KR20130092275A - Method for manufacturing sulfer fertilizer and sulfer fertilizer thereof - Google Patents

Abstract

PURPOSE: A manufacturing method of a sulfur fertilizer obtains a sulfur fertilizer with excellent disease protection function by mixing sulfur with a high toxicity removal rate and a humic acid through a four-step toxicity removal process. CONSTITUTION: A manufacturing method of a sulfur fertilizer includes a step of powderizing and neutralizing sulfur; a step of adding the neutralized sulfur powder into the mixed solution of nephrite powder, green tea leaves, great duckweed, and pyroligneous liquor; a step of adding neem powder, orostachys Herba, cudranic triloba, fine charcoal, and vinegar; a step of obtaining a sulfur powder by adding tuckahoe, Aconiti Tuber, agrimony, and Gastrodiae Rhizoma; a step of mixing 200-400 parts by weight of a humic acid aqueous solution and 1500-1700 parts by weight of water into 100.0 parts by weight of the sulfur powder. In the first step, a manufacturing method of the sulfur powder includes a step of impregnating raw sulfur into the mixed solution of water, radish juice, ginger juice, garlic juice, green bean juice, and semen juice; and a step of heating the sulfur to 400-500 °C and cooling the same to 20-30 °C and repeating the same 7-10 times. [Reference numerals] (AA,CC) Treated group; (BB,DD) Control group

Description

Sulfur fertilizer manufacturing method and sulfur fertilizer manufactured thereby {METHOD FOR MANUFACTURING SULFER FERTILIZER AND SULFER FERTILIZER THEREOF}

The present invention relates to a process for producing sulfur fertilizer and a sulfur fertilizer produced thereby. More particularly, the present invention relates to a sulfur detoxification method and a sulfur fertilizer produced by mixing sulfur, humic acid and water having high detoxification rate to prevent disease and increase high quality crop production and productivity.

Chemical fertilizers are used to protect the intellect of agricultural land and produce high quality agricultural products, which are mainly used in modern agriculture. In addition to acidifying the soil, overuse has been a major contributor to environmental pollution. In addition, chemical synthetic pesticides that are used to easily control pests of plants are highly toxic substances, so there are many dangerous elements to the human body, and it takes a lot of time to decompose after use, which causes side effects and causes environmental pollution. In addition, pesticides are used only for the purpose of sterilization and insecticide, it is common to use a separate fertilizer to supplement the nutrients necessary for the growth of the crop.

In recent years, the use of sulfur to cultivate natural fertilizers and pesticides has been increasing. Sulfur is not only a major component of cystine, cysteine, and methionine among amino acids that are protein components of the human body, but it is reported to be greatly involved in the yield and quality of crops, but sulfur is toxic. However, it is used in the form of legal sulfur or MSM (Methyl Sulfonyl Methane), which can not be sprayed to crops due to the secondary pollution due to its toxicity. However, sulfur and MSM are not completely removed to prevent crop growth. Cases of harm have been reported frequently.

On the other hand, in order to prevent the dissolution of fertilizer components, humic acid (humic acid) can be generally used together. The humic acid is an active ingredient mainly contained in humus soil and its preparation method is described in US Pat. No. 4,319,014 and US Pat. No. 5,670,345. The effect is to increase soil buffering and chelate metal ions under alkaline conditions. It transforms the ingredients necessary for plant growth into available water-soluble forms to promote nutrient absorption of plants, reduce soil salts, maximize organic substances, increase microbial activity, and strengthen plant roots and stems. Although it is known that active research is being conducted, it is true that its efficacy as a fertilizer is limited because the mineral content of nitrogen, phosphorus, potassium, calcium, sodium and boron, which are nutrients necessary for plant growth, is not high.

It is an object of the present invention to provide a method for producing sulfur-containing fertilizer with high toxicity reduction rate.

Another object of the present invention is to provide a method for producing sulfur fertilizers excellent in disease prevention.

It is still another object of the present invention to provide a sulfur fertilizer capable of producing high quality functional crops with high sulfur content.

