KR20140131565A - 리튬 함유 나노섬유들 - Google Patents
리튬 함유 나노섬유들 Download PDFInfo
- Publication number
- KR20140131565A KR20140131565A KR1020147027448A KR20147027448A KR20140131565A KR 20140131565 A KR20140131565 A KR 20140131565A KR 1020147027448 A KR1020147027448 A KR 1020147027448A KR 20147027448 A KR20147027448 A KR 20147027448A KR 20140131565 A KR20140131565 A KR 20140131565A
- Authority
- KR
- South Korea
- Prior art keywords
- lithium
- nanofibers
- metal
- nanofiber
- precursor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002121 nanofiber Substances 0.000 title claims abstract description 356
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 241
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 220
- 239000000463 material Substances 0.000 claims abstract description 117
- 238000000034 method Methods 0.000 claims abstract description 105
- 230000008569 process Effects 0.000 claims abstract description 44
- 239000002243 precursor Substances 0.000 claims description 137
- 239000002184 metal Substances 0.000 claims description 104
- 229910052751 metal Inorganic materials 0.000 claims description 102
- 239000012530 fluid Substances 0.000 claims description 98
- 229920000642 polymer Polymers 0.000 claims description 67
- 239000011159 matrix material Substances 0.000 claims description 51
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 45
- 229910001416 lithium ion Inorganic materials 0.000 claims description 41
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 40
- 239000011572 manganese Substances 0.000 claims description 33
- 239000002105 nanoparticle Substances 0.000 claims description 32
- 229910052799 carbon Inorganic materials 0.000 claims description 24
- -1 phosphite alkoxide Chemical class 0.000 claims description 24
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 19
- 229910052748 manganese Inorganic materials 0.000 claims description 18
- 229910052759 nickel Inorganic materials 0.000 claims description 18
- 238000001523 electrospinning Methods 0.000 claims description 16
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 15
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 claims description 12
- 229910017052 cobalt Inorganic materials 0.000 claims description 11
- 239000010941 cobalt Substances 0.000 claims description 11
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 11
- 229940071125 manganese acetate Drugs 0.000 claims description 11
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 229940011182 cobalt acetate Drugs 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 229910003002 lithium salt Inorganic materials 0.000 claims description 10
- 159000000002 lithium salts Chemical class 0.000 claims description 10
- 229910052755 nonmetal Inorganic materials 0.000 claims description 10
- 229910018091 Li 2 S Inorganic materials 0.000 claims description 9
- 229910012851 LiCoO 2 Inorganic materials 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 9
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 claims description 9
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 9
- 229910021450 lithium metal oxide Inorganic materials 0.000 claims description 9
- 229940078494 nickel acetate Drugs 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 9
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- 239000002114 nanocomposite Substances 0.000 claims description 7
- 229910001228 Li[Ni1/3Co1/3Mn1/3]O2 (NCM 111) Inorganic materials 0.000 claims description 6
- 150000004703 alkoxides Chemical class 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 239000012692 Fe precursor Substances 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 150000007942 carboxylates Chemical class 0.000 claims description 5
- 229910001960 metal nitrate Inorganic materials 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 229910010707 LiFePO 4 Inorganic materials 0.000 claims description 4
- 125000005594 diketone group Chemical group 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 229910015645 LiMn Inorganic materials 0.000 claims description 3
