KR20090115197A - 코발트 함유막 형성 재료, 및 상기 재료를 이용한 코발트 실리사이드막의 제조 방법 - Google Patents
코발트 함유막 형성 재료, 및 상기 재료를 이용한 코발트 실리사이드막의 제조 방법 Download PDFInfo
- Publication number
- KR20090115197A KR20090115197A KR1020097018337A KR20097018337A KR20090115197A KR 20090115197 A KR20090115197 A KR 20090115197A KR 1020097018337 A KR1020097018337 A KR 1020097018337A KR 20097018337 A KR20097018337 A KR 20097018337A KR 20090115197 A KR20090115197 A KR 20090115197A
- Authority
- KR
- South Korea
- Prior art keywords
- cobalt
- containing film
- forming material
- group
- film forming
- Prior art date
Links
- 229910017052 cobalt Inorganic materials 0.000 title claims abstract description 104
- 239000010941 cobalt Substances 0.000 title claims abstract description 104
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 239000000463 material Substances 0.000 title claims abstract description 62
- 229910021332 silicide Inorganic materials 0.000 title claims abstract description 35
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 40
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 16
- 229910052710 silicon Inorganic materials 0.000 claims description 16
- 239000010703 silicon Substances 0.000 claims description 16
- YDLSIWIVJBEBJO-UHFFFAOYSA-N C[Si](C)(C)C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](C)(C)C Chemical compound C[Si](C)(C)C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](C)(C)C YDLSIWIVJBEBJO-UHFFFAOYSA-N 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- MYXUPMPIEKAGJM-UHFFFAOYSA-N FC(F)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(F)(F)F Chemical compound FC(F)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(F)(F)F MYXUPMPIEKAGJM-UHFFFAOYSA-N 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 125000001153 fluoro group Chemical group F* 0.000 claims description 5
- 238000001179 sorption measurement Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 4
- 238000005229 chemical vapour deposition Methods 0.000 abstract description 24
- 238000002844 melting Methods 0.000 abstract description 11
- 230000008018 melting Effects 0.000 abstract description 11
- 239000007788 liquid Substances 0.000 abstract description 8
- 150000001868 cobalt Chemical class 0.000 abstract description 3
- 239000010408 film Substances 0.000 description 92
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 24
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000003786 synthesis reaction Methods 0.000 description 12
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- -1 tribromomethyl group Chemical group 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 238000004821 distillation Methods 0.000 description 5
- 238000002411 thermogravimetry Methods 0.000 description 5
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
- 150000001869 cobalt compounds Chemical class 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- AQRLNPVMDITEJU-UHFFFAOYSA-N triethylsilane Chemical compound CC[SiH](CC)CC AQRLNPVMDITEJU-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- CIXQIEOCFNVARN-UHFFFAOYSA-N cobalt(2+);5-ethylcyclopenta-1,3-diene Chemical compound [Co+2].CC[C-]1C=CC=C1.CC[C-]1C=CC=C1 CIXQIEOCFNVARN-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- CTNGBNUAYGHKMT-UHFFFAOYSA-N 1-(trifluoromethyl)cyclopent-2-en-1-ol Chemical compound FC(F)(F)C1(C=CCC1)O CTNGBNUAYGHKMT-UHFFFAOYSA-N 0.000 description 2
