KR101684036B1 - 레독스 플로우 2차 전지 및 레독스 플로우 2차 전지용 전해질막 - Google Patents

레독스 플로우 2차 전지 및 레독스 플로우 2차 전지용 전해질막 Download PDF

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KR101684036B1
KR101684036B1 KR1020147017289A KR20147017289A KR101684036B1 KR 101684036 B1 KR101684036 B1 KR 101684036B1 KR 1020147017289 A KR1020147017289 A KR 1020147017289A KR 20147017289 A KR20147017289 A KR 20147017289A KR 101684036 B1 KR101684036 B1 KR 101684036B1
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polymer
electrolyte
redox flow
mass
secondary battery
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KR20140098189A (ko
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나오토 미야케
기요아키 모리우치
미치루 구바타
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아사히 가세이 가부시키가이샤
스미토모덴키고교가부시키가이샤
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
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    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
    • C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
    • C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
    • C—CHEMISTRY; METALLURGY
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
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    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
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    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
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    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
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    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
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    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • H—ELECTRICITY
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    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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  • Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
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  • Sustainable Development (AREA)
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  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Conductive Materials (AREA)
KR1020147017289A 2011-12-28 2012-12-27 레독스 플로우 2차 전지 및 레독스 플로우 2차 전지용 전해질막 Active KR101684036B1 (ko)

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JPJP-P-2011-290035 2011-12-28
JP2011290035 2011-12-28
PCT/JP2012/083944 WO2013100079A1 (ja) 2011-12-28 2012-12-27 レドックスフロー二次電池及びレドックスフロー二次電池用電解質膜

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KR20140098189A KR20140098189A (ko) 2014-08-07
KR101684036B1 true KR101684036B1 (ko) 2016-12-07

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US (1) US9799906B2 (OSRAM)
EP (1) EP2800191B8 (OSRAM)
JP (1) JP6005065B2 (OSRAM)
KR (1) KR101684036B1 (OSRAM)
CN (2) CN105845958B (OSRAM)
AU (1) AU2012361558B2 (OSRAM)
IN (1) IN2014MN01284A (OSRAM)
TW (1) TWI499108B (OSRAM)
WO (1) WO2013100079A1 (OSRAM)

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KR20220098186A (ko) * 2020-04-24 2022-07-11 아사히 가세이 가부시키가이샤 레독스 플로 전지용 격막, 레독스 플로 전지용 격막의 제조 방법, 레독스 플로 전지용 격막 전극 접합체, 레독스 플로 전지용 셀, 및 레독스 플로 전지

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JP6101494B2 (ja) * 2012-01-20 2017-03-22 旭化成株式会社 レドックスフロー二次電池用電解質膜
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CN104377371A (zh) * 2013-08-13 2015-02-25 旭化成电子材料株式会社 氧化还原液流二次电池用电解质膜
JP6415807B2 (ja) * 2013-10-24 2018-10-31 国立研究開発法人物質・材料研究機構 パーフルオロスルホン酸ポリマー−アゾールブレンド膜及びその製造方法、並びに固体高分子型燃料電池
CN111304691A (zh) * 2015-05-18 2020-06-19 旭化成株式会社 离子交换膜
US10978721B2 (en) 2015-12-24 2021-04-13 Toray Industries, Inc. Polyolefin microporous membrane, battery separator and production method
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JP2017184586A (ja) * 2016-03-31 2017-10-05 旭化成株式会社 イオン交換型高分子アクチュエータ
KR102069407B1 (ko) * 2016-03-31 2020-01-22 주식회사 엘지화학 이온교환 분리막, 이를 포함하는 전기화학 전지, 흐름전지 및 연료 전지, 및 이의 제조방법
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KR101952923B1 (ko) * 2017-08-29 2019-02-27 한국화학연구원 비율이 조절된 측쇄를 포함하는 폴리벤즈이미다졸 전해질막, 제조방법, 이를 이용한 전기화학소자
KR20190026530A (ko) * 2017-09-05 2019-03-13 롯데케미칼 주식회사 레독스 흐름 전지용 분리막, 레독스 흐름 전지용 제조방법, 및 레독스 흐름 전지
KR102066239B1 (ko) 2017-09-18 2020-01-14 롯데케미칼 주식회사 분리막 복합체 및 레독스 흐름 전지
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WO2020060857A1 (en) 2018-09-14 2020-03-26 University Of South Carolina New method for producing pbi films without organic solvents
JP7523808B2 (ja) 2018-09-14 2024-07-29 ユニバーシティー オブ サウス カロライナ レドックスフロー電池膜を形成する方法
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CN112930365B (zh) * 2018-10-19 2023-07-21 Ａｇｃ株式会社 离子交换膜、氧化还原液流电池
CN111139498B (zh) * 2018-11-05 2022-06-03 旭化成株式会社 离子交换膜和电解槽
JP7421898B2 (ja) * 2018-11-05 2024-01-25 旭化成株式会社 イオン交換膜及び電解槽
KR20200065695A (ko) * 2018-11-30 2020-06-09 롯데케미칼 주식회사 레독스 흐름 전지용 분리막 및 이의 제조방법
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KR102485668B1 (ko) * 2019-05-17 2023-01-05 주식회사 엘지에너지솔루션 전기화학소자용 분리막 및 이를 포함하는 전기화학소자
US11777124B2 (en) 2020-03-06 2023-10-03 University Of South Carolina Proton-conducting PBI membrane processing with enhanced performance and durability
JP7478310B2 (ja) 2020-08-19 2024-05-02 ダブリュ．エル．ゴア アンド アソシエイツ，インコーポレイティド 改善された電気化学膜
US11271226B1 (en) 2020-12-11 2022-03-08 Raytheon Technologies Corporation Redox flow battery with improved efficiency
WO2023167545A1 (ko) * 2022-03-04 2023-09-07 한국화학연구원 보호기가 도입된 폴리벤즈이미다졸, 이를 이용한 막의 제조방법 및 이의 용도
EP4516845A4 (en) * 2022-04-27 2026-04-29 Asahi Chemical Ind Ion exchange membrane, membrane electrode assembly, cell for redox flow batteries, and redox flow battery
CN115353579B (zh) * 2022-10-20 2023-04-18 国家电投集团氢能科技发展有限公司 抗溶胀两性离子交换树脂及制备方法和离子交换膜及应用
GB202313728D0 (en) * 2023-09-08 2023-10-25 Superdielectrics Supercap Ltd Energy storage cell
CN118909288A (zh) * 2024-10-09 2024-11-08 杭州德海艾科能源科技有限公司 一种交联聚乙烯吡咯烷酮表面改性的全氟磺酸膜制备方法

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