JP6059987B2 - ヒドロシリル化触媒 - Google Patents

ヒドロシリル化触媒 Download PDF

Info

Publication number
JP6059987B2
JP6059987B2 JP2012519752A JP2012519752A JP6059987B2 JP 6059987 B2 JP6059987 B2 JP 6059987B2 JP 2012519752 A JP2012519752 A JP 2012519752A JP 2012519752 A JP2012519752 A JP 2012519752A JP 6059987 B2 JP6059987 B2 JP 6059987B2
Authority
JP
Japan
Prior art keywords
unsaturated
formula
group
complex
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2012519752A
Other languages
English (en)
Japanese (ja)
Other versions
JP2012532884A (ja
JP2012532884A5 (enExample
Inventor
デリス,ヨハネス,ジー,ピー
ナイ,スーザン,アダムス
ルイス,ケンリック,エム
ウェラー,キース,ジェイ
チリク,ポール、ジェイ
トンデロー,アーロン,エム
ラッセル,サラ,キャサリーン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cornell University
Momentive Performance Materials Inc
Original Assignee
Cornell University
Momentive Performance Materials Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cornell University, Momentive Performance Materials Inc filed Critical Cornell University
Publication of JP2012532884A publication Critical patent/JP2012532884A/ja
Publication of JP2012532884A5 publication Critical patent/JP2012532884A5/ja
Application granted granted Critical
Publication of JP6059987B2 publication Critical patent/JP6059987B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/18Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804Compounds having Si-O-C linkages
    • C07F7/1872Preparation; Treatments not provided for in C07F7/20
    • C07F7/1876Preparation; Treatments not provided for in C07F7/20 by reactions involving the formation of Si-C linkages
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02Iron compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02Iron compounds
    • C07F15/025Iron compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/18Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00Indexing scheme relating to specific properties of organic compounds
    • C07B2200/11Compounds covalently bound to a solid support
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S71/00Chemistry: fertilizers
    • Y10S71/02Chelating agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Pyridine Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2012519752A 2009-07-10 2010-07-09 ヒドロシリル化触媒 Active JP6059987B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US22459809P 2009-07-10 2009-07-10
US61/224,598 2009-07-10
US12/832,627 US8236915B2 (en) 2009-07-10 2010-07-08 Hydrosilylation catalysts
US12/832,627 2010-07-08
PCT/US2010/041487 WO2011006044A2 (en) 2009-07-10 2010-07-09 Hydrosilylation catalysts

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2016215022A Division JP6389220B2 (ja) 2009-07-10 2016-11-02 ヒドロシリル化触媒

Publications (3)

Publication Number Publication Date
JP2012532884A JP2012532884A (ja) 2012-12-20
JP2012532884A5 JP2012532884A5 (enExample) 2016-12-22
JP6059987B2 true JP6059987B2 (ja) 2017-01-11

Family

ID=43427966

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2012519752A Active JP6059987B2 (ja) 2009-07-10 2010-07-09 ヒドロシリル化触媒
JP2016215022A Active JP6389220B2 (ja) 2009-07-10 2016-11-02 ヒドロシリル化触媒

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2016215022A Active JP6389220B2 (ja) 2009-07-10 2016-11-02 ヒドロシリル化触媒

Country Status (8)

