CN104854028B - 脱硼mww沸石的后处理 - Google Patents

脱硼mww沸石的后处理 Download PDF

Info

Publication number
CN104854028B
CN104854028B CN201380065900.8A CN201380065900A CN104854028B CN 104854028 B CN104854028 B CN 104854028B CN 201380065900 A CN201380065900 A CN 201380065900A CN 104854028 B CN104854028 B CN 104854028B
Authority
CN
China
Prior art keywords
zeolitic material
iii
zeolitic
framework structure
molar ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380065900.8A
Other languages
English (en)
Chinese (zh)
Other versions
CN104854028A (zh
Inventor
安德烈-尼古拉·帕乌莱斯库
J·杨
S·毛雷尔
M·加布
K·塞德尔
O·格拉赫
U·穆勒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN104854028A publication Critical patent/CN104854028A/zh
Application granted granted Critical
Publication of CN104854028B publication Critical patent/CN104854028B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/007—Borosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CN201380065900.8A 2012-10-18 2013-10-09 脱硼mww沸石的后处理 Active CN104854028B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12189042 2012-10-18
EP12189042.0 2012-10-18
PCT/EP2013/071042 WO2014060261A1 (en) 2012-10-18 2013-10-09 Post-treatment of deboronated mww zeolite

Publications (2)

Publication Number Publication Date
CN104854028A CN104854028A (zh) 2015-08-19
CN104854028B true CN104854028B (zh) 2017-07-18

Family

ID=47046432

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380065900.8A Active CN104854028B (zh) 2012-10-18 2013-10-09 脱硼mww沸石的后处理

Country Status (13)

Country Link
US (1) US10099933B2 (enExample)
EP (1) EP2909141B1 (enExample)
JP (1) JP6267211B2 (enExample)
KR (1) KR102184609B1 (enExample)
CN (1) CN104854028B (enExample)
BR (1) BR112015008390B1 (enExample)
ES (1) ES2620030T3 (enExample)
MX (1) MX355246B (enExample)
MY (1) MY169039A (enExample)
RU (1) RU2638851C2 (enExample)
SG (1) SG11201503019SA (enExample)
WO (1) WO2014060261A1 (enExample)
ZA (1) ZA201503155B (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112015008391B1 (pt) 2012-10-18 2022-03-29 Basf Se Processo para o pós-tratamento de um material zeolítico, material zeolítico e uso de um material zeolítico
EP3152161A1 (en) * 2014-06-06 2017-04-12 Basf Se Synthesis of a boron-containing zeolite with an mww framework structure
WO2016038030A1 (en) * 2014-09-09 2016-03-17 Basf Se A process for the preparation of an mww zeolitic material comprising boron and titanium
JP6656242B2 (ja) 2014-10-15 2020-03-04 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ゼオライト材料の固体熱合成方法及びそれから得られるゼオライト
KR102470492B1 (ko) * 2016-09-06 2022-11-23 바스프 에스이 Mww 골격 구조를 갖는 붕소 함유 제올라이트의 고체열 합성
KR102503496B1 (ko) 2016-12-20 2023-02-23 바스프 에스이 골격 타입 mww를 갖는 티타늄 함유 제올라이트 물질을 포함하는 압출성 조성물의 제조 방법
WO2018115118A1 (en) 2016-12-20 2018-06-28 Basf Se Use of an acid treatment to decrease the plasticity of a composition comprising a titanium-containing zeolitic material having framework type mww
BR112019017044B1 (pt) 2017-02-28 2023-03-28 Basf Se Processo para preparar um composto, e, uso de um material zeolítico
WO2018210809A1 (en) * 2017-05-15 2018-11-22 Basf Se A process for preparing a zeolitic material having framework type aei