- AJBCIQUULNHHIX-UHFFFAOYSA-N 1-(trifluoromethyl)cyclopenta-1,3-diene Chemical compound FC(F)(F)C1=CC=CC1 AJBCIQUULNHHIX-UHFFFAOYSA-N 0.000 description 2
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 2
- MPFSKFMSDWZJFN-UHFFFAOYSA-N FC(F)(F)C1(C=CC=C1)[Na] Chemical compound FC(F)(F)C1(C=CC=C1)[Na] MPFSKFMSDWZJFN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 2
- AEVRNKXPLOTCBW-UHFFFAOYSA-N carbon monoxide;cobalt;cyclopenta-1,3-diene Chemical group [Co].[O+]#[C-].[O+]#[C-].C=1C=C[CH-]C=1 AEVRNKXPLOTCBW-UHFFFAOYSA-N 0.000 description 2
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 2
- BKFAZDGHFACXKY-UHFFFAOYSA-N cobalt(II) bis(acetylacetonate) Chemical compound [Co+2].CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O BKFAZDGHFACXKY-UHFFFAOYSA-N 0.000 description 2
- VHTUUTHYXRLKLY-UHFFFAOYSA-N cyclopenta-1,3-dien-1-yl(trimethyl)silane Chemical compound C[Si](C)(C)C1=CC=CC1 VHTUUTHYXRLKLY-UHFFFAOYSA-N 0.000 description 2
- UCXUKTLCVSGCNR-UHFFFAOYSA-N diethylsilane Chemical compound CC[SiH2]CC UCXUKTLCVSGCNR-UHFFFAOYSA-N 0.000 description 2
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 2
- PZPGRFITIJYNEJ-UHFFFAOYSA-N disilane Chemical compound [SiH3][SiH3] PZPGRFITIJYNEJ-UHFFFAOYSA-N 0.000 description 2
- KCWYOFZQRFCIIE-UHFFFAOYSA-N ethylsilane Chemical compound CC[SiH3] KCWYOFZQRFCIIE-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000010884 ion-beam technique Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- SAOOVFHGXPTXRN-UHFFFAOYSA-N sodium;cyclopenta-2,4-dien-1-yl(trimethyl)silane Chemical compound [Na+].C[Si](C)(C)[C-]1C=CC=C1 SAOOVFHGXPTXRN-UHFFFAOYSA-N 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 2
- VEDJZFSRVVQBIL-UHFFFAOYSA-N trisilane Chemical compound [SiH3][SiH2][SiH3] VEDJZFSRVVQBIL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- SABNEEPWEHWDOJ-UHFFFAOYSA-N C(C)C1=C(C(C=C1)([SiH2]C)[Co]C1(C(=C(C=C1)CC)CC)[SiH2]C)CC Chemical compound C(C)C1=C(C(C=C1)([SiH2]C)[Co]C1(C(=C(C=C1)CC)CC)[SiH2]C)CC SABNEEPWEHWDOJ-UHFFFAOYSA-N 0.000 description 1
- SJTFRMVYXZVCFO-UHFFFAOYSA-N C(C)C=1C(C=CC=1)([SiH](C)C)[Co]C1(C(=CC=C1)CC)[SiH](C)C Chemical compound C(C)C=1C(C=CC=1)([SiH](C)C)[Co]C1(C(=CC=C1)CC)[SiH](C)C SJTFRMVYXZVCFO-UHFFFAOYSA-N 0.000 description 1
- BWEYSWXMYIOGIW-UHFFFAOYSA-N C(C)[Si](CC)(CC)C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](CC)(CC)CC Chemical compound C(C)[Si](CC)(CC)C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](CC)(CC)CC BWEYSWXMYIOGIW-UHFFFAOYSA-N 0.000 description 1
- AQUKQOLLRLSLDX-UHFFFAOYSA-N C1(C=CC=C1)[Co]C1(C(=CC=C1)CC)[SiH](C)C Chemical compound C1(C=CC=C1)[Co]C1(C(=CC=C1)CC)[SiH](C)C AQUKQOLLRLSLDX-UHFFFAOYSA-N 0.000 description 1
- JJZMMALBTBCDCE-UHFFFAOYSA-N C1(C=CC=C1)[Co]C1(C=CC=C1)C(CCC)(F)F Chemical compound C1(C=CC=C1)[Co]C1(C=CC=C1)C(CCC)(F)F JJZMMALBTBCDCE-UHFFFAOYSA-N 0.000 description 1
- FHTZDECSNNVVJT-UHFFFAOYSA-N C1(C=CC=C1)[Co]C1(C=CC=C1)C(Cl)(Cl)Cl Chemical compound C1(C=CC=C1)[Co]C1(C=CC=C1)C(Cl)(Cl)Cl FHTZDECSNNVVJT-UHFFFAOYSA-N 0.000 description 1
- HNGLWPHIEQTZFS-UHFFFAOYSA-N C1(C=CC=C1)[Co]C1(C=CC=C1)C(F)(F)F Chemical compound C1(C=CC=C1)[Co]C1(C=CC=C1)C(F)(F)F HNGLWPHIEQTZFS-UHFFFAOYSA-N 0.000 description 1
