KR920012174A - 폴리우레탄을 제조하기 위한 히드록실-함유 유기 주석 촉매 - Google Patents

폴리우레탄을 제조하기 위한 히드록실-함유 유기 주석 촉매 Download PDF

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KR920012174A
KR920012174A KR1019910023357A KR910023357A KR920012174A KR 920012174 A KR920012174 A KR 920012174A KR 1019910023357 A KR1019910023357 A KR 1019910023357A KR 910023357 A KR910023357 A KR 910023357A KR 920012174 A KR920012174 A KR 920012174A
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hydroxyl
group
compound
organotin compound
divalent hydrocarbon
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더들리 니콜스 제임스
바트람 디키슨 죤
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윌리암 에프. 마쉬
에어 프로덕츠 앤드 케미칼스 인코오포레이티드
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Publication of KR920012174A publication Critical patent/KR920012174A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
    • C08G71/04—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0228—Sulfur-containing compounds with a metal-sulfur link, e.g. mercaptides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2224—Compounds having one or more tin-oxygen linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/226—Compounds with one or more Sn-S linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
    • C08G18/643—Reaction products of epoxy resins with at least equivalent amounts of amines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4457—Polyepoxides containing special additives, e.g. pigments, polymeric particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/10—Non-coordinating groups comprising only oxygen beside carbon or hydrogen

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  • Polymers & Plastics (AREA)
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  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음

Description

폴리우레탄을 제조하기 위한 히드록실-함유 유기 주석 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 촉매 존재하에서 히드록실-함유 화합물과 폴리이소시아네이트 또는 최소한 부분적으로 블로킹된 폴리이소 시아네이트의 반응을 촉진하는 방법에 있어서, 히드록실-함유 유기주석 화합물을 촉매로 이용함을 특징으로 하는 방법.
  2. 제1항에 있어서, 히드록실-함유 유기주석 화합물이 하기 일반식(I)-(II)의 화합물중 하나의 화합물이거나 또는 1:0.5-1의 몰비로 이유기주석 산화물(diorganotin oxide) 또는 이유기주석 이염화물(diorganotin dichloride)과 HSCH2CH(OH)CH2XH(여기서, X는 -S- 또는 -O-임)의 반응에 의해 제조된 중합체 유기 주석화합물인 방법:
    R2Sn〔X-R1-OH〕2(I)
    (II)
    R2Sn〔O2C(Y′)nCO2-Z-ON〕2(III)
    상기식에서, R은 C1-C8알킬 또는 아릴기이고; R1은 히드록실 치환체를 함유할 수 있는 C2-C22이가 탄화수소기이고; X는 -O-, -S- 또는 -O2C-일 수 있는 결합기이고; Y는 히드록실-함유 C3-C5알킬렌기이고; Y′는 C1-C9이가 탄화수소기이고; Z는 이가 유기결합기이고; 그리고 n은 0 또는1이다.
  3. 폴리이소시아네이트, 폴리올 및 우레탄 촉매를 포함하는 폴리우레탄 도료 조성물에 있어서, 히드록실-함유 유기 주석 화합물을 우레탄 촉매로서 포함함을 특징으로 하는 폴리우레탄 도료 조성물.
  4. 제3항에 있어서, 히드록실-함유 유기 주석 화합물이 하기 일반식(I)-(III)의 화합물중 하나의 화합물이거나 또는 1:0.5-1의 몰비로 이유기주석 산화물 또는 이유기주석 이염화물과 HSCH2CH(OH)CH2XH(여기서, X는 -S- 또는 -O-임)의 반응에 의해 제조된 중합체 유기주석 화합물인 폴리우레탄도료 조성물:;
    R2Sn〔X-R1-OH〕2(I)
    (II)
    R2Sn〔O2C(Y′)nCO2-Z-ON〕2(III)
    상기식에서, R은 C1-C8알킬 또는 아릴기이고; R1은 히드록실 치환체를 함유할 수 있는 C2-C22이가 탄화수소기이고; X는 -O-, -S- 또는 -O2C-일 수 있는 결합기이고; Y는 히드록실-함유 C3-C5알킬렌기이고; Y′는 C1-C9이가 탄화수소기이고; Z는 이가 유기결합기이고; 그리고 n은 0 또는1이다.
  5. 폴리이소시아네이트, 폴리올, 발포제 및 임의로 아민 촉매를 포함하는 폴리우레탄 포옴 조성물에 있어서, 히드록실-함유 유기 주석 화합물을 포함함을 특징으로 하는 폴리우레탄 도료 조성물.
  6. 제5항에 있어서, 히드록실-함유 유기주석 화합물이 하기 일반식(I)-(III)의 화합물중 하나의 화합물이거나 또는 1:0.5-1의 몰비로 이유기 주석 산화물 또는 이유기주석 이염화물과 HSCH2CH(OH)CH2XH(여기서, X는 -S- 또는 -O-임)의 반응에 의해 제조된 중합체 유기주석 화합물인 폴리우레탄포움 조성물:;
    R2Sn〔X-R1-OH〕2(I)
    (II)
    R2Sn〔O2C(Y′)nCO2-Z-ON〕 (III)
    상기식에서, R은 C1-C8알킬 또는 아릴기이고; R1은 히드록실 치환체를 함유할 수 있는 C2-C22이가 탄화수소기이고; X는 -O-, -S- 또는 -O2C-일 수 있는 결합기이고; Y는 히드록실-함유 C3-C5알킬렌기이고; Y′는 C1-C9이가 탄화수소기이고; Z는 이가 유기결합기이고; 그리고 n은 0 또는1이다.
    ※ 참고사항: 최초출원 내용에 의하여 공개하는 것임.
KR1019910023357A 1990-12-17 1991-12-18 폴리우레탄을 제조하기 위한 히드록실-함유 유기 주석 촉매 KR920012174A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/628,261 US5089645A (en) 1989-09-11 1990-12-17 Hydroxyl-containing organotin catalysts for making polyurethanes
US07/628261 1990-12-17

