KR20070099702A - 메탄올 증기 개질 촉매, 및 이를 함유하는 증기 개질기 및연료 전지 시스템 - Google Patents
메탄올 증기 개질 촉매, 및 이를 함유하는 증기 개질기 및연료 전지 시스템 Download PDFInfo
- Publication number
- KR20070099702A KR20070099702A KR1020077021822A KR20077021822A KR20070099702A KR 20070099702 A KR20070099702 A KR 20070099702A KR 1020077021822 A KR1020077021822 A KR 1020077021822A KR 20077021822 A KR20077021822 A KR 20077021822A KR 20070099702 A KR20070099702 A KR 20070099702A
- Authority
- KR
- South Korea
- Prior art keywords
- hydrogen
- catalyst
- methanol
- fuel cell
- reforming
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 133
- 239000000446 fuel Substances 0.000 title abstract description 72
- 238000001651 catalytic steam reforming of methanol Methods 0.000 title abstract description 44
- -1 steam reformers Substances 0.000 title 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 83
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 69
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 55
- 239000001257 hydrogen Substances 0.000 claims abstract description 54
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 46
- 238000002407 reforming Methods 0.000 claims abstract description 28
- 239000011787 zinc oxide Substances 0.000 claims abstract description 23
- 239000006227 byproduct Substances 0.000 claims abstract description 5
- 238000000926 separation method Methods 0.000 claims description 32
- 239000007789 gas Substances 0.000 claims description 23
- 239000000047 product Substances 0.000 claims description 23
- 238000000629 steam reforming Methods 0.000 claims description 19
- 238000010438 heat treatment Methods 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 229910001868 water Inorganic materials 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000012528 membrane Substances 0.000 abstract description 11
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract description 9
- 229910000423 chromium oxide Inorganic materials 0.000 abstract description 9
- 238000012545 processing Methods 0.000 abstract description 9
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 abstract description 8
- 150000002431 hydrogen Chemical class 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 5
- 239000002250 absorbent Substances 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 20
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical group [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 19
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 16
- 239000002994 raw material Substances 0.000 description 14
- 239000005751 Copper oxide Substances 0.000 description 13
- 229910002091 carbon monoxide Inorganic materials 0.000 description 13
- 229910000431 copper oxide Inorganic materials 0.000 description 13
- 239000012535 impurity Substances 0.000 description 13
- 239000003463 adsorbent Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 230000007246 mechanism Effects 0.000 description 7
