RU2638851C2 - Последующая обработка деборированного цеолита mww - Google Patents

Последующая обработка деборированного цеолита mww Download PDF

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Publication number
RU2638851C2
RU2638851C2 RU2015118225A RU2015118225A RU2638851C2 RU 2638851 C2 RU2638851 C2 RU 2638851C2 RU 2015118225 A RU2015118225 A RU 2015118225A RU 2015118225 A RU2015118225 A RU 2015118225A RU 2638851 C2 RU2638851 C2 RU 2638851C2
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RU
Russia
Prior art keywords
zeolite material
stage
iii
zeolite
ppm
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RU2015118225A
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English (en)
Russian (ru)
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RU2015118225A (ru
Inventor
Андрей-Николае ПАРВУЛЕСКУ
Джефф ЯНГ
Штефан Маурер
Мануэла ГААБ
Карстен ЗАЙДЕЛЬ
Ольга ГЕРЛАХ
Ульрих Мюллер
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Басф Се
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Publication of RU2015118225A publication Critical patent/RU2015118225A/ru
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Publication of RU2638851C2 publication Critical patent/RU2638851C2/ru

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/70Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/007Borosilicates
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026After-treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/16After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/37Acid treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/40Special temperature treatment, i.e. other than just for template removal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05Nuclear magnetic resonance [NMR]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10Infrared [IR]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
RU2015118225A 2012-10-18 2013-10-09 Последующая обработка деборированного цеолита mww RU2638851C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12189042 2012-10-18
EP12189042.0 2012-10-18
PCT/EP2013/071042 WO2014060261A1 (en) 2012-10-18 2013-10-09 Post-treatment of deboronated mww zeolite

Publications (2)

Publication Number Publication Date
RU2015118225A RU2015118225A (ru) 2016-12-10
RU2638851C2 true RU2638851C2 (ru) 2017-12-18

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2015118225A RU2638851C2 (ru) 2012-10-18 2013-10-09 Последующая обработка деборированного цеолита mww

Country Status (13)

Country Link
US (1) US10099933B2 (enExample)
EP (1) EP2909141B1 (enExample)
JP (1) JP6267211B2 (enExample)
KR (1) KR102184609B1 (enExample)
CN (1) CN104854028B (enExample)
BR (1) BR112015008390B1 (enExample)
ES (1) ES2620030T3 (enExample)
MX (1) MX355246B (enExample)
MY (1) MY169039A (enExample)
RU (1) RU2638851C2 (enExample)
SG (1) SG11201503019SA (enExample)
WO (1) WO2014060261A1 (enExample)
ZA (1) ZA201503155B (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102179936B1 (ko) 2012-10-18 2020-11-17 바스프 에스이 제올라이트 물질의 후처리
CN106536411B (zh) * 2014-06-06 2020-05-12 巴斯夫欧洲公司 具有mww骨架结构的含硼沸石的合成
SG11201701622TA (en) * 2014-09-09 2017-03-30 Basf Se A process for the preparation of an mww zeolitic material comprising boron and titanium
JP6656242B2 (ja) 2014-10-15 2020-03-04 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se ゼオライト材料の固体熱合成方法及びそれから得られるゼオライト
JP7055807B2 (ja) * 2016-09-06 2022-04-18 ビーエーエスエフ ソシエタス・ヨーロピア Mww骨格構造を有するホウ素含有ゼオライトの固体熱合成
BR112019010916B1 (pt) 2016-12-20 2023-03-28 Basf Se Processo para preparar uma composição, composição extrudável, usos de uma composição extrudável e de uma moldagem, e, moldagem.
JP7296880B2 (ja) * 2016-12-20 2023-06-23 ビーエーエスエフ ソシエタス・ヨーロピア 骨格型mwwを有するチタン含有ゼオライト材料を含む組成物の可塑性を低下させるための酸処理の使用方法
MX2019010265A (es) 2017-02-28 2019-10-14 Basf Se Proceso para preparar un alcohol insaturado.
BR112019021877A2 (pt) * 2017-05-15 2020-05-26 Basf Corporation Processo para preparar um material zeolítico, material zeolítico e uso de um material zeolítico

