KR102065510B1 - 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법 - Google Patents

중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법 Download PDF

Info

Publication number
KR102065510B1
KR102065510B1 KR1020140136958A KR20140136958A KR102065510B1 KR 102065510 B1 KR102065510 B1 KR 102065510B1 KR 1020140136958 A KR1020140136958 A KR 1020140136958A KR 20140136958 A KR20140136958 A KR 20140136958A KR 102065510 B1 KR102065510 B1 KR 102065510B1
Authority
KR
South Korea
Prior art keywords
solvent
lewis acid
lewis
lewis base
hydrocarbyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020140136958A
Other languages
English (en)
Korean (ko)
Other versions
KR20150042739A (ko
Inventor
루돌프 파우스트
라지브 쿠마르
제이콥 에멀트
Original Assignee
유니버시티 오브 매사추세츠
인피니움 인터내셔날 리미티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 유니버시티 오브 매사추세츠, 인피니움 인터내셔날 리미티드 filed Critical 유니버시티 오브 매사추세츠
Publication of KR20150042739A publication Critical patent/KR20150042739A/ko
Application granted granted Critical
Publication of KR102065510B1 publication Critical patent/KR102065510B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
KR1020140136958A 2013-10-11 2014-10-10 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법 Active KR102065510B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/052,490 2013-10-11
US14/052,490 US9631038B2 (en) 2013-10-11 2013-10-11 Polymerization initiating system and method to produce highly reactive olefin functional polymers

Publications (2)

Publication Number Publication Date
KR20150042739A KR20150042739A (ko) 2015-04-21
KR102065510B1 true KR102065510B1 (ko) 2020-01-13

Family

ID=51687843

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020140136958A Active KR102065510B1 (ko) 2013-10-11 2014-10-10 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법

Country Status (8)

Country Link
US (1) US9631038B2 (https=)
EP (1) EP2860206B1 (https=)
JP (1) JP6532664B2 (https=)
KR (1) KR102065510B1 (https=)
CN (1) CN104558304B (https=)
CA (1) CA2866525C (https=)
ES (1) ES2737074T3 (https=)
SG (1) SG10201405955XA (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190001943A (ko) * 2017-06-28 2019-01-07 인피니움 인터내셔날 리미티드 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법
KR20190001936A (ko) * 2017-06-28 2019-01-07 인피늄 인터내셔날 리미티드 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 중합체의 제조 방법

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9156924B2 (en) * 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9771442B2 (en) * 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
MY189238A (en) * 2016-02-16 2022-01-31 Basf Se Process for preparing high-reactivity isobutene homo-or copolymers
BR112018015440B1 (pt) * 2016-02-16 2022-07-05 Basf Se Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade
CA3031140C (en) * 2016-07-22 2024-05-14 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN106496538B (zh) * 2016-10-19 2021-12-03 安徽红太阳新材料有限公司 一种高分子量聚己内酯的合成方法
US10174138B1 (en) * 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
KR102301668B1 (ko) 2018-07-27 2021-09-14 주식회사 엘지화학 폴리부텐 올리고머의 제조 방법
US10829573B1 (en) * 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers
KR102469493B1 (ko) 2019-08-19 2022-11-23 주식회사 엘지화학 유기 보레이트계 촉매, 이를 이용한 이소부텐 올리고머의 제조방법 및 이로부터 제조된 이소부텐 올리고머
EP3943518A1 (en) 2020-07-22 2022-01-26 Indian Oil Corporation Limited Polymerization catalyst system and process to produce highly reactive polyisobutylene

