KR100593347B1 - 불투명도 및 충격 강도가 개선된 내후성 수지 조성물 - Google Patents

불투명도 및 충격 강도가 개선된 내후성 수지 조성물 Download PDF

Info

Publication number
KR100593347B1
KR100593347B1 KR1020007012112A KR20007012112A KR100593347B1 KR 100593347 B1 KR100593347 B1 KR 100593347B1 KR 1020007012112 A KR1020007012112 A KR 1020007012112A KR 20007012112 A KR20007012112 A KR 20007012112A KR 100593347 B1 KR100593347 B1 KR 100593347B1
Authority
KR
South Korea
Prior art keywords
grafted
styrene
group
phase
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020007012112A
Other languages
English (en)
Korean (ko)
Other versions
KR20010043189A (ko
Inventor
모 칭 올리버 창
리차드 엠. 오클레어
로버트 에이. 사녹키
Original Assignee
바이엘 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바이엘 코포레이션 filed Critical 바이엘 코포레이션
Publication of KR20010043189A publication Critical patent/KR20010043189A/ko
Application granted granted Critical
Publication of KR100593347B1 publication Critical patent/KR100593347B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/12Copolymers of styrene with unsaturated nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/12Powdering or granulating
    • C08J3/126Polymer particles coated by polymer, e.g. core shell structures
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
KR1020007012112A 1998-05-01 1999-04-27 불투명도 및 충격 강도가 개선된 내후성 수지 조성물 Expired - Fee Related KR100593347B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/071,089 US6187862B1 (en) 1998-05-01 1998-05-01 Weatherable resinous composition having improved opacity and impact strength
US09/071,089 1998-05-01

Publications (2)

Publication Number Publication Date
KR20010043189A KR20010043189A (ko) 2001-05-25
KR100593347B1 true KR100593347B1 (ko) 2006-06-26

Family

ID=22099182

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020007012112A Expired - Fee Related KR100593347B1 (ko) 1998-05-01 1999-04-27 불투명도 및 충격 강도가 개선된 내후성 수지 조성물

Country Status (12)

Country Link
US (1) US6187862B1 (https=)
EP (1) EP1084166B1 (https=)
JP (1) JP2002513825A (https=)
KR (1) KR100593347B1 (https=)
CN (1) CN1150230C (https=)
AU (1) AU3766699A (https=)
BR (1) BR9910096A (https=)
CA (1) CA2329985C (https=)
DE (1) DE69923449T2 (https=)
ES (1) ES2235482T3 (https=)
TW (1) TW402622B (https=)
WO (1) WO1999057168A1 (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100626954B1 (ko) * 2004-08-19 2006-09-20 주식회사 엘지화학 열가소성 투명수지 조성물 및 그 제조방법
KR100815995B1 (ko) 2006-06-08 2008-03-21 제일모직주식회사 저온 및 상온 내충격성과 착색성 및 내후성이 우수한asa 그라프트 공중합체 및 이를 포함한 열가소성 수지조성물
KR100998875B1 (ko) * 2008-10-29 2010-12-08 제일모직주식회사 저광 특성이 우수한 내후성 열가소성 수지 및 그 제조 방법
EP2308906A1 (en) * 2009-10-07 2011-04-13 Styron Europe GmbH Impact-modified monovinylidene aromatic polymer having low rubber crosslinking
EP2341090B1 (en) 2009-12-31 2012-09-12 Cheil Industries Inc. Weatherable thermoplastic resin having excellent low gloss characteristic and method of preparing the same
KR101286503B1 (ko) * 2009-12-31 2013-07-16 제일모직주식회사 저광 특성이 우수한 내후성 열가소성 수지 조성물 및 그 제조 방법
KR20120076301A (ko) 2010-12-29 2012-07-09 제일모직주식회사 내열성과 내후성이 우수한 저광 열가소성 수지 조성물
KR101469263B1 (ko) 2011-12-22 2014-12-05 제일모직주식회사 열가소성 수지 조성물 및 그 성형품
CN103930482B (zh) * 2012-10-11 2016-08-24 Lg化学株式会社 具有改善的低温冲击强度的丙烯酸烷基酯-芳族乙烯基化合物-乙烯基氰化合物共聚物以及包含该共聚物的聚碳酸酯组合物
CN103254365B (zh) * 2013-05-17 2015-03-25 合肥工业大学 一种采用水溶性氧化还原引发剂低温制备asa共聚物胶乳的方法
KR20150143834A (ko) * 2013-05-23 2015-12-23 아사히 가세이 케미칼즈 가부시키가이샤 열가소성 수지 조성물 및 그 성형품
JP6322000B2 (ja) * 2014-03-11 2018-05-09 旭化成株式会社 熱可塑性樹脂組成物、その成形体、及びその製造方法
MX2021000725A (es) * 2018-07-24 2021-04-12 Ineos Styrolution Group Gmbh Copolimero de caucho de injerto de poliacrilato y composicion de moldeo termoplastica.