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0013433A1 (fr) * 1979-01-05 1980-07-23 Association Pour La Recherche Et Le Developpement Des Methodes Et Processus Industriels (Armines) Matériau résistant à l'oxydation à chaud à base de nitrure de silicium, et procédé de fabrication de ce matériau
WO2002057181A2 (en) * 2000-12-22 2002-07-25 California Institute Of Technology Synthesis of molecular sieves by hydrothermal treatment with acid
WO2009016153A2 (en) * 2007-07-31 2009-02-05 Total Petrochemicals Research Feluy Phosphorus modified molecular sieves, their use in conversion of organics to olefins

Family Cites Families (10)

* Cited by examiner, † Cited by third party
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US4622166A (en) * 1982-03-17 1986-11-11 Mizusawa Kagaku Kogyo Kabushiki Kaisha Process for preparation of zeolite slurry excellent in static stability and dynamic stability
DE4207745A1 (de) * 1992-03-11 1993-09-16 Basf Ag Azofarbstoffe enthaltende molekularsiebe
JP4241068B2 (ja) * 2002-03-07 2009-03-18 昭和電工株式会社 Mww型ゼオライト物質の製造方法
US20090325790A1 (en) * 2004-06-17 2009-12-31 Yale University Size-controllable transition metal clusters in mcm-41 for improving chemical catalysis
CN100363259C (zh) 2004-12-23 2008-01-23 中国科学院大连化学物理研究所 一种高硅mcm-22分子筛的制备方法
KR101044495B1 (ko) * 2006-07-28 2011-06-27 엑손모빌 케미칼 패턴츠 인코포레이티드 분자체 조성물(emm-10), 이의 제조 방법, 및 탄화수소 전환에 있어서의 용도
US7737313B2 (en) * 2006-12-21 2010-06-15 Exxonmobil Chemical Patents Inc. Catalyst composition, the method of manufacturing, and the process of using thereof in hydrocarbon conversions
BRPI1011687A2 (pt) * 2009-03-13 2015-11-24 Sumitomo Chemical Co processo para produção de óxido de olefina.
WO2012074033A1 (ja) * 2010-11-30 2012-06-07 住友化学株式会社 チタン含有珪素酸化物成形体の製造方法及びオキシラン化合物の製造方法
US9522390B2 (en) * 2010-12-10 2016-12-20 The Regents Of The University Of California Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0013433A1 (fr) * 1979-01-05 1980-07-23 Association Pour La Recherche Et Le Developpement Des Methodes Et Processus Industriels (Armines) Matériau résistant à l'oxydation à chaud à base de nitrure de silicium, et procédé de fabrication de ce matériau
WO2002057181A2 (en) * 2000-12-22 2002-07-25 California Institute Of Technology Synthesis of molecular sieves by hydrothermal treatment with acid
WO2009016153A2 (en) * 2007-07-31 2009-02-05 Total Petrochemicals Research Feluy Phosphorus modified molecular sieves, their use in conversion of organics to olefins

Also Published As

Publication number Publication date
KR20150074076A (ko) 2015-07-01
US10099933B2 (en) 2018-10-16
ZA201503155B (en) 2017-11-29
RU2015118225A (ru) 2016-12-10
JP6267211B2 (ja) 2018-01-24
KR102184609B1 (ko) 2020-12-01
US20150329368A1 (en) 2015-11-19
CN104854028B (zh) 2017-07-18
MX355246B (es) 2018-04-11
BR112015008390B1 (pt) 2021-11-03
BR112015008390A2 (pt) 2017-08-08
CN104854028A (zh) 2015-08-19
ES2620030T3 (es) 2017-06-27
SG11201503019SA (en) 2015-05-28
MY169039A (en) 2019-02-07
MX2015004948A (es) 2016-01-20
WO2014060261A1 (en) 2014-04-24
EP2909141A1 (en) 2015-08-26
EP2909141B1 (en) 2016-12-14
JP2015532259A (ja) 2015-11-09

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