KR101322668B1 - 제어된 자유 라디칼 중합반응에 의해 제조된 단독중합체 및공중합체의 후개질방법 - Google Patents
제어된 자유 라디칼 중합반응에 의해 제조된 단독중합체 및공중합체의 후개질방법 Download PDFInfo
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- KR101322668B1 KR101322668B1 KR1020077018443A KR20077018443A KR101322668B1 KR 101322668 B1 KR101322668 B1 KR 101322668B1 KR 1020077018443 A KR1020077018443 A KR 1020077018443A KR 20077018443 A KR20077018443 A KR 20077018443A KR 101322668 B1 KR101322668 B1 KR 101322668B1
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- alkyl
- formula
- copolymer
- monomer
- alcohol
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- 229920001577 copolymer Polymers 0.000 title claims abstract description 84
- 238000010526 radical polymerization reaction Methods 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims description 65
- 230000008569 process Effects 0.000 title claims description 32
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- 229920001519 homopolymer Polymers 0.000 title description 9
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- 239000012141 concentrate Substances 0.000 claims abstract description 21
- 239000002270 dispersing agent Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- -1 nitroxy radical Chemical class 0.000 claims description 114
- 239000000178 monomer Substances 0.000 claims description 105
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 84
- 239000000203 mixture Substances 0.000 claims description 78
- 125000000217 alkyl group Chemical group 0.000 claims description 71
- 238000006116 polymerization reaction Methods 0.000 claims description 42
- 229920001400 block copolymer Polymers 0.000 claims description 40
- 125000004432 carbon atom Chemical group C* 0.000 claims description 39
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 35
- 229910052739 hydrogen Inorganic materials 0.000 claims description 34
- 239000001257 hydrogen Substances 0.000 claims description 32
- 150000003254 radicals Chemical class 0.000 claims description 31
- 150000001875 compounds Chemical class 0.000 claims description 25
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 23
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 18
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 17
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 16
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical group C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 14
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 14
- 150000002431 hydrogen Chemical group 0.000 claims description 14
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- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 9
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 9
- FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 claims description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 7
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- 238000002360 preparation method Methods 0.000 claims description 7
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims description 7
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 6
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 claims description 6
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 6
- 125000003282 alkyl amino group Chemical group 0.000 claims description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 6
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
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- 125000004648 C2-C8 alkenyl group Chemical group 0.000 claims description 4
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- 150000001450 anions Chemical class 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical compound O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
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- 239000011593 sulfur Substances 0.000 claims description 2
- MJPPGVVIDGQOQT-UHFFFAOYSA-N 2-bromo-5-(2-bromo-2-nitroethenyl)furan Chemical compound [O-][N+](=O)C(Br)=CC1=CC=C(Br)O1 MJPPGVVIDGQOQT-UHFFFAOYSA-N 0.000 claims 2
- LCIYFINKFGDAHD-UHFFFAOYSA-N azepane;3-nitrobenzoic acid Chemical compound C1CCCNCC1.OC(=O)C1=CC=CC([N+]([O-])=O)=C1 LCIYFINKFGDAHD-UHFFFAOYSA-N 0.000 claims 2
- NIXVAPHNPNMUIX-UHFFFAOYSA-N 6-amino-2-methylhex-2-enamide Chemical compound NC(=O)C(C)=CCCCN NIXVAPHNPNMUIX-UHFFFAOYSA-N 0.000 claims 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