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013021058A1 (de) 2011-08-11 2013-02-14 Basf Se Verfahren zur herstellung von hochreaktiven isobutenhomo- oder -copolymeren
WO2013090764A1 (en) 2011-12-16 2013-06-20 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2682531A (en) 1951-03-31 1954-06-29 Standard Oil Dev Co Zirconium tetrachloride-ether complexes as low temperature polymerization catalyst
JPS4839599A (https=) 1971-09-20 1973-06-11
US3850897A (en) 1971-11-26 1974-11-26 Snam Progetti Procedure for the production of polymers and copolymers of isobutylene
DE2702604C2 (de) 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
CA2019908A1 (en) 1989-12-28 1991-06-28 Rudolf Lukas Graft copolymers and the method and initiation system for preparation thereof
US5254649A (en) 1990-11-28 1993-10-19 Bp Chemicals Limited Cationic polymerization of 1-olefins
US5286823A (en) 1991-06-22 1994-02-15 Basf Aktiengesellschaft Preparation of highly reactive polyisobutenes
US5350819A (en) 1993-02-19 1994-09-27 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts
WO1994028036A1 (en) 1993-05-20 1994-12-08 Exxon Chemical Patents Inc. Heterogeneous lewis acid-type catalysts
JP3203917B2 (ja) 1993-11-30 2001-09-04 ソニー株式会社 プロジェクタ用アクティブマトリクス液晶表示パネル
EP0920909A1 (en) 1994-03-31 1999-06-09 Exxon Chemical Patents Inc. Supported lewis acid catalysts for hydrocarbon conversion reactions
US5710225A (en) 1996-08-23 1998-01-20 The Lubrizol Corporation Heteropolyacid catalyzed polymerization of olefins
DE19704482A1 (de) 1997-02-06 1998-08-13 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
DE19734176A1 (de) 1997-08-07 1999-02-11 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
US6407186B1 (en) 1997-12-12 2002-06-18 Basf Aktiengesellschaft Method for producing low-molecular, highly reactive polyisobutylene
JP2002517571A (ja) 1998-06-12 2002-06-18 ユニベーション・テクノロジーズ・エルエルシー 活性化されたルイス酸−塩基錯体を使用するオレフィン重合方法
US6407170B1 (en) 1999-06-24 2002-06-18 The Lubrizol Corporation Dispersants prepared from high polydispersity olefin polymers
US6346585B1 (en) 1999-06-24 2002-02-12 The Lubrizol Corporation Ammonium heteropolyacid catalized polymerization of olefins
JP2001017864A (ja) * 1999-07-06 2001-01-23 Kawamura Inst Of Chem Res エポキシ化触媒及び該触媒を用いたオレフィン類のエポキシ化物の製造方法
US6562913B1 (en) 1999-09-16 2003-05-13 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
DE19952030A1 (de) 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung von hochreaktiven Polyisobutenen
US6858690B2 (en) 1999-11-15 2005-02-22 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
JP3735026B2 (ja) * 2000-02-17 2006-01-11 住友化学株式会社 シタロプラムの製造方法、およびその中間体とその製造方法
DE10035298A1 (de) 2000-07-18 2002-01-31 Basf Ag Verfahren zur Herstellung von Polysiobutenen
JP4106265B2 (ja) 2000-11-17 2008-06-25 ビーエーエスエフ ソシエタス・ヨーロピア ポリイソブテンの製造における三フッ化ホウ素の不活性化及び回復のための方法
DE10061715A1 (de) 2000-12-12 2002-06-13 Basf Ag Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens
DE10118182A1 (de) 2001-04-11 2002-10-17 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Reaktionsaustrages der kationischen Polymerisation von Isobuten
DE10211418A1 (de) 2002-03-15 2003-09-25 Bayer Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
CA2493729A1 (en) 2002-08-13 2004-02-19 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
CN100402558C (zh) 2002-12-20 2008-07-16 埃克森美孚化学专利公司 聚合方法
AU2003297458A1 (en) 2002-12-20 2004-07-22 Exxonmobil Chemical Patents Inc. Polymerization processes
DE10303212A1 (de) 2003-01-24 2004-08-05 Basf Ag Verfahren zur Herstellung von Polyisobuten
DE10356768A1 (de) 2003-12-04 2005-07-07 Universität Karlsruhe (TH) - Körperschaft des öffentlichen Rechts Verfahren zur Herstellung von Salzen schwach koordinierender Anionen, derartige Salze sowie deren Verwendung
WO2006074211A1 (en) 2005-01-05 2006-07-13 University Of Massachusetts Polymerization of olefins
DE102005055818A1 (de) 2005-11-21 2007-05-24 Basf Ag Verfahren zur Herstellung von hochreaktiven Isobutenhomo- oder -copolymeren mittels metallhaltiger Katalysatorkomplexe
WO2008095933A1 (de) 2007-02-09 2008-08-14 Basf Se Verfahren zur polymerisation von ethylenisch ungesättigten monomeren
US8394897B2 (en) 2008-03-25 2013-03-12 Chevron Oronite Company Llc Production of vinylidene-terminated polyolefins via quenching with monosulfides
US20090258803A1 (en) 2008-04-14 2009-10-15 Harrison James J Copolymers made with quasi-living polyolefins and unsaturated acidic reagents, dispersants using same, and methods of making same
US8063154B2 (en) 2008-06-24 2011-11-22 The University Of Southern Mississippi Preparation of exo-olefin terminated polyolefins via quenching with alkoxysilanes or ethers
CN101613423B (zh) * 2008-06-27 2011-05-18 北京化工大学 一种用于合成高反应活性聚异丁烯的引发体系
US8530577B2 (en) 2008-06-30 2013-09-10 Fina Technology, Inc. Compatibilized polypropylene heterophasic copolymer and polylactic acid blends for injection molding applications
WO2010139684A1 (de) 2009-06-05 2010-12-09 Basf Se Verbindung aus einem protonierten aromaten und einem schwach koordinierenden anion als polymerisationskatalysator für isobuten oder ein isobuten-haltiges monomerengemisch
CN101955558B (zh) 2009-07-15 2013-03-13 北京化工大学 制备高反应活性聚异丁烯及其共聚物的引发体系
WO2011054785A1 (de) 2009-11-04 2011-05-12 Basf Se Verfahren zur herstellung von homo- oder copolymeren
RU2555400C2 (ru) * 2010-02-17 2015-07-10 Басф Се Способ получения высокореакционноспособных гомополимеров или сополимеров изобутена
US8349977B2 (en) 2010-02-17 2013-01-08 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US9562117B2 (en) 2010-11-30 2017-02-07 Basf Se Preparation of derivatives of isobutene copolymers
US8697820B2 (en) * 2011-08-11 2014-04-15 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US9156924B2 (en) * 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9771442B2 (en) 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013021058A1 (de) 2011-08-11 2013-02-14 Basf Se Verfahren zur herstellung von hochreaktiven isobutenhomo- oder -copolymeren
WO2013090764A1 (en) 2011-12-16 2013-06-20 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US20130158217A1 (en) 2011-12-16 2013-06-20 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190001943A (ko) * 2017-06-28 2019-01-07 인피니움 인터내셔날 리미티드 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법
KR20190001936A (ko) * 2017-06-28 2019-01-07 인피늄 인터내셔날 리미티드 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 중합체의 제조 방법
KR102291980B1 (ko) 2017-06-28 2021-08-23 인피늄 인터내셔날 리미티드 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 중합체의 제조 방법
KR102333045B1 (ko) 2017-06-28 2021-11-29 인피니움 인터내셔날 리미티드 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법

