KR920002494A - 시클로 올레핀의 제조법 - Google Patents

시클로 올레핀의 제조법 Download PDF

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KR920002494A
KR920002494A KR1019910011951A KR910011951A KR920002494A KR 920002494 A KR920002494 A KR 920002494A KR 1019910011951 A KR1019910011951 A KR 1019910011951A KR 910011951 A KR910011951 A KR 910011951A KR 920002494 A KR920002494 A KR 920002494A
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carrier
pore
capacity
pore capacity
ruthenium
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KR1019910011951A
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KR0160308B1 (ko
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도오루 세또야마
다까히꼬 다께와끼
다까오 마끼
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에또오 다께또시
미쓰비시가세이 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/16—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a six-membered ring
    • C07C13/20—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a six-membered ring with a cyclohexene ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

시클로 올레핀의 제조법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 루베늄을 주성분으로 하는 담체담지촉매 및 물의 존재하 액상중에서 방향족 탄화수소를 수소로 부분수소화 하여 대응하는 시클로올레핀을 제조하는 방법에 있어서, 세공반경 20∼100,000Å의 전세공용량이 0.3∼10cc/g이며, 또한 세공반경 20∼200Å의 세공용량의 전세공용량에 대한 비율이 15% 이하인 산화물을 촉매의 담체로 사용하는 것을 특징으로 하는 시클로올레핀의 제조방법.
  2. 루테늄을 주성분으로하는 담체담지촉매, 금속염 및 물의 존재하 액상중에 방향족 탄화수소를 수소에 의해 부분수소화하여 대응하는 시클로올레핀을 제조하는 방법에 있어서, 촉매담체로서 세공반경 20∼100,000Å의 전 세공용량이 0.3∼10cc/g이며, 또한 세공반경 20∼200Å의 세공용량의 전세공용량에 대한 비율이 15% 이하인 산화물을 사용하는 것을 특징으로 하는 시클로올레핀의 제조방법.
  3. 제1항 또는 제2항에 있어서, 세공반경 20∼200Å의 세공용량이 0.2cc/g 이하인 것을 특징으로 하는 방법.
  4. 제1항 또는 제2항에 있어서, 세공반경 20∼100,000Å의 전세공용량이 0.3∼5cc/g인 방법.
  5. 제1항 또는 제2항에 있어서, 담체의 세공반경 20∼200Å인 세공용량의 20∼100,000Å의 전세공용량에 대한 비율이 10% 이하인 방법.
  6. 제1항 또는 제2항에 있어서, 담체가, SiO2인 방법.
  7. 제1항 또는 제2항에 있어서, 담체가, ZrSiO4인 방법.
  8. 제1항 또는 제2항에 있어서, 담체에 담지된 루테늄의 농도가 0.001∼10 중량%인 방법.
  9. 제1항 또는 제2항에 있어서, 담체에 루테늄과 함께 적어도 1종의 기타 금속의 담지시킨 방법.
  10. 제9항에 있어서, 금속이, 망간, 철, 코발트, 아연으로 구성된 군에서 선택된 적어도 한 종류인 방법.
  11. 제10항에 있어서, 루테늄에 대한 기타 금속의 담지량의 원자비로 0.01∼20인 방법.
  12. 제1항 또는 제2항에 있어서, 방향족 탄화수소가 벤젠인 방법.
  13. 제1항 또는 제2항에 있어서, 방향족 탄화수소에 대한 물의 용량비가 0.01 내지 10인 방법.
  14. 제2항에 있어서, 금속염이 아연의 염인 방법.
  15. 제2항에 있어서, 물에 대한 금속염의 양이 1×10-5∼1 중량배인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910011951A 1990-07-13 1991-07-13 시클로 올레핀의 제조법 KR0160308B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP90/185842 1990-07-13
JP90-185842 1990-07-13
JP2185842A JP2814711B2 (ja) 1990-07-13 1990-07-13 シクロオレフィンの製造法

Publications (2)

Publication Number Publication Date
KR920002494A true KR920002494A (ko) 1992-02-28
KR0160308B1 KR0160308B1 (ko) 1999-01-15

Family

ID=16177834

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910011951A KR0160308B1 (ko) 1990-07-13 1991-07-13 시클로 올레핀의 제조법

Country Status (6)