- C08G81/025—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/30—Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Graft Or Block Polymers (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05100102 | 2005-01-11 | ||
| EP05100102.2 | 2005-01-11 | ||
| PCT/EP2006/050000 WO2006074969A1 (en) | 2005-01-11 | 2006-01-02 | Process for the post-modification of homo and copolymers prepared by controlled free radical polymerization processes |
Publications (2)
| Publication Number | Publication Date |
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| KR20070099646A KR20070099646A (ko) | 2007-10-09 |
| KR101322668B1 true KR101322668B1 (ko) | 2013-10-30 |
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| BR (1) | BRPI0606305A2 (enExample) |
| RU (1) | RU2401281C2 (enExample) |
| WO (1) | WO2006074969A1 (enExample) |
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| CN101490620B (zh) * | 2006-07-11 | 2013-02-20 | 西巴控股有限公司 | 滤色器组合物 |
| WO2008079677A2 (en) * | 2006-12-20 | 2008-07-03 | Arkema Inc. | Polymer encapsulation and/or binding |
| DE102007021867A1 (de) * | 2007-05-10 | 2008-11-20 | Clariant International Limited | Pigmentpräparationen auf Wasserbasis |
| DE102007021870A1 (de) * | 2007-05-10 | 2008-11-20 | Clariant International Limited | Wässrige Pigmentpräparationen |
| DE102007039783A1 (de) * | 2007-08-23 | 2009-02-26 | Clariant International Ltd. | Wässrige Pigmentpräparationen mit anionischen Additiven auf Allyl- und Vinyletherbasis |
| DE102007039781A1 (de) * | 2007-08-23 | 2009-02-26 | Clariant International Ltd. | Wässrige Pigmentpräparationen mit nichtionischen Additiven auf Allyl- und Vinyletherbasis |
| KR101517873B1 (ko) | 2007-09-07 | 2015-05-08 | 바스프 에스이 | 전기영동 이동성 유기 착색제를 포함하는 캡슐화된 분산액 |
| WO2009077396A1 (en) * | 2007-12-18 | 2009-06-25 | Basf Se | Biodiesel cold flow improver |
| CN101952379B (zh) * | 2008-02-22 | 2014-02-26 | 巴斯夫欧洲公司 | 氟流平剂 |
| WO2009135784A1 (en) | 2008-05-09 | 2009-11-12 | Basf Se | Pearlescent pigments coated with a metal oxide/hydroxide layer and an acrylic copolymer |
| EP2291422B1 (en) | 2008-06-23 | 2015-10-21 | Basf Se | Pigment dispersants with modified copolymers |
| DE102008037973A1 (de) * | 2008-08-16 | 2010-02-18 | Clariant International Limited | Trockene Pigmentpräparationen mit anionischen Additiven |
| CN102196849B (zh) | 2008-10-28 | 2014-12-31 | 阿科玛股份有限公司 | 水通性聚合物薄膜 |
| WO2010081756A1 (en) | 2009-01-19 | 2010-07-22 | Basf Se | Black pigment dispersion |
| EP2448985B1 (en) * | 2009-07-01 | 2015-01-14 | Bridgestone Corporation | Method of making hydroxyaryl-functionalized interpolymer by free radical initiated polymerization |
| CN102958993B (zh) | 2010-06-29 | 2015-07-22 | 巴斯夫欧洲公司 | 改善聚合物熔体的流动性能的方法 |
| US9051478B2 (en) | 2010-07-22 | 2015-06-09 | Basf Se | Additive combination for sealants applications |
| CN102199261B (zh) * | 2011-04-13 | 2012-09-19 | 山东交通学院 | 聚乙二醇-b-聚苯乙烯-b-聚全氟己基乙基丙烯酸酯及其制备方法 |
| RU2014120925A (ru) * | 2011-10-25 | 2015-12-10 | Басф Се | Применение гребенчатых или блок-сополимеров в качестве средств против повторного осаждения загрязнения и грязеотталкивающих средств в процессах стирки |
| DE102011120474A1 (de) * | 2011-12-08 | 2013-06-13 | Treofan Germany Gmbh & Co. Kg | Hochporöse Separator- Folie mit Beschichtung |
| DE102011121606A1 (de) * | 2011-12-20 | 2013-06-20 | Treofan Germany Gmbh & Co. Kg | Hochporöse Separator-Folie mit Beschichtung und Abschaltfunktion |
| US9404009B2 (en) | 2012-02-24 | 2016-08-02 | Basf Se | Polymer dispersants |
| JP5835054B2 (ja) * | 2012-03-28 | 2015-12-24 | 日本ゼオン株式会社 | 静電荷像現像用カラートナーの製造方法 |
| US9790452B2 (en) | 2013-03-27 | 2017-10-17 | Basf Se | Block copolymers as soil release agents in laundry processes |
| JP5853988B2 (ja) * | 2013-05-14 | 2016-02-09 | コニカミノルタ株式会社 | 静電潜像用現像剤 |
| WO2014195440A1 (en) | 2013-06-07 | 2014-12-11 | Basf Se | Novel polymer dispersants |
| EP3024874B1 (en) | 2013-07-22 | 2017-09-06 | Basf Se | Novel polymers and use of these as dispersants |
| FR3040171B1 (fr) * | 2015-08-17 | 2017-08-25 | Ecole Superieure Physique & Chimie Ind Ville De Paris | Composition comprenant un reseau de polymeres reticules, prepare par copolymerisation radicalaire, comprenant des liaisons pendantes et des points de reticulation echangeables par reaction d'echange aldehyde-imine et/ou par reaction d'echange imine-imine, procede de preparation et utilisation |
| US11220602B2 (en) | 2015-08-20 | 2022-01-11 | Basf Se | Universal pigment preparations for point-of-sale use |