- 229910013290 LiNiO 2 Inorganic materials 0.000 claims description 3
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 claims description 3
- 229910001507 metal halide Inorganic materials 0.000 claims description 3
- 150000005309 metal halides Chemical class 0.000 claims description 3
- 229910003266 NiCo Inorganic materials 0.000 claims 2
- 229910052909 inorganic silicate Inorganic materials 0.000 claims 2
- 229910012528 LiNi0.4Co0.4Mn0.2O2 Inorganic materials 0.000 claims 1
- 238000005259 measurement Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- 238000009987 spinning Methods 0.000 abstract description 9
- 239000013078 crystal Substances 0.000 abstract description 4
- 239000007789 gas Substances 0.000 description 55
- 238000010438 heat treatment Methods 0.000 description 44
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 22
- 125000000217 alkyl group Chemical group 0.000 description 20
- 239000011162 core material Substances 0.000 description 19
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 19
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 18
- 239000000203 mixture Substances 0.000 description 18
- 238000000921 elemental analysis Methods 0.000 description 14
- 238000001878 scanning electron micrograph Methods 0.000 description 14
- 238000002441 X-ray diffraction Methods 0.000 description 13
- 125000004429 atom Chemical group 0.000 description 13
- 238000001354 calcination Methods 0.000 description 12
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 12
- 229910052786 argon Inorganic materials 0.000 description 11
- 239000000835 fiber Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000003153 chemical reaction reagent Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 9
- 238000007254 oxidation reaction Methods 0.000 description 9
- 239000003792 electrolyte Substances 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 238000011282 treatment Methods 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 229920001400 block copolymer Polymers 0.000 description 7
- 125000001072 heteroaryl group Chemical group 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229910021293 PO 4 Inorganic materials 0.000 description 6
- 125000003545 alkoxy group Chemical group 0.000 description 6
- 150000004696 coordination complex Chemical class 0.000 description 6
- 125000000623 heterocyclic group Chemical group 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 229910004493 Li(Ni1/3Co1/3Mn1/3)O2 Inorganic materials 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 5
- 125000005843 halogen group Chemical group 0.000 description 5
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 5
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000004627 transmission electron microscopy Methods 0.000 description 5
- 239000001856 Ethyl cellulose Substances 0.000 description 4
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 4
- 229910004283 SiO 4 Inorganic materials 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920001249 ethyl cellulose Polymers 0.000 description 4
- 235000019325 ethyl cellulose Nutrition 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 238000009830 intercalation Methods 0.000 description 4
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
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- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- 229910000733 Li alloy Inorganic materials 0.000 description 3
- 229910018804 Li0.8Mn0.4Ni0.4Co0.4O2 Inorganic materials 0.000 description 3
- 229910013716 LiNi Inorganic materials 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 150000002641 lithium Chemical class 0.000 description 3
- 239000001989 lithium alloy Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 229920000954 Polyglycolide Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
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- 229910052797 bismuth Inorganic materials 0.000 description 2