- 239000004480 active ingredient Substances 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- 238000004146 energy storage Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 230000002269 spontaneous effect Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910001252 Pd alloy Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000003981 vehicle Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- OYPRJOBELJOOCE-IGMARMGPSA-N Calcium-40 Chemical compound [40Ca] OYPRJOBELJOOCE-IGMARMGPSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009979 protective mechanism Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006057 reforming reaction Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000011664 signaling Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
- C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
- H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
- C01B2203/041—In-situ membrane purification during hydrogen production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (1)
- 개질 촉매 베드를 함유하고, 물과 메탄올을 함유하는 증발된 원료류를 수용하도록 개조된 개질 영역;상기 개질 영역을 300 내지 500℃ 범위의 온도로 가열하는 수단;개질 촉매 베드 내에 존재하여 원료류로부터 물 및 메탄올을 증기 개질함으로써 수소 기체 및 다른 기체를 함유하는 혼합 기체류의 형성을 촉매하고, 20-80중량%의 산화아연, 및 20-80중량%의 산화크롬을 함유하는 비자연발화성 촉매; 및상기 혼합 기체류를 수용하여 이 혼합 기체류를 수소산물류와 부산물류로 분리하도록 개조된 분리 영역으로서, 상기 수소산물류는 상기 혼합 기체류보다 고농도의 수소 기체를 보유하고 상기 혼합 기체류보다 감소된 농도의 다른 기체 성분을 보유하며, 상기 부산물류는 상기 혼합 기체류보다 낮은 농도의 수소 기체를 보유하고 상기 혼합 기체류보다 높은 농도의 다른 기체 성분을 보유하는 분리 영역을 포함하는 연료 처리 시스템.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US39248202P | 2002-06-27 | 2002-06-27 | |
US60/392,482 | 2002-06-27 | ||
US10/600,808 US7128769B2 (en) | 2002-06-27 | 2003-06-20 | Methanol steam reforming catalysts, steam reformers, and fuel cell systems incorporating the same |
US10/600,808 | 2003-06-20 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR10-2004-7020907A Division KR20050013232A (ko) | 2002-06-27 | 2003-06-23 | 메탄올 증기 개질 촉매, 및 이를 함유하는 증기 개질기 및연료 전지 시스템 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20070099702A true KR20070099702A (ko) | 2007-10-09 |
KR100899914B1 KR100899914B1 (ko) | 2009-05-28 |
Family
ID=30003256
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020077021822A KR100899914B1 (ko) | 2002-06-27 | 2003-06-23 | 메탄올 증기 개질 촉매를 포함하는 증기 개질 연료 처리 장치, 및 메탄올을 증기 개질하여 수소 가스를 생성하는 방법 |
KR10-2004-7020907A KR20050013232A (ko) | 2002-06-27 | 2003-06-23 | 메탄올 증기 개질 촉매, 및 이를 함유하는 증기 개질기 및연료 전지 시스템 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR10-2004-7020907A KR20050013232A (ko) | 2002-06-27 | 2003-06-23 | 메탄올 증기 개질 촉매, 및 이를 함유하는 증기 개질기 및연료 전지 시스템 |
Country Status (10)
Country | Link |
---|---|
US (3) | US7128769B2 (ko) |
EP (1) | EP1534428B8 (ko) |
JP (1) | JP2005530675A (ko) |
KR (2) | KR100899914B1 (ko) |
CN (1) | CN1662306B (ko) |
AU (1) | AU2003247627A1 (ko) |
CA (1) | CA2483674C (ko) |
DK (1) | DK1534428T3 (ko) |
GB (1) | GB2406529B (ko) |
WO (1) | WO2004002616A2 (ko) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021230456A1 (ko) * | 2020-05-11 | 2021-11-18 | 여영찬 | 연료전지 시스템 |
KR20230036715A (ko) | 2021-09-08 | 2023-03-15 | 김슬기 | 중고폰 시세조회가 가능한 중고폰 악세사리 거래 중개 플랫폼 |
KR20230116279A (ko) | 2022-01-28 | 2023-08-04 | 김영환 | 핸드폰 수리 업체 중개 및 악세사리 판매 서비스 플랫폼 |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7967878B2 (en) | 2002-01-04 | 2011-06-28 | Meggitt (Uk) Limited | Reformer apparatus and method |
US8177868B2 (en) | 2002-01-04 | 2012-05-15 | Meggitt (Uk) Limited | Reforming apparatus and method |
