KR100316615B1 - 지방족에스테르폴리머조성물을제조하는벌크반응성압출중합공정 - Google Patents

지방족에스테르폴리머조성물을제조하는벌크반응성압출중합공정 Download PDF

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Publication number
KR100316615B1
KR100316615B1 KR1019980708567A KR19980708567A KR100316615B1 KR 100316615 B1 KR100316615 B1 KR 100316615B1 KR 1019980708567 A KR1019980708567 A KR 1019980708567A KR 19980708567 A KR19980708567 A KR 19980708567A KR 100316615 B1 KR100316615 B1 KR 100316615B1
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KR
South Korea
Prior art keywords
starch
polymerization
aliphatic ester
caprolactone
monomer
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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KR1019980708567A
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English (en)
Korean (ko)
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KR20000065023A (ko
Inventor
라마니 나라얀
모한 크리쉬난
요셉 비. 스누크
아자이 굽타
필립 듀보이스
Original Assignee
로저 윌킨슨
미시간 스테이트 유니버시티
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Publication of KR20000065023A publication Critical patent/KR20000065023A/ko
Application granted granted Critical
Publication of KR100316615B1 publication Critical patent/KR100316615B1/ko
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/26—Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
KR1019980708567A 1996-04-26 1997-04-18 지방족에스테르폴리머조성물을제조하는벌크반응성압출중합공정 Expired - Fee Related KR100316615B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/639,198 US5801224A (en) 1996-04-26 1996-04-26 Bulk reactive extrusion polymerization process producing aliphatic ester polymer compositions
US8/639,198 1996-04-26
US08/639,198 1996-04-26
PCT/US1997/006440 WO1997041165A1 (en) 1996-04-26 1997-04-18 Bulk reactive extrusion polymerization process producing aliphatic ester polymer compositions

Publications (2)

Publication Number Publication Date
KR20000065023A KR20000065023A (ko) 2000-11-06
KR100316615B1 true KR100316615B1 (ko) 2002-02-28

Family

ID=24563127

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019980708567A Expired - Fee Related KR100316615B1 (ko) 1996-04-26 1997-04-18 지방족에스테르폴리머조성물을제조하는벌크반응성압출중합공정

Country Status (5)

Country Link
US (3) US5801224A (enExample)
EP (1) EP0895518A1 (enExample)
JP (1) JP3140791B2 (enExample)
KR (1) KR100316615B1 (enExample)
WO (1) WO1997041165A1 (enExample)

