KR101482038B1 - Method for manufacturing sulfer fertilizer and sulfer fertilizer thereof - Google Patents

Abstract

The present invention relates to a method for producing sulfur fertilizer and a sulfur fertilizer produced by the method, comprising the steps of: (a) pulverizing and neutralizing legal sulfur; (b) adding the neutralized sulfur to a mixture of nephrite powder, green tea leaf, fried rice, and wood vinegar to remove them; (c) adding the ginseng powder, waseong, gujippon, white coal, and vinegar to the step (b); (d) adding sulfuric acid, boric acid, sandalwood herb, or chewing gum in step (c), thereby obtaining a sulfur powder; And (e) mixing 200-400 parts by weight of humic acid aqueous solution and 1500-1700 parts by weight of water with respect to 100 parts by weight of the sulfur powder obtained in step (d), wherein the humic acid aqueous solution comprises 100 parts by weight of humic acid, And may be diluted in 1500 to 2000 parts by weight of water.

Description

METHOD FOR MANUFACTURING SULFER FERTILIZER AND SULFER FERTILIZER THEREOF FIELD OF THE INVENTION [0001]

The present invention relates to a process for producing sulfur fertilizer and a sulfur fertilizer produced thereby. More particularly, the present invention relates to a sulfur decontamination method and a sulfur fertilizer produced by mixing sulfur, humic acid and water having a high toxic removal rate to prevent disease and increase production of high quality crops and productivity.

The chemical fertilizer, which is used to protect the intellect of agricultural land and used to produce high quality agricultural products, which is mainly used in modern agriculture, is made up only of essential ingredients suitable for the growing season of crops and can be conveniently used by users. Not only does it acidify the soil, but it also causes environmental pollution due to overuse. In addition, chemical synthetic pesticides used to easily rescue plant insects are very toxic substances, so there are a lot of dangerous elements in the human body and it takes a lot of time to decompose after use, which causes side effects and causes environmental pollution. In addition, pesticides are used only for sterilization and insecticidal purposes, and it is common to use a separate fertilizer to supplement the nutrients required for crop growth.

In recent years, there has been an increasing number of cases of using sulfur for the use of natural fertilizers and pesticides. Sulfur is not only a major component of cystine, cysteine, and methionine among the amino acids of human body protein, but it is also reported to be highly involved in the yield and quality of crops. Sulfur is toxic , It is used in the form of legal sulfur or MSM (Methyl Sulfonyl Methane) which can not be sprayed enough to the crops due to the toxicity of the second pollution. However, since the sulfur and MSM are not completely removed, Damage cases are frequently reported.

On the other hand, in order to prevent leaching of the fertilizer component, humic acid may be commonly used. The humic acid is an active ingredient mainly contained in the humus soil, and its preparation method is described in U.S. Patent No. 4,319,014 and U.S. Patent No. 5,670,345. The effect is to increase the bufferability of the soil, , It is necessary to change the components necessary for plant growth into usable water-soluble form to promote nutrient absorption of plants, reduce soil salinity, maximize organic matter, increase microbial activity, and strengthen roots and stem of plants However, it is true that the nutrients required for plant growth such as nitrogen, phosphorus, potassium, calcium, sodium, and boron are not high enough to be effective as fertilizer.

It is an object of the present invention to provide a method for producing a sulfur fertilizer containing sulfur having a high toxicity reduction rate.

Another object of the present invention is to provide a method for producing sulfur fertilizer excellent in prevention of disease.

It is still another object of the present invention to provide a sulfur fertilizer capable of producing high quality functional crops having a high sulfur content.

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One aspect of the present invention relates to a method for producing sulfur fertilizer. The method for producing the sulfur fertilizer comprises the steps of: (a) pulverizing and neutralizing a sulfur-containing gas; (b) adding the neutralized sulfur to a mixture of nephrite powder, green tea leaf, fried rice, and wood vinegar to remove them; (c) adding the ginseng powder, waseong, gujippon, white coal, and vinegar to the step (b); (d) adding sulfuric acid, boric acid, sandalwood herb, or chewing gum in step (c), thereby obtaining a sulfur powder; And (e) mixing 200-400 parts by weight of humic acid aqueous solution and 1500-1700 parts by weight of water with respect to 100 parts by weight of the sulfur powder obtained in step (d), wherein the humic acid aqueous solution comprises 100 parts by weight of humic acid, And may be diluted in 1500 to 2000 parts by weight of water.
In step (a), the process sulfur is dipped in a mixed solution of water, no-juice, ginger juice, garlic juice, mung bean juice and frost juice, and heated to 400~500 ° C. to cool 20~30 ° C. to 7~10 Repeatedly.

