KR102184609B1 - 탈붕소화 mww 제올라이트의 후처리 - Google Patents

탈붕소화 mww 제올라이트의 후처리 Download PDF

Info

Publication number
KR102184609B1
KR102184609B1 KR1020157012912A KR20157012912A KR102184609B1 KR 102184609 B1 KR102184609 B1 KR 102184609B1 KR 1020157012912 A KR1020157012912 A KR 1020157012912A KR 20157012912 A KR20157012912 A KR 20157012912A KR 102184609 B1 KR102184609 B1 KR 102184609B1
Authority
KR
South Korea
Prior art keywords
zeolite material
zeolite
iii
ppm
zeolitic material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020157012912A
Other languages
English (en)
Korean (ko)
Other versions
KR20150074076A (ko
Inventor
안드레이-니콜라 파르불레스쿠
제프 양
슈테판 마우러
마누엘라 가아브
카르슈텐 자이델
올가 게르라히
울리히 뮐러
Original Assignee
바스프 에스이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바스프 에스이 filed Critical 바스프 에스이
Publication of KR20150074076A publication Critical patent/KR20150074076A/ko
Application granted granted Critical
Publication of KR102184609B1 publication Critical patent/KR102184609B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/007—Borosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
KR1020157012912A 2012-10-18 2013-10-09 탈붕소화 mww 제올라이트의 후처리 Active KR102184609B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12189042 2012-10-18
EP12189042.0 2012-10-18
PCT/EP2013/071042 WO2014060261A1 (en) 2012-10-18 2013-10-09 Post-treatment of deboronated mww zeolite

Publications (2)

Publication Number Publication Date
KR20150074076A KR20150074076A (ko) 2015-07-01
KR102184609B1 true KR102184609B1 (ko) 2020-12-01

Family

ID=47046432

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020157012912A Active KR102184609B1 (ko) 2012-10-18 2013-10-09 탈붕소화 mww 제올라이트의 후처리

Country Status (13)

Country Link
US (1) US10099933B2 (enExample)
EP (1) EP2909141B1 (enExample)
JP (1) JP6267211B2 (enExample)
KR (1) KR102184609B1 (enExample)
CN (1) CN104854028B (enExample)
BR (1) BR112015008390B1 (enExample)
ES (1) ES2620030T3 (enExample)
MX (1) MX355246B (enExample)
MY (1) MY169039A (enExample)
RU (1) RU2638851C2 (enExample)
SG (1) SG11201503019SA (enExample)
WO (1) WO2014060261A1 (enExample)
ZA (1) ZA201503155B (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6367812B2 (ja) 2012-10-18 2018-08-01 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ゼオライト材料の後処理
US10196276B2 (en) * 2014-06-06 2019-02-05 Basf Se Synthesis of a boron-containing zeolite with an MWW framework structure
SG11201701622TA (en) * 2014-09-09 2017-03-30 Basf Se A process for the preparation of an mww zeolitic material comprising boron and titanium
WO2016058541A1 (en) 2014-10-15 2016-04-21 Basf Se Solidothermal synthesis of zeolitic materials and zeolites obtained therefrom
JP7055807B2 (ja) * 2016-09-06 2022-04-18 ビーエーエスエフ ソシエタス・ヨーロピア Ｍｗｗ骨格構造を有するホウ素含有ゼオライトの固体熱合成
JP7296880B2 (ja) * 2016-12-20 2023-06-23 ビーエーエスエフ ソシエタス・ヨーロピア 骨格型ｍｗｗを有するチタン含有ゼオライト材料を含む組成物の可塑性を低下させるための酸処理の使用方法
CN110072618B (zh) 2016-12-20 2022-12-30 巴斯夫欧洲公司 制备包含具有mww骨架类型的含钛沸石材料的可挤出组合物的方法
MX2019010265A (es) 2017-02-28 2019-10-14 Basf Se Proceso para preparar un alcohol insaturado.
JP7254715B2 (ja) * 2017-05-15 2023-04-10 ビーエーエスエフ コーポレーション フレームワークタイプａｅｉを有するゼオライト系材料を製造する方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003327425A (ja) 2002-03-07 2003-11-19 Showa Denko Kk Ｍｗｗ型ゼオライト物質、その前駆体物質およびそれらの製造方法
JP2010513020A (ja) 2006-12-21 2010-04-30 エクソンモービル・ケミカル・パテンツ・インク 触媒組成物とその製造方法、およびこの触媒を用いた炭化水素の転換方法
US20120148487A1 (en) 2010-12-10 2012-06-14 Chevron U.S.A. Inc. Novel oxide materials and synthesis by fluoride/chloride anion promoted exfoliation
JP2012131696A (ja) 2010-11-30 2012-07-12 Sumitomo Chemical Co Ltd チタン含有珪素酸化物成形体の製造方法及びオキシラン化合物の製造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2445747A1 (fr) 1979-01-05 1980-08-01 Armines Procede de fabrication de pieces en silicium nitrure
US4622166A (en) * 1982-03-17 1986-11-11 Mizusawa Kagaku Kogyo Kabushiki Kaisha Process for preparation of zeolite slurry excellent in static stability and dynamic stability
DE4207745A1 (de) * 1992-03-11 1993-09-16 Basf Ag Azofarbstoffe enthaltende molekularsiebe
US7011802B2 (en) 2000-12-22 2006-03-14 California Institute Of Technology Synthesis of molecular sieves by hydrothermal treatment with acid
WO2006002116A2 (en) * 2004-06-17 2006-01-05 Yale University Size-controllable transition metal clusters in mcm-41 for improving chemical catalysts
CN100363259C (zh) 2004-12-23 2008-01-23 中国科学院大连化学物理研究所 一种高硅mcm-22分子筛的制备方法
KR101044495B1 (ko) * 2006-07-28 2011-06-27 엑손모빌 케미칼 패턴츠 인코포레이티드 분자체 조성물(ｅｍｍ-10), 이의 제조 방법, 및 탄화수소 전환에 있어서의 용도
EP2025402A1 (en) 2007-07-31 2009-02-18 Total Petrochemicals Research Feluy Phosphorus modified molecular sieves, their use in conversion of organics to olefins
CN102348699A (zh) * 2009-03-13 2012-02-08 住友化学株式会社 生产烯烃氧化物的方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003327425A (ja) 2002-03-07 2003-11-19 Showa Denko Kk Ｍｗｗ型ゼオライト物質、その前駆体物質およびそれらの製造方法
JP2010513020A (ja) 2006-12-21 2010-04-30 エクソンモービル・ケミカル・パテンツ・インク 触媒組成物とその製造方法、およびこの触媒を用いた炭化水素の転換方法
JP2012131696A (ja) 2010-11-30 2012-07-12 Sumitomo Chemical Co Ltd チタン含有珪素酸化物成形体の製造方法及びオキシラン化合物の製造方法
US20120148487A1 (en) 2010-12-10 2012-06-14 Chevron U.S.A. Inc. Novel oxide materials and synthesis by fluoride/chloride anion promoted exfoliation

