KR0160308B1 - 시클로 올레핀의 제조법 - Google Patents

시클로 올레핀의 제조법 Download PDF

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Publication number
KR0160308B1
KR0160308B1 KR1019910011951A KR910011951A KR0160308B1 KR 0160308 B1 KR0160308 B1 KR 0160308B1 KR 1019910011951 A KR1019910011951 A KR 1019910011951A KR 910011951 A KR910011951 A KR 910011951A KR 0160308 B1 KR0160308 B1 KR 0160308B1
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KR
South Korea
Prior art keywords
carrier
ruthenium
catalyst
pore
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1019910011951A
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English (en)
Korean (ko)
Other versions
KR920002494A (ko
Inventor
도오루 세또야마
다까히꼬 다께와끼
다까오 마끼
Original Assignee
에또오 다께또시
미쓰비시가세이 가부시끼가이샤
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Publication date
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Publication of KR920002494A publication Critical patent/KR920002494A/ko
Application granted granted Critical
Publication of KR0160308B1 publication Critical patent/KR0160308B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/16—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a six-membered ring
    • C07C13/20—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a six-membered ring with a cyclohexene ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1019910011951A 1990-07-13 1991-07-13 시클로 올레핀의 제조법 Expired - Fee Related KR0160308B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP90/185842 1990-07-13
JP2185842A JP2814711B2 (ja) 1990-07-13 1990-07-13 シクロオレフィンの製造法
JP90-185842 1990-07-13

Publications (2)

Publication Number Publication Date
KR920002494A KR920002494A (ko) 1992-02-28
KR0160308B1 true KR0160308B1 (ko) 1999-01-15

Family

ID=16177834

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910011951A Expired - Fee Related KR0160308B1 (ko) 1990-07-13 1991-07-13 시클로 올레핀의 제조법

Country Status (6)

Country Link
US (1) US5157179A (OSRAM)
EP (1) EP0466128B1 (OSRAM)
JP (1) JP2814711B2 (OSRAM)
KR (1) KR0160308B1 (OSRAM)
DE (1) DE69108120T2 (OSRAM)
TW (1) TW253882B (OSRAM)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100464581B1 (ko) * 1996-06-19 2005-07-04 바스프 악티엔게젤샤프트 지지된루테늄촉매의존재하에유기화합물을반응시키는방법

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW218865B (OSRAM) * 1992-01-24 1994-01-11 Asahi Carbon Kabushiki Kaisha
US5414171A (en) * 1992-02-26 1995-05-09 Catalytica, Inc. Process and washed catalyst for partially hydrogenating aromatics to produce cycloolefins
DE69403885T2 (de) * 1993-12-24 1998-01-29 Mitsubishi Chem Corp Verfahren zur Herstellung von Cycloolefinen
BE1009128A3 (fr) * 1994-12-19 1996-12-03 Mitsubishi Chem Corp Procede de production de cycloolefines.
EP0769484B1 (en) 1995-10-20 2001-06-13 Mitsubishi Chemical Corporation Method for separating cyclohexene
JPH1129503A (ja) * 1997-07-08 1999-02-02 Asahi Chem Ind Co Ltd シクロオレフィンの製造方法
US6417135B1 (en) * 1999-08-27 2002-07-09 Huntsman Petrochemical Corporation Advances in dehydrogenation catalysis
US6376622B1 (en) * 1999-12-08 2002-04-23 The Dow Chemical Company Process for hydrogenating aromatic polymers
DE10128204A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Herstellung von cycloaliphatischen Verbindungen I, die Seitenketten mit Epoxidgruppen aufweisen
JP4931099B2 (ja) * 2003-09-30 2012-05-16 旭化成ケミカルズ株式会社 シクロオレフィン製造用触媒及び、シクロオレフィンの製造方法
KR100830726B1 (ko) * 2004-07-09 2008-05-20 아사히 가세이 케미칼즈 가부시키가이샤 시클로올레핀 제조용 촉매 및 제조 방법
CN1304109C (zh) * 2004-08-12 2007-03-14 郑州大学 苯选择加氢制环己烯催化剂，其制备方法及调变方法和再生方法
CN101198570B (zh) * 2005-08-26 2011-11-02 旭化成化学株式会社 环烯烃的制造方法
EP2238217A1 (en) * 2008-02-01 2010-10-13 Johnson Matthey PLC Process for the conversion of fatty acids and derivatives thereof
GB0913193D0 (en) * 2009-07-29 2009-09-02 Johnson Matthey Plc Deoxygenation process
IT1402745B1 (it) * 2010-10-27 2013-09-18 Polimeri Europa Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
ITMI20121724A1 (it) * 2012-10-12 2014-04-13 Versalis Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
CN103787816B (zh) * 2012-11-01 2015-06-17 中国石油化工股份有限公司 一种苯部分加氢制环己烯工艺
WO2015057311A1 (en) * 2013-10-18 2015-04-23 Exxonmobile Chemical Patents Inc. A hydrogenation catalyst, its method of preparation and use
CN106140154B (zh) * 2015-04-17 2019-01-08 中国石油化工股份有限公司 一种苯选择加氢制环己烯的催化剂及其制备方法与应用
CN105056971A (zh) * 2015-08-07 2015-11-18 郑州大学 一种苯选择加氢制环己烯用Ru-Zn催化剂的原位再生方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3637878A (en) * 1970-04-13 1972-01-25 Union Oil Co Hydrogenation process and catalyst
US3703461A (en) * 1971-07-16 1972-11-21 Union Oil Co Hydrogenation process and catalyst
US3767720A (en) * 1972-02-25 1973-10-23 Du Pont Selective hydrogenation of aromatic hydrocarbons to cycloolefins
US4197415A (en) * 1976-10-08 1980-04-08 Toray Industries, Inc. Process for preparing cyclic olefins by selective partial hydrogenation of aromatic hydrocarbons
JPS6059215B2 (ja) * 1983-02-24 1985-12-24 工業技術院長 ベンゼンからのシクロヘキセンの製法
CA1267914A (en) * 1985-10-03 1990-04-17 Hajime Nagahara Process for producing cycloolefins

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100464581B1 (ko) * 1996-06-19 2005-07-04 바스프 악티엔게젤샤프트 지지된루테늄촉매의존재하에유기화합물을반응시키는방법

Also Published As

Publication number Publication date
EP0466128B1 (en) 1995-03-15
JP2814711B2 (ja) 1998-10-27
US5157179A (en) 1992-10-20
KR920002494A (ko) 1992-02-28
TW253882B (OSRAM) 1995-08-11
JPH0474141A (ja) 1992-03-09
EP0466128A1 (en) 1992-01-15
DE69108120D1 (de) 1995-04-20
DE69108120T2 (de) 1995-11-02

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