KR910007976A - 폴리우레탄계에 유용한 중합체성 이유기주석촉매 - Google Patents

폴리우레탄계에 유용한 중합체성 이유기주석촉매 Download PDF

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KR910007976A
KR910007976A KR1019900016684A KR900016684A KR910007976A KR 910007976 A KR910007976 A KR 910007976A KR 1019900016684 A KR1019900016684 A KR 1019900016684A KR 900016684 A KR900016684 A KR 900016684A KR 910007976 A KR910007976 A KR 910007976A
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South Korea
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composition
general formula
weaning
butyl
alkyl
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KR1019900016684A
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KR930006916B1 (ko
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두들리 니콜스 제임스
바트램 디켄슨 존
Original Assignee
윌리암 에프. 마쉬
에어프로덕츠 앤드 케미칼스, 인코오포레이티드
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Priority claimed from US07/424,795 external-priority patent/US4981925A/en
Priority claimed from US07/424,855 external-priority patent/US5089584A/en
Application filed by 윌리암 에프. 마쉬, 에어프로덕츠 앤드 케미칼스, 인코오포레이티드 filed Critical 윌리암 에프. 마쉬
Publication of KR910007976A publication Critical patent/KR910007976A/ko
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Publication of KR930006916B1 publication Critical patent/KR930006916B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4457—Polyepoxides containing special additives, e.g. pigments, polymeric particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
    • C08G18/643—Reaction products of epoxy resins with at least equivalent amounts of amines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음.

Description

폴리우레탄계에 유용한 중합체성 이유기주석촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (23)

  1. 이유기주석산화물 또는 이유기주석 이염화물 단위몰당 약 1.5 내지 1몰의 HSCH2CH(OH)CH2XH(여기에서, X는 -S- 또는 -O-이다)를 반응시킴으로써 제조된 조성물.
  2. 제1항에 있어서, 상기 이유기주석산화물이 일반식 R2SnO(여기에서, R은 C1-C8알킬 또는 아릴기이다)이고 이유기주석 이염화물은 일반식 R2SnCl2(여기에서, R은 상기 정의한 바와 같다)인 조성물.
  3. 제1항에 있어서, X가 -O-인 조성물.
  4. 제2항에 있어서, X가 -O-인 조성물.
  5. 하기 일반식의 반복유닛을 포함하는 중합체 조성물 :
    상기식중, R은 C1-C8알킬 또는 아릴기이고 X는 -S-또는 -O-이다.
  6. 제5항에 있어서, R이 부틸, 옥틸 또는 페닐인 조성물.
  7. 제6항에 있어서, X가 -O-인 조성물.
  8. 제7항에 있어서, R이 부틸인 조성물.
  9. 이소시아네이트 또는 차단된 이소시아네이트와 수소 함유화합물과의 반응을 촉매화시키는 방법에 있어서, 촉매로서, 이유기주석 산화물 또는 이유기주석 이염화물 단위몰당 약 0.5 내지 1몰의 HSCH2CH(OH)CH2XH(여기에서, X는 -S- 또는 -O-이다)를 반응시킴으로써 제조된 조성물을 사용하는 방법.
  10. 제9항에 있어서, 상기 이유기주석산화물이 일반식 R2SnO(여기에서, C1-C8알킬 또는 아릴기이다)이고 이유기주석 이염화물은 일반식 R2SnCl2(여기에서, R은 상기 정의한 바와 같다)인 방법.
  11. 제9항에 있어서, X가 -O-인 방법.
  12. 이소시아네이트 또는 차단된 이소시아네이트와 반응성 수소함유화합물과의 반응을 촉매화시키는 방법에 있어서, 촉매로서, 하기일반식의 반복유닛을 포함하는 중합 조성물을 사용하는 방법.
    상기식중, R은 C1-C8알킬 또는 아릴기이고 X는 -S- 또는 -O-이다.
  13. 제12항에 있어서, R이 부틸, 옥틸 또는 페닐인 방법.
  14. 제13항에 있어서, X가 -O-인 방법.
  15. 제14항에 있어서, R이 부틸인 방법.
  16. 적어도 부분적으로 차단된 폴리이소시아네이트, 에폭시기 함유수지의 아민부가물 및 유기주석 촉매를 포함하는 양이온 전기증착성 조성물에 있어서, 상기 촉매로서, 이유기주석 산화물 또는 이유기주석 이염화물 단위몰당 약 0.5 내지 1몰의 HSCH2CH(OH)CH2XH(여기에서, X는 -S- 또는 -O-이다)를 반응시킴으로써 제조된 조성물을 포함하는 조성물.
  17. 제16항에 있어서, 상기 이유기 주석산화물이 일반식 R2SnO(여기에서, R은 C1-C8알킬 또는 아릴기이다)이고 이유기주석 이염화물은 일반식 R2SnCl2(여기에서, R은 상기 정의한 바와 같다)인 조성물.
  18. 제16항에 있어서, X가 -O-인 조성물.
  19. 제17항에 있어서, X가 -O-인 조성물.
  20. 적어도 부분적으로 차단된 폴리이소시아네이트, 에폭시기 함유수지의 아민부가물 및 유기주석촉매를 포함하는 양이온 전기증착성 조성물에 있어서, 상기 유기주석 촉매로서 하기 일반식의 반복유닛을 포함하는 중합체 조성물을 포함하는 조성물.
    상기식중, R은 C1-C8알킬 또는 아릴기이고 X는 -S- 또는 -O-이다.
  21. 제20항에 있어서, R이 부틸, 옥틸 또는 페닐인 조성물.
  22. 제21항에 있어서, X가 -O-인 조성물.
  23. 제22항에 있어서, R이 부틸인 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900016684A 1989-10-20 1990-10-19 폴리우레탄계에 유용한 중합체성 이유기주석촉매 KR930006916B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US424795 1989-10-20
US07/424,795 US4981925A (en) 1989-10-20 1989-10-20 Cationic electrodepositable compositions of partially-blocked polyisocyanates and amine-epoxy resins containing polymeric diorganotin catalysts
US07/424,855 US5089584A (en) 1989-10-20 1989-10-20 Polymeric diorganotin catalysts for use in polyurethane systems
US424855 1995-04-19

