알카노일이고, A는 스페이서 그룹 A[(CH2)0Y]n-[((CH2)MX]1이고, 상기식에서, S,Y 및 Z는 상호 독립적으로 각기 단일 결합, -O-, -S-, -NH, -CO-, -COO, -CONH-, -O-CO-, -NH-CO-, 또는 NH-COO-이고, 1 및 m은 1 내지 4이고, n 및 o는 0 내지 4이고, RG는 기능적인 반응성 그룹 HO-, HS-, H2N-, 할로겐, HO-CO-, H2N-CO, O=C=N, S=C=N, N3-, SO3H, SO|2CI 중의 하나이고, RcRbC=CRa-(여기에서 Ra, Rb및 Rc는 각기 H 또는 CH3이고 단, Z는 n이 0이고 R5는 OR7이면 -COO-가 아니다)이고, RG는 또한 할로겐, 시클로프로필, 옥시탄일, O=C=N-Rd는 C1-6-알킬렌 또는 페틸렌이다), N2+, (Re)3Si(여기에서 Re은 할로겐 C1-12-알킬, C1-12-알콕시 또는 C1-12-알카노일옥시이다) 이다.
  2. 제1항에 있어서, 공지된 광개시제 및 또는 증감제와 합께 사용하는 일반식(Ⅰ) 화합물의 용도.
  3. 제1항에 있어서, UV-경화가능한 페인트 및 경합제 계를 함유한 코팅물의 방사선 경화에의 일반식(Ⅰ)의 화합물의 용도.
  4. 제1항에 있어서, 혼성 결합제계의 방사선 경화예의 일반식(Ⅰ) 화합물의 용도.
  5. 적어도 1종의 일반식(Ⅰ)의 화합물을 광중합 개시전에 광중합 혼합물에 공반응성 광개시제로 첨가시키는 것을 특징으로 하는 에틸렌적으로 불포화된 화합물을 함유한 제의 광중합 방법.
  6. 제5항에 있어서, 일반식(Ⅰ)의 화합물의 0.1 내지 20중량％로 과중합 개시전에 중합된 혼합물에 첨가시키는 것을 특징으로 하는 방법.
  7. 적어도 1종의 에틸렌적으로 불포화된 광중합 가능한 화합물 및 필요시, 다른 공지되고 통상적인 첨가제를 함유한 광중합 가능한 계에 있어서, 이들계에 공반응성 관개시제로서 일반식(Ⅰ)의 적어도 1종의 화합물을 함유시키는 것을 특징으로 하는 방법.
  8. 혼성 결합계에 있어서, 이들계에 공반응성 관개시제로서 적어도 1종의 일반식(Ⅰ)의 화합물을 함유시킨 것을 특징으로 하는 혼성결합제계.
  9. 제7항 및 제8항에 있어서, 광중합 가능한 계에 일반식(Ⅰ)의 화합물을 0.1 내지 20중량 ％로 함유시키는 것을 특징으로 하는 광중합 가능한 계.
  10. 다른 기능화된 광개시제 및 공유적으로 결합된 광개시제를 함유한 방사선-반응계의 제조시 합성 중간물질로서 일반식(Ⅰ)의 화합물의 용도.
  11. 다음 일반식(Ⅰ)의 화합물, 4-[2-(옥시란일메톡시)에톡시]페닐, 2-히드록시-2-프로필 케톤, 4-[2-(알릴옥시에톡시)페닐] 2-히드록시-2-프로필 케톤, 4-[2-(3-트리에톡시실릴프로폭시)에톡시]페닐 2-히드록시-2-프로필 케톤, 4-[2-(아지도에톡시)페닐] 2-히드록시-2-프로필 케톤, 4-(히드록시카보닐메톡시)페닐2-히드록시-2-프로필 케톤, 4-알릴옥시페닐 2-히드록시-2-프로필케톤, 4-옥시란일메톡시페닐 2-히드록시-2-프로필 케톤,4-[3-(트리에톡시실릴)프로폭시]페닐 2-히드록시-2-프로필 케톤, 4-[2-(3-트리에톡시실릴 프로필티오)에틸]페닐 2-히드록시-2-프로필 케톤, 4-2-(클로로에톡시)페닐 (2-히드록시-2-프로필)케톤, 4-(옥시란일메톡시카보닐메톡시)페닐 2-히드록시-2-프로필 케톤, 4-옥시란일메톡시페닐 α-이소프로폭시벤질 케톤, 4-[3-(트리에톡시실릴)프로폭시]페닐 α-이소프로폭시벤질 케톤, 4-옥시란일메톡시페닐 α,α-디메톡시벤질케톤, 4-[3-(트리에톡시실릴)프로폭시]페닐 α,α-디메톡시벤질 메톤, 4-(2-이소시아네이토에톡시)페닐 2-히드록시-2-프로필 케톤, 4-(2-이소티오시아네이토에톡시)페닐 2-히드록시-2-프로필 케톤, 4-(2-히드록시-2-메틸프로피오닐)페녹시아세트아미드, 4-(2-히드록시-2-메틸프로피오닐)페녹시아 세모히드라지드, N-[4-(2-히드록시-2-메틸프로피오닐)페녹시아세틸]-히드록실아민, N-[4-(2-히드록시-2-메틸프로피오닐)페녹시아세틸]-N'-아크릴오힐히드라진, 4-(이소시아네이토메톡시페닐 2-히드록시-2-프로필 케톤, 비닐4-(2-히드록시-2-메티르로필티오)페녹시아세테이트, 2-[2-(히드록시에틸티오)티오크산톤, 2-[2-아미노에틸티오]티오크산톤 2-[2-(아크릴로일옥시)에틸티오]티오크산톤 2-[2-(아크릴로일아미노)에틸티오]티오크산톤 2-[2-(알일옥시)에틸티오]티오크산톤 2-[2-(아릴아미노)에틸티오)]티오크산톤 2-[2-(6-이소시아네이토복실아미노카복실산옥시)에톡시]티오크산톤 2-(옥시란일메톡시)티오크산톤 2-{3-(트리에톡시실릴)프로폭시]티오크산톤.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880001709A 1987-03-12 1988-02-15 공반응성 광개시제 KR960015191B1 (ko)

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DEP3707891.7 1987-03-12
DE3707891 1987-03-12
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DE3707891.7 1987-11-13
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DE19873738567 DE3738567A1 (de) 1987-03-12 1987-11-13 Coreaktive fotoinitiatoren

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AU1262488A (en) 1988-09-15
DK133788A (da) 1988-09-13
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US5744512A (en) 1998-04-28
DE3738567A1 (de) 1988-09-22
JPS63254105A (ja) 1988-10-20
ES2060611T3 (es) 1994-12-01
FI881166A (fi) 1988-09-13
EP0281941B1 (de) 1993-12-08
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JP2855429B2 (ja) 1999-02-10
FI98817B (fi) 1997-05-15
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FI98817C (fi) 1997-08-25
US5837746A (en) 1998-11-17
DK133788D0 (da) 1988-03-11
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