US20050280392A1 (en) * | 2004-06-22 | 2005-12-22 | Nguyen Don J | Fuel cell power adapter for computer system |
KR100671681B1 (ko) * | 2005-08-12 | 2007-01-19 | 삼성에스디아이 주식회사 | 연료전지시스템 및 이에 사용하기 위한 혼합연료공급장치와물공급장치 |
US7563525B2 (en) * | 2006-02-15 | 2009-07-21 | Egt Enterprises, Inc. | Electric reaction technology for fuels processing |
CN100420517C (zh) * | 2006-05-26 | 2008-09-24 | 西南化工研究设计院 | 甲醇水蒸汽重整制氢用铜基催化剂的还原方法 |
AU2008338506A1 (en) * | 2007-12-17 | 2009-06-25 | Shell Internationale Research Maatschappij B.V. | Fuel cell-based process for generating electric power |
US20090155649A1 (en) * | 2007-12-17 | 2009-06-18 | Jingyu Cui | System and process for generating electrical power |
AU2008338503B2 (en) * | 2007-12-17 | 2011-05-19 | Shell Internationale Research Maatschappij B.V. | System and process for generating electrical power |
EP2220718A1 (en) * | 2007-12-17 | 2010-08-25 | Shell Internationale Research Maatschappij B.V. | System and process for generating electrical power |
EP2220714A1 (en) * | 2007-12-17 | 2010-08-25 | Shell Internationale Research Maatschappij B.V. | Fuel cell-based process for generating electrical power |
CN101946359A (zh) * | 2007-12-17 | 2011-01-12 | 国际壳牌研究有限公司 | 用于产生电力的基于燃料电池的方法 |
BRPI0820844A2 (pt) * | 2007-12-17 | 2015-06-16 | Shell Int Research | Processo para gerar eletricidade |
AU2008338510A1 (en) * | 2007-12-17 | 2009-06-25 | Shell Internationale Research Maatschappij B.V. | Fuel cell-based process for generating electrical power |
CN101919099A (zh) * | 2007-12-17 | 2010-12-15 | 国际壳牌研究有限公司 | 用于产生电力的基于燃料电池的方法 |
US9017436B2 (en) | 2008-08-26 | 2015-04-28 | Dcns | Fuel processing systems with thermally integrated componentry |
US20100055518A1 (en) | 2008-08-26 | 2010-03-04 | Idatech, Llc | Hydrogen-producing assemblies, fuel cell systems including the same, methods of producing hydrogen gas, and methods of powering an energy-consuming device |
US9174199B2 (en) | 2009-05-26 | 2015-11-03 | Basf Corporation | Methanol steam reforming catalysts |
WO2011063326A1 (en) * | 2009-11-20 | 2011-05-26 | Egt Enterprises, Inc. | Carbon capture with power generation |
US8920996B2 (en) | 2010-05-11 | 2014-12-30 | Dcns | Systems and methods for regulating fuel cell air flow during low loads or cold temperature operation |
EP2602228B1 (en) * | 2010-08-03 | 2017-11-08 | Panasonic Intellectual Property Management Co., Ltd. | Hydrogen generation device and fuel cell system |
WO2012099287A1 (ko) * | 2011-01-21 | 2012-07-26 | 대우조선해양 주식회사 | 상선의 전기 생산 장치 및 방법 |
CN102796656B (zh) * | 2012-08-06 | 2014-03-05 | 上海合既得动氢机器有限公司 | 一种利用生物质发电的系统及方法 |
CN109950590B (zh) * | 2019-04-02 | 2020-11-10 | 中氢新能技术有限公司 | 燃料电池甲醇重整器 |
CN112960645B (zh) * | 2019-12-14 | 2022-08-05 | 中国科学院大连化学物理研究所 | 一种自热重整制氢反应用水汽变换反应器及提高水汽变换反应co转化率的方法 |
US11618676B2 (en) | 2020-10-23 | 2023-04-04 | H2 Powertech, Llc | Systems and methods for increasing the hydrogen permeance of hydrogen-separation membranes in situ |
KR102327169B1 (ko) | 2021-07-01 | 2021-11-17 | 국방과학연구소 | 메탄올 수증기 개질 장치 및 그것을 포함하는 연료전지 시스템 |
CN117715858A (zh) | 2021-08-13 | 2024-03-15 | 巴斯夫欧洲公司 | 用于燃料电池操作的从甲醇或氨中获得高纯度氢气的方法和装置 |