The mixed solution is prepared by mixing 80 to 120 parts by weight of water, 70 to 120 parts by weight of juice, 70 to 120 parts by weight of ginger juice, 30 to 70 parts by weight of garlic juice, 30 to 60 parts by weight of mung bean juice, And 30 to 50 parts by weight.

In step (a), the pH of the chitosan aqueous solution may be adjusted by adjusting the pH to 6.5 to 7.5 by adding an aqueous solution of chitosan to the milled formaldehyde. The chitosan aqueous solution may be diluted with water at a ratio of 1:10 to 15 by weight.

In the step (b), 15 to 25 parts by weight of nephrite powder, 5 to 20 parts by weight of green tea leaves, 10 to 20 parts by weight of frog rice and 80 to 120 parts by weight of bamboo wood vinegar are contained in 100 parts by weight of fresh sulfur. .

In step (c), 80 to 120 parts by weight of nim powder, 70 to 100 parts by weight of feed, 40 to 70 parts by weight of gojipol, 60 to 80 parts by weight of white coal, and 80 to 120 parts by weight of vinegar are added to 100 parts by weight of green sulfur .

In step (d), 150 to 250 parts by weight of bamboo, 150 to 250 parts by weight, 10 to 30 parts by weight of straw, and 10 to 30 parts by weight of rhizome are added to 100 parts by weight of fresh sulfur.

The sulfur fertilizer produced according to the production method of the present invention contains sulfur having a high toxicity reduction rate, and is capable of producing high-quality functional crops having an excellent disease-preventing function and high sulfur content, which is useful for increasing the profitability of the farm.

1 (a) is a photograph of the flowering period of the treatment area of Experimental Example 1,
(b) is a photograph of the treatment in Experimental Example 1,
(c) is a comparative photograph of the apple leaf front face of the treated and general sphere of Experimental Example 1,
(d) is a comparative photograph of the apple leaf back surface of the treated and general sphere of Experimental Example 1. Fig.
2 (a) is a photograph of the cultivation area of the treatment plot of Experimental Example 2,
(b) is a comparative photograph of the treatment group of Experimental Example 2 and General Sections 1 to 3,
(c) is an inspection report of the treatment area of Experimental Example 2.
3 (a) is a photograph of cabbage cultivation in Experimental Example 3,
(b) is a photograph of the size of the treated Chinese cabbage of Experimental Example 3 compared with the hat.
4 (a) is a photograph of the cotton plantation of Experimental Example 4,
(b) is a photograph showing the treatment cotton of Experimental Example 4. Fig.
5 is a comparative photograph of the general sphere (a) and the treatment sphere (b) of Experimental Example 5. Fig.

The process for producing sulfur fertilizer according to the present invention will be described step by step.

Here, unless otherwise defined in the technical terms and the scientific terms used, those having ordinary skill in the art to which the present invention belongs have a common meaning.

(1) Sewage Sulfur Advisory Stage

The raw sulfur of 99.9% purity is immersed in a mixture of water, juice, ginger juice, garlic juice, mung bean juice and frost juice solution for 10 ~ 15 hours which is known to have the effect of removing toxic components of sulfur.

The mixed solution is prepared by mixing 80 to 120 parts by weight of water, 70 to 120 parts by weight of juice, 70 to 120 parts by weight of ginger juice, 30 to 70 parts by weight of garlic juice, 30 to 60 parts by weight of mung bean juice, 30 to 50 parts by weight, and has excellent admiral effect in the above range. The water to be used at this time may be any kind of water such as drinking water and weak water, but distilled water is preferable.

