KR100511701B1 - 다관능화 폴리오가노실록산을 커플링제(백색충전제/탄성중합체)로서 포함하는, 백색 충전제로 강화된디엔 고무 조성물 - Google Patents
다관능화 폴리오가노실록산을 커플링제(백색충전제/탄성중합체)로서 포함하는, 백색 충전제로 강화된디엔 고무 조성물 Download PDFInfo
- Publication number
- KR100511701B1 KR100511701B1 KR10-2000-7000257A KR20007000257A KR100511701B1 KR 100511701 B1 KR100511701 B1 KR 100511701B1 KR 20007000257 A KR20007000257 A KR 20007000257A KR 100511701 B1 KR100511701 B1 KR 100511701B1
- Authority
- KR
- South Korea
- Prior art keywords
- formula
- radical
- pos
- composition
- white filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0008—Compositions of the inner liner
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/392—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/5403—Silicon-containing compounds containing no other elements than carbon or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR97/09047 | 1997-07-11 | ||
| FR9709047 | 1997-07-11 | ||
| FR98/01452 | 1998-02-04 | ||
| FR9801452 | 1998-02-04 | ||
| PCT/EP1998/004308 WO1999002602A1 (fr) | 1997-07-11 | 1998-07-10 | Composition de caoutchouc dienique renforcee d'une charge blanche, comportant a titre d'agent de couplage (charge blanche/elastomere) un polyorganosiloxane multifonctionnalise |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20010021698A KR20010021698A (ko) | 2001-03-15 |
| KR100511701B1 true KR100511701B1 (ko) | 2005-09-02 |
Family
ID=26233680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR10-2000-7000257A Expired - Fee Related KR100511701B1 (ko) | 1997-07-11 | 1998-07-10 | 다관능화 폴리오가노실록산을 커플링제(백색충전제/탄성중합체)로서 포함하는, 백색 충전제로 강화된디엔 고무 조성물 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6313205B1 (enExample) |
| EP (1) | EP0996676B1 (enExample) |
| JP (1) | JP2001509530A (enExample) |
| KR (1) | KR100511701B1 (enExample) |
| CN (1) | CN1214069C (enExample) |
| AU (1) | AU8807198A (enExample) |
| BR (1) | BR9811001A (enExample) |
| CA (1) | CA2296010A1 (enExample) |
| DE (1) | DE69806008T2 (enExample) |
| ES (1) | ES2177038T3 (enExample) |
| PL (1) | PL338041A1 (enExample) |
| WO (1) | WO1999002602A1 (enExample) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19905820A1 (de) * | 1998-10-27 | 2000-05-04 | Degussa | Schwefelfunktionelle Polyorganosilane |
| CA2412360A1 (fr) * | 2000-06-16 | 2001-12-20 | Michelin Recherche Et Technique S.A. | Composition de caoutchouc pour pneumatique comportant un polyorganosiloxane multifonctionnel a titre d'agent de couplage |
| KR100820033B1 (ko) | 2000-07-31 | 2008-04-08 | 소시에떼 드 테크놀로지 미쉐린 | 주행 트레드를 갖는 타이어 |
| DE10044989A1 (de) * | 2000-09-11 | 2002-03-21 | Bayer Ag | Flüssige schwefelhaltige Oligosiloxane und ihre Verwendung in Kautschukmischungen |
| DE60221184T2 (de) * | 2001-05-15 | 2008-04-10 | Sumitomo Rubber Industries Ltd., Kobe | Kautschukzusammensetzung für Reifenlauffläche und Reifen mit derselben |
| CN1325549C (zh) | 2001-06-28 | 2007-07-11 | 米其林技术公司 | 采用具有非常低比表面积的二氧化硅增强的轮胎胎面 |
| DE60236090D1 (de) | 2001-06-28 | 2010-06-02 | Michelin Soc Tech | Iedriger spezifischer oberfläche |