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- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical group CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- KBXUTBMGSKKPFL-UHFFFAOYSA-N 3-hydroxy-2-methylprop-2-enoic acid Chemical compound OC=C(C)C(O)=O KBXUTBMGSKKPFL-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
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- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 239000012691 Cu precursor Substances 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229910013733 LiCo Inorganic materials 0.000 description 1
- 229910011281 LiCoPO 4 Inorganic materials 0.000 description 1
- 229910015118 LiMO Inorganic materials 0.000 description 1
- 229910014397 LiNi1/3Co1/3Mn1/3 Inorganic materials 0.000 description 1
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- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
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- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
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- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 125000005595 acetylacetonate group Chemical group 0.000 description 1
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- 230000002776 aggregation Effects 0.000 description 1
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- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
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- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
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- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- KEQHHFKPFQFWAJ-UHFFFAOYSA-M lithium;acetate;hydrate Chemical compound [Li+].O.CC([O-])=O KEQHHFKPFQFWAJ-UHFFFAOYSA-M 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
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- HIIGGQNLPWIVAG-UHFFFAOYSA-L nickel(2+);diacetate;hydrate Chemical compound O.[Ni+2].CC([O-])=O.CC([O-])=O HIIGGQNLPWIVAG-UHFFFAOYSA-L 0.000 description 1
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| US61/701,854 | 2012-09-17 | ||
| PCT/US2013/028186 WO2013130723A1 (en) | 2012-03-02 | 2013-02-28 | Lithium containing nanofibers |
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Cited By (1)
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| KR20230096446A (ko) * | 2021-12-23 | 2023-06-30 | 광운대학교 산학협력단 | 전기방사 기반 수소결합 하이브리드 나노 섬유 막 과 압력센서 및 그 제조방법 |
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| US10847810B2 (en) | 2013-10-22 | 2020-11-24 | Cornell University | Nanostructures for lithium air batteries |
| WO2015077686A1 (en) * | 2013-11-25 | 2015-05-28 | Cornell University | High capacity lithium ion battery button cells |
| ES2567647B1 (es) * | 2014-09-23 | 2017-01-31 | Acondicionamiento Tarrasense | Procedimiento para la preparación de skutteruditas nanoestructuradas del tipo cosb3 |
| WO2016126969A1 (en) * | 2015-02-04 | 2016-08-11 | Axium Ip, Llc | Silicon-carbon nanostructured composites |
| DE102015210404A1 (de) * | 2015-06-05 | 2016-12-08 | Robert Bosch Gmbh | Elektrospinnen von Kathodenaktivmaterialfasern |
| US11398627B2 (en) * | 2015-06-12 | 2022-07-26 | The Board Of Trustees Of The Leland Stanford Junior University | Cathode additives for lithium-ion batteries |
| CN108886136A (zh) | 2016-01-20 | 2018-11-23 | 康奈尔大学 | 多区域的硫电极及其制造方法 |
| CN108221066A (zh) * | 2016-12-22 | 2018-06-29 | 南京理工大学 | 一种基于气动的静电纺丝装置 |
| KR102484888B1 (ko) | 2016-12-26 | 2023-01-04 | 현대자동차주식회사 | 안정성이 향상된 이차전지용 분리막 및 이의 제조방법 |
| KR102115600B1 (ko) * | 2017-07-13 | 2020-05-26 | 주식회사 엘지화학 | 구조체의 제조방법 |
| GB201803983D0 (en) | 2017-09-13 | 2018-04-25 | Unifrax I Llc | Materials |
| WO2019150083A1 (en) | 2018-02-01 | 2019-08-08 | Thermal Ceramics Uk Limited | Energy storage device and ionic conducting composition for use therein |
| GB2576165A (en) * | 2018-08-07 | 2020-02-12 | Thermal Ceram Uk Ltd | Energy storage device and inorganic fibres for use therein |
