JPWO2016158013A1 - 消臭組成物、消臭布帛、及び繊維製品 - Google Patents
消臭組成物、消臭布帛、及び繊維製品 Download PDFInfo
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- A—HUMAN NECESSITIES
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- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
- B01J20/28038—Membranes or mats made from fibers or filaments
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/22—Treatment by sorption, e.g. absorption, adsorption, chemisorption, scrubbing, wet cleaning
Abstract
Description
ヒドロキシエチリデンホスホン酸及びその塩、アルキルスルホコハク酸及びその塩、アルキルスルホン酸及びその塩、モノアルキルホスフェートからなる群より選ばれる少なくとも1種のアニオン系界面活性剤と、を含有することを特徴とする消臭組成物。
銅と、
亜鉛、マンガン、コバルト及びニッケルからなる群より選ばれる1種または2種以上の金属と、を含む前項1に記載の消臭組成物。
・銅と、
・亜鉛、マンガン、コバルト及びニッケルからなる群より選ばれる1種または2種以上の金属と、を含む構成であるのが好ましい。
銅ケイ酸塩20質量部とヒドロキシエチリデンホスホン酸2質量部と水78質量部を加えた後、撹拌機によって撹拌を行い、消臭組成物を得た。前記消臭組成物10質量部に、さらにアクリル系バインダー樹脂(固形分50%)5質量部と水85質量部を加え、撹拌機によって撹拌を行い、処理液を得た。前記処理液中にポリエステル布帛(目付150g/m2)を浸漬し、マングルで絞った(ピックアップ量100g/m2)後、130℃で15分間乾燥させ、消臭布帛を得た。消臭布帛への付着量は、銅ケイ酸塩2g/m2、ヒドロキシエチリデンホスホン酸0.2g/m2、アクリル系バインダー樹脂2.5g/m2であった。
消臭組成物の配合組成を表1のようにした以外は実施例1と同様にして消臭組成物、消臭布帛を得た。また、液安定性の評価結果を表1に記載した。また、布帛に付着させる処理液の組成を表2に、布帛への付着量を表3に、メチルメルカプタン及び硫化水素を用いた消臭試験を行った際の臭気成分減少率と評価を表4に、それぞれ記載した。
表1に記載の各配合液を45℃の環境下で120時間放置後に、それぞれ目視で判定した。凝集又は沈降又は金属の溶出のいずれも認められないものを「○」、いずれかでも認められたものを「×」と評価した。
消臭性の測定は、SEKマーク繊維製品認証基準(JEC301 平成25年4月1日改訂、一般社団法人繊維評価技術協議会)に準拠し行った。
試験試料(10cm×10cm)を内容量5Lの袋内に入れた後、袋内において濃度が8ppmとなるようにメチルメルカプタンガスを3L注入し、2時間経過後にメチルメルカプタンガスの残存濃度を測定し、試験試料を入れない以外は同様にしてブランクを用意し、このブランクのメチルメルカプタンガスの残存濃度を測定し、両者の測定値よりメチルメルカプタンガスを除去した総量を算出し、これよりメチルメルカプタンガスの臭気成分減少率(%)を算出した。
メチルメルカプタンに代えて硫化水素ガスを用いて袋内において濃度が4ppmとなるように注入した以外は、上記メチルメルカプタン消臭性能測定と同様にして硫化水素の臭気成分減少率(%)を算出した。
SEKマーク繊維製品の洗濯方法(JEC326 平成26年4月1日改訂、一般社団法人繊維評価技術協議会)に準拠し洗濯を10回行った後の布帛を、消臭性試験で評価した。
10…繊維製品
Claims (6)
- 金属ケイ酸塩を含む消臭剤と、
ヒドロキシエチリデンホスホン酸及びその塩、アルキルスルホコハク酸及びその塩、アルキルスルホン酸及びその塩、モノアルキルホスフェートからなる群より選ばれる少なくとも1種のアニオン系界面活性剤と、を含有することを特徴とする消臭組成物。 - 前記金属ケイ酸塩は、銅ケイ酸塩である請求項1に記載の消臭組成物。
- 前記金属ケイ酸塩を構成する金属として、
銅と、
亜鉛、マンガン、コバルト及びニッケルからなる群より選ばれる1種または2種以上の金属と、を含む請求項1に記載の消臭組成物。 - 請求項1〜3のいずれか1項に記載の消臭組成物が、バインダー樹脂によって布帛の少なくとも一部に付着してなる消臭布帛。
- 請求項4に記載の消臭布帛を少なくとも一部に備えてなる繊維製品。
- 請求項1〜3のいずれか1項に記載の消臭組成物と、水と、バインダー樹脂と、を含有する処理液を布帛の少なくとも一部に塗布することを特徴とする消臭布帛の製造方法。
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JP2015072763 | 2015-03-31 | ||