Country Link
US (1) US8236915B2 (enExample)
EP (1) EP2451820B1 (enExample)
JP (2) JP6059987B2 (enExample)
KR (2) KR20120023149A (enExample)
CN (3) CN102471358B (enExample)
BR (1) BR112012000169A2 (enExample)
TW (1) TWI492789B (enExample)
WO (1) WO2011006044A2 (enExample)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112013012733A2 (pt) 2010-11-24 2016-09-13 Univ Cornell ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação
EP2643330B1 (en) 2010-11-24 2017-01-04 Momentive Performance Materials Inc. Metal-catalyzed mono-hydrosilylation of polyunsaturated compounds
EP2643335B1 (en) * 2010-11-24 2015-03-11 Momentive Performance Materials Inc. Hydrosilylation catalyst
US9394325B2 (en) * 2011-08-19 2016-07-19 The Trustees Of Princeton University Enantiopure base-metal catalysts for asymmetric catalysis and bis(imino)pyridine iron alkyl complexes for catalysis
US20140231702A1 (en) * 2011-09-20 2014-08-21 Dow Corning Corporation Cobalt Containing Hydrosilylation Catalysts and Compositions Containing the Catalysts
JP6101695B2 (ja) * 2011-09-20 2017-03-22 ダウ コーニング コーポレーションDow Corning Corporation ニッケル含有ヒドロシリル化触媒及びその触媒を含有する組成物
US20140249311A1 (en) * 2011-09-20 2014-09-04 Dow Corning Corporation Iron Containing Hydrosilylation Catalysts and Compositions Containing the Catalysts
CN103842441B (zh) * 2011-10-04 2015-12-23 道康宁公司 含铁(iii)络合物和缩合反应催化剂、制备该催化剂的方法及含有该催化剂的组合物
US9139699B2 (en) 2012-10-04 2015-09-22 Dow Corning Corporation Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
WO2013081794A1 (en) * 2011-12-01 2013-06-06 Dow Corning Corporation Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use
US9782763B2 (en) * 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
US9447125B2 (en) * 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US8927674B2 (en) 2012-08-16 2015-01-06 Princeton University Dehydrogenative silylation and crosslinking using cobalt catalysts
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
JP6125222B2 (ja) * 2012-08-16 2017-05-10 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒を用いる脱水素シリル化および架橋
FR3000069B1 (fr) 2012-12-21 2015-02-06 Bluestar Silicones France Procede d'hydrosilylation d'un siloxane photocatalyse par un compose polyoxometallate
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
WO2014182670A2 (en) 2013-05-06 2014-11-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
JP2016520083A (ja) 2013-05-15 2016-07-11 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド シリルヒドリドによる金属塩の活性化およびヒドロシリル化反応におけるその使用
US9708355B2 (en) 2013-06-12 2017-07-18 Arizona Board Of Regents On Behalf Of Arizona State University First-row transition metal hydrogenation and hydrosilylation catalysts
WO2015023328A1 (en) 2013-08-14 2015-02-19 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine dimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
EP3052452A1 (de) * 2013-10-02 2016-08-10 Basf Se Verwendung von poly(oxyalkylen)oxy- bzw. poly(oxyalkylen)aminoalkyltrialkoxysilanen als dispergiermittel
EP3071583B1 (en) 2013-11-19 2018-05-09 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
WO2015077306A1 (en) 2013-11-19 2015-05-28 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
TW201524603A (zh) * 2013-11-19 2015-07-01 Momentive Performance Mat Inc 鈷觸媒及其於矽氫化與脫氫甲矽烷化之用途
US9387468B2 (en) 2013-11-19 2016-07-12 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
WO2015171881A1 (en) * 2014-05-08 2015-11-12 Momentive Performance Materials Inc. Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
WO2016024611A1 (ja) 2014-08-12 2016-02-18 国立大学法人九州大学 ヒドロシリル化反応触媒
WO2016024607A1 (ja) 2014-08-12 2016-02-18 国立大学法人九州大学 ヒドロシリル化反応触媒
JP6761997B2 (ja) * 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
CN104478919B (zh) * 2014-11-18 2018-02-02 浙江大学 一种合成手性硅烷化合物的方法
US10046318B2 (en) 2014-12-19 2018-08-14 Dow Silicones Corporation Ligand components, associated reaction products, activated reaction products, hydrosilylation catalysts and hydrosilylation curable compositions including the ligand components, and associated methods for preparing same
CN107847921B (zh) 2015-07-14 2022-01-14 国立大学法人九州大学 氢化硅烷化反应催化剂
US10717752B2 (en) * 2015-07-24 2020-07-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using pyridinediimine cobalt carboxylate catalysts
WO2017100106A1 (en) * 2015-12-07 2017-06-15 Dow Corning Corporation Method and composition for hydrosilylation of carboxylic acid alkenyl esters and hydrogen terminated organosiloxane oligomers with an iridium complex catalyst
EP3406616B1 (en) 2016-01-22 2022-06-29 Shin-Etsu Chemical Co., Ltd. Novel isocyanide compound and hydrosilylation reaction catalyst
JP6933835B2 (ja) * 2017-01-25 2021-09-08 公立大学法人大阪 鉄錯体触媒を用いたカルボニル化合物のヒドロシリル化反応によるアルコキシシランの製造方法
CN110366449B (zh) 2017-02-28 2022-10-21 国立大学法人九州大学 氢化硅烷化反应、氢化反应和氢硅烷还原反应用催化剂
FR3068699B1 (fr) * 2017-07-05 2019-08-16 Elkem Silicones France Sas Compose du fer utile comme catalyseur d'hydrosilylation, de silylation deshydrogenante et de reticulation de compositions silicones
JP2019064950A (ja) 2017-09-29 2019-04-25 国立大学法人九州大学 コバルト錯体、その製造方法およびヒドロシリル化反応用触媒
US11273432B2 (en) 2018-05-31 2022-03-15 Arizona Board Of Regents On Behalf Of Arizona State University Beta-diketiminate manganese catalysts for hydrosilylation, hydroboration, and dehydrogenative pnictogen-silicon and pnictogen-boron bond formation
CN109046463B (zh) * 2018-08-16 2021-05-04 中山大学 双齿氮杂卡宾锰催化剂及其制备方法和烷基化合成应用
KR102807413B1 (ko) 2018-09-13 2025-05-13 모멘티브 퍼포먼스 머티리얼즈 게엠베하 기능성 폴리실록산
JP6806299B2 (ja) * 2019-02-15 2021-01-06 国立大学法人九州大学 ヒドロシリル化鉄触媒の調製方法
EP3915995B1 (en) 2020-05-29 2025-11-26 Momentive Performance Materials Inc. Process for the stepwise synthesis of silahydrocarbons
CN114015055B (zh) * 2021-11-17 2023-04-14 江西晨光新材料股份有限公司 一种功能硅烷封端聚硅氧烷的合成方法及应用
CN119751516B (zh) * 2024-12-27 2025-11-28 南京杰运医药科技有限公司 一种用于制备甲酚曲唑三硅氧烷的pdi催化剂、制备方法及甲酚曲唑三硅氧烷的制备方法