One aspect of the present invention relates to a method for producing sulfur fertilizer. The sulfur fertilizer manufacturing method includes the steps of (a) pulverizing the sulfur of the legal process; (b) detoxifying by adding the neutralized sulfur powder to the nephrite powder, green tea leaf, frog rice and wood vinegar mixture solution; (c) detoxifying by adding nim powder, wasong, gujippong, white charcoal and vinegar in step (b); (d) detoxifying by adding fugyeong, rich, straw, and cheonma in the step (c) to obtain sulfur powder; And (e) mixing 200 to 400 parts by weight of the aqueous humic acid solution and 1500 to 1700 parts by weight of water with respect to 100 parts by weight of the sulfur powder obtained in step (d).

In the step (a), the legal sulfur is immersed in raw sulfur in water, radish juice, ginger juice, garlic juice, mung bean juice and frost juice, heated to 400 ~ 500 ℃ 7 ~ 10 to the process of cooling to 20 ~ 30 ℃ It is characterized in that it is prepared by repeating once.

The mixed solution is 80 to 120 parts by weight of water, 70 to 120 parts by weight of juice, 70 to 120 parts by weight of ginger juice, 30 to 70 parts by weight of garlic juice, 30 to 60 parts by weight of mung bean juice and frost juice Characterized in that it comprises 30 to 50 parts by weight.

The pH is adjusted to 6.5 to 7.5 by adding chitosan aqueous solution to the legal sulfur pulverized in step (a).

In the step (b), the mixed solution includes 15 to 25 parts by weight of jade powder, 5 to 20 parts by weight of green tea leaves, 10 to 20 parts by weight of duckweed, and 80 to 120 parts by weight of bamboo wood vinegar, based on 100 parts by weight of raw sulfur. It is done.

In step (c), 80 to 120 parts by weight of nim powder, 70 to 100 parts by weight of feed, 40 to 70 parts by weight of gojipol, 60 to 80 parts by weight of white coal, and 80 to 120 parts by weight of vinegar are added to 100 parts by weight of green sulfur .

The step (d) is characterized by adding 150 to 250 parts by weight, rich 150 to 250 parts by weight, 10 to 30 parts by weight of straw vinegar, 10 to 30 parts by weight of cheonma with respect to 100 parts by weight of live sulfur.

Another aspect of the present invention relates to a sulfur fertilizer, characterized in that produced by the production method.

Sulfur fertilizer prepared according to the production method of the present invention contains sulfur with high toxicity reduction rate, and can produce high quality functional crops having excellent disease prevention function and high sulfur content, which is also useful for increasing farm income.

1 (a) is a photograph of the flowering device of the treatment zone of Experimental Example 1,
(b) is a non-atmosphere photograph of the treatment zone of Experimental Example 1,
(c) is an apple leaf front comparison photo of the treated and normal sphere of Experimental Example 1,
(d) is a comparison photo of the apple leaf back of the treated and normal sphere of Experimental Example 1.
Figure 2 (a) is a plantation photograph of the treatment zone of Experimental Example 2,
(b) is a comparative photograph of the treatment and general spheres 1 to 3 of Experimental Example 2,
(c) is the test report of the treatment tool of Experimental Example 2.
Figure 3 (a) is a photo of cabbage plantation of Experimental Example 3,
(b) is a photograph comparing the size of the treated cabbage of Experimental Example 3 with the cap.
Figure 4 (a) is a cotton plantation photograph of Experimental Example 4,
(b) is a photograph showing the treated cotton of Experimental Example 4.
5 is a comparative photograph of the general sphere (a) and the treatment (b) of Experimental Example 5.

The manufacturing method of the sulfur fertilizer according to the present invention will be described in detail step by step.

Here, unless otherwise defined in the technical terms and the scientific terms used, those having ordinary skill in the art to which the present invention belongs have the same meaning as commonly understood by those skilled in the art.

(1) Live sulfur decontamination stage

Raw sulfur with a purity of 99.9% is immersed in water, radish juice, ginger juice, garlic juice, mung bean juice and frost juice mixed solution for 10-15 hours, which are known to have the effect of removing toxic components of sulfur.

The mixed solution is 80-120 parts by weight of water, 70-120 parts by weight of juice, 70-120 parts by weight of ginger juice, 30-70 parts by weight of garlic juice, 30-60 parts by weight of mung bean juice and frost juice It contains 30 to 50 parts by weight, and has an excellent detoxification effect in the above range. The water used at this time is any type of drinking water, weak water, etc., distilled water is preferred.