| JP3826081B2 (ja) * | 2001-09-04 | 2006-09-27 | 横浜ゴム株式会社 | 空気入りタイヤ及びその製造方法 |
| FR2849045B1 (fr) * | 2002-12-19 | 2005-01-21 | Rhodia Chimie Sa | Oligomeres polyorganosiloxane portant des fonctions thiols ou episulfures et leurs procedes de preparation |
| EP1576044A1 (fr) * | 2002-12-19 | 2005-09-21 | Société de Technologie Michelin | COMPOSITION DE CAOUTCHOUC POUR PNEUMATIQUE COMPORTANT UN OLIGOMERE POLYORGANOSILOXANE A TITRE D’AGENT DE COUPLAGE |
| JP4243962B2 (ja) * | 2003-02-27 | 2009-03-25 | 横浜ゴム株式会社 | 空気入りタイヤ及びその製造方法 |
| CA2446474C (en) * | 2003-10-24 | 2011-11-29 | Rui Resendes | Silica-filled elastomeric compounds |
| MY164448A (en) * | 2003-12-15 | 2017-12-15 | Ciba Holding Inc | Coupling agents between filler and elastomer |
| JP5433233B2 (ja) * | 2005-03-24 | 2014-03-05 | 株式会社ブリヂストン | 揮発性有機化合物(voc)の放出が少ないシリカ補強ゴムの配合 |
| FR2886303B1 (fr) * | 2005-05-26 | 2007-07-20 | Rhodia Chimie Sa | Utilisation d'une combinaison particuliere d'un agent de couplage et d'un agent de recouvrement, comme systeme de couplage(charge blanche-elastomere) dans les compositions de caoutchouc comprenant une charge inorganique |
| US8119710B2 (en) * | 2005-09-21 | 2012-02-21 | Basf Se | Filled rubber compounds with improved processability |
| US7915368B2 (en) | 2007-05-23 | 2011-03-29 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes |
| US8501895B2 (en) | 2007-05-23 | 2013-08-06 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes |
| US8962746B2 (en) | 2007-12-27 | 2015-02-24 | Bridgestone Corporation | Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds |
| US8513371B2 (en) | 2007-12-31 | 2013-08-20 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxanes and method of preparation |
| US8794282B2 (en) | 2007-12-31 | 2014-08-05 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
| DE102008001007A1 (de) * | 2008-04-04 | 2009-10-08 | Robert Bosch Gmbh | Silikon-Polymer modifizierte Gummi-Zusammensetzungen, Verfahren zu ihrer Herstellung sowie dieses Material umfassende Scheibenwischer |
| CN101260190B (zh) * | 2008-04-28 | 2011-04-27 | 华南理工大学 | 多官能度聚硅氧烷偶联剂及其制备方法 |
| FR2940290B1 (fr) | 2008-12-22 | 2010-12-31 | Michelin Soc Tech | Agent de couplage mercaptosilane bloque |
| FR2945815B1 (fr) | 2009-05-20 | 2011-07-01 | Michelin Soc Tech | Composition de caoutchouc comportant un agent de couplage organosilane |
| FR2947552B1 (fr) | 2009-05-20 | 2011-08-26 | Michelin Soc Tech | Agent de couplage organosilane |
| FR2952064B1 (fr) | 2009-10-30 | 2012-08-31 | Michelin Soc Tech | Methode de preparation d'un melange maitre d'elastomere dienique et de silice |
| FR2954775B1 (fr) | 2009-10-30 | 2012-03-30 | Michelin Soc Tech | Methode de preparation d'un melange maitre d'elastomere dienique synthetique et de silice |
| FR2954774B1 (fr) | 2009-10-30 | 2012-01-06 | Michelin Soc Tech | Methode de preparation d'un melange maitre de caoutchouc naturel et de silice |