(2) Repetition of heating and cooling of sulfur

The decontaminated sulfur is placed in a container, heated to 400 to 500 ° C, and then cooled to 20 to 30 ° C. The process of heating and cooling the cooled sulfur to the above range is repeated 7 to 10 times.

When heated to the above temperature, the sulfur is melted into a liquid phase, and the sulfur is denatured by repeating the process of cooling and reheating the sulfur several times, so that the sulfur can be more effectively removed from the toxin.

(3) Sulfur grinding and pH control step

The decontaminated sulfur is dried and pulverized by the heating and cooling, and is sieved into a powder form in a size of 200 to 300 mesh. The pH of the sulfur powder is adjusted to 6.5 to 7.5 by adding an aqueous chitosan solution. Chitosan is produced by deacetylation of chitin present in crustaceans such as crabs, shrimps, and quasars and molluscs. It belongs to polysaccharides which are widely present in nature. In the present invention, edible chitosan which can be easily purchased commercially An aqueous chitosan solution of edible chitosan diluted with water at a ratio of 1:10 to 15 can be used.

In addition, for the purpose of further removing the toxicity of the neutralized sulfur powder, it is possible to add an aqueous solution of chrysotile and chitosan and mix them for 10-15 hours. The chitosan aqueous solution is prepared by adding edible chitosan, which is commercially available, to water in a ratio of 1:10 to 1: 1, 15 aqueous chitosan solution diluted with water may be used. The mixed solution may contain 300 to 400 parts by weight of triglyceride and 5 to 10 parts by weight of the edible chitosan aqueous solution based on 100 parts by weight of the raw sulfur. In the above range, the adverse effect of sulfur is excellent.

(4) Sulfur Second Admiral Stage

To further decontaminate sulfur, add nephrite powder, green tea leaf, frog rice, and bamboo vinegar to the mixed solution of step (3), mix and decontaminate for 20 to 25 hours.

The mixed solution includes 15 to 25 parts by weight of nephrite powder, 5 to 20 parts by weight of green tea leaves, 10 to 20 parts by weight of frogbill, and 80 to 120 parts by weight of bamboo wood vinegar per 100 parts by weight of fresh sulfur. The effect is excellent.

The nephrite powder is ground and pulverized, and then sieved with a 3-500 mesh sieve to form fine powder.

The green tea leaf means a leaf of tea tree which is an evergreen tree belonging to a tea tree branch. The young leaf of the tea tree is picked and heated to inhibit the action of the enzyme and dried.

The frog is a perennial oily plant belonging to the frog family and is mainly collected in July ~ September, dried in sunlight and is excellent in the toxic removal effect of sulfur.

The bamboo wood vinegar is a liquid obtained by separating pyrolysis of bamboo by pyrolysis at high temperature and separating the smoke generated in the process of carbonization by polymerization reaction into a gas and a liquid by the trapping gas cooling principle and purifying and separating through a period of aging use.

(5) Sulfur Third Admiral Stage

To further decontaminate the sulfur, 80 to 120 parts by weight of nimpa powder, 70 to 100 parts by weight of persimmon powder, 40 to 70 parts by weight of gojippon, 60 to 80 parts by weight of white coal, And vinegar in an amount of 80 to 120 parts by weight, and the mixture is mixed for 20 to 25 hours.

The neem powder is used for insecticide and bactericide, organic fertilizer for soil improvement, and the leaves and seeds of nim are precipitated and washed, and after drying, the skin is removed and crushed.

It is known that the above-mentioned wort is excellent in the admiral effect, and it is preferable to dry the flower or stem after washing with water and use it as a powder.

It is preferable that the above-mentioned Gojippong is dried and pulverized and used in the form of powder, after flowers, roots, seeds and seeds of Gujippong tree are washed.

The carbon black is produced by carbonizing a carbonaceous material at a temperature of 1000 ° C or higher in a kiln. The porous carbon has an effect of adsorbing and filtering foreign substances and toxic substances contained in the powdery sulfur.

(6) Sulfur 4th phase

To further decontaminate the sulfur, 150 to 250 parts by weight, 150 to 250 parts by weight, 10 to 30 parts by weight of straw, 10 to 30 parts by weight of rhizome are added to the mixed solution of the step (5) And mixed for 7 to 10 days for decontamination, followed by filtration using a filter paper to obtain a sulfur powder.

