KR850006687A - 폴리우레탄 조성물용 촉매 시스템 - Google Patents

폴리우레탄 조성물용 촉매 시스템 Download PDF

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KR850006687A
KR850006687A KR1019850001482A KR850001482A KR850006687A KR 850006687 A KR850006687 A KR 850006687A KR 1019850001482 A KR1019850001482 A KR 1019850001482A KR 850001482 A KR850001482 A KR 850001482A KR 850006687 A KR850006687 A KR 850006687A
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composition
component
aliphatic
iii
polyol
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KR1019850001482A
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KR930004364B1 (ko
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치에 창 유진유
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존 제이 헤이간
아메리칸 사이아나밋드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/06—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

폴리우레탄 조성물용 촉매 시스템
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 지방족 히드록실-함유 화합물과 차폐된 지방족 2차 또는 3차이소시아네이트기 함유 화합물 간의 반응을 촉매하며, 하기 (i), (ii) 및 (iii)으로 구성되는 촉매 조성물. (i) 1,8-디아자비시클로(5,4,0)-운데센-7 또는 그외염; (ii) 유기 주석 화합물; 및, 임의적으로 (iii) 유기 납 화합물[(i):(ii):(iii)의 중량비는 각각 약 0.5:1:0 내지 약 2:1:3이다.]
  2. 제1항에 있어서, 성분(i)이 페놀산염인 조성물.
  3. 제1항에 있어서, 성분(ii)가 디카르복실산디알킬주석인 조성물.
  4. 제1항에 있어서, 상기 디카르복실산디알킬주석이 다음과 같은 구조를 갖는 조성물.
    상기식에서, R은 C1-C8알킬이고, R'은 C1-C18알킬이다.
  5. 제4항에 있어서, 상기 디카르복실산디알킬주석이 디라우릴산 디메틸주석 및 디라우릴산디부틸주석으로 부터 선택되는 조성물.
  6. 제1항에 있어서, 성분(iii)이 나프텐산납인 조성물.
  7. 하기 (a),(b) 및 (c)로 구성되는 경화성 조성물, (a) 지방족 히드록실 함유 화합물; (b) 차폐된 지방족 2차 또는 3차 이소시아네이트기를 갖는 화합물; 및 (c) 하기 (i),(ii) 및 (iii)으로 구성되는, 촉매적 유효량의 촉매조성물. (i) 1,8-디아자비시클로(5,4,0)-운덴센-7 또는 그의 염; (ii) 유기 주석 화합물; 및, 임의적으로, (iii) 유기 납화합물, [(i):(ii):(iii)의 중량비는, 각각 약 0.5:1:0 내지 약 2:1:3이다.]
  8. 제7항에 있어서, 성분(a)가 중합체 폴리올로 구성되는 조성물.
  9. 제8항에 있어서, 성분(a)가 지방족 폴리올 또는 지방족폴리아민 폴리올과 결합된 중합체 폴리올로 구성되는 조성물.
  10. 제8항에 있어서, 성분(a)가 폴리에테르 폴리올로 구성되는 조성물.
  11. 제8항에 있어서, 성분(a)가 지방족 폴리올과 결합된 폴리에테르 폴리올로 구성되는 조성물.
  12. 제8항에 있어서, 성분(a)가 하기 구조를 갖는 조성물.
    상기식에서, R1과 R2는 각기 수소 또는 C1-C4알킬기이다.
  13. 제8항에 있어서, 성분(a)가 α,α',α'-테트라메틸-m-크실틸 디이소시아네이트인 조성물.
  14. 반응 혼합물 내에서 지방족 히드록실-함유 화합물과 차폐된 지방족 2차 및/또는 3차 이소시아네이트 화합물과의 반응에 대한 촉매 공정에 있어서, 제1항의 촉매 조성물 약 0.05-약 5중량%를 상기 반응 혼합물 내에 첨가하는 것으로 구성되는 방법.
  15. 제14항에 있어서, 상기 반응 혼합물이 하기 구조의 이소시아네이트 화합물로 구성되는 방법.
    상기식에서 R1과 R2는 각기 수소 또는 C1-C4알킬이다.
  16. 제15항에 있어서, 상기 이소시아네이트 화합물이 α,α,α',α'-테트라메틸-m-크실틸 디이소시아네이트인 방법.
  17. 제14항에 있어서, 상기 지방족 히드록실-함유화합물이 중합체폴리올 또는 폴리에테르 폴리올리거나, 또는 지방족 폴리올 또는 지방족 폴리아민 폴리올과의 결합상태의 것인 방법.
  18. 제14항에 있어서, 상기 촉매 조성물의 성분(i)은 1,8-디아자비시클로(5,4,0)-운데센-7이고; 성분(ii)는 디카르복실산 디알킬주석이며; 성분(iii)이 존재할 경우 이것은 나프텐산납인 방법.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019850001482A 1984-03-09 1985-03-08 폴리우레탄 조성물용 촉매시스템 KR930004364B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US588015 1984-03-09
US06/588,015 US4547478A (en) 1984-03-09 1984-03-09 Catalyst systems for polyurethane compositions
US588,015 1984-03-09

Publications (2)

Publication Number Publication Date
KR850006687A true KR850006687A (ko) 1985-10-16
KR930004364B1 KR930004364B1 (ko) 1993-05-26

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US (2) US4547478A (ko)
EP (1) EP0154180B1 (ko)
JP (1) JPS60190411A (ko)
KR (1) KR930004364B1 (ko)
AT (1) ATE88199T1 (ko)
CA (1) CA1262595A (ko)
DE (1) DE3587254T2 (ko)
ES (1) ES8606434A1 (ko)

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Publication number Publication date
ES541095A0 (es) 1986-04-16
CA1262595A (en) 1989-10-31
US4598103A (en) 1986-07-01
EP0154180A3 (en) 1986-10-01
US4547478A (en) 1985-10-15
EP0154180B1 (en) 1993-04-14
KR930004364B1 (ko) 1993-05-26
DE3587254D1 (de) 1993-05-19
ATE88199T1 (de) 1993-04-15
JPH0562610B2 (ko) 1993-09-08
JPS60190411A (ja) 1985-09-27
ES8606434A1 (es) 1986-04-16
EP0154180A2 (en) 1985-09-11
DE3587254T2 (de) 1993-11-25

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