| WO2018193083A1 (en) | 2017-04-21 | 2018-10-25 | Basf Colors & Effects Gmbh | Process for preparing an aqueous dispersion of pigment containing particles |
| US11130879B2 (en) * | 2017-12-28 | 2021-09-28 | Axalta Coating Systems Ip Co., Llc | Dispersants, coating compositions including dispersants, and methods of forming the same |
| CN108417836B (zh) * | 2018-01-31 | 2021-05-04 | 闽南师范大学 | 一种锂离子电池的电极粘结剂及其制备方法 |
| EP3802714A4 (en) * | 2018-06-11 | 2022-03-23 | Swimc Llc | PACKAGING COATING WITH WATER-DISPERSABLE ACRYLIC BLOCK COPOLYMER |
| CN108727892A (zh) * | 2018-06-15 | 2018-11-02 | 鲁东大学 | 一种纤维素基流平剂的制备方法 |
| EP3837301B1 (en) | 2018-08-16 | 2022-06-15 | Basf Se | Polymer composition |
| CA3114995A1 (en) | 2018-10-18 | 2020-04-23 | Basf Se | Microparticle composition comprising an organic ir absorbing pigment |
| JP6829286B2 (ja) * | 2019-03-22 | 2021-02-10 | 大日精化工業株式会社 | 水性顔料分散液 |
| WO2020224982A1 (en) | 2019-05-06 | 2020-11-12 | Basf Se | Compositions, comprising silver nanoplatelets |
| WO2021209349A1 (en) * | 2020-04-14 | 2021-10-21 | Basf Se | An amine-modified polymer, a controlled free radical polymerization for preparing the same and implementations thereof |
| US12043047B2 (en) | 2020-04-23 | 2024-07-23 | Sicpa Holding Sa | Process for producing dichroic security features for securing value documents |
| CN115279518A (zh) | 2020-04-23 | 2022-11-01 | 巴斯夫欧洲公司 | 包含片状过渡金属颗粒的组合物 |
| KR102353641B1 (ko) * | 2020-10-14 | 2022-01-21 | 한국화학연구원 | 불소계 고분자의 제조 방법, 불소계 고분자, 및 이를 포함하는 고분자막 |
| JP7625243B2 (ja) * | 2020-10-16 | 2025-02-03 | 山陽色素株式会社 | 黒色顔料分散体 |
| CA3197947A1 (en) | 2020-11-10 | 2022-05-19 | Nikolay A. Grigorenko | Compositions, comprising silver nanoplatelets |
| KR20230098858A (ko) | 2020-11-10 | 2023-07-04 | 시크파 홀딩 에스에이 | 이색성 보안 특징을 제조하기 위한 UV-Vis 방사선 경화성 보안 잉크 |
| US12215242B2 (en) | 2020-11-10 | 2025-02-04 | Sicpa Holding Sa | UV-VIS radiation curable security inks for producing dichroic security features |
| EP4288229A1 (en) | 2021-02-03 | 2023-12-13 | Basf Se | Compositions, comprising silver nanoplatelets |
| WO2022200398A1 (en) | 2021-03-26 | 2022-09-29 | Basf Se | Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant |
| WO2022238468A1 (en) | 2021-05-12 | 2022-11-17 | Basf Se | Compositions, comprising platelet-shaped transition metal particles |
| EP4423176A1 (en) | 2021-10-26 | 2024-09-04 | Basf Se | A method for producing interference elements |
| WO2023088805A1 (en) | 2021-11-18 | 2023-05-25 | Sicpa Holding Sa | Methods for producing overt security features exhibiting one or more indicia |
| KR20250170672A (ko) | 2023-05-11 | 2025-12-05 | 비와이케이-케미 게엠베하 | 블록 공중합체를 제조하는 방법 |
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2006
- 2006-01-02 CN CN200680001969A patent/CN100577692C/zh active Active
- 2006-01-02 JP JP2007550778A patent/JP5225689B2/ja active Active
- 2006-01-02 KR KR1020077018443A patent/KR101322668B1/ko active Active
- 2006-01-02 US US11/794,707 patent/US20090221739A1/en not_active Abandoned
- 2006-01-02 BR BRPI0606305-5A patent/BRPI0606305A2/pt not_active IP Right Cessation
- 2006-01-02 EP EP06700677A patent/EP1861429B1/en active Active
- 2006-01-02 RU RU2007130535/04A patent/RU2401281C2/ru not_active IP Right Cessation
- 2006-01-02 WO PCT/EP2006/050000 patent/WO2006074969A1/en not_active Ceased
-
2011
- 2011-05-20 US US13/112,280 patent/US20110224375A1/en not_active Abandoned
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2012
- 2012-10-25 US US13/660,260 patent/US8658741B2/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5744523A (en) * | 1992-10-28 | 1998-04-28 | Th. Goldschmidt Ag | Use of polyacrylate esters as dispersants |
| KR20020089192A (ko) * | 2001-05-21 | 2002-11-29 | 시바 스페셜티 케미칼스 홀딩 인크. | 개질된 블록 공중합체 분산제를 포함하는 안료 조성물 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20070099646A (ko) | 2007-10-09 |
| CN101103049A (zh) | 2008-01-09 |
| WO2006074969A1 (en) | 2006-07-20 |
| CN100577692C (zh) | 2010-01-06 |
| JP5225689B2 (ja) | 2013-07-03 |
| BRPI0606305A2 (pt) | 2009-06-16 |
| RU2401281C2 (ru) | 2010-10-10 |
| US20130059964A1 (en) | 2013-03-07 |
| RU2007130535A (ru) | 2009-02-20 |
| EP1861429A1 (en) | 2007-12-05 |
| JP2008527130A (ja) | 2008-07-24 |
| US8658741B2 (en) | 2014-02-25 |
| EP1861429B1 (en) | 2013-03-13 |
| US20090221739A1 (en) | 2009-09-03 |
| US20110224375A1 (en) | 2011-09-15 |
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