| GB2576166A (en) * | 2018-08-07 | 2020-02-12 | Thermal Ceram Uk Ltd | Energy storage device and inorganic fibres for use therein |
| CN108682774B (zh) * | 2018-06-12 | 2022-01-14 | 桑德新能源技术开发有限公司 | 隔膜及其制备方法、锂电池 |
| US20200287207A1 (en) * | 2019-03-06 | 2020-09-10 | Nanotek Instruments, Inc. | Process for producing porous particulates of graphene shell-protected alkali metal, electrodes, and alkali metal battery |
| CN110048096A (zh) * | 2019-03-25 | 2019-07-23 | 天津大学 | 用于锂/钠离子电池负极的氧化锡/碳纤维复合材料及制备方法 |
| CN110350173B (zh) * | 2019-07-10 | 2020-08-04 | 南京海泰纳米材料有限公司 | 一种锂硫软包电池及其制备方法 |
| CN113604904A (zh) * | 2021-09-02 | 2021-11-05 | 和也健康科技有限公司 | 一种梭形三元@碳@砭石纳米纤维材料的制备方法及产品和应用 |
| CN114086321B (zh) * | 2021-11-25 | 2023-05-12 | 太原理工大学 | 一种基于同轴静电纺丝技术制备碳/硫化锂复合材料的方法 |
| CN115377606B (zh) * | 2022-08-23 | 2023-12-12 | 北京化工大学 | 一种多功能锂硫电池用高性能壳聚糖/聚丙烯腈隔膜及其制备方法和应用 |
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| EP1709219A4 (en) * | 2003-09-05 | 2008-03-05 | Univ Louisiana State | NANOFIBRES AND DEVICE FOR MANUFACTURING NANOFIBRES BY REACTIVE ELECTROLYZATION |
| US7326043B2 (en) | 2004-06-29 | 2008-02-05 | Cornell Research Foundation, Inc. | Apparatus and method for elevated temperature electrospinning |
| JP5095179B2 (ja) * | 2006-11-10 | 2012-12-12 | 株式会社東芝 | 非水電解質電池、リチウムチタン複合酸化物および電池パック |
| US7709139B2 (en) * | 2007-01-22 | 2010-05-04 | Physical Sciences, Inc. | Three dimensional battery |
| KR100934956B1 (ko) * | 2007-09-13 | 2010-01-06 | 한국과학기술연구원 | 광에너지에 의한 자가충전형 이차전지 |
| KR101037590B1 (ko) * | 2008-11-05 | 2011-05-30 | 한국과학기술연구원 | 망간산화물-전도성 금속산화물 복합층을 구비한 수퍼커패시터용 전극 및 그 제조 방법과, 이를 이용한 수퍼커패시터 |
| CZ2008763A3 (cs) * | 2008-12-03 | 2010-06-16 | Elmarco S.R.O. | Zpusob výroby nanovláken a/nebo nanovlákenných struktur fosfo-olivínu, nanovlákna fosfo-olivínu a nanovlákenná struktura tvorená nanovlákny fosfo-olivínu |
| KR101265093B1 (ko) | 2008-12-26 | 2013-05-16 | 한국과학기술연구원 | 나노 분말, 나노 잉크 및 마이크로 로드와 그 제조 방법 |
| US20120028116A1 (en) * | 2009-02-17 | 2012-02-02 | Won-Gil Choi | Composition for producing positive electrode for electricity storage device, positive electrode for electricity storage device made with said composition, and electricity storage device comprising same |
| WO2010104829A2 (en) * | 2009-03-13 | 2010-09-16 | North Carolina State University | Lithium alloy-carbon composite nanofibers and methods of fabrication |
| KR101103248B1 (ko) * | 2009-04-09 | 2012-01-10 | 주식회사 아모그린텍 | 리튬이온 2차 전지용 정극 활물질의 제조방법 |
| DE102009027449A1 (de) | 2009-07-03 | 2011-01-05 | Hochschule für angewandte Wissenschaft und Kunst Fachhochschule Hildesheim/Holzminden/Göttingen | Erfassung von Rundholzpoltern |
| US20120280435A1 (en) * | 2009-11-02 | 2012-11-08 | Basvah, Llc | Active materials for lithium-ion batteries |
| CN102668173B (zh) * | 2009-11-03 | 2015-08-12 | 阿莫绿色技术有限公司 | 具有耐热性和高强度的超细纤维多孔隔板及其制造方法以及使用所述隔板的二次电池 |
| KR101313156B1 (ko) * | 2009-12-04 | 2013-09-30 | 주식회사 아모그린텍 | 다성분계 나노 복합산화물 분말과 그 제조방법, 이를 이용한 전극의 제조방법과 이를 이용한 박막 전지 및 그 제조방법 |
| KR101092606B1 (ko) * | 2009-12-22 | 2011-12-13 | 한국과학기술연구원 | 중공 구조를 가진 금속 및 금속산화물 나노 섬유와 그 제조방법 |
| CN102803585A (zh) * | 2010-02-15 | 2012-11-28 | 康奈尔大学 | 电纺丝设备及由其生产的纳米纤维 |
| JP5679260B2 (ja) * | 2010-04-13 | 2015-03-04 | 国立大学法人山口大学 | 硫黄と導電性ポリマーよりなる複合体 |
| JP5682172B2 (ja) * | 2010-08-06 | 2015-03-11 | Tdk株式会社 | 活物質、活物質の製造方法及びリチウムイオン二次電池 |
| KR20140125416A (ko) | 2012-02-16 | 2014-10-28 | 코넬 유니버시티 | 정돈된 다공성 나노섬유들, 방법들, 및 응용들 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20230096446A (ko) * | 2021-12-23 | 2023-06-30 | 광운대학교 산학협력단 | 전기방사 기반 수소결합 하이브리드 나노 섬유 막 과 압력센서 및 그 제조방법 |
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| US20150132642A1 (en) | 2015-05-14 |
| WO2013130723A9 (en) | 2014-10-09 |
| TW201348537A (zh) | 2013-12-01 |
| JP2015515435A (ja) | 2015-05-28 |
| EP2820704A4 (en) | 2015-11-18 |
| EP2820704A1 (en) | 2015-01-07 |
| US10903482B2 (en) | 2021-01-26 |
| WO2013130723A1 (en) | 2013-09-06 |
| US20180130999A1 (en) | 2018-05-10 |
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