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1796279A (zh) * 2004-12-23 2006-07-05 中国科学院大连化学物理研究所 一种高硅mcm－22分子筛的制备方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2445747A1 (fr) * 1979-01-05 1980-08-01 Armines Procede de fabrication de pieces en silicium nitrure
US4622166A (en) * 1982-03-17 1986-11-11 Mizusawa Kagaku Kogyo Kabushiki Kaisha Process for preparation of zeolite slurry excellent in static stability and dynamic stability
DE4207745A1 (de) * 1992-03-11 1993-09-16 Basf Ag Azofarbstoffe enthaltende molekularsiebe
US7011802B2 (en) 2000-12-22 2006-03-14 California Institute Of Technology Synthesis of molecular sieves by hydrothermal treatment with acid
JP4241068B2 (ja) * 2002-03-07 2009-03-18 昭和電工株式会社 Ｍｗｗ型ゼオライト物質の製造方法
WO2006002116A2 (en) * 2004-06-17 2006-01-05 Yale University Size-controllable transition metal clusters in mcm-41 for improving chemical catalysts
EP2051806B1 (en) * 2006-07-28 2016-08-17 ExxonMobil Chemical Patents Inc. Molecular sieve composition (emm-10), its method of making, and use for hydrocarbon conversions
EP2025402A1 (en) * 2007-07-31 2009-02-18 Total Petrochemicals Research Feluy Phosphorus modified molecular sieves, their use in conversion of organics to olefins
US7737313B2 (en) * 2006-12-21 2010-06-15 Exxonmobil Chemical Patents Inc. Catalyst composition, the method of manufacturing, and the process of using thereof in hydrocarbon conversions
CN102348699A (zh) * 2009-03-13 2012-02-08 住友化学株式会社 生产烯烃氧化物的方法
WO2012074033A1 (ja) * 2010-11-30 2012-06-07 住友化学株式会社 チタン含有珪素酸化物成形体の製造方法及びオキシラン化合物の製造方法
US9522390B2 (en) 2010-12-10 2016-12-20 The Regents Of The University Of California Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1796279A (zh) * 2004-12-23 2006-07-05 中国科学院大连化学物理研究所 一种高硅mcm－22分子筛的制备方法

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
Organic–silicate hybrid catalysts based on various defined structures for Knoevenagel condensation;Yoshihiro Kubota et al.;《Microporous and Mesoporous Materials》;20041231;第70卷;135-149 *
Synthesis and characterization of the MCM-22 zeolite;A.Corma et al.;《Zeoliltes》;19951231;第15卷;2-8 *
Synthesis of Hydrophobic Molecular Sieves by Hydrothermal Treatment with Acetic Acid;Christopher W. Jones et al.;《Chemistry of Materials》;20010123;第13卷;1041-1050 *
疏水性沸石分子筛的特性及表面改性研究;黄燕;《精细化工中间体》;20021231;第32卷(第6期);36-37 *

Also Published As

Publication number Publication date
MY169039A (en) 2019-02-07
ES2620030T3 (es) 2017-06-27
KR20150074076A (ko) 2015-07-01
KR102184609B1 (ko) 2020-12-01
MX355246B (es) 2018-04-11
SG11201503019SA (en) 2015-05-28
JP2015532259A (ja) 2015-11-09
CN104854028A (zh) 2015-08-19
RU2638851C2 (ru) 2017-12-18
EP2909141A1 (en) 2015-08-26
US10099933B2 (en) 2018-10-16
BR112015008390A2 (pt) 2017-08-08
BR112015008390B1 (pt) 2021-11-03
US20150329368A1 (en) 2015-11-19
EP2909141B1 (en) 2016-12-14
RU2015118225A (ru) 2016-12-10
MX2015004948A (es) 2016-01-20
ZA201503155B (en) 2017-11-29
WO2014060261A1 (en) 2014-04-24
JP6267211B2 (ja) 2018-01-24

Similar Documents

Publication Publication Date Title
CN104854028B (zh) 脱硼mww沸石的后处理
CN104854031B (zh) 沸石材料的后处理
ES2821890T3 (es) Procedimiento de preparación de melonal
RU2623575C2 (ru) МИКРОПОРОШОК И ФОРМОВАННОЕ ИЗДЕЛИЕ, СОДЕРЖАЩИЕ ЦЕОЛИТНЫЙ МАТЕРИАЛ, СОДЕРЖАЩИЙ Ti И Zn
CN104918885B (zh) 脱硼β沸石的后处理
JP2016536268A (ja) Ｂｅａ骨格構造を有するスズ含有ゼオライト材料
CN107074567A (zh) 制备包含硼和钛的mww沸石材料的方法
JP2018536614A (ja) Ｂｅａ骨格構造を有するスズ含有ゼオライト材料
KR102582814B1 (ko) 골격체형 cha를 갖고, 칼륨 및 세슘 중 하나 이상 및 전이 금속을 포함하는 제올라이트 물질
US11291980B2 (en) Process for preparing an extrudable composition comprising a titanium-containing zeolitic material, having framework type MWW
CN110062654B (zh) 制备含钛沸石的方法
TW201526988A (zh) 具有ｂｅａ骨架結構之含錫沸石材料

Legal Events

Date Code Title Description
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant