KR102580277B1 - 계층적 다공성 ts-1 분자체의 제조 방법 - Google Patents

계층적 다공성 ts-1 분자체의 제조 방법 Download PDF

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KR102580277B1
KR102580277B1 KR1020217017399A KR20217017399A KR102580277B1 KR 102580277 B1 KR102580277 B1 KR 102580277B1 KR 1020217017399 A KR1020217017399 A KR 1020217017399A KR 20217017399 A KR20217017399 A KR 20217017399A KR 102580277 B1 KR102580277 B1 KR 102580277B1
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moles
silicon
titanate
silicate
reaction
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KR1020217017399A
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Korean (ko)
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KR20210087526A (ko
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단후아 위안
지아청 싱
윈펑 쉬
종민 리우
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달리안 인스티튜트 오브 케미컬 피직스, 차이니즈 아카데미 오브 사이언시즈
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Publication of KR20210087526A publication Critical patent/KR20210087526A/ko
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Polyesters Or Polycarbonates (AREA)
KR1020217017399A 2018-11-15 2018-11-15 계층적 다공성 ts-1 분자체의 제조 방법 KR102580277B1 (ko)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2018/115719 WO2020097876A1 (fr) 2018-11-15 2018-11-15 Procédé de préparation de tamis moléculaire de ts-1 à pores hiérarchiques

Publications (2)

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KR20210087526A KR20210087526A (ko) 2021-07-12
KR102580277B1 true KR102580277B1 (ko) 2023-09-18

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Country Status (6)

Country Link
US (1) US20210403332A1 (fr)
EP (1) EP3862319A4 (fr)
JP (1) JP7393425B2 (fr)
KR (1) KR102580277B1 (fr)
AU (1) AU2018449556B2 (fr)
WO (1) WO2020097876A1 (fr)

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CN110743605B (zh) 2018-07-23 2021-07-27 中国科学院大连化学物理研究所 一种用于乙醇和苯制备乙苯的催化剂及其制备和应用
CN112537777A (zh) * 2020-11-11 2021-03-23 大连理工大学 一种钝化钛硅沸石六配位钛物种的方法
CN113210017B (zh) * 2021-04-02 2023-03-21 辽宁师范大学 有机碱、硅烷化连续改性TS-1负载Keggin结构磷钼钒酸催化剂
CN113731484B (zh) * 2021-08-26 2024-04-12 武汉理工大学 一种Pd基等级孔介孔-微孔TS-1分子筛单晶催化剂及其制备方法
CN115869962A (zh) * 2022-11-29 2023-03-31 西南化工研究设计院有限公司 一种高活性抗硫中毒低温脱硝催化剂及其制备方法

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CN108658087A (zh) 2017-03-31 2018-10-16 中国石油化工股份有限公司 一种多级孔道ts-1沸石材料及其制备方法

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CN1246224C (zh) * 2002-08-15 2006-03-22 中国石油化工股份有限公司 一种高钛含量中孔分子筛的制备方法
US6960671B2 (en) * 2002-09-20 2005-11-01 Arco Chemical Technology, L.P. Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein
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CN101327934B (zh) * 2008-07-17 2010-09-15 连云港三吉利化学工业有限公司 具有mfi结构的钛硅分子筛的制备方法
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CN108658087A (zh) 2017-03-31 2018-10-16 中国石油化工股份有限公司 一种多级孔道ts-1沸石材料及其制备方法

Also Published As

Publication number Publication date
KR20210087526A (ko) 2021-07-12
WO2020097876A1 (fr) 2020-05-22
US20210403332A1 (en) 2021-12-30
AU2018449556B2 (en) 2022-08-25
JP7393425B2 (ja) 2023-12-06
JP2022506869A (ja) 2022-01-17
EP3862319A4 (fr) 2021-10-27
AU2018449556A1 (en) 2021-06-24
EP3862319A1 (fr) 2021-08-11

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