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3220972A (en) * 1962-07-02 1965-11-30 Gen Electric Organosilicon process using a chloroplatinic acid reaction product as the catalyst
US3159601A (en) * 1962-07-02 1964-12-01 Gen Electric Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes
US3775452A (en) * 1971-04-28 1973-11-27 Gen Electric Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes
US4550152A (en) * 1983-10-28 1985-10-29 General Electric Company Nickel complex catalyst for hydrosilation reactions
CA2079308A1 (en) * 1991-09-30 1993-03-31 Lenin J. Petroff Herbicidal compositions containing a silicone adjuvant
JPH05295269A (ja) * 1991-11-29 1993-11-09 General Electric Co <Ge> 熱硬化性オルガノポリシロキサン組成物、予備生成済み潜伏性白金触媒およびそれの調製方法
CA2080153A1 (en) * 1991-11-29 1993-05-30 Chris A. Sumpter Heat curable organopolysiloxane compositions, preformed latent platinum catalysts, and methods for making
US5880241A (en) * 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
US6417305B2 (en) * 1996-12-17 2002-07-09 E. I. Du Pont De Nemours And Company Oligomerization of ethylene
US6214761B1 (en) * 1996-12-17 2001-04-10 E. I. Du Pont De Nemours And Company Iron catalyst for the polymerization of olefins
US6432862B1 (en) * 1996-12-17 2002-08-13 E. I. Du Pont De Nemours And Company Cobalt catalysts for the polymerization of olefins
IL129929A0 (en) * 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
US6423848B2 (en) * 1996-12-17 2002-07-23 E. I. Du Pont De Nemours And Company Tridentate ligand
US6103946A (en) * 1997-07-15 2000-08-15 E. I. Du Pont De Nemours And Company Manufacture of α-olefins
PT1015501E (pt) * 1997-09-05 2002-11-29 Bp Chem Int Ltd Catalisadores de polimerizacao
DE69921304T2 (de) * 1998-03-12 2005-02-24 Bp Chemicals Ltd. Polymerisationskatalysatoren
ID27209A (id) * 1998-03-12 2001-03-08 Bp Chem Int Ltd Katalis-katalis polimerisasi
JP4467181B2 (ja) * 1998-03-12 2010-05-26 イネオス ユーロープ リミテッド 重合触媒
CA2619692A1 (en) * 1998-03-12 1999-09-16 Ineos Europe Limited Homopolymer of ethylene
US7906451B2 (en) * 1998-03-30 2011-03-15 E.I. Du Pont De Nemours And Company Mixed polymerization catalyst component for polymerizing olefins
US6297338B1 (en) * 1998-03-30 2001-10-02 E. I. Du Pont De Nemours And Company Polymerization of olefins
US5986022A (en) * 1998-04-01 1999-11-16 Witco Corporation Continuous manufacture of silicone coploymers
GB9819847D0 (en) * 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
US6181303B1 (en) * 1998-10-05 2001-01-30 The United States Of America As Represented By The Secretary Of The Army Flat panel three-dimensional display unit
US6620895B1 (en) * 1999-03-22 2003-09-16 E. I. Du Pont De Nemours And Company Processing polyethylenes
DE19931873A1 (de) * 1999-04-14 2000-10-19 Bayer Ag Katalysatorsystem zur Olefinpolymerisation
US6281303B1 (en) 1999-07-27 2001-08-28 Eastman Chemical Company Olefin oligomerization and polymerization catalysts
US6458905B1 (en) * 1999-08-16 2002-10-01 Phillips Petroleum Company Complexes of pyridldiimines with vanadium and other transition metals, and their use as olefin oligomerization and polymerization catalysts
JP4883253B2 (ja) * 2001-01-11 2012-02-22 信越化学工業株式会社 シリコーンゴム用ポリウレタン系樹脂コート剤及びシリコーンゴム部材
DE60211884T2 (de) * 2001-04-30 2006-11-23 Ciba Speciality Chemicals Holding Inc. Verwendung von metallkomplexverbindungen als oxidationskatalysatoren
FR2825707B1 (fr) * 2001-06-07 2004-11-26 Rhodia Chimie Sa Procede de preparation de catalyseurs metalliques a base de carbenes, pour l'hydrosilylation de composes insatures et catalyseurs de ce type
WO2003042131A1 (en) 2001-11-15 2003-05-22 Stichting Voor De Technische Wetenschappen Hydrogenation catalyst and catalysed hydrogenation process
US7247687B2 (en) * 2002-07-17 2007-07-24 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin polymerization and oligomerization
EP1542797B1 (en) * 2002-09-25 2006-05-31 Shell Internationale Researchmaatschappij B.V. Catalyst systems for ethylene oligomerisation to linear alpha olefins
WO2005103118A1 (en) * 2004-04-20 2005-11-03 Dow Corning Corporation Aqueous dispersions of silicone polyether block copolymers
US7442819B2 (en) * 2004-07-09 2008-10-28 E. I. Du Pont De Nemours And Company Catalysts for olefin polymerization or oligomerization
KR20130058766A (ko) * 2005-04-12 2013-06-04 다우 코닝 코포레이션 에폭시 관능성 폴리실록산, 실리콘 조성물 및 피복 광섬유
US8062552B2 (en) * 2005-05-19 2011-11-22 Brookhaven Science Associates, Llc Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates
CN100378111C (zh) * 2005-07-01 2008-04-02 中国科学院上海有机化学研究所 含碳氧醚键有机硅化合物、合成方法及其应用
US7268096B2 (en) * 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
EP1948738B1 (en) * 2005-10-26 2018-02-28 Basf Se Coloured particles for electrophoretic displays
JP2009513661A (ja) * 2005-11-01 2009-04-02 ダウ・コーニング・コーポレイション 活性剤を含むシリコーンベシクル
DE102005057460A1 (de) * 2005-12-01 2007-06-06 Wacker Chemie Ag Zu hochfesten Elastomeren vernetzbare ionisch und/oder organometallisch funktionalisierte Siliconpolymere
US7407666B2 (en) * 2006-02-23 2008-08-05 Siltech Llc Linear silicone resins in personal care applications
JP5071931B2 (ja) * 2007-07-19 2012-11-14 独立行政法人産業技術総合研究所 固体触媒