(2) repeated heating and cooling steps of sulfur

The detoxified sulfur is put in a container and heated to 400 to 500 ° C. and then cooled to 20 to 30 ° C. The process of heating and cooling the cooled sulfur back to a temperature in the above range is repeated 7-10 times.

When heated to the above temperature, the sulfur melts to become a liquid phase, and the sulfur is denatured while repeating a process of cooling and heating it again several times, thereby more effectively performing toxin removal of sulfur.

(3) sulfur grinding and pH adjusting step

The sulfur detoxified by the heating and cooling is dried and pulverized to obtain a powder form by sieving through a sieve of 200 to 300 mesh. The chitosan aqueous solution is added to the sulfur powder to adjust the pH to 6.5 to 7.5. Chitosan is a material belonging to polysaccharides widely present in nature, prepared by deacetylating crustaceans, such as crabs and shrimps, and chitin present in arthropods and molluscs, and in the present invention, edible chitosan commercially available Edible chitosan aqueous solution diluted in 1: 10-15 weight ratio in water can be used.

In addition, it is possible to detoxify 10-15 hours after mixing by adding Jijisu and chitosan aqueous solution for the purpose of further removing the toxicity of the neutralized sulfur powder. The Jijangsu refers to water that is filtered and precipitated with foreign substances after pouring water after stirring by pouring uncontaminated ocher in a bowl. The aqueous chitosan solution is commercially available edible chitosan in water 1:10 to Edible chitosan aqueous solution diluted to 15 weight ratio can be used. The mixed solution may include 300 to 400 parts by weight of Jijisu, 5 to 10 parts by weight of an edible chitosan aqueous solution, based on 100 parts by weight of live sulfur. The detoxification effect of sulfur is excellent in the above range.

(4) Sulfur Second Decontamination Stage

To further detoxify the sulfur, add jade powder, green tea leaf, duckweed, and bamboo vinegar to the mixed solution of step (3), mix, and add 20 to 25 hours for detoxification.

The mixed solution includes 15 to 25 parts by weight of nephrite powder, 5 to 20 parts by weight of green tea leaves, 10 to 20 parts by weight of frog rice, and 80 to 120 parts by weight of bamboo wood vinegar, in the above range. The effect is excellent.

The nephrite powder is collected by pulverizing the nephrite and then sieved through a sieve of 3 to 500 mesh to use in the form of fine powder.

The green tea leaf refers to the leaves of the evergreen sub-tree belonging to the tea tree, the young leaves of the tea tree steamed or heated to suppress the action of the enzyme to be used and dried to use.

The duckweed is a yearly floating plant belonging to the duckweed family, mainly harvested in July-September and used to dry in daylight, and has excellent sulfur removal effect.

The bamboo wood vinegar is a liquid obtained by separating the gas generated from the process of carbonization by heating the bamboo and pyrolyzing at a high temperature by polymerization reaction. use.

(5) Sulfur third decontamination stage

In order to further decontaminate sulfur, 80 to 120 parts by weight of Nim powder, 70 to 100 parts by weight, guasong, 40 to 70 parts by weight, and white sand 60 to 80 parts by weight of 100 parts by weight of raw sulfur in the mixed solution of step (4). Add 80 to 120 parts by weight of vinegar and vinegar, mix, and leave for 20 to 25 hours to detoxify.

The neem powder is used for insecticides and fungicides, organic fertilizers for soil improvement, and used to precipitate and wash the leaves and seeds of neem to remove the epidermis and dry it.

It is known that the above-mentioned wort is excellent in the admiral effect, and it is preferable to dry the flower or stem after washing with water and use it as a powder.

The Gujippong is preferably dried and crushed after washing the flowers and stems, roots and seeds of Gujippong tree to use in powder form.

The charcoal is produced by carbonizing charcoal at 1000 ° C. or higher in a kiln, and has the effect of adsorbing and filtering foreign substances and toxic substances contained in the powdered sulfur due to the characteristics of porous charcoal.

(6) Sulfur Fourth Decontamination Stage

In order to further detoxify sulfur in the mixed solution of step (5) with respect to 100 parts by weight of raw sulfur 150-250 parts by weight, rich 150-250 parts by weight, 10-30 parts by weight of straw thin herbs, 10-30 parts by weight Add, mix, leave for 7 to 10 days to detoxify and filter using a filter paper to obtain a sulfur powder.