Also Published As

Publication number Publication date
CN104854028A (zh) 2015-08-19
ZA201503155B (en) 2017-11-29
KR20150074076A (ko) 2015-07-01
BR112015008390A2 (pt) 2017-08-08
ES2620030T3 (es) 2017-06-27
US10099933B2 (en) 2018-10-16
CN104854028B (zh) 2017-07-18
JP2015532259A (ja) 2015-11-09
MX355246B (es) 2018-04-11
MX2015004948A (es) 2016-01-20
JP6267211B2 (ja) 2018-01-24
EP2909141B1 (en) 2016-12-14
EP2909141A1 (en) 2015-08-26
RU2638851C2 (ru) 2017-12-18
BR112015008390B1 (pt) 2021-11-03
RU2015118225A (ru) 2016-12-10
US20150329368A1 (en) 2015-11-19
MY169039A (en) 2019-02-07
SG11201503019SA (en) 2015-05-28
WO2014060261A1 (en) 2014-04-24

Similar Documents

Publication Publication Date Title
KR102184609B1 (ko) 탈붕소화 mww 제올라이트의 후처리
JP6955815B2 (ja) Ｍｗｗフレームワーク構造を有するチタン含有ゼオライト材料を製造するための方法
RU2637021C2 (ru) Последующая обработка цеолитного материала
ES2821890T3 (es) Procedimiento de preparación de melonal
RU2740556C2 (ru) МИКРОПОРОШОК И ФОРМОВАННОЕ ИЗДЕЛИЕ, СОДЕРЖАЩЕЕ ЦЕОЛИТНЫЙ МАТЕРИАЛ, СОДЕРЖАЩИЙ Ti И Zn
KR102149320B1 (ko) 탈붕소화된 제올라이트 베타의 후처리
ES2970242T3 (es) Regeneración de una zeolita que contiene titanio
RU2670616C2 (ru) Формованное изделие из гидрофобного цеолитного материала и способ его получения
JP6775491B2 (ja) ホウ素およびチタンを含むｍｗｗゼオライト系材料の製造のための方法
EP3386919B1 (en) A tin-containing zeolitic material having a bea framework structure
JP2016536268A (ja) Ｂｅａ骨格構造を有するスズ含有ゼオライト材料
JP2009143737A (ja) メソポーラスアルミノシリケートおよびその合成方法
US20200070134A1 (en) Extrudable composition comprising a titanium-containing zeolitic material having framework type mww
US20200376472A1 (en) Process for preparing a molding comprising zinc and a titanium-containing zeolite

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20150515

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20181008

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20200210

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20200824

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20201124

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20201125

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20241105

Start annual number: 5

End annual number: 5