KR100617886B1 - 촉매,촉매의제조방법및촉매를사용하는비닐아세테이트의제조방법 - Google Patents

촉매,촉매의제조방법및촉매를사용하는비닐아세테이트의제조방법 Download PDF

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Publication number
KR100617886B1
KR100617886B1 KR1019980054067A KR19980054067A KR100617886B1 KR 100617886 B1 KR100617886 B1 KR 100617886B1 KR 1019980054067 A KR1019980054067 A KR 1019980054067A KR 19980054067 A KR19980054067 A KR 19980054067A KR 100617886 B1 KR100617886 B1 KR 100617886B1
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South Korea
Prior art keywords
catalyst
support
palladium
alkali metal
gold
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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KR1019980054067A
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English (en)
Korean (ko)
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KR19990062950A (ko
Inventor
베른하르트 헤르조크
Original Assignee
셀라네제 쉐미칼스 오이로페 게엠베하
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Publication of KR19990062950A publication Critical patent/KR19990062950A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/344—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
    • C07C69/01—Vinyl esters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
KR1019980054067A 1997-12-11 1998-12-10 촉매,촉매의제조방법및촉매를사용하는비닐아세테이트의제조방법 Expired - Fee Related KR100617886B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19754992A DE19754992C2 (de) 1997-12-11 1997-12-11 Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators
DE19754992.6 1997-12-11

Publications (2)

Publication Number Publication Date
KR19990062950A KR19990062950A (ko) 1999-07-26
KR100617886B1 true KR100617886B1 (ko) 2007-04-25

Family

ID=7851508

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019980054067A Expired - Fee Related KR100617886B1 (ko) 1997-12-11 1998-12-10 촉매,촉매의제조방법및촉매를사용하는비닐아세테이트의제조방법

Country Status (24)