| US8642691B2 (en) | 2009-12-28 | 2014-02-04 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
| FR2962440B1 (fr) * | 2010-07-12 | 2012-08-03 | Total Raffinage Marketing | Procede de preparation de polymeres greffes sans amorceur et sans solvant et compositions bitume/polymere comprenant lesdits polymeres greffes |
| FR2974093B1 (fr) | 2011-04-15 | 2015-05-08 | Michelin Soc Tech | Procede de preparation d'un melange maitre d'elastomere et d'une charge inorganique renforcante |
| FR2981081B1 (fr) | 2011-10-11 | 2013-11-01 | Michelin Soc Tech | Methode de preparation d'un melange maitre de caoutchouc naturel et de silice |
| FR2981080B1 (fr) | 2011-10-11 | 2013-11-01 | Michelin Soc Tech | Methode de preparation d'un melange maitre de caoutchouc naturel et de silice dopee magnesium |
| FR2981077B1 (fr) | 2011-10-11 | 2013-11-01 | Michelin Soc Tech | Methode pour preparer un melange maitre d'elastomere dienique et de silice |
| FR2981076B1 (fr) | 2011-10-11 | 2013-11-01 | Michelin Soc Tech | Methode pour preparer un melange maitre d'elastomere dienique et de silice |
| FR2981078B1 (fr) | 2011-10-11 | 2013-11-01 | Michelin Soc Tech | Methode pour preparer un melange maitre d'elastomere dienique et de silice |
| FR2981079B1 (fr) | 2011-10-11 | 2013-11-01 | Michelin Soc Tech | Methode pour preparer un melange maitre d'elastomere dienique et de silice |
| FR2984326B1 (fr) | 2011-12-16 | 2014-01-10 | Michelin Soc Tech | Agent de couplage mercaptosilane bloque |
| US9550850B2 (en) * | 2013-02-25 | 2017-01-24 | The Yokohama Rubber Co., Ltd. | Rubber composition for tire tread, and pneumatic tire using same |
| WO2014129661A1 (ja) * | 2013-02-25 | 2014-08-28 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物及びこれを用いる空気入りタイヤ |
| US9593181B2 (en) * | 2013-02-25 | 2017-03-14 | The Yokohama Rubber Co., Ltd. | Rubber composition for tires, and pneumatic tire using same |
| JP6591422B2 (ja) * | 2013-12-27 | 2019-10-16 | 株式会社ブリヂストン | メルカプト官能性シロキサンを含む組成物から調製した加硫ゴム及びタイヤ部品 |
| JP6247591B2 (ja) * | 2014-05-08 | 2017-12-13 | 株式会社ブリヂストン | ゴム組成物、インナーライナー、シーラントおよび空気入りタイヤ |
| CN114016318A (zh) | 2014-12-31 | 2022-02-08 | 株式会社普利司通 | 用于将钢合金粘附到橡胶的氨基烷氧基改性倍半硅氧烷粘合剂 |
| FR3038320A1 (fr) | 2015-07-02 | 2017-01-06 | Michelin & Cie | Composition de caoutchouc comprenant une silice de tres haute surface specifique et une resine hydrocarbonee de faible temperature de transition vitreuse |
| EP3263359A1 (en) * | 2016-06-28 | 2018-01-03 | Sumitomo Rubber Industries, Ltd. | Rubber composition for sealants |
| FR3053345B1 (fr) | 2016-06-30 | 2018-07-06 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant un agent de couplage polysulfure de monohydroxysilane |
| FR3053337B1 (fr) | 2016-06-30 | 2018-07-06 | Compagnie Generale Des Etablissements Michelin | Polysulfure de monohydroxysilane |
| CN109641482B (zh) | 2016-09-02 | 2021-11-05 | 株式会社普利司通 | 具有通过聚合物胶水的原位硅氢加成制备的多个硅烷官能团的顺式-1,4-聚二烯的制备 |
| FR3060565A1 (fr) | 2016-12-16 | 2018-06-22 | Michelin & Cie | Polysulfure d'alcoxysilane |