Family Cites Families (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE877746C (de) * | 1951-05-05 | 1953-05-26 | Basf Ag | Verfahren zur Herstellung von Wasserstoff |
US2824620A (en) * | 1955-09-12 | 1958-02-25 | Universal Oil Prod Co | Purification of hydrogen utilizing hydrogen-permeable membranes |
US3094391A (en) * | 1960-04-22 | 1963-06-18 | Kellogg M W Co | Hydrocarbon conversion |
US3338681A (en) * | 1963-12-18 | 1967-08-29 | Union Carbide Corp | Apparatus for hydrogen generation |
US3350176A (en) * | 1964-03-24 | 1967-10-31 | Engelhard Ind Inc | Hydrogen generator |
US3336730A (en) * | 1964-11-17 | 1967-08-22 | Union Carbide Corp | Hydrogen continuous production method and apparatus |
US3469944A (en) * | 1968-05-13 | 1969-09-30 | Joseph P Bocard | Process and apparatus for the manufacture of hydrogen for fuel cells |
JPS584577B2 (ja) | 1974-12-11 | 1983-01-27 | カブシキガイシヤ ニツポンジドウシヤブヒンソウゴウケンキユウシヨ | メチルアルコ−ルカイシツヨウノ シヨクバイ |
US4003343A (en) * | 1975-04-04 | 1977-01-18 | Phillips Petroleum Company | Method and apparatus for maintaining the operating temperature in a device for reducing engine exhaust pollutants |
GB1525017A (en) * | 1975-09-29 | 1978-09-20 | British Gas Corp | Steam reforming and methanation catalysts methods of making them and processes for the production of fuel gases |
US4098960A (en) * | 1976-12-27 | 1978-07-04 | United Technologies Corporation | Fuel cell fuel control system |
US4098959A (en) * | 1976-12-27 | 1978-07-04 | United Technologies Corporation | Fuel cell fuel control system |
US4214969A (en) * | 1979-01-02 | 1980-07-29 | General Electric Company | Low cost bipolar current collector-separator for electrochemical cells |
US4468235A (en) * | 1979-02-15 | 1984-08-28 | Hill Eugene F | Hydrogen separation using coated titanium alloys |
DE2949011A1 (de) * | 1979-12-06 | 1981-06-11 | Varta Batterie Ag, 3000 Hannover | Verfahren und vorrichtung zur elektrochemischen energiegewinnung |
DE3340569A1 (de) * | 1983-11-09 | 1985-05-23 | Sued Chemie Ag | Katalysator zur herstellung von synthesegas bzw. von wasserstoff und verfahren zu dessen herstellung |
AU4695985A (en) * | 1984-09-04 | 1986-03-13 | Mitsubishi Jukogyo Kabushiki Kaisha | Process for reforming methanol |
EP0201670B1 (de) * | 1985-05-08 | 1993-05-26 | Volkswagen Aktiengesellschaft | Einrichtung zur Aufbereitung von im wesentlichen aus Methanol bestehenden Flüssigkeiten |
US4946667A (en) * | 1985-06-10 | 1990-08-07 | Engelhard Corporation | Method of steam reforming methanol to hydrogen |
FR2611194B1 (fr) * | 1987-02-19 | 1989-05-19 | Inst Francais Du Petrole | Procede de fabrication de gaz de synthese ou d'hydrogene, par conversion catalytique du methanol en phase liquide |
JP2807053B2 (ja) * | 1989-07-21 | 1998-09-30 | 三井化学株式会社 | メタノールの分解方法 |
FR2661902A1 (fr) * | 1990-05-09 | 1991-11-15 | Air Liquide | Procede et installation de production d'hydrogene a partir de methanol. |
JPH0427434A (ja) | 1990-05-23 | 1992-01-30 | Mitsubishi Heavy Ind Ltd | メタノール改質用触媒 |
EP0559816B1 (en) * | 1990-11-23 | 1997-05-28 | Vickers Shipbuilding & Engineering Limited | Application of fuel cells to power generation systems |
JP2888717B2 (ja) * | 1992-04-06 | 1999-05-10 | 公生 石丸 | エネルギー供給システム |
