KR101535199B1 - 개선된 분산성을 갖는 슬러리 및 그의 용도 - Google Patents

개선된 분산성을 갖는 슬러리 및 그의 용도 Download PDF

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KR101535199B1
KR101535199B1 KR1020130147428A KR20130147428A KR101535199B1 KR 101535199 B1 KR101535199 B1 KR 101535199B1 KR 1020130147428 A KR1020130147428 A KR 1020130147428A KR 20130147428 A KR20130147428 A KR 20130147428A KR 101535199 B1 KR101535199 B1 KR 101535199B1
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South Korea
Prior art keywords
inorganic particles
slurry
lithium
group
oxide
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KR1020130147428A
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Korean (ko)
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KR20140070465A (ko
Inventor
이주성
윤수진
한다경
유보경
김종훈
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주식회사 엘지화학
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Priority to JP2015535583A priority Critical patent/JP6110949B2/ja
Priority to PCT/KR2013/011056 priority patent/WO2014084692A1/ko
Priority to EP13859566.5A priority patent/EP2784843B1/en
Priority to HUE13859566A priority patent/HUE046104T2/hu
Priority to BR112014017660-4A priority patent/BR112014017660B1/pt
Priority to CN201380007578.3A priority patent/CN104094447A/zh
Priority to CN201811177429.2A priority patent/CN109309185A/zh
Priority to IN2238MUN2014 priority patent/IN2014MN02238A/en
Priority to PL13859566T priority patent/PL2784843T3/pl
Priority to US14/258,137 priority patent/US9991491B2/en
Publication of KR20140070465A publication Critical patent/KR20140070465A/ko
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Publication of KR101535199B1 publication Critical patent/KR101535199B1/ko
Priority to JP2017013025A priority patent/JP6387127B2/ja
Priority to US15/969,345 priority patent/US11031656B2/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/446—Composite material consisting of a mixture of organic and inorganic materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/431—Inorganic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/443—Particulate material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
    • H01M50/451—Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
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    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/137—Electrodes based on electro-active polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1399—Processes of manufacture of electrodes based on electro-active polymers
    • H—ELECTRICITY
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    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Cell Separators (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
KR1020130147428A 2012-11-30 2013-11-29 개선된 분산성을 갖는 슬러리 및 그의 용도 Active KR101535199B1 (ko)

Priority Applications (12)

Application Number Priority Date Filing Date Title
PL13859566T PL2784843T3 (pl) 2012-11-30 2013-12-02 Zawiesina o ulepszonej dyspergowalności i jej zastosowanie
EP13859566.5A EP2784843B1 (en) 2012-11-30 2013-12-02 Slurry with improved dispersibility and use therefor
HUE13859566A HUE046104T2 (hu) 2012-11-30 2013-12-02 Zagy javított diszpergálhatósággal, és ennek alkalmazása
BR112014017660-4A BR112014017660B1 (pt) 2012-11-30 2013-12-02 Pasta com dispersibilidade melhorada compreendendo partículas inorgânicas, separador do compósito para um dispositivo eletroquímico, composto de cátodo, composto de ânodo e dispositivo eletroquímico
CN201380007578.3A CN104094447A (zh) 2012-11-30 2013-12-02 具有改善的分散性的浆料及其用途
CN201811177429.2A CN109309185A (zh) 2012-11-30 2013-12-02 具有改善的分散性的浆料及其用途
JP2015535583A JP6110949B2 (ja) 2012-11-30 2013-12-02 改善された分散性を有するスラリー及びその用途
IN2238MUN2014 IN2014MN02238A (enExample) 2012-11-30 2013-12-02
PCT/KR2013/011056 WO2014084692A1 (ko) 2012-11-30 2013-12-02 개선된 분산성을 갖는 슬러리 및 그의 용도
US14/258,137 US9991491B2 (en) 2012-11-30 2014-04-22 Slurry including inorganic particles with improve dispersibility by controlling particle size and slurry viscosity
JP2017013025A JP6387127B2 (ja) 2012-11-30 2017-01-27 改善された分散性を有するスラリー及びその用途
US15/969,345 US11031656B2 (en) 2012-11-30 2018-05-02 Composite separator including porous coating layer made from slurry having improved dispersibility

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20120138434 2012-11-30
KR1020120138434 2012-11-30

Publications (2)

Publication Number Publication Date
KR20140070465A KR20140070465A (ko) 2014-06-10
KR101535199B1 true KR101535199B1 (ko) 2015-07-09

Family

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KR1020130147428A Active KR101535199B1 (ko) 2012-11-30 2013-11-29 개선된 분산성을 갖는 슬러리 및 그의 용도

Country Status (10)