Country Link
US (2) US5968860A (enExample)
EP (1) EP0922491B1 (enExample)
JP (1) JP4116170B2 (enExample)
KR (1) KR100617886B1 (enExample)
CN (1) CN1101731C (enExample)
AR (1) AR013796A1 (enExample)
AT (1) ATE314142T1 (enExample)
AU (1) AU9705298A (enExample)
BR (1) BR9805322A (enExample)
CA (1) CA2255326C (enExample)
CZ (1) CZ294655B6 (enExample)
DE (2) DE19754992C2 (enExample)
DK (1) DK0922491T3 (enExample)
ES (1) ES2255125T3 (enExample)
HU (1) HUP9802833A3 (enExample)
ID (1) ID21457A (enExample)
MY (1) MY117157A (enExample)
NO (1) NO985784L (enExample)
NZ (1) NZ333248A (enExample)
PL (1) PL330213A1 (enExample)
SG (1) SG75903A1 (enExample)
TR (1) TR199802558A2 (enExample)
TW (1) TW474914B (enExample)
ZA (1) ZA9811282B (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19828491A1 (de) * 1998-06-26 1999-12-30 Degussa Formkörper auf Basis von Siliciumdioxid
DE19843693A1 (de) * 1998-09-24 2000-03-30 Degussa Trägerkatalysator für die Produktion von Vinylacetatmonomer
CN1101729C (zh) * 1999-11-10 2003-02-19 大连化学工业股份有限公司 氧酰化反应用催化剂和其制备方法及其应用
US6303537B1 (en) * 1999-11-17 2001-10-16 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
BR0015179A (pt) * 1999-11-17 2002-06-18 Celanese Int Corp Catalisador constituido de paládio metálico e ouro metálico que são úteis para a produção de acetato de vinila pela reação de etileno, oxigênio e ácido acético
US6420308B1 (en) 2000-07-07 2002-07-16 Saudi Basic Industries Corp Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
US6794332B2 (en) * 2000-07-07 2004-09-21 Saudi Basic Industries Corporation Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
ATE361784T1 (de) * 2000-11-09 2007-06-15 Dairen Chemical Corp Verfahren zur herstellung von katalysatoren
WO2002078843A1 (en) * 2001-03-30 2002-10-10 Shell Internationale Research Maatschappij B.V. Process for preparing a group viii-metal containing catalyst, use thereof for preparing an alkenyl carboxylate
JP4421201B2 (ja) * 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
US6936568B2 (en) 2002-06-12 2005-08-30 Sud-Chemie Inc. Selective hydrogenation catalyst
TW200539941A (en) * 2003-12-19 2005-12-16 Celanese Int Corp Methods of making alkenyl alkanoates
CA2586584C (en) 2004-12-20 2011-01-18 Celanese International Corporation Modified support materials for catalysts
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
CN100551523C (zh) * 2005-10-28 2009-10-21 厦门大学 一种金属氧化物负载的贵金属催化剂制备方法
EP2368629B1 (en) 2008-11-26 2019-04-03 China Petroleum&Chemical Corporation Metal loaded catalyst and preparation method thereof
CN102247838B (zh) * 2010-05-21 2013-03-27 中国石油化工股份有限公司 具有特定红外吸收特征的负载型钯催化剂
RU2015103051A (ru) * 2012-07-02 2016-08-20 Басф Корпорейшн Способ и каталитический композит для получения мономера винилацетата
TW202204039A (zh) 2020-06-11 2022-02-01 美商瑟蘭斯國際股份有限公司 用於乙酸乙烯酯製造之催化劑的製備方法
CN116550383B (zh) * 2023-07-12 2023-10-31 中国天辰工程有限公司 一种不饱和醋酸酯及其催化剂的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3627821A (en) * 1967-12-23 1971-12-14 Knapsack Ag Process for the manufacture of unsaturated esters of carboxylic acids
FR2677898B1 (fr) * 1991-06-19 1994-10-07 Georges Roussy Procede de fabrication des catalyseurs metalliques deposes sur supports d'oxydes.
EP0519824A1 (fr) * 1991-06-19 1992-12-23 Georges Roussy Procédé catalytique micro-onde de réformage des hydrocarbures
DE4120492A1 (de) * 1991-06-21 1992-12-24 Hoechst Ag Verfahren zur herstellung von vinylacetat
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
DE19613791C2 (de) * 1996-04-04 2002-01-31 Celanese Chem Europe Gmbh Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat

Also Published As

Publication number Publication date
MY117157A (en) 2004-05-31
CA2255326C (en) 2007-05-29
ZA9811282B (en) 1999-06-10
ID21457A (id) 1999-06-17
US5968860A (en) 1999-10-19
DE19754992A1 (de) 1999-06-24
EP0922491B1 (de) 2005-12-28
TR199802558A3 (tr) 1999-07-21
NO985784L (no) 1999-06-14
CN1101731C (zh) 2003-02-19
EP0922491A3 (de) 2000-03-29
DK0922491T3 (da) 2006-02-13
CA2255326A1 (en) 1999-06-11
JPH11244696A (ja) 1999-09-14
BR9805322A (pt) 1999-11-23
TW474914B (en) 2002-02-01
PL330213A1 (en) 1999-06-21
TR199802558A2 (xx) 1999-07-21
ATE314142T1 (de) 2006-01-15
CN1221651A (zh) 1999-07-07
NZ333248A (en) 2000-04-28
NO985784D0 (no) 1998-12-10
SG75903A1 (en) 2000-10-24
AR013796A1 (es) 2001-01-10
CZ294655B6 (cs) 2005-02-16
US6114573A (en) 2000-09-05
HU9802833D0 (en) 1999-02-01
EP0922491A2 (de) 1999-06-16
DE59813314D1 (de) 2006-02-02
ES2255125T3 (es) 2006-06-16
HUP9802833A3 (en) 2000-10-30
AU9705298A (en) 1999-07-01
DE19754992C2 (de) 2000-03-23
KR19990062950A (ko) 1999-07-26
JP4116170B2 (ja) 2008-07-09
CZ404998A3 (cs) 1999-06-16
HUP9802833A2 (hu) 1999-10-28

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