JP3577781B2 (ja) * | 1995-05-22 | 2004-10-13 | 富士電機ホールディングス株式会社 | 燃料電池発電装置の出力制御装置 |
US6537352B2 (en) * | 1996-10-30 | 2003-03-25 | Idatech, Llc | Hydrogen purification membranes, components and fuel processing systems containing the same |
US5997594A (en) * | 1996-10-30 | 1999-12-07 | Northwest Power Systems, Llc | Steam reformer with internal hydrogen purification |
US6221117B1 (en) * | 1996-10-30 | 2001-04-24 | Idatech, Llc | Hydrogen producing fuel processing system |
US5861137A (en) * | 1996-10-30 | 1999-01-19 | Edlund; David J. | Steam reformer with internal hydrogen purification |
US6547858B1 (en) * | 1999-03-22 | 2003-04-15 | Idatech, Llc | Hydrogen-permeable metal membrane and hydrogen purification assemblies containing the same |
US6152995A (en) * | 1999-03-22 | 2000-11-28 | Idatech Llc | Hydrogen-permeable metal membrane and method for producing the same |
US6494937B1 (en) | 2001-09-27 | 2002-12-17 | Idatech, Llc | Hydrogen purification devices, components and fuel processing systems containing the same |
US6319306B1 (en) * | 2000-03-23 | 2001-11-20 | Idatech, Llc | Hydrogen-selective metal membrane modules and method of forming the same |
DE19707814C1 (de) * | 1997-02-27 | 1998-08-20 | Dbb Fuel Cell Engines Gmbh | Brennstoffzellen-Energieerzeugungsanlage |
EP1063011B1 (de) * | 1999-05-22 | 2001-12-12 | OMG AG & Co. KG | Verwendung eines Katalysators für die Dampfreformierung von Methanol |
MX267940B (es) * | 1999-08-17 | 2009-07-03 | Battelle Memorial Institute | Reactor quimico y metodo para reacciones cataliticas de reactivo en fase gaseosa. |
US6383670B1 (en) * | 1999-10-06 | 2002-05-07 | Idatech, Llc | System and method for controlling the operation of a fuel processing system |
WO2001047800A1 (fr) * | 1999-12-28 | 2001-07-05 | Daikin Industries,Ltd. | Dispositif de modification par oxydation partielle |
JP2001357306A (ja) | 2000-06-13 | 2001-12-26 | Nagase & Co Ltd | Dvd又はcdコンテンツの提供・販売方法 |
US20020061277A1 (en) | 2000-09-25 | 2002-05-23 | Engelhard Corporation | Non-pyrophoric water-gas shift reaction catalysts |
-
2003
- 2003-06-20 US US10/600,808 patent/US7128769B2/en not_active Expired - Lifetime
- 2003-06-23 AU AU2003247627A patent/AU2003247627A1/en not_active Abandoned
- 2003-06-23 GB GB0501373A patent/GB2406529B/en not_active Expired - Lifetime
- 2003-06-23 JP JP2004517771A patent/JP2005530675A/ja active Pending
- 2003-06-23 KR KR1020077021822A patent/KR100899914B1/ko active IP Right Grant
- 2003-06-23 WO PCT/US2003/019901 patent/WO2004002616A2/en active Application Filing
- 2003-06-23 EP EP03762002.8A patent/EP1534428B8/en not_active Expired - Lifetime
- 2003-06-23 DK DK03762002.8T patent/DK1534428T3/da active
- 2003-06-23 KR KR10-2004-7020907A patent/KR20050013232A/ko not_active Application Discontinuation
- 2003-06-23 CN CN038143607A patent/CN1662306B/zh not_active Expired - Lifetime
- 2003-06-23 CA CA002483674A patent/CA2483674C/en not_active Expired - Lifetime
-
2006
- 2006-06-23 US US11/474,024 patent/US7662195B2/en not_active Expired - Lifetime
-
2009
- 2009-10-22 US US12/604,157 patent/US7736404B2/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021230456A1 (ko) * | 2020-05-11 | 2021-11-18 | 여영찬 | 연료전지 시스템 |
