DE69108120D1 - Verfahren zur Herstellung eines Cycloolefins. - Google Patents

Verfahren zur Herstellung eines Cycloolefins.

Info

Publication number
DE69108120D1
DE69108120D1 DE69108120T DE69108120T DE69108120D1 DE 69108120 D1 DE69108120 D1 DE 69108120D1 DE 69108120 T DE69108120 T DE 69108120T DE 69108120 T DE69108120 T DE 69108120T DE 69108120 D1 DE69108120 D1 DE 69108120D1
Authority
DE
Germany
Prior art keywords
cycloolefin
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69108120T
Other languages
English (en)
Other versions
DE69108120T2 (de
Inventor
Tohru Setoyama
Takahiko Takewaki
Takao Maki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Application granted granted Critical
Publication of DE69108120D1 publication Critical patent/DE69108120D1/de
Publication of DE69108120T2 publication Critical patent/DE69108120T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/16—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a six-membered ring
    • C07C13/20—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a six-membered ring with a cyclohexene ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69108120T 1990-07-13 1991-07-10 Verfahren zur Herstellung eines Cycloolefins. Expired - Fee Related DE69108120T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2185842A JP2814711B2 (ja) 1990-07-13 1990-07-13 シクロオレフィンの製造法

Publications (2)

Publication Number Publication Date
DE69108120D1 true DE69108120D1 (de) 1995-04-20
DE69108120T2 DE69108120T2 (de) 1995-11-02

Family

ID=16177834

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69108120T Expired - Fee Related DE69108120T2 (de) 1990-07-13 1991-07-10 Verfahren zur Herstellung eines Cycloolefins.

Country Status (6)

Country Link
US (1) US5157179A (de)
EP (1) EP0466128B1 (de)
JP (1) JP2814711B2 (de)
KR (1) KR0160308B1 (de)
DE (1) DE69108120T2 (de)
TW (1) TW253882B (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW218865B (de) * 1992-01-24 1994-01-11 Asahi Carbon Kabushiki Kaisha
US5414171A (en) * 1992-02-26 1995-05-09 Catalytica, Inc. Process and washed catalyst for partially hydrogenating aromatics to produce cycloolefins
DE69403885T2 (de) * 1993-12-24 1998-01-29 Mitsubishi Chem Corp Verfahren zur Herstellung von Cycloolefinen
BE1009128A3 (fr) * 1994-12-19 1996-12-03 Mitsubishi Chem Corp Procede de production de cycloolefines.
EP0769484B1 (de) 1995-10-20 2001-06-13 Mitsubishi Chemical Corporation Verfahren zur Abtrennung von Cyclohexen
US6248924B1 (en) * 1996-06-19 2001-06-19 Basf Aktiengesellschaft Process for reacting an organic compound in the presence of a supported ruthenium catalyst
JPH1129503A (ja) * 1997-07-08 1999-02-02 Asahi Chem Ind Co Ltd シクロオレフィンの製造方法
US6417135B1 (en) * 1999-08-27 2002-07-09 Huntsman Petrochemical Corporation Advances in dehydrogenation catalysis
US6376622B1 (en) * 1999-12-08 2002-04-23 The Dow Chemical Company Process for hydrogenating aromatic polymers
DE10128204A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Herstellung von cycloaliphatischen Verbindungen I, die Seitenketten mit Epoxidgruppen aufweisen
JP4931099B2 (ja) * 2003-09-30 2012-05-16 旭化成ケミカルズ株式会社 シクロオレフィン製造用触媒及び、シクロオレフィンの製造方法
EP1767270A4 (de) * 2004-07-09 2012-09-19 Asahi Kasei Chemicals Corp Katalysator für die cycloolefinproduktion und verfahren zu dessen herstellung
CN1304109C (zh) * 2004-08-12 2007-03-14 郑州大学 苯选择加氢制环己烯催化剂，其制备方法及调变方法和再生方法
CN101198570B (zh) * 2005-08-26 2011-11-02 旭化成化学株式会社 环烯烃的制造方法
WO2009095711A1 (en) * 2008-02-01 2009-08-06 Johnson Matthey Plc Process for the conversion of fatty acids and derivatives thereof
GB0913193D0 (en) * 2009-07-29 2009-09-02 Johnson Matthey Plc Deoxygenation process
IT1402745B1 (it) * 2010-10-27 2013-09-18 Polimeri Europa Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
ITMI20121724A1 (it) * 2012-10-12 2014-04-13 Versalis Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
CN103787816B (zh) * 2012-11-01 2015-06-17 中国石油化工股份有限公司 一种苯部分加氢制环己烯工艺
US9861960B2 (en) 2013-10-18 2018-01-09 Exxonmobil Chemical Patents Inc. Hydrogenation catalyst, its method of preparation and use
CN106140154B (zh) * 2015-04-17 2019-01-08 中国石油化工股份有限公司 一种苯选择加氢制环己烯的催化剂及其制备方法与应用
CN105056971A (zh) * 2015-08-07 2015-11-18 郑州大学 一种苯选择加氢制环己烯用Ru-Zn催化剂的原位再生方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3637878A (en) * 1970-04-13 1972-01-25 Union Oil Co Hydrogenation process and catalyst
US3703461A (en) * 1971-07-16 1972-11-21 Union Oil Co Hydrogenation process and catalyst
US3767720A (en) * 1972-02-25 1973-10-23 Du Pont Selective hydrogenation of aromatic hydrocarbons to cycloolefins
US4197415A (en) * 1976-10-08 1980-04-08 Toray Industries, Inc. Process for preparing cyclic olefins by selective partial hydrogenation of aromatic hydrocarbons
JPS6059215B2 (ja) * 1983-02-24 1985-12-24 工業技術院長 ベンゼンからのシクロヘキセンの製法
CA1267914A (en) * 1985-10-03 1990-04-17 Hajime Nagahara Process for producing cycloolefins

Also Published As

Publication number Publication date
EP0466128A1 (de) 1992-01-15
JP2814711B2 (ja) 1998-10-27
US5157179A (en) 1992-10-20
DE69108120T2 (de) 1995-11-02
KR0160308B1 (ko) 1999-01-15
EP0466128B1 (de) 1995-03-15
TW253882B (de) 1995-08-11
JPH0474141A (ja) 1992-03-09
KR920002494A (ko) 1992-02-28

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Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: MITSUBISHI CHEMICAL CORP., TOKIO/TOKYO, JP

8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee