KR101710043B1 - 하이드로실릴화 촉매 - Google Patents

하이드로실릴화 촉매 Download PDF

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Publication number
KR101710043B1
KR101710043B1 KR1020147035506A KR20147035506A KR101710043B1 KR 101710043 B1 KR101710043 B1 KR 101710043B1 KR 1020147035506 A KR1020147035506 A KR 1020147035506A KR 20147035506 A KR20147035506 A KR 20147035506A KR 101710043 B1 KR101710043 B1 KR 101710043B1
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alkyl
group
unsaturated
formula
complex
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KR20150013833A (ko
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요하네스 쥐.피. 델리스
수잔 아담스 나이
켄릭 엠 루이스
케이스 제이. 웰러
폴 제이. 취릭
아론 엠. 톤드레아우
사라 캐슬린 러셀
Original Assignee
모멘티브 퍼포먼스 머티리얼즈 인크.
코넬 유니버시티
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1872—Preparation; Treatments not provided for in C07F7/20
    • C07F7/1876—Preparation; Treatments not provided for in C07F7/20 by reactions involving the formation of Si-C linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/11—Compounds covalently bound to a solid support
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S71/00—Chemistry: fertilizers
    • Y10S71/02—Chelating agent

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Pyridine Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020147035506A 2009-07-10 2010-07-09 하이드로실릴화 촉매 Active KR101710043B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US22459809P 2009-07-10 2009-07-10
US61/224,598 2009-07-10
US12/832,627 US8236915B2 (en) 2009-07-10 2010-07-08 Hydrosilylation catalysts
US12/832,627 2010-07-08
PCT/US2010/041487 WO2011006044A2 (en) 2009-07-10 2010-07-09 Hydrosilylation catalysts

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1020117031667A Division KR20120023149A (ko) 2009-07-10 2010-07-09 하이드로실릴화 촉매

Publications (2)

Publication Number Publication Date
KR20150013833A KR20150013833A (ko) 2015-02-05
KR101710043B1 true KR101710043B1 (ko) 2017-03-08

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KR1020147035506A Active KR101710043B1 (ko) 2009-07-10 2010-07-09 하이드로실릴화 촉매
KR1020117031667A Ceased KR20120023149A (ko) 2009-07-10 2010-07-09 하이드로실릴화 촉매