Country Link
US (2) US9991491B2 (enExample)
EP (1) EP2784843B1 (enExample)
JP (2) JP6110949B2 (enExample)
KR (1) KR101535199B1 (enExample)
CN (2) CN104094447A (enExample)
BR (1) BR112014017660B1 (enExample)
HU (1) HUE046104T2 (enExample)
IN (1) IN2014MN02238A (enExample)
PL (1) PL2784843T3 (enExample)
WO (1) WO2014084692A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
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US11990643B2 (en) 2020-07-07 2024-05-21 Sk Innovation Co., Ltd. Separator having inorganic composite layer including inorganic particles and one-dimensional inorganic material without polymer-based organic binder and electrochemical device using the same
US12021258B2 (en) 2020-07-07 2024-06-25 Sk Innovation Co., Ltd. Separator having inorganic composite layer including inorganic particles and one-dimensional inorganic material and electrochemical device using the same

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KR102372086B1 (ko) * 2014-12-19 2022-03-10 삼성전자주식회사 복합막, 그 제조방법, 이를 포함한 음극 구조체 및 리튬이차전지
EP3518317B1 (en) * 2016-11-18 2020-09-23 LG Chem, Ltd. Separator and electrochemical device comprising same
US11843118B2 (en) 2017-07-07 2023-12-12 Ppg Industries Ohio, Inc. Electrode binder slurry composition for lithium ion electrical storage devices
AU2018297173B2 (en) 2017-07-07 2021-03-11 Ppg Industries Ohio, Inc. Electrode binder slurry composition for lithium ion electrical storage devices
KR20200026967A (ko) 2017-07-07 2020-03-11 피피지 인더스트리즈 오하이오 인코포레이티드 리튬 이온 전기 저장 장치용 전극 슬러리 조성물
US11799086B2 (en) 2017-07-07 2023-10-24 Ppg Industries Ohio, Inc. Electrode binder slurry composition for lithium ion electrical storage devices
JP6851928B2 (ja) * 2017-07-26 2021-03-31 旭化成株式会社 正極スラリー
KR102144878B1 (ko) 2017-08-25 2020-08-14 주식회사 엘지화학 이차전지 분리막 코팅용 슬러리 및 이를 이용한 이차전지 분리막
WO2019097449A1 (en) 2017-11-16 2019-05-23 3M Innovative Properties Company Method of making polymer matrix composites
KR102132756B1 (ko) 2017-12-06 2020-07-13 주식회사 엘지화학 이차전지 분리막 코팅용 슬러리 조성물 및 이를 이용한 이차전지 분리막
CN108987754A (zh) * 2018-07-25 2018-12-11 力信（江苏）能源科技有限责任公司 分散剂、含分散剂的正极浆料及其锂电池的制备方法
KR102344926B1 (ko) * 2018-09-12 2021-12-30 주식회사 엘지화학 전기화학소자용 세퍼레이터 및 이의 제조방법
WO2020101363A1 (ko) * 2018-11-14 2020-05-22 주식회사 엘지화학 리튬이차전지용 세퍼레이터 및 이의 제조방법
CN112544007B (zh) * 2019-01-10 2024-01-09 株式会社Lg新能源 固体电解质膜以及包含其的全固态电池
CN110157258B (zh) * 2019-04-01 2021-12-24 中国船舶重工集团公司第七二五研究所 一种压电/电磁混合驱动防污涂层材料及其制备方法
KR102524662B1 (ko) 2019-05-09 2023-04-20 주식회사 엘지에너지솔루션 바인더 수지 조성물 및 이를 포함하는 전기화학소자용 분리막
CN111916617A (zh) * 2019-05-10 2020-11-10 湖南农业大学 一种纤维素基功能化隔膜及其制备方法和应用
US11094998B2 (en) * 2019-06-19 2021-08-17 GM Global Technology Operations LLC Ceramic-coated separators for lithium-containing electrochemical cells and methods of making the same
CN112186140B (zh) * 2019-07-04 2022-01-28 江苏天奈科技股份有限公司 应用于硅碳负极的硅基活性复合导电浆料及负极合浆方法
KR102787908B1 (ko) * 2019-11-18 2025-03-26 주식회사 엘지에너지솔루션 전기화학소자용 분리막 및 이를 포함하는 전기화학소자
CN111900314B (zh) * 2020-08-04 2022-02-22 中国科学院物理研究所 一种金属复合氧化物涂覆的电池隔膜及其制备方法和应用
CN114730864B (zh) * 2020-09-07 2025-06-17 株式会社Lg新能源 用于二次电池的电极和制造其的方法
CN112993488A (zh) * 2021-02-08 2021-06-18 哈尔滨工业大学 一种锂离子电池隔膜材料及其制备方法

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