KR880010191A - 중합체와 2:1로 층을 이룬 규산염의 내수성 구조물질 및 그의 제조방법 - Google Patents

중합체와 2:1로 층을 이룬 규산염의 내수성 구조물질 및 그의 제조방법 Download PDF

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KR880010191A
KR880010191A KR1019880001715A KR880001715A KR880010191A KR 880010191 A KR880010191 A KR 880010191A KR 1019880001715 A KR1019880001715 A KR 1019880001715A KR 880001715 A KR880001715 A KR 880001715A KR 880010191 A KR880010191 A KR 880010191A
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polymer
dispersion
cationic flocculant
alkyl group
polar liquid
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존 보온 윌터
앨런 브루베이커 리차아드
니즈닉 가아먼 쉘리
코울러 호스펠드 루이스
마이클 타이먼 토마스
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끌로드 엘르 보드앵
암스트롱 월드 인더스트리이즈 인코포레이팃트
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/76—Processes or apparatus for adding material to the pulp or to the paper characterised by choice of auxiliary compounds which are added separately from at least one other compound, e.g. to improve the incorporation of the latter or to obtain an enhanced combined effect
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D21H13/38—Inorganic fibres or flakes siliceous
    • D21H13/40—Inorganic fibres or flakes siliceous vitreous, e.g. mineral wool, glass fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D21H13/38—Inorganic fibres or flakes siliceous
    • D21H13/44—Flakes, e.g. mica, vermiculite
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S106/00—Compositions: coating or plastic
    • Y10S106/03—Mica
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/251—Mica

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paper (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

내용 없음

Description

중합체와 2:1로 층을 이룬 규산염의 내수성 구조물질 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 하기(1)-(2) 단계로 구성되는 것을 특징으로 하는 중합체 및 2:1로 층을 이룬 규산염의 내수성 구조물을 제조하는 방법 : (1) 하기(a)-(c)의 공-분산액을 제조하는 단계 : (a) 구조단위당 약-0.4 내지 약 1.0의 평균 전하를 갖는 2:1로 층을 이룬 규산염 물질, (b) 중합체, 및 (c) 극성액체 ; (2) 이 공-분산액을 양이온성 응집제와 접촉시키고 그럼으로써 이 공-분산액을 불안정화시켜 중합체로 함유하는 규산염 응집괴를 형성시키는 단계.
  2. 제 1항에 있어서, 중합체가 극성 액체내에서는 분산성이 아니고, 상기한 중합체가 극성액체내에 분산된 규산염내에서는 분산될 수 있다는 것을 특징으로 하는 방법.
  3. 제 2항에 있어서, 극성 액체가 글리콜, 물, 아세톤, 메탄올, 에탄올, 프로판올, 이소프로판올, 및 부탄올로 된 군으로부터 선택되며, 바람직하게는 본질적으로 수성인 것을 특징으로 하는 방법.
  4. 제 3항에 있어서, 중합체가 폴리아미드인 것을 특징으로 하는 방법.
  5. 제 2항에 있어서, 이암모늄 화합물이 하기 일반식을 갖는 것을 특징으로 하는 방법 :
    상기식에서 (1) 각 R2는 수소 및 C1-C8포화 또는 불포화, 직쇄 또는 측쇄알킬기에서 독립적으로 선택되고 ; (2) R3는 수소, 1-18개의 탄소원자를 지니는 포화 또는 불포화, 측쇄 또는 직선상 알킬기, 또는 1-18개의 탄소원자를 갖는 아릴기에서 선택된다.
  6. 제 1항에 있어서, 중합체가 극성 액체내에서 분산성임을 특징으로 하는 방법.
  7. 제 2항 또는 제 6항에 있어서, 양이온성 응집제가 하기 일반식을 갖는 화합물에서 유도되는 것을 특징으로 하는 방법 :
    [(R1)3N-(CX2)n-N(R1)3]+2
    상기식에서, (1) R1은 수소, C1-C8직쇄 또는 측쇄알킬기, C3-C6비환식 알킬기 또는 아릴기에서 독립적으로 선택되고(단, 각 질소위에 단지 하나정도의 아릴기가 있음), (2) 각 X는 수소, 알킬기 또는 아릴기에서 독립적으로 선택되며 (3) n은 2-15인 정수이며, 선택적으로 n이 3 또는 그 이상인 경우, CX2기는 방향족이 될 수 있는 고리부분을 형성할 수 있다.
  8. 제 1항에 있어서, (1) 단계후에, 균질의 공-분산액으로써 필름을 제조하고 이어 필름을 (2)단계에서 양이온성 응집제와 접촉시키는 것을 특징으로 하는 방법.
  9. 제 8항에 있어서, (2) 단계후에, 필름을 건조시키고 이어 고온 압축시키는 것을 특징으로 하는 방법.
  10. 제 2항, 제 6항 또는 제 8항에 있어서, 양이온성 응집제가 아미노메틸렌이민 양이온인 것을 특징으로 하는 방법.
  11. 제 2항 또는 제 6항에 있어서, 중합체도 응집되는 것을 특징으로 하는 방법.
  12. 제 2항, 제 6항 또는 제 8항에 있어서, 양이온성 응집제가 이암모늄 화합물인 것을 특징으로 하는 방법.
  13. 제 1항에 있어서, 단계의 공-분산액을 직조 섬유상 기질에 적용시키고 이어(2) 단계에서 양이온성 응집제와 접촉시키는 것을 특징으로 하는 방법.
  14. 제 1항에 있어서, (1) 단계에서의 공-분산액이 섬유도 함유한다는 것을 특징으로 하는 방법.
  15. 제 1항에 있어서, (1) 단계의 공-분산액을 성형하고 이어 (2) 단계에서 양이온성 응집제와 접촉시키는 것을 특징으로 하는 방법.
  16. 구조단위당 -0.4 내지 약 -1의 평균 전하를 갖는 응집되고, 팽윤된, 2:1로 층을 이룬 규산염과 중합체를 포함하는 내수성 규산염 및 중합체 구조물질(단, 상기한 중합체와 규산염은 균질하게 혼합되어 있어야 함).
  17. 제 16항에 있어서, 규산염이 디아민 화합물에서 또는 아미노메틸렌이민에서 유도되는 적어도 일부의 격자간 양이온을 함유하는 것을 특징으로 하는 물질.
  18. 제 16항에 있어서, 직조 또는 부직 섬유도 함유하는 것을 특징으로 하는 물질.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880001715A 1987-02-17 1988-02-16 중합체와 2:1로 층을 이룬 규산염의 내수성 구조물질 및 그의 제조방법 KR930002077B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US015262 1987-02-17
US07/015,262 US4775586A (en) 1987-02-17 1987-02-17 Paper, paper products, films composites and other silicate-polymer, construction materials
US15262 1987-02-17