The filtered sulfur powder has a particle size of 100 to 350 μm, and the sulfur fertilizer of the present invention can be easily produced within the above range.

The bamboo is a kind of mushrooms parasitic on tree roots such as pine trees and has excellent various effects such as diuretic action, soothing action, mental and physical contraction strengthening action, and is mainly used for a liquid raw material. In the present invention, Do.

The above-mentioned riches are roots of the minarial reed buds similar to the taro, and can be used mainly by natural drying.

The straw sandal is preferably a perennial plant belonging to the rose family, and the flower, leaf or root of the sandal herb is preferably ground and then used in powder form.

It is a perennial plant of orchid and uses the root of root of chunmein.

(7) Sulfur fertilizer manufacturing stage

200 to 400 parts by weight of humic acid aqueous solution and 1500 to 1700 parts by weight of water are mixed with 100 parts by weight of the obtained sulfur powder and stirred at 70 to 90 ° C for 2 to 3 hours to prepare a sulfur fertilizer. The water to be used at this time may be any kind of water such as drinking water and weak water, but distilled water is preferable.

The humic acid aqueous solution has an effect of increasing the absorption capacity of the fertilizer such as the sulfur component of the present invention due to solubilization of insoluble salts in the soil, chelating function of cationic nutrients and membrane membrane permeability, To prepare a humic acid aqueous solution. The object of the present invention can be easily achieved when the sulfur fertilizer is produced at the above mixing ratio.

Another aspect of the present invention relates to a sulfur fertilizer which is produced by the above-described method for producing sulfur fertilizer. The sulfur fertilizer produced by the method of the present invention contains sulfur having a high toxicity reduction rate and is excellent in the function of preventing disease and the crop cultivated using the sulfur fertilizer of the present invention can produce high quality functional crop with high sulfur content, It is also useful for increasing profits.

Hereinafter, the configuration and operation of the present invention will be described in more detail with reference to preferred embodiments of the present invention. However, the following examples are provided to aid understanding of the present invention, and the scope of the present invention is not limited to the following examples. The contents not described here are sufficiently technically inferior to those skilled in the art, and a description thereof will be omitted.

Example  1: Manufacture of sulfur fertilizer

1 kg of distilled water, 0.8 kg of juice, 1.1 kg of ginger juice, 0.6 kg of garlic juice, 0.4 kg of mung bean juice and 0.4 kg of frost juice were mixed to prepare a solution. 1 kg of fresh sulfur having a purity of 99.9% was immersed in the mixed solution for 15 hours, And filtered to prepare the legal sulfur. The above-described sulfur was charged into a conventional pot and heated to 500 ° C and then cooled to 25 ° C. This procedure was repeated seven times to produce a powder in the form of a powder in a 300 mesh screen.

200 kg of edible chitosan available on the market was diluted with 2 kg of distilled water to adjust pH to 7.0 and then added with 3 kg of chrysanthemum and 100 g of edible chitosan solution. To the mixed solution, 0.15 kg of nephrite powder, 0.1 kg of green tea leaves, 0.2 kg of frog rice, and 1.0 kg of bamboo wood vinegar were added and mixed. After 20 hours, the mixture was admixed with 1.1 kg of powdery mildew, 0.7 kg of white coal, and 1.1 kg of vinegar were added and left to stand for 10 hours.

2.0 kg of bamboo shoots, 2.0 kg of rich sand, 0.25 kg of sandalwood, and 0.3 kg of gum were added to the mixed solution, and the mixture was mixed for 7 days to be decontaminated and filtered using filter paper to obtain decontaminated sulfur powder. Water-soluble humic acid (150 g) was mixed with 2.85 kg of water to prepare 3 kg of humic acid aqueous solution, and 3 kg of humic acid aqueous solution and 15 kg of distilled water were mixed with 1 kg of the obtained sulfur powder and stirred at 80 캜 for 3 hours to prepare sulfur fertilizer.