KR20230036715A (ko) | 2021-09-08 | 2023-03-15 | 김슬기 | 중고폰 시세조회가 가능한 중고폰 악세사리 거래 중개 플랫폼 |
KR20230116279A (ko) | 2022-01-28 | 2023-08-04 | 김영환 | 핸드폰 수리 업체 중개 및 악세사리 판매 서비스 플랫폼 |
Also Published As
Publication number | Publication date |
---|---|
CA2483674C (en) | 2006-12-19 |
KR20050013232A (ko) | 2005-02-03 |
WO2004002616A3 (en) | 2004-07-15 |
GB2406529B (en) | 2007-01-24 |
CA2483674A1 (en) | 2004-01-08 |
GB0501373D0 (en) | 2005-03-02 |
EP1534428B8 (en) | 2020-08-12 |
EP1534428A2 (en) | 2005-06-01 |
CN1662306A (zh) | 2005-08-31 |
CN1662306B (zh) | 2011-09-21 |
US20100040918A1 (en) | 2010-02-18 |
US7128769B2 (en) | 2006-10-31 |
EP1534428A4 (en) | 2006-05-17 |
GB2406529A (en) | 2005-04-06 |
AU2003247627A1 (en) | 2004-01-19 |
DK1534428T3 (da) | 2020-07-06 |
US7736404B2 (en) | 2010-06-15 |
US7662195B2 (en) | 2010-02-16 |
AU2003247627A8 (en) | 2004-01-19 |
EP1534428B1 (en) | 2020-06-10 |
US20040006915A1 (en) | 2004-01-15 |
US20060236607A1 (en) | 2006-10-26 |
KR100899914B1 (ko) | 2009-05-28 |
JP2005530675A (ja) | 2005-10-13 |
WO2004002616A2 (en) | 2004-01-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100899914B1 (ko) | 메탄올 증기 개질 촉매를 포함하는 증기 개질 연료 처리 장치, 및 메탄올을 증기 개질하여 수소 가스를 생성하는 방법 | |
US8691463B2 (en) | Thermally primed hydrogen-producing fuel cell system | |
CA2704679C (en) | Systems and methods for reliable feedstock delivery at variable delivery rates | |
CA2477294C (en) | Feedstock delivery system and fuel processing systems containing the same | |
US20070062116A1 (en) | Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same | |
US20050232855A1 (en) | Reactor with carbon dioxide fixing material | |
JP2004525488A (ja) | 貯蔵した水素を使用した燃料電池システム | |
EP1337320A2 (en) | Sulfur-absorbent bed and fuel processing assembly incorporating the same | |
US20040197616A1 (en) | Oxidant-enriched fuel cell system | |
JP4292362B2 (ja) | 固体高分子型燃料電池発電システム及び固体高分子型燃料電池発電方法 | |
CN117615988A (zh) | 氢生成组件 | |
US20020192136A1 (en) | Process for preparing a low-sulfur reformate gas for use in a fuel cell system | |
JP4931865B2 (ja) | 固体高分子型燃料電池発電システム及び固体高分子型燃料電池発電方法 | |
KR100647331B1 (ko) | 연료전지용 쉬프트 반응기, 이를 채용한 연료전지 시스템및 상기 연료전지용 쉬프트 반응기의 운전 방법 | |
JP5098073B2 (ja) | エネルギーステーション | |
JP5135606B2 (ja) | 定置型水素製造装置の起動方法 | |
JP5741510B2 (ja) | 燃料電池発電システム | |
AU2024203357A1 (en) | Hydrogen generation assemblies | |
JP2005330139A (ja) | 水素生成装置および燃料電池発電システム | |
JP2005093214A (ja) | 燃料電池用水素製造システムへの液化石油ガス供給方法 | |
CA2529998A1 (en) | Feedstock delivery system and fuel processing systems containing the same | |
JP2013159529A (ja) | 改質器を備える燃料改質装置、及びその改質器内を掃気する方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A107 | Divisional application of patent | ||
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20120511 Year of fee payment: 4 |
|
FPAY | Annual fee payment |
Payment date: 20131111 Year of fee payment: 5 |
|
FPAY | Annual fee payment |
Payment date: 20141111 Year of fee payment: 6 |
|
FPAY | Annual fee payment |
Payment date: 20150511 Year of fee payment: 7 |
|
FPAY | Annual fee payment |
Payment date: 20160406 Year of fee payment: 8 |
|
FPAY | Annual fee payment |
Payment date: 20170324 Year of fee payment: 9 |
|
FPAY | Annual fee payment |
Payment date: 20180322 Year of fee payment: 10 |