The filtered sulfur powder has a particle size of 100 ~ 350㎛, can easily prepare the sulfur fertilizer of the present invention in the above range.

The bokyeong is a kind of mushrooms parasitic on the roots of pine trees, such as diuretic effect, sedation effect, strengthening of mental and physical contraction, and its various effects are excellent. Do.

The rich can be used primarily as a natural root as a tuber of the buttercups of the form of the Taro similar to Taro.

The straw herb is a perennial plant belonging to the family Rosaceae, it is preferable to crush the flowers, leaves or roots of the straw herb after washing with water to use it in powder form.

The cheonma is a perennial plant of the orchid family, used to chop the tuber of cheonma.

(7) sulfur fertilizer manufacturing stage

With respect to 100 parts by weight of the sulfur powder obtained, 200 to 400 parts by weight of aqueous humic acid solution and 1500 to 1700 parts by weight of water were mixed and stirred at 70 to 90 ° C. for 2 to 3 hours to prepare a sulfur fertilizer. At this time, the water used is any type of drinking water, weak water, etc., distilled water is preferred.

The aqueous humic acid solution has the effect of increasing the fertilizer absorption of the sulfur component of the present invention due to the insoluble salt solubilization in the soil, the chelate function of the cationic nutrient material and the increase in the cell membrane osmotic force, water 1500 ~ 2000 weight based on 100 parts by weight of water-soluble humic acid Dilution with water to prepare an aqueous humic acid solution. When preparing the sulfur fertilizer in the mixing ratio can easily achieve the object of the present invention.

Another aspect of the present invention relates to a sulfur fertilizer, characterized in that produced by the sulfur fertilizer manufacturing method. The sulfur fertilizer produced by the method of the present invention contains sulfur with high toxicity reduction rate, and the crops cultivated using the sulfur fertilizer of the present invention with excellent disease prevention function can produce high quality functional crops with high sulfur content. It is also useful for increasing profits.

Hereinafter, the configuration and operation of the present invention will be described in more detail with reference to preferred embodiments of the present invention. However, the following examples are provided to aid understanding of the present invention, and the scope of the present invention is not limited to the following examples. Details that are not described herein will be omitted since those skilled in the art can sufficiently infer technically.

Example  1: sulfur fertilizer manufacturing

1 kg of distilled water, 0.8 kg of radish juice, 1.1 kg of ginger juice, 0.6 kg of garlic juice, 0.4 kg of mung bean juice, and 0.4 kg of frost juice were prepared to prepare a solution. Soaked 2 kg of fresh sulfur with a purity of 99.9% in the mixed solution for 15 hours and filtered Filtration was carried out to produce legal sulfur. The sulfur was put into a conventional earthenware and heated to 500 ° C. and then cooled to 25 ° C. by repeating the process seven times, and pulverized in a 300 mesh net to prepare a sulfur powder.

200 g of edible chitosan commercially available in the sulfur powder was adjusted by adding an aqueous solution of edible chitosan diluted with 2 kg of distilled water until pH 7.0, and then, 6 kg of Jijisoo and 200 g of edible chitosan solution were added and mixed for 10 hours to detoxify. Add 0.15kg of nephrite powder and 0.1kg of green tea leaf, 0.2kg of frog rice, 1.0kg of bamboo grass liquor to the mixed solution, add 20 kg of detoxification and detoxify it, add 1.1kg of powder, 0.8kg of wasong, 0.5kg of Gujippong, 0.7 kg of white charcoal and 1.1 kg of vinegar were added for 10 hours to detoxify.

Fukgyeong 2.0kg, rich 2.0kg, straw sand 0.25kg, 0.3kg Cheonma was added to the mixed solution and mixed for 7 days to detoxify and filtered using filter paper to obtain detoxified sulfur powder. 300g of an aqueous humic acid was mixed with 2.7kg of water to prepare 3kg of an aqueous humic acid solution. 1kg of the sulfur powder was mixed with 3kg of an aqueous humic acid and 15kg of distilled water, followed by stirring at 80 ° C. for 3 hours to prepare a sulfur fertilizer.