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US (1) US8236915B2 (enExample)
EP (1) EP2451820B1 (enExample)
JP (2) JP6059987B2 (enExample)
KR (2) KR101710043B1 (enExample)
CN (3) CN109289923B (enExample)
BR (1) BR112012000169A2 (enExample)
TW (1) TWI492789B (enExample)
WO (1) WO2011006044A2 (enExample)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112013012742A2 (pt) * 2010-11-24 2016-09-13 Univ Cornell catalisadores de hidrossililação
US8765987B2 (en) 2010-11-24 2014-07-01 Cornell University In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts
EP2643330B1 (en) 2010-11-24 2017-01-04 Momentive Performance Materials Inc. Metal-catalyzed mono-hydrosilylation of polyunsaturated compounds
US9394325B2 (en) * 2011-08-19 2016-07-19 The Trustees Of Princeton University Enantiopure base-metal catalysts for asymmetric catalysis and bis(imino)pyridine iron alkyl complexes for catalysis
WO2013043912A2 (en) * 2011-09-20 2013-03-28 Dow Corning Corporation Iron containing hydrosilylation catalysts and compositions containing the catalysts
JP6101695B2 (ja) * 2011-09-20 2017-03-22 ダウ コーニング コーポレーションＤｏｗ Ｃｏｒｎｉｎｇ Ｃｏｒｐｏｒａｔｉｏｎ ニッケル含有ヒドロシリル化触媒及びその触媒を含有する組成物
WO2013043783A2 (en) * 2011-09-20 2013-03-28 Dow Corning Corporation Cobalt containing hydrosilylation catalysts and compositions containing the catalysts
US9139699B2 (en) 2012-10-04 2015-09-22 Dow Corning Corporation Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
EP2764052B1 (en) * 2011-10-04 2018-07-18 Dow Silicones Corporation Iron(iii) containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
WO2013081794A1 (en) * 2011-12-01 2013-06-06 Dow Corning Corporation Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
US8927674B2 (en) 2012-08-16 2015-01-06 Princeton University Dehydrogenative silylation and crosslinking using cobalt catalysts
US9447125B2 (en) * 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
JP6125222B2 (ja) * 2012-08-16 2017-05-10 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒を用いる脱水素シリル化および架橋
FR3000069B1 (fr) * 2012-12-21 2015-02-06 Bluestar Silicones France Procede d'hydrosilylation d'un siloxane photocatalyse par un compose polyoxometallate
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
WO2014182670A2 (en) 2013-05-06 2014-11-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
EP2996804B1 (en) 2013-05-15 2020-12-30 Momentive Performance Materials Inc. Activation of metal salts with silylhydrides and their use in hydrosilylation reactions
WO2014201082A1 (en) 2013-06-12 2014-12-18 Arizona Board Of Regents On Behalf Of Arizona State University First-row transition metal hydrogenation and hydrosilylation catalysts
WO2015023328A1 (en) 2013-08-14 2015-02-19 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine dimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
CN105612134A (zh) * 2013-10-02 2016-05-25 巴斯夫欧洲公司 聚(氧化烯)氧基-和/或聚(氧化烯)氨基烷基三烷氧基硅烷作为分散剂的用途
CN105916869B (zh) * 2013-11-19 2019-11-22 莫门蒂夫性能材料股份有限公司 钴催化剂及它们用于氢化硅烷化和脱氢硅烷化的用途