Also Published As

Publication number Publication date
EP2860206B1 (en) 2019-04-17
CA2866525C (en) 2020-03-24
US9631038B2 (en) 2017-04-25
SG10201405955XA (en) 2015-05-28
CA2866525A1 (en) 2015-04-11
EP2860206A1 (en) 2015-04-15
JP2015074785A (ja) 2015-04-20
US20150105525A1 (en) 2015-04-16
CN104558304A (zh) 2015-04-29
CN104558304B (zh) 2018-08-10
JP6532664B2 (ja) 2019-06-19
KR20150042739A (ko) 2015-04-21
ES2737074T3 (es) 2020-01-10

Similar Documents

Publication Publication Date Title
KR102065510B1 (ko) 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법
US9156924B2 (en) Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9771442B2 (en) Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9034998B2 (en) Polymerization initiating system and method to produce highly reactive olefin functional polymers
CA3031293C (en) Method for forming highly reactive olefin functional polymers

Legal Events

Date Code Title Description
PA0109 Patent application

St.27 status event code: A-0-1-A10-A12-nap-PA0109

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

A201 Request for examination
A302 Request for accelerated examination
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PA0302 Request for accelerated examination

St.27 status event code: A-1-2-D10-D17-exm-PA0302

St.27 status event code: A-1-2-D10-D16-exm-PA0302

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U11-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 6