Experimental Example  1: apple cultivation

In order to clarify the effect of sulfur fertilizer according to the present invention in apple cultivation, flowering, fruiting, hypertrophy of the treatment sphere sprayed with sulfur fertilizer according to Example 1 and the general sphere sprayed with commercial fertilizer (Comparative Example 1) Color, sugar, and hardness were compared.

In the treatment zone, the sulfur fertilizer of Example 1 of the present invention was diluted in water at a ratio of 1: 500, and was cultivated with the members of the Hanwoo Farming Association in 2010-2011 at a plantation area of 10,000 pyeong, located in Jinju-myeon, Cheongsong-gun, Gyeongbuk. In the general sphere, Comparative Example 1 was used, and the rest were all grown under the same conditions, and the results obtained by selecting and measuring 20 samples each are shown in Table 1 and FIG. 1.

Referring to Table 1 and FIG. 1, it can be seen that the treatment has superior results in all respects to the general treatment.

In particular, if the fruit is too large, the tree should be fallen down or artificially pruned according to the nutritional supply by itself. Production can contribute significantly to farm income.

division Flowering and fruiting Hypertrophy Color Sugar content
(brix) pesticide
Frequency of use output/
1 tree Sulfur content
(%) Treatment Example 1 Great Very good Great 15.2 8 times 35 kg 0.017 General Comparative Example 1 usually usually usually 13.4 About 20 times 30 kg 0.0077

Experimental Example  2: rice cultivation

In order to clarify the effect of increasing the production of sulfur fertilizer, prevention of diseases and taste in the cultivation of rice, spraying treatment equipment spraying sulfur fertilizer of Example 1 and commercially available sulfur fertilizer (Comparative Examples 1 to 3) The grain count and sulfur content of one treatment were compared.

In the treatment section, the sulfur fertilizer of Example 1 was diluted 1: 500 in water and cultivated from June to September 2010 at the planting site of Seoryong Farming Association, located in Seosan, using soil irrigation method. General fertilizer sold (Comparative Example 1-3) was used, and the rest were all grown under the same conditions, and the averaged results of the 20 selected samples were shown in Table 2 below.

Referring to Table 2 and Figure 2, the treatment (Example 1) is less than the normal ball (Comparative Examples 1-3), the number of grains and rice grains and grain number increased about 20%, the duration of the implementation While weather conditions such as typhoons were poor, the yield difference increased.

In addition, referring to the inspection report (c) of FIG. 2, it can be seen that the sulfur content of the treated rice is high as 0.07%, which may contribute to farm income as a functional rice.

Item Average weight  Average number of grains Average sulfur content Treatment Example 1 3.628 g 151 (3) 0.070% General Comparative Example 1 2.868 g 109 (8) 0.038% Comparative Example 2 2.958 g 105 (6) 0.041% Comparative Example 3 2.112 g 115 (18) 0.032%

Experimental Example  3: Chinese cabbage cultivation

In order to examine the effect of sulfur fertilizer according to the present invention on the representative cabbage cultivation among leafy vegetables, in the large cabbage cultivation complex located in Anjung-eup, Pyeongtaek-si, the fertilizer spraying the sulfur fertilizer of Example 1 and commercial commercial fertilizer (commercially available) Comparative Example 1) The average weight, the number of times of pesticide use, and the detected sulfur component of the treated area were compared.

In the treatments, the sulfur fertilizer of Example 1 was diluted with water at a ratio of 1: 500 and cultivated using the soil control method. In Comparative Example 1, the rest of the specimens were cultivated under the same conditions. And the results are shown in Table 3 and FIG.

Referring to Table 3 below, the number of times the pesticide use of the treatment is less, the sulfur content of the treatment is 0.103%, it can be confirmed that more than twice as high as normal. Therefore, the sulfur fertilizer according to the present invention can be seen that the disease prevention function is superior to the existing fertilizer and can produce crops with excellent functionality.

Item Treatment tool (Example 1) General phrase (comparative example 1) Average weight 4.0kg 3.5 kg Pesticide Use Count Episode 2 4 times Sulfur content 0.103% 0.049%

Experimental Example  4: cotton cultivation

In order to examine the effect of sulfur fertilizer according to the present invention on cotton cultivation, cotton cultivation was carried out twice from the test plant located in Namangan Agricultural University, Uzbekistan.