Publications (2)

Publication Number Publication Date
KR910007976A true KR910007976A (ko) 1991-05-30
KR930006916B1 KR930006916B1 (ko) 1993-07-24

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KR1019900016684A KR930006916B1 (ko) 1989-10-20 1990-10-19 폴리우레탄계에 유용한 중합체성 이유기주석촉매

Country Status (6)

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EP (1) EP0423642A3 (ko)
JP (1) JPH03153723A (ko)
KR (1) KR930006916B1 (ko)
AU (1) AU629056B2 (ko)
BR (1) BR9005203A (ko)
CA (1) CA2027668A1 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6043373A (en) * 1995-07-12 2000-03-28 Yungjin Pharmaceutical Co., Ltd. Heterocycle-fused thiazole derivatives

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2088930T3 (es) * 1989-09-11 1996-10-01 Air Prod & Chem Catalizadores de organoestaño para uso en sistemas poliuretano.
AU620737B2 (en) * 1989-10-20 1992-02-20 Air Products And Chemicals Inc. Cationic electrodepositable compositions containing heterocyclic diorganotin catalysts
US5089100A (en) * 1990-08-06 1992-02-18 E. I. Du Pont De Nemours And Company Method of incorporating polyamine into a cationic resin
AU652991B2 (en) * 1991-02-21 1994-09-15 Morton International Limited Isocyanate-cured polysulphide polymers
ES2038909B1 (es) * 1991-09-25 1994-02-16 Gonzalez Hernandez Adelaido Procedimiento de obtencion de un producto ambientador y limpiador.
US5356529A (en) * 1993-05-03 1994-10-18 Ppg Industries, Inc. Electrodepositable compositions containing triorganotin catalysts
DE69527224T2 (de) * 1994-04-15 2002-10-17 Ppg Industries Ohio, Inc. Beschichtungsverfahren
US5767191A (en) * 1994-10-25 1998-06-16 Ppg Industries, Inc. Electrodepositable coating compositions and method for improved cure response
WO1996012771A1 (en) * 1994-10-25 1996-05-02 Ppg Industries, Inc. Electrodepositable coating compositions having improved cure response
AU2005315627B2 (en) * 2004-12-15 2011-06-02 Akzo Nobel Coatings International B.V. Water borne coating composition containing thiol functional compounds
US8389653B2 (en) * 2006-03-30 2013-03-05 Basf Corporation Method of catalyzing a reaction to form a urethane coating and a complex for use in the method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2885415A (en) * 1953-01-22 1959-05-05 Metal & Thermit Corp Organotin compounds and process of preparation
US4059562A (en) * 1977-03-21 1977-11-22 Tenneco Chemicals, Inc. Liquid stabilizer systems and vinyl halide resin compositions containing same
US4310454A (en) * 1979-04-03 1982-01-12 Ciba-Geigy Corporation Novel organo-tin compounds

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6043373A (en) * 1995-07-12 2000-03-28 Yungjin Pharmaceutical Co., Ltd. Heterocycle-fused thiazole derivatives

Also Published As

Publication number Publication date
EP0423642A2 (en) 1991-04-24
EP0423642A3 (en) 1991-07-03
CA2027668A1 (en) 1991-04-21
KR930006916B1 (ko) 1993-07-24
AU6466590A (en) 1991-04-26
BR9005203A (pt) 1991-09-17
AU629056B2 (en) 1992-09-24
JPH03153723A (ja) 1991-07-01

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