WO2015077306A1 (en) 2013-11-19 2015-05-28 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP6486925B2 (ja) * 2013-11-19 2019-03-20 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用
JP2016537377A (ja) 2013-11-19 2016-12-01 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒を用いる脱水素シリル化、ヒドロシリル化、及び架橋結合
CN106536046A (zh) * 2014-05-08 2017-03-22 莫门蒂夫性能材料股份有限公司 二烷基钴催化剂及它们用于氢化硅烷化和脱氢硅烷化的用途
JP6327426B2 (ja) 2014-08-12 2018-05-23 国立大学法人九州大学 ヒドロシリル化反応触媒
JP6515930B2 (ja) 2014-08-12 2019-05-22 国立大学法人九州大学 ヒドロシリル化反応触媒
JP6761997B2 (ja) * 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
CN104478919B (zh) * 2014-11-18 2018-02-02 浙江大学 一种合成手性硅烷化合物的方法
US10046318B2 (en) 2014-12-19 2018-08-14 Dow Silicones Corporation Ligand components, associated reaction products, activated reaction products, hydrosilylation catalysts and hydrosilylation curable compositions including the ligand components, and associated methods for preparing same
EP3323505B1 (en) 2015-07-14 2024-07-17 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
JP6846423B2 (ja) * 2015-07-24 2021-03-24 モメンティブ パフォーマンス マテリアルズ インコーポレイテッドＭｏｍｅｎｔｉｖｅ Ｐｅｒｆｏｒｍａｎｃｅ Ｍａｔｅｒｉａｌｓ Ｉｎｃ． ピリジンジイミンコバルトカルボキシレート触媒を用いた脱水素シリル化、ヒドロシリル化および架橋
WO2017100106A1 (en) * 2015-12-07 2017-06-15 Dow Corning Corporation Method and composition for hydrosilylation of carboxylic acid alkenyl esters and hydrogen terminated organosiloxane oligomers with an iridium complex catalyst
EP3406616B1 (en) 2016-01-22 2022-06-29 Shin-Etsu Chemical Co., Ltd. Novel isocyanide compound and hydrosilylation reaction catalyst
JP6933835B2 (ja) * 2017-01-25 2021-09-08 公立大学法人大阪 鉄錯体触媒を用いたカルボニル化合物のヒドロシリル化反応によるアルコキシシランの製造方法
EP3590596B1 (en) 2017-02-28 2023-07-12 Kyushu University, National University Corporation Catalyst for hydrosilylation reaction, hydrogenation reaction, and hydrosilane reduction reaction
FR3068699B1 (fr) * 2017-07-05 2019-08-16 Elkem Silicones France Sas Compose du fer utile comme catalyseur d'hydrosilylation, de silylation deshydrogenante et de reticulation de compositions silicones
JP2019064950A (ja) 2017-09-29 2019-04-25 国立大学法人九州大学 コバルト錯体、その製造方法およびヒドロシリル化反応用触媒
US11273432B2 (en) 2018-05-31 2022-03-15 Arizona Board Of Regents On Behalf Of Arizona State University Beta-diketiminate manganese catalysts for hydrosilylation, hydroboration, and dehydrogenative pnictogen-silicon and pnictogen-boron bond formation
CN109046463B (zh) * 2018-08-16 2021-05-04 中山大学 双齿氮杂卡宾锰催化剂及其制备方法和烷基化合成应用
JP2022500530A (ja) 2018-09-13 2022-01-04 モメンティブ パフォーマンス マテリアルズ ゲーエムベーハーMomentive Performance Materials GmbH 官能性ポリシロキサン
JP6806299B2 (ja) * 2019-02-15 2021-01-06 国立大学法人九州大学 ヒドロシリル化鉄触媒の調製方法
EP3915995B1 (en) 2020-05-29 2025-11-26 Momentive Performance Materials Inc. Process for the stepwise synthesis of silahydrocarbons
CN114015055B (zh) * 2021-11-17 2023-04-14 江西晨光新材料股份有限公司 一种功能硅烷封端聚硅氧烷的合成方法及应用
CN119751516B (zh) * 2024-12-27 2025-11-28 南京杰运医药科技有限公司 一种用于制备甲酚曲唑三硅氧烷的pdi催化剂、制备方法及甲酚曲唑三硅氧烷的制备方法