JP2015072763 | 2015-03-31 | ||
PCT/JP2016/053628 WO2016158013A1 (ja) | 2015-03-31 | 2016-02-08 | 消臭組成物、消臭布帛、及び繊維製品 |
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JPWO2016158013A1 true JPWO2016158013A1 (ja) | 2018-01-25 |
JP6735731B2 JP6735731B2 (ja) | 2020-08-05 |
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US (1) | US10517978B2 (ja) |
JP (1) | JP6735731B2 (ja) |
CN (1) | CN107427597B (ja) |
DE (1) | DE112016001579T5 (ja) |
WO (1) | WO2016158013A1 (ja) |
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US10753017B2 (en) * | 2015-08-04 | 2020-08-25 | Siny Corp. | Insulating fabric and method for making the same |
JP6348532B2 (ja) * | 2016-03-31 | 2018-06-27 | 大王製紙株式会社 | トイレットペーパー |
JP2018143595A (ja) * | 2017-03-07 | 2018-09-20 | 住江織物株式会社 | 消臭抗菌防水シート及び該消臭抗菌防水シートを用いた寝具用シート及びベッドパット |
JP6896296B2 (ja) * | 2018-09-21 | 2021-06-30 | 理研香料ホールディングス株式会社 | 亜硫酸塩水溶液の安定化剤および消臭剤 |
JP7405507B2 (ja) | 2019-01-09 | 2023-12-26 | イビデン株式会社 | 硫黄系ガス吸着構造体及び組電池 |
JP7442770B2 (ja) * | 2019-07-12 | 2024-03-05 | 住江織物株式会社 | 消臭、抗菌、抗アレルゲン、抗ウイルス、防ダニ性能を有する繊維布帛 |
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2016
- 2016-02-08 WO PCT/JP2016/053628 patent/WO2016158013A1/ja active Application Filing
- 2016-02-08 US US15/559,952 patent/US10517978B2/en active Active
- 2016-02-08 JP JP2017509348A patent/JP6735731B2/ja active Active
- 2016-02-08 DE DE112016001579.8T patent/DE112016001579T5/de not_active Withdrawn
- 2016-02-08 CN CN201680020171.8A patent/CN107427597B/zh active Active
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JP2005087630A (ja) * | 2003-09-19 | 2005-04-07 | Toagosei Co Ltd | 硫黄系悪臭の消臭に適した消臭剤 |
JP2008105370A (ja) * | 2006-09-25 | 2008-05-08 | Toyota Motor Corp | 消臭加工布帛及び布帛の消臭加工方法 |
US20110123393A1 (en) * | 2007-12-21 | 2011-05-26 | Hubert Kuhn | Surface-active metal complexes on carrier material for adsorbing noxious substances and method for production thereof |
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US20180071423A1 (en) | 2018-03-15 |
WO2016158013A1 (ja) | 2016-10-06 |
JP6735731B2 (ja) | 2020-08-05 |
US10517978B2 (en) | 2019-12-31 |
CN107427597A (zh) | 2017-12-01 |
DE112016001579T5 (de) | 2017-12-28 |
CN107427597B (zh) | 2021-03-23 |
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