JP6267211B2 - 脱ホウ素化ｍｗｗゼオライトの後処理 - Google Patents

脱ホウ素化ｍｗｗゼオライトの後処理 Download PDF

Info

Publication number
JP6267211B2
JP6267211B2 JP2015537193A JP2015537193A JP6267211B2 JP 6267211 B2 JP6267211 B2 JP 6267211B2 JP 2015537193 A JP2015537193 A JP 2015537193A JP 2015537193 A JP2015537193 A JP 2015537193A JP 6267211 B2 JP6267211 B2 JP 6267211B2
Authority
JP
Japan
Prior art keywords
zeolitic material
iii
range
ppm
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2015537193A
Other languages
English (en)
Japanese (ja)
Other versions
JP2015532259A (ja
JP2015532259A5 (enExample
Inventor
パルフレスク，アンドライ−ニコラエ
ヤン，ジェフ
マウラー，シュテファン
ガープ，マヌエラ
ザイデル，カルシュテン
ガーラッハ，オルガ
ミュラー，ウルリヒ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of JP2015532259A publication Critical patent/JP2015532259A/ja
Publication of JP2015532259A5 publication Critical patent/JP2015532259A5/ja
Application granted granted Critical
Publication of JP6267211B2 publication Critical patent/JP6267211B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/007—Borosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
JP2015537193A 2012-10-18 2013-10-09 脱ホウ素化ｍｗｗゼオライトの後処理 Active JP6267211B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12189042 2012-10-18
EP12189042.0 2012-10-18
PCT/EP2013/071042 WO2014060261A1 (en) 2012-10-18 2013-10-09 Post-treatment of deboronated mww zeolite

Publications (3)

Publication Number Publication Date
JP2015532259A JP2015532259A (ja) 2015-11-09
JP2015532259A5 JP2015532259A5 (enExample) 2016-12-01
JP6267211B2 true JP6267211B2 (ja) 2018-01-24

Family

ID=47046432

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2015537193A Active JP6267211B2 (ja) 2012-10-18 2013-10-09 脱ホウ素化ｍｗｗゼオライトの後処理

Country Status (13)

Country Link
US (1) US10099933B2 (enExample)
EP (1) EP2909141B1 (enExample)
JP (1) JP6267211B2 (enExample)
KR (1) KR102184609B1 (enExample)
CN (1) CN104854028B (enExample)
BR (1) BR112015008390B1 (enExample)
ES (1) ES2620030T3 (enExample)
MX (1) MX355246B (enExample)
MY (1) MY169039A (enExample)
RU (1) RU2638851C2 (enExample)
SG (1) SG11201503019SA (enExample)
WO (1) WO2014060261A1 (enExample)
ZA (1) ZA201503155B (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6367812B2 (ja) 2012-10-18 2018-08-01 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ゼオライト材料の後処理
US10196276B2 (en) * 2014-06-06 2019-02-05 Basf Se Synthesis of a boron-containing zeolite with an MWW framework structure
SG11201701622TA (en) * 2014-09-09 2017-03-30 Basf Se A process for the preparation of an mww zeolitic material comprising boron and titanium
WO2016058541A1 (en) 2014-10-15 2016-04-21 Basf Se Solidothermal synthesis of zeolitic materials and zeolites obtained therefrom
JP7055807B2 (ja) * 2016-09-06 2022-04-18 ビーエーエスエフ ソシエタス・ヨーロピア Ｍｗｗ骨格構造を有するホウ素含有ゼオライトの固体熱合成
JP7296880B2 (ja) * 2016-12-20 2023-06-23 ビーエーエスエフ ソシエタス・ヨーロピア 骨格型ｍｗｗを有するチタン含有ゼオライト材料を含む組成物の可塑性を低下させるための酸処理の使用方法
CN110072618B (zh) 2016-12-20 2022-12-30 巴斯夫欧洲公司 制备包含具有mww骨架类型的含钛沸石材料的可挤出组合物的方法
MX2019010265A (es) 2017-02-28 2019-10-14 Basf Se Proceso para preparar un alcohol insaturado.
JP7254715B2 (ja) * 2017-05-15 2023-04-10 ビーエーエスエフ コーポレーション フレームワークタイプａｅｉを有するゼオライト系材料を製造する方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2445747A1 (fr) 1979-01-05 1980-08-01 Armines Procede de fabrication de pieces en silicium nitrure
US4622166A (en) * 1982-03-17 1986-11-11 Mizusawa Kagaku Kogyo Kabushiki Kaisha Process for preparation of zeolite slurry excellent in static stability and dynamic stability
DE4207745A1 (de) * 1992-03-11 1993-09-16 Basf Ag Azofarbstoffe enthaltende molekularsiebe
US7011802B2 (en) 2000-12-22 2006-03-14 California Institute Of Technology Synthesis of molecular sieves by hydrothermal treatment with acid
JP4241068B2 (ja) * 2002-03-07 2009-03-18 昭和電工株式会社 Ｍｗｗ型ゼオライト物質の製造方法
WO2006002116A2 (en) * 2004-06-17 2006-01-05 Yale University Size-controllable transition metal clusters in mcm-41 for improving chemical catalysts
CN100363259C (zh) 2004-12-23 2008-01-23 中国科学院大连化学物理研究所 一种高硅mcm-22分子筛的制备方法
KR101044495B1 (ko) * 2006-07-28 2011-06-27 엑손모빌 케미칼 패턴츠 인코포레이티드 분자체 조성물(ｅｍｍ-10), 이의 제조 방법, 및 탄화수소 전환에 있어서의 용도
EP2025402A1 (en) 2007-07-31 2009-02-18 Total Petrochemicals Research Feluy Phosphorus modified molecular sieves, their use in conversion of organics to olefins
US7737313B2 (en) * 2006-12-21 2010-06-15 Exxonmobil Chemical Patents Inc. Catalyst composition, the method of manufacturing, and the process of using thereof in hydrocarbon conversions
CN102348699A (zh) * 2009-03-13 2012-02-08 住友化学株式会社 生产烯烃氧化物的方法
WO2012074033A1 (ja) * 2010-11-30 2012-06-07 住友化学株式会社 チタン含有珪素酸化物成形体の製造方法及びオキシラン化合物の製造方法
US9522390B2 (en) * 2010-12-10 2016-12-20 The Regents Of The University Of California Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation