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3220972A (en) * 1962-07-02 1965-11-30 Gen Electric Organosilicon process using a chloroplatinic acid reaction product as the catalyst
US3159601A (en) * 1962-07-02 1964-12-01 Gen Electric Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes
US3775452A (en) * 1971-04-28 1973-11-27 Gen Electric Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes
US4550152A (en) * 1983-10-28 1985-10-29 General Electric Company Nickel complex catalyst for hydrosilation reactions
JPH05238910A (ja) * 1991-09-30 1993-09-17 Dow Corning Corp シリコン補助剤を含む除草剤組成物
CA2080153A1 (en) * 1991-11-29 1993-05-30 Chris A. Sumpter Heat curable organopolysiloxane compositions, preformed latent platinum catalysts, and methods for making
JPH05295269A (ja) * 1991-11-29 1993-11-09 General Electric Co <Ge> 熱硬化性オルガノポリシロキサン組成物、予備生成済み潜伏性白金触媒およびそれの調製方法
US5880241A (en) * 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
US6423848B2 (en) * 1996-12-17 2002-07-23 E. I. Du Pont De Nemours And Company Tridentate ligand
US6432862B1 (en) * 1996-12-17 2002-08-13 E. I. Du Pont De Nemours And Company Cobalt catalysts for the polymerization of olefins
US6214761B1 (en) * 1996-12-17 2001-04-10 E. I. Du Pont De Nemours And Company Iron catalyst for the polymerization of olefins
US6417305B2 (en) * 1996-12-17 2002-07-09 E. I. Du Pont De Nemours And Company Oligomerization of ethylene
IL129929A0 (en) * 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
US6103946A (en) * 1997-07-15 2000-08-15 E. I. Du Pont De Nemours And Company Manufacture of α-olefins
CA2300841C (en) * 1997-09-05 2008-11-18 Bp Chemicals Limited Polymerisation catalysts
EP1062249B1 (en) * 1998-03-12 2004-10-20 BP Chemicals Limited Polymerisation catalysts
AU2738499A (en) * 1998-03-12 1999-09-27 Bp Chemicals Limited Homopolymer of ethylene
ID27209A (id) * 1998-03-12 2001-03-08 Bp Chem Int Ltd Katalis-katalis polimerisasi
DZ2737A1 (fr) * 1998-03-12 2003-09-01 Bp Chem Int Ltd Catalyseurs de polymérisation.
US6297338B1 (en) * 1998-03-30 2001-10-02 E. I. Du Pont De Nemours And Company Polymerization of olefins
US7906451B2 (en) * 1998-03-30 2011-03-15 E.I. Du Pont De Nemours And Company Mixed polymerization catalyst component for polymerizing olefins
US5986022A (en) * 1998-04-01 1999-11-16 Witco Corporation Continuous manufacture of silicone coploymers
GB9819847D0 (en) * 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
US6181303B1 (en) * 1998-10-05 2001-01-30 The United States Of America As Represented By The Secretary Of The Army Flat panel three-dimensional display unit
US6620895B1 (en) * 1999-03-22 2003-09-16 E. I. Du Pont De Nemours And Company Processing polyethylenes
DE19931873A1 (de) * 1999-04-14 2000-10-19 Bayer Ag Katalysatorsystem zur Olefinpolymerisation
US6281303B1 (en) 1999-07-27 2001-08-28 Eastman Chemical Company Olefin oligomerization and polymerization catalysts
US6458905B1 (en) * 1999-08-16 2002-10-01 Phillips Petroleum Company Complexes of pyridldiimines with vanadium and other transition metals, and their use as olefin oligomerization and polymerization catalysts
JP4883253B2 (ja) * 2001-01-11 2012-02-22 信越化学工業株式会社 シリコーンゴム用ポリウレタン系樹脂コート剤及びシリコーンゴム部材
ES2265041T3 (es) * 2001-04-30 2007-02-01 Ciba Specialty Chemicals Holding Inc. Uso de compuestos de complejos metalicos como catalizadores de oxidacion.
FR2825707B1 (fr) * 2001-06-07 2004-11-26 Rhodia Chimie Sa Procede de preparation de catalyseurs metalliques a base de carbenes, pour l'hydrosilylation de composes insatures et catalyseurs de ce type
WO2003042131A1 (en) 2001-11-15 2003-05-22 Stichting Voor De Technische Wetenschappen Hydrogenation catalyst and catalysed hydrogenation process
WO2004007509A1 (en) * 2002-07-17 2004-01-22 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin polymerization and oligomerization
AU2003293320A1 (en) * 2002-09-25 2004-05-13 Shell Internationale Research Maatschappij B.V. Catalyst systems for ethylene oligomerisation to linear alpha olefins
ATE434639T1 (de) * 2004-04-20 2009-07-15 Dow Corning Wässrige dispersionen von silikon-polyether- blockcopolymeren
US7442819B2 (en) * 2004-07-09 2008-10-28 E. I. Du Pont De Nemours And Company Catalysts for olefin polymerization or oligomerization
EP1869107A1 (en) * 2005-04-12 2007-12-26 Dow Corning Corporation Epoxy-functional polysiloxanes, silicone composition, and coated optical fiber
US8062552B2 (en) * 2005-05-19 2011-11-22 Brookhaven Science Associates, Llc Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates
CN100378111C (zh) * 2005-07-01 2008-04-02 中国科学院上海有机化学研究所 含碳氧醚键有机硅化合物、合成方法及其应用
US7268096B2 (en) * 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
CA2627466A1 (en) * 2005-10-26 2007-05-03 Ciba Holding Inc. Coloured particles for electrophoretic displays
JP2009513661A (ja) * 2005-11-01 2009-04-02 ダウ・コーニング・コーポレイション 活性剤を含むシリコーンベシクル
DE102005057460A1 (de) * 2005-12-01 2007-06-06 Wacker Chemie Ag Zu hochfesten Elastomeren vernetzbare ionisch und/oder organometallisch funktionalisierte Siliconpolymere
US7407666B2 (en) * 2006-02-23 2008-08-05 Siltech Llc Linear silicone resins in personal care applications
JP5071931B2 (ja) * 2007-07-19 2012-11-14 独立行政法人産業技術総合研究所 固体触媒

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
J. Am. Chem. Soc., Vol.128, pp.13340-13341 (2006)*
Organic Letters, Vol.10, pp.2789-2792 (2008)*
Organometallics, Vol.21, pp.74-82 (2001)*

Also Published As

Publication number Publication date
JP2017078068A (ja) 2017-04-27
CN102471358B (zh) 2015-09-30
EP2451820B1 (en) 2020-03-18
WO2011006044A2 (en) 2011-01-13
CN105085580B (zh) 2018-10-09
BR112012000169A2 (pt) 2017-08-22
KR20150013833A (ko) 2015-02-05
CN102471358A (zh) 2012-05-23
JP6389220B2 (ja) 2018-09-12
CN109289923B (zh) 2021-09-07
WO2011006044A3 (en) 2011-03-03
TWI492789B (zh) 2015-07-21
JP2012532884A (ja) 2012-12-20
KR20120023149A (ko) 2012-03-12
TW201111040A (en) 2011-04-01
CN109289923A (zh) 2019-02-01
EP2451820A2 (en) 2012-05-16
JP6059987B2 (ja) 2017-01-11
CN105085580A (zh) 2015-11-25
US8236915B2 (en) 2012-08-07
US20110009573A1 (en) 2011-01-13

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