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL221084A (https=) 1956-09-28
DE1260135B (de) 1965-01-05 1968-02-01 Basf Ag Schlagfeste thermoplastische Formmassen
DE1911882B2 (de) 1969-03-08 1975-04-17 Basf Ag, 6700 Ludwigshafen Schlagfeste thermoplastische Massen
JPS5953513A (ja) 1982-09-22 1984-03-28 Japan Synthetic Rubber Co Ltd 熱可塑性樹脂の製造方法
DE3421353A1 (de) 1984-06-08 1985-12-12 Bayer Ag, 5090 Leverkusen Pfropfpolymerisate mit matter oberflaeche
DE3447249A1 (de) 1984-12-22 1986-07-03 Bayer Ag, 5090 Leverkusen Kerbschlagzaehe thermoplastformmassen
DE3629150A1 (de) 1986-08-27 1988-03-10 Basf Ag Thermoplastische formmasse auf basis von abs
GB9007199D0 (en) * 1990-03-30 1990-05-30 Tioxide Group Plc Preparation of polymeric particles
DE4131728A1 (de) 1991-09-24 1993-03-25 Basf Ag Teilchenfoermiges pfropfcopolymerisat mit kern/schale-aufbau
EP0807144B2 (en) 1995-02-01 2004-11-10 Bayer Antwerpen N.V. Polymer blends with improved colorability
DE19503545A1 (de) * 1995-02-03 1996-08-08 Basf Ag Teilchenförmige Pfropfcopolymerisate und diese enthaltende thermoplastische Formmassen mit verbesserter Einfärbbarkeit
JP2853987B2 (ja) 1996-01-29 1999-02-03 奇美実業股▲分▼有限公司 スチレン系樹脂の製造方法

Also Published As

Publication number Publication date
EP1084166B1 (en) 2005-01-26
CN1299381A (zh) 2001-06-13
AU3766699A (en) 1999-11-23
WO1999057168A1 (en) 1999-11-11
JP2002513825A (ja) 2002-05-14
DE69923449D1 (de) 2005-03-03
CA2329985A1 (en) 1999-11-11
EP1084166A1 (en) 2001-03-21
BR9910096A (pt) 2000-12-26
US6187862B1 (en) 2001-02-13
KR20010043189A (ko) 2001-05-25
CN1150230C (zh) 2004-05-19
ES2235482T3 (es) 2005-07-01
CA2329985C (en) 2008-03-25
DE69923449T2 (de) 2005-12-29
TW402622B (en) 2000-08-21

Similar Documents

Publication Publication Date Title
KR950006131B1 (ko) 열가소성 수지 조성물의 제조 방법
KR0177813B1 (ko) 그라프트 기초물질과 그라프트 외장물질 사이의 부착성이 개선된 입자상 그라프트 중합체
KR100593347B1 (ko) 불투명도 및 충격 강도가 개선된 내후성 수지 조성물
US5932655A (en) Weatherable resinous composition having improved opacity and impact strength
EP0231933B2 (en) Thermoplastic resin compositions having excellent impact resistance, weather resistance and moldability, and process for preparing the same
US6310137B1 (en) Acrylic polymer having multilayer structure and methacrylic resin composition containing the same
US5373060A (en) Particulate graft copolymer
CA2076112A1 (en) Methacrylate-butadiene-styrene graft polymer and its pvc blends having low yellowness, good clarity, and improved impact strength
US6528583B1 (en) Thermoplastic molding composition having improved dimensional stability and low gloss
JPS6377963A (ja) 熱可塑性樹脂組成物
JPH11502540A (ja) 改善された着色性を有する重合体配合物
JP3059201B2 (ja) 熱可塑性樹脂組成物およびそれに適した多段階硬質重合体
JPH11217412A (ja) アクリル系多層構造共重合体およびそれを用いたメタクリル樹脂組成物ならびにランプレンズ
KR100384380B1 (ko) 투명성이우수한내후성수지조성물및그의제조방법
JPH05214202A (ja) 熱可塑性成形材料
JP3025333B2 (ja) 熱可塑性樹脂組成物
JPH04285653A (ja) メタアクリル樹脂組成物
US6072002A (en) Weatherable resinous composition
MXPA00010507A (en) Weatherable resinous composition having improved opacity and impact strength
JPH06192535A (ja) 熱可塑性樹脂組成物
HK1037649A (en) Weatherable resinous composition having improved opacity and impact strength
MXPA98008518A (en) Resinous composition alternative to intent
JPS6323222B2 (https=)
JPH0436183B2 (https=)
JPH01101354A (ja) メタクリル樹脂組成物

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R11-asn-PN2301

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R14-asn-PN2301

FPAY Annual fee payment

Payment date: 20090618

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20100620

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20100620

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000