Also Published As

Publication number Publication date
TW201111040A (en) 2011-04-01
WO2011006044A2 (en) 2011-01-13
WO2011006044A3 (en) 2011-03-03
JP2012532884A (ja) 2012-12-20
EP2451820B1 (en) 2020-03-18
JP2017078068A (ja) 2017-04-27
US20110009573A1 (en) 2011-01-13
US8236915B2 (en) 2012-08-07
KR20120023149A (ko) 2012-03-12
CN109289923A (zh) 2019-02-01
CN102471358B (zh) 2015-09-30
CN105085580B (zh) 2018-10-09
KR20150013833A (ko) 2015-02-05
CN105085580A (zh) 2015-11-25
TWI492789B (zh) 2015-07-21
BR112012000169A2 (pt) 2017-08-22
EP2451820A2 (en) 2012-05-16
CN109289923B (zh) 2021-09-07
KR101710043B1 (ko) 2017-03-08
JP6389220B2 (ja) 2018-09-12
CN102471358A (zh) 2012-05-23

Similar Documents

Publication Publication Date Title
JP6389220B2 (ja) ヒドロシリル化触媒
JP5969387B2 (ja) ヒドロシリル化触媒
US8765987B2 (en) In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts
US8637626B2 (en) Non-precious metal-containing 2,8-bis(imino)quinoline complexes and their use as hydrosilylation catalysts
US11052383B2 (en) Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
WO2016024607A1 (ja) ヒドロシリル化反応触媒

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20130703

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20140717

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20140722

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20141016

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20141023

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20141120

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20141128

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20141222

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20150331

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20150623

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20151201

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20160229

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20160314

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20160705

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20161004

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20161102

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20161206

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20161212

R150 Certificate of patent or registration of utility model

Ref document number: 6059987

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250