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KR920012174A true KR920012174A (ko) 1992-07-25

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US (1) US5089645A (ko)
EP (1) EP0491268A3 (ko)
JP (1) JPH04335015A (ko)
KR (1) KR920012174A (ko)
AU (1) AU8972391A (ko)
BR (1) BR9104889A (ko)
CA (1) CA2057342A1 (ko)
MX (1) MX9102575A (ko)
ZA (1) ZA919759B (ko)

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EP0539802A1 (de) * 1991-10-28 1993-05-05 Bayer Ag Freifliessende, thermoplastisch verarbeitbare und dabei nachvernetzende, gegebenenfalls expandierbare Polyurethan-Pulver (-Zubereitungen)
AU7000194A (en) * 1993-06-18 1995-01-17 Henkel Kommanditgesellschaft Auf Aktien Open-pore mouldings for use in the construction industry
DE19924101A1 (de) * 1999-05-26 2000-11-30 Witco Gmbh Verfahren zur Herstellung wasserlöslicher Katalysatoren
US6475616B1 (en) 1999-11-30 2002-11-05 3M Innovative Properties Company Paint replacement appliques
US7527861B2 (en) * 2004-01-12 2009-05-05 Ecolab, Inc. Jobsite-renewable multilayer floor finish with enhanced hardening rate
US8389653B2 (en) * 2006-03-30 2013-03-05 Basf Corporation Method of catalyzing a reaction to form a urethane coating and a complex for use in the method
DE102009031291A1 (de) 2009-06-30 2011-01-05 Hans-Peter Kohlstadt Substratanordnung zur Begrünung
FR3078707B1 (fr) 2018-03-06 2020-12-25 Vencorex France Composition de polyisocyanates

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US5089645A (en) 1992-02-18
EP0491268A3 (en) 1992-10-28
CA2057342A1 (en) 1992-06-18
BR9104889A (pt) 1992-08-18
MX9102575A (es) 1992-06-01
ZA919759B (en) 1993-06-11
AU8972391A (en) 1992-07-02
EP0491268A2 (en) 1992-06-24
JPH04335015A (ja) 1992-11-24

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