Families Citing this family (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1011157A3 (fr) * 1997-05-16 1999-05-04 Solvay Procede de fabrication d'un film souffle biodegradable.
EP0882751A3 (en) * 1997-06-03 1999-02-10 KABUSHIKI KAISHA KOBE SEIKO SHO also known as Kobe Steel Ltd. Biodegradable polyester with improved moulding characteristics and its production
BE1012801A3 (fr) * 1999-07-27 2001-03-06 Solvay Procede d'introduction d'au moins un compose chimique dans une extrudeuse, dispositif d'introduction, extrudeuse equipee d'un tel dispositif et procedes utilisant une telle extrudeuse.
US6376643B1 (en) * 2000-11-08 2002-04-23 Invigor Biotechnology Co., Ltd. Method of polymerization of lactide and polylactide homopolymer thereof
US6747096B2 (en) 2001-04-10 2004-06-08 University Of Akron Block copolymers of lactone and lactam, compatibilizing agents, and compatiblized polymer blends
US6486257B1 (en) 2001-04-10 2002-11-26 University Of Akron Block copolymers of lactone and lactam, compatabilizing agents, and compatibilized polymer blends
US7132423B2 (en) * 2001-09-21 2006-11-07 Reddy Us Therapeutics, Inc. Methods and compositions of novel triazine compounds
US7173032B2 (en) * 2001-09-21 2007-02-06 Reddy Us Therapeutics, Inc. Methods and compositions of novel triazine compounds
US7169785B2 (en) * 2001-09-21 2007-01-30 Reddy Us Therapeutics, Inc. Methods and compositions of novel triazine compounds
US7112587B2 (en) * 2001-09-21 2006-09-26 Reddy Us Therapeutics, Inc. Methods and compositions of novel triazine compounds
WO2003050153A1 (en) * 2001-12-12 2003-06-19 North Carolina State University Methods of co2-assisted reactive extrusion
US20040173779A1 (en) * 2002-01-22 2004-09-09 Gencer Mehmet A. Biodegradable shaped article containing a corrosion inhibitor and inert filler particles
US7270775B2 (en) * 2002-01-22 2007-09-18 Northern Technologies International Corp. Corrosion inhibiting composition and article containing it
US20030220436A1 (en) * 2002-01-22 2003-11-27 Gencer Mehmet A. Biodegradable polymers containing one or more inhibitors and methods for producing same
US7261839B2 (en) * 2002-01-22 2007-08-28 Northern Technologies International Corp. Tarnish inhibiting composition and article containing it
US8008373B2 (en) * 2002-01-22 2011-08-30 Northern Technologies International Corp. Biodegradable polymer masterbatch, and a composition derived therefrom having improved physical properties
AR038816A1 (es) * 2002-02-07 2005-01-26 Baylor College Medicine Desarrollo modificado de la glandula pituitaria en la progenie de las hembras prenadas tratadas con terapia con la hormona liberadora de la hormona de crecimiento
US7053029B2 (en) * 2002-03-27 2006-05-30 Kimberly-Clark Worldwide, Inc. Use indicating soap
US20050020945A1 (en) * 2002-07-02 2005-01-27 Tosaya Carol A. Acoustically-aided cerebrospinal-fluid manipulation for neurodegenerative disease therapy
US7960326B2 (en) * 2002-09-05 2011-06-14 Kimberly-Clark Worldwide, Inc. Extruded cleansing product
EP1684679B1 (en) * 2003-10-21 2009-06-03 Hollister Incorporated Peelable and flushable ostomy pouch and method of use
US7179245B2 (en) * 2003-10-21 2007-02-20 Hollister Incorporated Flushable body waste collection pouch, pouch-in-pouch appliance using the same, and method relating thereto
BRPI0514166A (pt) 2004-08-09 2008-06-03 Univ Michigan State processo aperfeiçoado para formação de um copolìmero de poli (1, 4-dioxan-2-ona) com um monÈmero de éster cìclico, processo para formação de um copolìmero de poli (1, 4-dioxan-2-ona) e um monÈmer de éster cìclico, processo para formação de um copolìmero de poli (1, 4-dioxan-2-ona) e um éster cìclico misturado com ingredientes adicionais, copolìmero de poli (1, 4-dioxan-2-ona) anidra, e copolìmero de poli (1, 4-dioxan-2-ona) com um monÈmero de éster cìclico
US7553919B2 (en) * 2005-05-06 2009-06-30 Board Of Trustees Of Michigan State University Starch-vegetable oil graft copolymers and their biofiber composites, and a process for their manufacture
US7592413B2 (en) * 2005-09-22 2009-09-22 E. I. Du Pont De Nemours And Company Manufacture of aromatic polyester
US20080039540A1 (en) * 2005-12-28 2008-02-14 Reitz Robert R Process for recycling polyesters
JP2009524706A (ja) * 2006-01-24 2009-07-02 インターテープ ポリマー コーポレーション 遊星ローラー押出機における連続バルク重合
US7906598B2 (en) * 2006-08-30 2011-03-15 Intertape Polymer Corp. Recirculation loop reactor bulk polymerization process
US20100105847A1 (en) 2006-01-24 2010-04-29 Intertape Polymer Corp. Plug flow bulk polymerization of vinyl monomers
US7591974B2 (en) * 2006-01-25 2009-09-22 Absorbent Technologies, Inc. Methods for producing superabsorbent polymers for use in agricultural applications
US20070203261A1 (en) * 2006-02-24 2007-08-30 Board Of Trustees Of Michigan State University Reactively blended polyester and filler composite compositions and process
JP5933889B2 (ja) * 2006-03-21 2016-06-15 ザ・ガバナーズ・オブ・ザ・ユニバーシティー・オブ・アルバータ 新規なポリ（エチレンオキサイド）−ブロックーポリ（エステル）ブロック共重合体
US8110678B2 (en) * 2006-05-11 2012-02-07 University Of South Florida Antibiotic-bound poly(caprolactone) polymer
ES2286945B1 (es) * 2006-05-23 2008-09-16 Quinorgan, S.L. Procedimiento de fabricacion para la obtencion de laminas termoconformables y termoadherentes para la industria del calzado.
KR101311060B1 (ko) 2006-07-14 2013-09-24 킴벌리-클라크 월드와이드, 인크. 부직 웹에 사용하기 위한 생분해성 지방족-방향족코폴리에스테르
US9091004B2 (en) 2006-07-14 2015-07-28 Kimberly-Clark Worldwide, Inc. Biodegradable polylactic acid for use in nonwoven webs
MX2009000525A (es) 2006-07-14 2009-01-27 Kimberly Clark Co Poliester alifatico biodegradable para usarse en telas no tejidas.
EP2057197B1 (en) * 2006-08-30 2011-07-20 Intertape Polymer Corp. Recirculation loop reactor bulk polymerization process
ATE506472T1 (de) 2007-08-22 2011-05-15 Kimberly Clark Co Mehrkomponentige biologisch abbaubare filamente und daraus gebildete vliesstoffe
WO2009145778A1 (en) 2008-05-30 2009-12-03 Kimberly-Clark Worldwide, Inc. Polylactic acid fibers
FI125448B (fi) 2009-03-11 2015-10-15 Onbone Oy Uudet materiaalit
US8461262B2 (en) 2010-12-07 2013-06-11 Kimberly-Clark Worldwide, Inc. Polylactic acid fibers
WO2012175338A1 (fr) * 2011-06-23 2012-12-27 Agc Glass Europe Materiau polymere a base de poly(acide lactique)
CN102321249B (zh) * 2011-06-30 2013-01-16 无锡碧杰生物材料科技有限公司 一种热塑性淀粉和生物降解聚酯/淀粉复合材料及其制备
CO6350195A1 (es) * 2011-09-23 2011-12-20 Univ Del Cauca Peliculas y empaques biodegradables obtenidos a partir de almidon de yuca y proceso de fabricacion de los mismos
JP2015232113A (ja) * 2014-05-13 2015-12-24 株式会社リコー 脂肪族ポリエステル、脂肪族ポリエステルの製造方法、及びポリマー成形体
US10428189B2 (en) 2014-07-18 2019-10-01 Chroma Color Corporation Process and composition for well dispersed, highly loaded color masterbatch
US9969881B2 (en) 2014-07-18 2018-05-15 Carolina Color Corporation Process and composition for well-dispersed, highly loaded color masterbatch
CN107108864A (zh) * 2015-03-30 2017-08-29 株式会社吴羽 脂肪族聚酯组合物及成型物以及脂肪族聚酯的制造方法
KR101637994B1 (ko) * 2016-01-18 2016-07-08 주식회사 수연 방향족/지방족 코폴리에스테르 수지 조성물
WO2019217641A1 (en) 2018-05-11 2019-11-14 Carbon, Inc. Sustainable chemistry systems for recyclable dental models and other additively manufactured products
EP3814408B1 (en) * 2018-06-28 2024-07-24 Fedchem, LLC Aluminum organic thickeners for thermoset resins
US10745552B2 (en) 2018-06-28 2020-08-18 Fedchem, Llc Aluminum organic thickeners for thermoset resins
JP7676023B2 (ja) 2018-07-13 2025-05-14 ノボマー， インコーポレイテッド ポリラクトン発泡体及びその製造方法
TWI760875B (zh) 2020-10-05 2022-04-11 財團法人工業技術研究院 共聚物與其形成方法
CN115232292B (zh) * 2021-04-22 2025-03-04 中国石油化工股份有限公司 一种聚乙醇酸的制备方法和得到的聚乙醇酸
CN114230773B (zh) * 2022-01-17 2023-08-29 美瑞新材料创新中心(山东)有限公司 一种利用双螺杆反应器制备聚己内酯树脂的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4469613A (en) * 1983-02-23 1984-09-04 International Flavors & Fragrances Inc. Detergent bar containing poly(epsilon caprolactone) and aromatizing agent
US5468837A (en) * 1993-05-17 1995-11-21 Solvay (Societe Anonyme) Process for the manufacture of poly-epsilon-caprolactones and poly-epsilon-caprolactones which have high molecular masses obtainable by this process