- UKEMKTXOLIZFNX-UHFFFAOYSA-N C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](C)(C)C Chemical compound C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](C)(C)C UKEMKTXOLIZFNX-UHFFFAOYSA-N 0.000 description 1
- QHZFWAAQHFADGH-UHFFFAOYSA-N C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](CC)(CC)CC Chemical compound C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](CC)(CC)CC QHZFWAAQHFADGH-UHFFFAOYSA-N 0.000 description 1
- WHRPNWYUCPFGJN-UHFFFAOYSA-N C[Si](C)(C)C1(C=CC=C1)[Co]C1(C=C(C=C1)[Si](C)(C)C)[Si](C)(C)C Chemical compound C[Si](C)(C)C1(C=CC=C1)[Co]C1(C=C(C=C1)[Si](C)(C)C)[Si](C)(C)C WHRPNWYUCPFGJN-UHFFFAOYSA-N 0.000 description 1
- NLRSDNUFUWZGKF-UHFFFAOYSA-N C[Si](C1(C=C(C=C1)[Si](C)(C)C)[Co]C1(C=C(C=C1)[Si](C)(C)C)[Si](C)(C)C)(C)C Chemical compound C[Si](C1(C=C(C=C1)[Si](C)(C)C)[Co]C1(C=C(C=C1)[Si](C)(C)C)[Si](C)(C)C)(C)C NLRSDNUFUWZGKF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- TYLBFGJMYXJUGU-UHFFFAOYSA-N ClC(Cl)(Cl)C1(C=CC=C1)[Co]C1(C=CC=C1)C(Cl)(Cl)Cl Chemical compound ClC(Cl)(Cl)C1(C=CC=C1)[Co]C1(C=CC=C1)C(Cl)(Cl)Cl TYLBFGJMYXJUGU-UHFFFAOYSA-N 0.000 description 1
- BZKFMUIJRXWWQK-UHFFFAOYSA-N Cyclopentenone Chemical compound O=C1CCC=C1 BZKFMUIJRXWWQK-UHFFFAOYSA-N 0.000 description 1
- NZTUGXCBWYHHDW-UHFFFAOYSA-N FC(C(F)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(C(C(F)(F)F)(F)F)(F)F)(C(F)(F)F)F Chemical compound FC(C(F)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(C(C(F)(F)F)(F)F)(F)F)(C(F)(F)F)F NZTUGXCBWYHHDW-UHFFFAOYSA-N 0.000 description 1
- IVYMIAQKSRYFTR-UHFFFAOYSA-N FC(C(F)(F)F)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(C(F)(F)F)(F)F Chemical compound FC(C(F)(F)F)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(C(F)(F)F)(F)F IVYMIAQKSRYFTR-UHFFFAOYSA-N 0.000 description 1
- HVRJMUFHGJDJPP-UHFFFAOYSA-N FC(C)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(C)(F)F Chemical compound FC(C)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(C)(F)F HVRJMUFHGJDJPP-UHFFFAOYSA-N 0.000 description 1
- MFDBPUSVRGOBHB-UHFFFAOYSA-N FC(C)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](C)(C)C Chemical compound FC(C)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](C)(C)C MFDBPUSVRGOBHB-UHFFFAOYSA-N 0.000 description 1
- VMJHQYAUSQXIMF-UHFFFAOYSA-N FC(CC)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(CC)(F)F Chemical compound FC(CC)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(CC)(F)F VMJHQYAUSQXIMF-UHFFFAOYSA-N 0.000 description 1
- CYKHQOPNNLXMJA-UHFFFAOYSA-N FC(CCC)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(CCC)(F)F Chemical compound FC(CCC)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)C(CCC)(F)F CYKHQOPNNLXMJA-UHFFFAOYSA-N 0.000 description 1
- TZHFDMGBJNFEND-UHFFFAOYSA-N FC(F)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](C)(C)C Chemical compound FC(F)(F)C1(C=CC=C1)[Co]C1(C=CC=C1)[Si](C)(C)C TZHFDMGBJNFEND-UHFFFAOYSA-N 0.000 description 1
- YHGKTQMJGSNIOF-UHFFFAOYSA-N [Co].c1cccc1.BrC(Br)(Br)c1cccc1 Chemical compound [Co].c1cccc1.BrC(Br)(Br)c1cccc1 YHGKTQMJGSNIOF-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 1