In the treatment section, the sulfur fertilizer prepared in Example 1 was diluted with water in a ratio of 500 and grown using the soil irrigation method. In the general section, commercial fertilizer (comparative example 1) was used, and the rest were all the same. It was cultivated under conditions. Figure 4 shows a cotton plantation (a) and a photo (b) of the treated cotton.

As a result of using the sulfur fertilizer of the present invention the yield increased by about 20%, it was able to produce cotton with excellent quality.

In particular, the grains of cotton burst between September and October, and harvesting in early September is common, but the sulfur fertilizer according to the present invention shows a phenomenon that crops burst from the end of August to produce cotton of good quality. It was confirmed.

Experimental Example  5: pepper cultivation

In order to examine the effect of sulfur fertilizer according to the present invention on pepper cultivation, pepper cultivation was carried out together with the official in charge of the region from April 2010 to September 2011 in Daklak, Vietnam's main production area.

In the treatment section, the sulfur fertilizer prepared in Example 1 was cultivated in a method of diluting foliar by diluting it in water at a ratio of 1: 500, and in the general ward, a commercial fertilizer (comparative example 1) was used. It was cultivated under conditions. Figure 5 shows a contrast picture of the general sphere (a) and the treatment (b) of the pepper tree.

Pepper cultivated using the sulfur fertilizer of the present invention showed an increase of about 20% more than the conventional bulb (Comparative Example 1) using the conventional fertilizer, harvested about 15 days early harvest, the quality was better.

Claims (8)

(a) pulverizing and neutralizing legal sulfur;
(b) detoxifying by adding the neutralized sulfur powder to the nephrite powder, green tea leaf, duckweed, and wood vinegar mixture solution;
(c) detoxifying by adding nim powder, wasong, gujippong, white charcoal and vinegar in step (b);
(d) detoxifying by adding fugyeong, rich, straw, and cheonma in the step (c) to obtain sulfur powder; And
(e) a sulfur fertilizer manufacturing method comprising a; mixing 100 parts by weight of the sulfur powder obtained in step (d), 200 to 400 parts by weight of aqueous humic acid solution and 1500 to 1700 parts by weight of water.
The method of claim 1,
In the step (a), the legal sulfur is immersed in raw sulfur in water, radish juice, ginger juice, garlic juice, mung bean juice and frost juice, heated to 400 ~ 500 ℃ 7 ~ 10 to the process of cooling to 20 ~ 30 ℃ Sulfur fertilizer manufacturing method characterized in that it was produced by repeating once.
The method of claim 2,
The mixed solution is 80 to 120 parts by weight of water, 70 to 120 parts by weight of juice, 70 to 120 parts by weight of ginger juice, 30 to 70 parts by weight of garlic juice, 30 to 60 parts by weight of mung bean juice and frost juice Sulfur fertilizer manufacturing method comprising 30 to 50 parts by weight.
The method of claim 1,
Sulfur fertilizer manufacturing method characterized in that the pH is adjusted to 6.5 to 7.5 by adding an aqueous chitosan solution to the legal sulfur pulverized in the step (a).
The method of claim 1,
In the step (b), the mixed solution includes 15 to 25 parts by weight of jade powder, 5 to 20 parts by weight of green tea leaves, 10 to 20 parts by weight of duckweed, and 80 to 120 parts by weight of bamboo wood vinegar, based on 100 parts by weight of raw sulfur. Sulfur fertilizer manufacturing method.
The method of claim 1,
In step (c), 80 to 120 parts by weight of Nim powder, 70 to 100 parts by weight, Gujippong 40 to 70 parts by weight, 60 to 80 parts by weight of white charcoal and 80 to 120 parts by weight of vinegar are added to 100 parts by weight of raw sulfur. Sulfur fertilizer manufacturing method characterized in that.
The method of claim 1,
Sulfur fertilizer production, characterized in that for adding 100 parts by weight of raw sulfur in step (d) 150 to 250 parts by weight, rich 150 to 250 parts by weight, 10 to 30 parts by weight of straw vinegar, 10 to 30 parts by weight of cheonma Way.
Sulfur fertilizer, characterized in that produced by the manufacturing method of any one of claims 1 to 7.

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