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL9001641A (nl) * 1990-07-19 1992-02-17 Stamicarbon Werkwijze voor het maken van polymere producten van cyclische esters.
US5412005A (en) * 1991-05-03 1995-05-02 Novamont S.P.A. Biodegradable polymeric compositions based on starch and thermoplastic polymers
EP0525245A1 (en) * 1991-08-01 1993-02-03 NOVAMONT S.p.A. Disposable absorbent articles
US5310599A (en) * 1993-05-06 1994-05-10 E. I. Du Pont De Nemours And Company Method for making polymers of alpha-hydroxy acids
US5500465A (en) * 1994-03-10 1996-03-19 Board Of Trustees Operating Michigan State University Biodegradable multi-component polymeric materials based on unmodified starch-like polysaccharides
BE1009255A3 (fr) * 1995-04-07 1997-01-07 Solvay Procede perfectionne pour la fabrication en continu de poly- -caprolactones.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4469613A (en) * 1983-02-23 1984-09-04 International Flavors & Fragrances Inc. Detergent bar containing poly(epsilon caprolactone) and aromatizing agent
US5468837A (en) * 1993-05-17 1995-11-21 Solvay (Societe Anonyme) Process for the manufacture of poly-epsilon-caprolactones and poly-epsilon-caprolactones which have high molecular masses obtainable by this process

Also Published As

Publication number Publication date
WO1997041165A1 (en) 1997-11-06
JPH11510549A (ja) 1999-09-14
EP0895518A4 (enExample) 1999-03-10
EP0895518A1 (en) 1999-02-10
JP3140791B2 (ja) 2001-03-05
US5906783A (en) 1999-05-25
KR20000065023A (ko) 2000-11-06
US5969089A (en) 1999-10-19
US5801224A (en) 1998-09-01

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