- ILZSSCVGGYJLOG-UHFFFAOYSA-N cobaltocene Chemical compound [Co+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 ILZSSCVGGYJLOG-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000010485 coping Effects 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000006343 heptafluoro propyl group Chemical group 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- OHUVHDUNQKJDKW-UHFFFAOYSA-N sodium;cyclopenta-1,3-diene Chemical compound [Na+].C=1C=C[CH-]C=1 OHUVHDUNQKJDKW-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229910021341 titanium silicide Inorganic materials 0.000 description 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
- MWKJTNBSKNUMFN-UHFFFAOYSA-N trifluoromethyltrimethylsilane Chemical compound C[Si](C)(C)C(F)(F)F MWKJTNBSKNUMFN-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/42—Silicides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
- C23C16/18—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metallo-organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
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JP (1) | JPWO2008111499A1 (fr) |
KR (1) | KR20090115197A (fr) |
CN (1) | CN101578390A (fr) |
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KR101384395B1 (ko) * | 2009-12-25 | 2014-04-10 | 제이에스알 가부시끼가이샤 | 결정성 코발트 실리사이드막의 형성 방법 |
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CN105503618A (zh) | 2010-11-02 | 2016-04-20 | 宇部兴产株式会社 | (酰胺氨基烷烃)金属化合物及使用所述金属化合物制备含金属的薄膜的方法 |
JP2013213269A (ja) * | 2012-04-04 | 2013-10-17 | Tokyo Electron Ltd | 成膜方法及び記憶媒体 |
JP6584150B2 (ja) * | 2014-06-09 | 2019-10-02 | 東ソー株式会社 | コバルト錯体及びその製造方法、コバルト含有薄膜及びその作製方法 |
TW201602120A (zh) * | 2014-06-09 | 2016-01-16 | 東曹股份有限公司 | 鈷錯合物及其製造方法、含有鈷的薄膜及其製作方法 |
JP6436826B2 (ja) * | 2015-03-25 | 2018-12-12 | 東ソー株式会社 | コバルト錯体及びその製造方法、コバルト含有薄膜及びその作製方法 |
JP6537365B2 (ja) * | 2015-06-22 | 2019-07-03 | 東ソー株式会社 | 置換シクロペンタジエニルコバルト錯体及びその製造方法、コバルト含有薄膜及びその作製方法 |
JP6808281B2 (ja) * | 2015-12-16 | 2021-01-06 | 東ソー株式会社 | 置換シクロペンタジエニルコバルト錯体及びその製造方法、コバルト含有薄膜及びその作製方法 |
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DE59103871D1 (de) * | 1990-07-27 | 1995-01-26 | Kali Chemie Ag | Verfahren zur Abscheidung einer Kupfer enthaltenden Schicht II. |
JP2004059544A (ja) * | 2002-07-31 | 2004-02-26 | Tosoh Corp | 置換シクロペンタジエニル銅錯体及びその製造方法 |
JP2005060814A (ja) * | 2002-12-03 | 2005-03-10 | Jsr Corp | ルテニウム化合物および金属ルテニウム膜の製造法 |
US6989457B2 (en) * | 2003-01-16 | 2006-01-24 | Advanced Technology Materials, Inc. | Chemical vapor deposition precursors for deposition of tantalum-based materials |
JP4501379B2 (ja) * | 2003-09-02 | 2010-07-14 | Jsr株式会社 | ルテニウム−シリコン混合膜を形成する方法 |
JP2006037123A (ja) * | 2004-07-22 | 2006-02-09 | Toyoshima Seisakusho:Kk | 薄膜用cvd原料及びそれを用いて得られる薄膜 |
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- 2008-03-07 KR KR1020097018337A patent/KR20090115197A/ko not_active Application Discontinuation
- 2008-03-07 JP JP2009504017A patent/JPWO2008111499A1/ja active Pending
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KR101384395B1 (ko) * | 2009-12-25 | 2014-04-10 | 제이에스알 가부시끼가이샤 | 결정성 코발트 실리사이드막의 형성 방법 |
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WO2008111499A1 (fr) | 2008-09-18 |
CN101578390A (zh) | 2009-11-11 |
JPWO2008111499A1 (ja) | 2010-06-24 |
TW200902748A (en) | 2009-01-16 |
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