Also Published As

Publication number Publication date
KR102184609B1 (ko) 2020-12-01
CN104854028A (zh) 2015-08-19
ZA201503155B (en) 2017-11-29
KR20150074076A (ko) 2015-07-01
BR112015008390A2 (pt) 2017-08-08
ES2620030T3 (es) 2017-06-27
US10099933B2 (en) 2018-10-16
CN104854028B (zh) 2017-07-18
JP2015532259A (ja) 2015-11-09
MX355246B (es) 2018-04-11
MX2015004948A (es) 2016-01-20
EP2909141B1 (en) 2016-12-14
EP2909141A1 (en) 2015-08-26
RU2638851C2 (ru) 2017-12-18
BR112015008390B1 (pt) 2021-11-03
RU2015118225A (ru) 2016-12-10
US20150329368A1 (en) 2015-11-19
MY169039A (en) 2019-02-07
SG11201503019SA (en) 2015-05-28
WO2014060261A1 (en) 2014-04-24

Similar Documents

Publication Publication Date Title
JP6267211B2 (ja) 脱ホウ素化ｍｗｗゼオライトの後処理
JP6367812B2 (ja) ゼオライト材料の後処理
JP6598789B2 (ja) Ｂｅａ骨格構造を有するスズ含有ゼオライト材料
CN104271241B (zh) 包括含Ti和Zn的沸石材料的超细粉和模制品
JP6775491B2 (ja) ホウ素およびチタンを含むｍｗｗゼオライト系材料の製造のための方法
JP6306029B2 (ja) 脱ホウ素化ゼオライトベータの後処理
EP3386919B1 (en) A tin-containing zeolitic material having a bea framework structure
JP6526689B2 (ja) Ｍｗｗ型の骨格構造を有するスズ含有のゼオライト材料
CN105873912A (zh) 氧化有机羰基化合物的方法
EP3554694B1 (en) A process for the preparation of a titanium-containing zeolite
TW201526988A (zh) 具有ｂｅａ骨架結構之含錫沸石材料

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20161007

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20161007

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170808

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20171108

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20171128

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20171221

R150 Certificate of patent or registration of utility model

Ref document number: 6267211

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250