| FR3065960B1 (fr) | 2017-05-05 | 2019-06-28 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant au moins une silice en tant que charge renforcante inorganique |
| FR3079841B1 (fr) | 2018-04-06 | 2020-10-09 | Michelin & Cie | Pneumatique comportant une composition de caoutchouc comprenant un nouvel agent de couplage polysulfure porteur de groupes associatifs azotes |
| FR3079842B1 (fr) | 2018-04-06 | 2020-10-09 | Michelin & Cie | Pneumatique comportant une composition de caoutchouc comprenant un nouvel agent de couplage polysulfure porteur de groupes associatifs azotes |
| FR3113905B1 (fr) | 2020-09-04 | 2022-08-05 | Michelin & Cie | Composition de caoutchouc a base d’elastomere dienique fortement sature |
| FR3113906B1 (fr) | 2020-09-04 | 2022-08-05 | Michelin & Cie | Composition de caoutchouc a base d’elastomere dienique fortement sature |
| CN116082641B (zh) * | 2021-11-08 | 2024-07-09 | 中蓝晨光化工有限公司 | 一种t型对称结构的大分子烷氧基硅烷处理剂及其制备方法与应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1310379A (en) * | 1970-12-10 | 1973-03-21 | Ppg Industries Inc | Tire tread |
| JPS6248743A (ja) * | 1985-08-28 | 1987-03-03 | Shin Etsu Chem Co Ltd | ゴム組成物 |
| US4725630A (en) * | 1987-06-01 | 1988-02-16 | Wacker Silicones Corporation | α, β-unsaturated carbonyl-functional silicone compositions |
| US6191247B1 (en) * | 1996-04-10 | 2001-02-20 | The Yokohama Rubber Co., Ltd. | Polysiloxane composition having superior storage stability and rubber composition containing same |
-
1998
- 1998-07-10 KR KR10-2000-7000257A patent/KR100511701B1/ko not_active Expired - Fee Related
- 1998-07-10 DE DE69806008T patent/DE69806008T2/de not_active Expired - Fee Related
- 1998-07-10 EP EP98939630A patent/EP0996676B1/fr not_active Expired - Lifetime
- 1998-07-10 WO PCT/EP1998/004308 patent/WO1999002602A1/fr not_active Ceased
- 1998-07-10 ES ES98939630T patent/ES2177038T3/es not_active Expired - Lifetime
- 1998-07-10 CN CNB988076578A patent/CN1214069C/zh not_active Expired - Fee Related
- 1998-07-10 BR BR9811001-2A patent/BR9811001A/pt not_active IP Right Cessation
- 1998-07-10 AU AU88071/98A patent/AU8807198A/en not_active Abandoned
- 1998-07-10 CA CA002296010A patent/CA2296010A1/fr not_active Abandoned
- 1998-07-10 PL PL98338041A patent/PL338041A1/xx unknown
- 1998-07-10 JP JP2000502111A patent/JP2001509530A/ja not_active Ceased
-
2000
- 2000-01-10 US US09/480,768 patent/US6313205B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2296010A1 (fr) | 1999-01-21 |
| WO1999002602A1 (fr) | 1999-01-21 |
| US6313205B1 (en) | 2001-11-06 |
| DE69806008T2 (de) | 2002-11-28 |
| EP0996676A1 (fr) | 2000-05-03 |
| ES2177038T3 (es) | 2002-12-01 |
| DE69806008D1 (de) | 2002-07-18 |
| JP2001509530A (ja) | 2001-07-24 |
| CN1214069C (zh) | 2005-08-10 |
| BR9811001A (pt) | 2000-11-07 |
| CN1265126A (zh) | 2000-08-30 |
| EP0996676B1 (fr) | 2002-06-12 |
| AU8807198A (en) | 1999-02-08 |
| KR20010021698A (ko) | 2001-03-15 |
| PL338041A1 (en) | 2000-09-25 |
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