Country Link
US (1) US5157179A (ko)
EP (1) EP0466128B1 (ko)
JP (1) JP2814711B2 (ko)
KR (1) KR0160308B1 (ko)
DE (1) DE69108120T2 (ko)
TW (1) TW253882B (ko)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW218865B (ko) * 1992-01-24 1994-01-11 Asahi Carbon Kabushiki Kaisha
US5414171A (en) * 1992-02-26 1995-05-09 Catalytica, Inc. Process and washed catalyst for partially hydrogenating aromatics to produce cycloolefins
DE69403885T2 (de) * 1993-12-24 1998-01-29 Mitsubishi Chem Corp Verfahren zur Herstellung von Cycloolefinen
BE1009128A3 (fr) * 1994-12-19 1996-12-03 Mitsubishi Chem Corp Procede de production de cycloolefines.
EP0769484B1 (en) 1995-10-20 2001-06-13 Mitsubishi Chemical Corporation Method for separating cyclohexene
US6248924B1 (en) * 1996-06-19 2001-06-19 Basf Aktiengesellschaft Process for reacting an organic compound in the presence of a supported ruthenium catalyst
JPH1129503A (ja) * 1997-07-08 1999-02-02 Asahi Chem Ind Co Ltd シクロオレフィンの製造方法
US6417135B1 (en) * 1999-08-27 2002-07-09 Huntsman Petrochemical Corporation Advances in dehydrogenation catalysis
US6376622B1 (en) * 1999-12-08 2002-04-23 The Dow Chemical Company Process for hydrogenating aromatic polymers
DE10128204A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Herstellung von cycloaliphatischen Verbindungen I, die Seitenketten mit Epoxidgruppen aufweisen
JP4931099B2 (ja) * 2003-09-30 2012-05-16 旭化成ケミカルズ株式会社 シクロオレフィン製造用触媒及び、シクロオレフィンの製造方法
EP1767270A4 (en) * 2004-07-09 2012-09-19 Asahi Kasei Chemicals Corp CATALYST FOR PRODUCTION OF CYCLOOLEFINS AND PROCESS FOR PRODUCTION
CN1304109C (zh) * 2004-08-12 2007-03-14 郑州大学 苯选择加氢制环己烯催化剂，其制备方法及调变方法和再生方法
CN101198570B (zh) * 2005-08-26 2011-11-02 旭化成化学株式会社 环烯烃的制造方法
WO2009095711A1 (en) * 2008-02-01 2009-08-06 Johnson Matthey Plc Process for the conversion of fatty acids and derivatives thereof
GB0913193D0 (en) * 2009-07-29 2009-09-02 Johnson Matthey Plc Deoxygenation process
IT1402745B1 (it) * 2010-10-27 2013-09-18 Polimeri Europa Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
ITMI20121724A1 (it) * 2012-10-12 2014-04-13 Versalis Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
CN103787816B (zh) * 2012-11-01 2015-06-17 中国石油化工股份有限公司 一种苯部分加氢制环己烯工艺
US9861960B2 (en) 2013-10-18 2018-01-09 Exxonmobil Chemical Patents Inc. Hydrogenation catalyst, its method of preparation and use
CN106140154B (zh) * 2015-04-17 2019-01-08 中国石油化工股份有限公司 一种苯选择加氢制环己烯的催化剂及其制备方法与应用
CN105056971A (zh) * 2015-08-07 2015-11-18 郑州大学 一种苯选择加氢制环己烯用Ru-Zn催化剂的原位再生方法

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US3637878A (en) * 1970-04-13 1972-01-25 Union Oil Co Hydrogenation process and catalyst
US3703461A (en) * 1971-07-16 1972-11-21 Union Oil Co Hydrogenation process and catalyst
US3767720A (en) * 1972-02-25 1973-10-23 Du Pont Selective hydrogenation of aromatic hydrocarbons to cycloolefins
US4197415A (en) * 1976-10-08 1980-04-08 Toray Industries, Inc. Process for preparing cyclic olefins by selective partial hydrogenation of aromatic hydrocarbons
JPS6059215B2 (ja) * 1983-02-24 1985-12-24 工業技術院長 ベンゼンからのシクロヘキセンの製法
CA1267914A (en) * 1985-10-03 1990-04-17 Hajime Nagahara Process for producing cycloolefins

Also Published As

Publication number Publication date
EP0466128A1 (en) 1992-01-15
JP2814711B2 (ja) 1998-10-27
US5157179A (en) 1992-10-20
DE69108120T2 (de) 1995-11-02
KR0160308B1 (ko) 1999-01-15
EP0466128B1 (en) 1995-03-15
TW253882B (ko) 1995-08-11
JPH0474141A (ja) 1992-03-09
DE69108120D1 (de) 1995-04-20

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