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KR880010191A true KR880010191A (ko) 1988-10-07
KR930002077B1 KR930002077B1 (ko) 1993-03-26

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US (1) US4775586A (ko)
JP (1) JPH01224250A (ko)
KR (1) KR930002077B1 (ko)
CN (1) CN1030531A (ko)
AU (1) AU593978B2 (ko)
BE (1) BE1001197A3 (ko)
BR (1) BR8800638A (ko)
DE (1) DE3804089A1 (ko)
ES (1) ES2005780A6 (ko)
FI (1) FI880722A (ko)
FR (1) FR2610954A1 (ko)
GB (1) GB2202228B (ko)
IT (1) IT1215883B (ko)
LU (1) LU87133A1 (ko)
NL (1) NL8800400A (ko)
NO (1) NO880670L (ko)
SE (1) SE8800507L (ko)

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DE3804089A1 (de) 1988-08-25
NL8800400A (nl) 1988-09-16
FI880722A0 (fi) 1988-02-16
BR8800638A (pt) 1988-09-27
FR2610954A1 (fr) 1988-08-19
US4775586A (en) 1988-10-04
GB2202228A (en) 1988-09-21
JPH01224250A (ja) 1989-09-07
AU593978B2 (en) 1990-02-22
ES2005780A6 (es) 1989-03-16
SE8800507L (sv) 1988-08-18
SE8800507D0 (sv) 1988-02-16
NO880670L (no) 1988-08-18
BE1001197A3 (fr) 1989-08-16
IT1215883B (it) 1990-02-22
LU87133A1 (de) 1988-07-14
KR930002077B1 (ko) 1993-03-26
NO880670D0 (no) 1988-02-16
FI880722A (fi) 1988-08-18
AU1173888A (en) 1988-08-18
GB8803539D0 (en) 1988-03-16
IT8819420A0 (it) 1988-02-16
CN1030531A (zh) 1989-01-25
GB2202228B (en) 1991-05-15

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