CN104854028B - 脱硼mww沸石的后处理 - Google Patents

脱硼mww沸石的后处理 Download PDF

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Publication number
CN104854028B
CN104854028B CN201380065900.8A CN201380065900A CN104854028B CN 104854028 B CN104854028 B CN 104854028B CN 201380065900 A CN201380065900 A CN 201380065900A CN 104854028 B CN104854028 B CN 104854028B
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Prior art keywords
zeolitic material
iii
zeolitic
framework structure
molar ratio
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Chinese (zh)
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CN104854028A (zh
Inventor
安德烈-尼古拉·帕乌莱斯库
J·杨
S·毛雷尔
M·加布
K·塞德尔
O·格拉赫
U·穆勒
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/007—Borosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CN201380065900.8A 2012-10-18 2013-10-09 脱硼mww沸石的后处理 Active CN104854028B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12189042 2012-10-18
EP12189042.0 2012-10-18
PCT/EP2013/071042 WO2014060261A1 (en) 2012-10-18 2013-10-09 Post-treatment of deboronated mww zeolite

Publications (2)

Publication Number Publication Date
CN104854028A CN104854028A (zh) 2015-08-19
CN104854028B true CN104854028B (zh) 2017-07-18

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380065900.8A Active CN104854028B (zh) 2012-10-18 2013-10-09 脱硼mww沸石的后处理

Country Status (13)

Country Link
US (1) US10099933B2 (enExample)
EP (1) EP2909141B1 (enExample)
JP (1) JP6267211B2 (enExample)
KR (1) KR102184609B1 (enExample)
CN (1) CN104854028B (enExample)
BR (1) BR112015008390B1 (enExample)
ES (1) ES2620030T3 (enExample)
MX (1) MX355246B (enExample)
MY (1) MY169039A (enExample)
RU (1) RU2638851C2 (enExample)
SG (1) SG11201503019SA (enExample)
WO (1) WO2014060261A1 (enExample)
ZA (1) ZA201503155B (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY181782A (en) 2012-10-18 2021-01-06 Basf Se Post-treatment of a zeolitic material
EP3152161A1 (en) * 2014-06-06 2017-04-12 Basf Se Synthesis of a boron-containing zeolite with an mww framework structure
BR112017004074B1 (pt) * 2014-09-09 2022-03-03 Basf Se Processo para a preparação de um material zeolítico, material zeolítico, moldagem e usos de um material zeolítico
CN107074566A (zh) 2014-10-15 2017-08-18 巴斯夫欧洲公司 沸石材料的固热合成以及由此得到的沸石
KR102470492B1 (ko) * 2016-09-06 2022-11-23 바스프 에스이 Mww 골격 구조를 갖는 붕소 함유 제올라이트의 고체열 합성
EP3558516A1 (en) 2016-12-20 2019-10-30 Basf Se A process for preparing an extrudable composition comprising a titanium-containing zeolitic material having framework type mww
MY199977A (en) 2016-12-20 2023-12-01 Basf Se Use of an acid treatment to decrease the plasticity of a composition comprising a titanium-containing zeolitic material having framework type mww
ES2887554T3 (es) 2017-02-28 2021-12-23 Basf Se Procedimiento de preparación de un alcohol insaturado
BR112019021877A2 (pt) * 2017-05-15 2020-05-26 Basf Corporation Processo para preparar um material zeolítico, material zeolítico e uso de um material zeolítico

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1796279A (zh) * 2004-12-23 2006-07-05 中国科学院大连化学物理研究所 一种高硅mcm－22分子筛的制备方法

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FR2445747A1 (fr) 1979-01-05 1980-08-01 Armines Procede de fabrication de pieces en silicium nitrure
US4622166A (en) * 1982-03-17 1986-11-11 Mizusawa Kagaku Kogyo Kabushiki Kaisha Process for preparation of zeolite slurry excellent in static stability and dynamic stability
DE4207745A1 (de) * 1992-03-11 1993-09-16 Basf Ag Azofarbstoffe enthaltende molekularsiebe
WO2002057181A2 (en) 2000-12-22 2002-07-25 California Institute Of Technology Synthesis of molecular sieves by hydrothermal treatment with acid
JP4241068B2 (ja) * 2002-03-07 2009-03-18 昭和電工株式会社 Ｍｗｗ型ゼオライト物質の製造方法
US20090325790A1 (en) * 2004-06-17 2009-12-31 Yale University Size-controllable transition metal clusters in mcm-41 for improving chemical catalysis
BRPI0713674A2 (pt) * 2006-07-28 2012-10-23 Exxonmobil Chemical Patents Inc. formulações farmarcêuticas e composições de um antagonista seletivo cxcr2 ou cxcr1 e métodos para o uso do mesmo visando o tratamento de distúrbios inflamatórios
EP2025402A1 (en) 2007-07-31 2009-02-18 Total Petrochemicals Research Feluy Phosphorus modified molecular sieves, their use in conversion of organics to olefins
US7737313B2 (en) 2006-12-21 2010-06-15 Exxonmobil Chemical Patents Inc. Catalyst composition, the method of manufacturing, and the process of using thereof in hydrocarbon conversions
WO2010104214A2 (en) * 2009-03-13 2010-09-16 Sumitomo Chemical Company, Limited Method for producing olefin oxide
WO2012074033A1 (ja) 2010-11-30 2012-06-07 住友化学株式会社 チタン含有珪素酸化物成形体の製造方法及びオキシラン化合物の製造方法
US9522390B2 (en) 2010-12-10 2016-12-20 The Regents Of The University Of California Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation

Patent Citations (1)

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CN1796279A (zh) * 2004-12-23 2006-07-05 中国科学院大连化学物理研究所 一种高硅mcm－22分子筛的制备方法

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Organic–silicate hybrid catalysts based on various defined structures for Knoevenagel condensation;Yoshihiro Kubota et al.;《Microporous and Mesoporous Materials》;20041231;第70卷;135-149 *
Synthesis and characterization of the MCM-22 zeolite;A.Corma et al.;《Zeoliltes》;19951231;第15卷;2-8 *
Synthesis of Hydrophobic Molecular Sieves by Hydrothermal Treatment with Acetic Acid;Christopher W. Jones et al.;《Chemistry of Materials》;20010123;第13卷;1041-1050 *
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Also Published As

Publication number Publication date
MY169039A (en) 2019-02-07
EP2909141B1 (en) 2016-12-14
ZA201503155B (en) 2017-11-29
BR112015008390B1 (pt) 2021-11-03
WO2014060261A1 (en) 2014-04-24
ES2620030T3 (es) 2017-06-27
CN104854028A (zh) 2015-08-19
EP2909141A1 (en) 2015-08-26
KR102184609B1 (ko) 2020-12-01
US10099933B2 (en) 2018-10-16
US20150329368A1 (en) 2015-11-19
MX2015004948A (es) 2016-01-20
RU2015118225A (ru) 2016-12-10
MX355246B (es) 2018-04-11
RU2638851C2 (ru) 2017-12-18
BR112015008390A2 (pt) 2017-08-08
JP6267211B2 (ja) 2018-01-24
SG11201503019SA (en) 2015-05-28
JP2015532259A (ja) 2015-11-09
KR20150074076A (ko) 2015-07-01

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