Experimental Example  1: Apple cultivation

In order to investigate the effect of the sulfur fertilizer according to the present invention in the cultivation of apple, the flowering of the general fertilizer sprayed with the sulfur fertilizer according to Example 1 and the commercial fertilizer sold on the market (Comparative Example 1) Color, sugar content, and hardness.

In the treatment area, the sulfur fertilizer of Example 1 of the present invention was diluted with water at a ratio of 1: 500 and cultivated with the members of the Hanwoo Farming Union Act from 2010 to 2011 at a land area of 10,000 pyeong located in Jindong-myeon, Cheongbok-myeon, , And Comparative Example 1 was used in the general cultures. The rest of the cultivars were grown under the same conditions, and the results were averaged by measuring 20 samples each, and the results are shown in Table 1 and FIG.

Referring to the following Table 1 and FIG. 1, it can be seen that the treatments are superior to the ordinary treatments in all aspects.

Especially, when the seedling is too much, the tree must be dropped or artificially cut down by the nutrition supply itself. In the treatments, the process is omitted and the experiment is carried out in a state where it is open. As a result, Production can contribute significantly to farm income.

division Flowering and fruiting Hypertrophy Color Sugar content
(brix) pesticide
Number of Uses output/
1 tree Sulfur content
(%) Treatment Example 1 Great Very good Great 15.2 8 times Approximately 35kg 0.017 General sphere Comparative Example 1 usually usually usually 13.4 About 20 times Approximately 30kg 0.0077

Experimental Example  2: Growing rice

In order to increase the yield of the sulfur fertilizer according to the present invention, to prevent the disease and to improve the taste, the sulfur fertilizer of Example 1 and the commercially available sulfur fertilizer (Comparative Examples 1 to 3) were sprayed The number of grains and the sulfur content in one treatment were compared.

In the treatment area, the sulfur fertilizer of Example 1 was diluted with water at a ratio of 1: 500, and cultivated in a planting area of 300 pyeong in Seosan located in Seosan, from June to September 2010, (Comparative Example 1-3) were used. The rest were cultivated under the same conditions, and the results were averaged by selecting 20 samples each. The results are shown in Table 2 below.

Referring to the following Table 2 and FIG. 2, it can be seen that the treated lot (Example 1) had fewer lattice counts than the ordinary lot (Comparative Example 1-3), and the rice weight and number of grains were increased by about 20% The weather condition such as typhoon was poor, but the difference in yield was increased in bad condition.

Also, referring to the inspection report (c) of FIG. 2, the sulfur content of treated rice is as high as 0.07%, indicating that it can contribute to farm income as functional rice.

Item Average weight  Average number of grains (number of chaff) Average sulfur content Treatment Example 1 3.628 g 151 (3) 0.070% General sphere Comparative Example 1 2.868 g 109 (8) 0.038% Comparative Example 2 2.958 g 105 (6) 0.041% Comparative Example 3 2.112 g 115 (18) 0.032%

Experimental Example  3: Cabbage cultivation

In order to investigate the effect of the sulfur fertilizer according to the present invention on the typical Chinese cabbage cultivation among leafy vegetables, in the large-scale cabbage cultivation complex located in Anjung-eup, Pyeongtaek City, between 2011.10 ~ 2011.12, the treatment of the sulfur fertilizer of Example 1 and the commercial fertilizer Comparative Example 1), the number of times of pesticide application, and the detected sulfur component were compared.

In the treatments, the sulfur fertilizer of Example 1 was diluted with water at a ratio of 1: 500 and cultivated using the soil control method. In Comparative Example 1, the rest of the specimens were cultivated under the same conditions. And the results are shown in Table 3 and FIG.

Referring to Table 3, it can be seen that the number of pesticide use was lower in the treated area, while the sulfur content in the treated area was 0.103%, which was more than twice as high as that in the general sphere. Therefore, it can be seen that the sulfur fertilizer according to the present invention is capable of producing a crop having superior function and superior function than the conventional fertilizer.

Item Treatment (Example 1) General Sphere (Comparative Example 1) Average weight 4.0kg 3.5kg Number of pesticide use Episode 2 4 times Sulfur content 0.103% 0.049%

Experimental Example  4: Cotton cultivation

In order to investigate the effect of sulfur fertilizer according to the present invention on cotton cultivation, cotton cultivation was carried out twice from April, 2010 to October, 2011 at a test plant located in Uzbekistan or Mangangan Agricultural University.

In the treated area, the sulfur fertilizer prepared in Example 1 was diluted with water at a ratio of 1: 500 and cultivated using the soil-rooting method. In the general district, a commercially available common fertilizer (Comparative Example 1) was used, Lt; / RTI > Fig. 4 shows the cotton plantation site (a) and the photograph of the treatment cotton (b).

As a result of using the sulfur fertilizer of the present invention, a production amount of about 20% was increased, and cotton of excellent quality could be produced.

Particularly, cotton seedlings bloom between September and October, and it is generally harvested in early September. However, the sulfur fertilizer according to the present invention shows a phenomenon that the seedlings are popped from the end of August, so that it is possible to produce high quality cotton Respectively.

Experimental Example  5: pepper cultivation

In order to investigate the effect of sulfur fertilizer according to the present invention on pepper cultivation, black pepper cultivation was carried out in Daklak, which is the main production area of Vietnam, from October 4 to 2011,

In the treated area, the sulfur fertilizer prepared in Example 1 was diluted with water at a ratio of 1: 500 and foliarly fertilized. In the general district, a commercially available common fertilizer (Comparative Example 1) was used, Lt; / RTI > Fig. 5 shows a contrast photograph of the general plant (a) and the treatment plant (b) of the pepper tree.

The pepper cultivated using the sulfur fertilizer of the present invention showed a 20% increase in yield compared to the general fertilizer using conventional fertilizer (Comparative Example 1), early harvest about 15 days, and superior quality.

Claims (8)

(a) neutralizing the process sulfur by grinding;
(b) adding the neutralized sulfur to the mixture of nephrite powder, green tea leaf, fried rice, and vinegar to remove them;
(c) adding the ginseng powder, waseong, gujippon, white coal, and vinegar to the step (b);
(d) adding sulfuric acid, boric acid, sandalwood herb, or chewing gum in step (c), thereby obtaining a sulfur powder; And
(e) 200 to 400 parts by weight of humic acid aqueous solution and 1500 to 1700 parts by weight of water, based on 100 parts by weight of the sulfur powder obtained in the step (d)
Wherein the humic acid aqueous solution is prepared by diluting 100 parts by weight of humic acid with 1500 to 2000 parts by weight of water.
The method according to claim 1,
In step (a), the process sulfur is dipped in a mixed solution of water, no-juice, ginger juice, garlic juice, mung bean juice and frost juice, and heated to 400~500 ° C. to cool 20~30 ° C. to 7~10 Wherein the sulfur fertilizer is produced by repeating the above steps.
3. The method of claim 2,
The mixed solution is prepared by mixing 80 to 120 parts by weight of water, 70 to 120 parts by weight of juice, 70 to 120 parts by weight of ginger juice, 30 to 70 parts by weight of garlic juice, 30 to 60 parts by weight of mung bean juice, And 30 to 50 parts by weight of the composition.
The method according to claim 1,
In step (a), the pH of the chitosan aqueous solution is adjusted to 6.5 to 7.5,
Wherein the aqueous chitosan solution is prepared by diluting chitosan in water at a weight ratio of 1:10 to 15.
The method according to claim 1,
In the step (b), 15 to 25 parts by weight of nephrite powder, 5 to 20 parts by weight of green tea leaves, 10 to 20 parts by weight of frog rice and 80 to 120 parts by weight of bamboo wood vinegar are contained in 100 parts by weight of fresh sulfur. By weight.
The method according to claim 1,
In step (c), 80 to 120 parts by weight of nim powder, 70 to 100 parts by weight of feed, 40 to 70 parts by weight of gojipol, 60 to 80 parts by weight of white coal, and 80 to 120 parts by weight of vinegar are added to 100 parts by weight of green sulfur Wherein the method comprises the steps of:
The method according to claim 1,
Wherein in step (d), 150 to 250 parts by weight of bamboo, 150 to 250 parts by weight, 10 to 30 parts by weight of straw, and 10 to 30 parts by weight of rhizome are added to 100 parts by weight of fresh sulfur. Way.
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