JPS6324545B2 - - Google Patents
Info
- Publication number
- JPS6324545B2 JPS6324545B2 JP55114883A JP11488380A JPS6324545B2 JP S6324545 B2 JPS6324545 B2 JP S6324545B2 JP 55114883 A JP55114883 A JP 55114883A JP 11488380 A JP11488380 A JP 11488380A JP S6324545 B2 JPS6324545 B2 JP S6324545B2
- Authority
- JP
- Japan
- Prior art keywords
- phthalocyanine
- formula
- integer
- fraction
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 24
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 21
- -1 phthalocyanine compound Chemical class 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 16
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 14
- 238000004043 dyeing Methods 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical group [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229940124530 sulfonamide Drugs 0.000 claims description 6
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 6
- 239000004753 textile Substances 0.000 claims description 6
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- QUQFTIVBFKLPCL-UHFFFAOYSA-L copper;2-amino-3-[(2-amino-2-carboxylatoethyl)disulfanyl]propanoate Chemical compound [Cu+2].[O-]C(=O)C(N)CSSCC(N)C([O-])=O QUQFTIVBFKLPCL-UHFFFAOYSA-L 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Chemical group 0.000 claims description 5
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- JMSCRSRHQXBZSD-UHFFFAOYSA-N sulfonylcyanamide Chemical compound O=S(=O)=NC#N JMSCRSRHQXBZSD-UHFFFAOYSA-N 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims 3
- 150000003456 sulfonamides Chemical class 0.000 claims 3
- 230000003301 hydrolyzing effect Effects 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 35
- 239000000975 dye Substances 0.000 description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 150000001875 compounds Chemical class 0.000 description 21
- 239000000243 solution Substances 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 17
- 150000003863 ammonium salts Chemical class 0.000 description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 11
- 229910052802 copper Inorganic materials 0.000 description 11
- 239000010949 copper Substances 0.000 description 11
- 235000011121 sodium hydroxide Nutrition 0.000 description 11
- 238000007792 addition Methods 0.000 description 10
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 10
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 9
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 8
- 239000010981 turquoise Substances 0.000 description 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 230000007935 neutral effect Effects 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 238000006482 condensation reaction Methods 0.000 description 4
- 239000002657 fibrous material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 125000000565 sulfonamide group Chemical group 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000020477 pH reduction Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- WDEQGLDWZMIMJM-UHFFFAOYSA-N benzyl 4-hydroxy-2-(hydroxymethyl)pyrrolidine-1-carboxylate Chemical compound OCC1CC(O)CN1C(=O)OCC1=CC=CC=C1 WDEQGLDWZMIMJM-UHFFFAOYSA-N 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- 239000001045 blue dye Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 125000002837 carbocyclic group Chemical group 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000005185 salting out Methods 0.000 description 2
- 150000005619 secondary aliphatic amines Chemical class 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- BIIBYWQGRFWQKM-JVVROLKMSA-N (2S)-N-[4-(cyclopropylamino)-3,4-dioxo-1-[(3S)-2-oxopyrrolidin-3-yl]butan-2-yl]-2-[[(E)-3-(2,4-dichlorophenyl)prop-2-enoyl]amino]-4,4-dimethylpentanamide Chemical compound CC(C)(C)C[C@@H](C(NC(C[C@H](CCN1)C1=O)C(C(NC1CC1)=O)=O)=O)NC(/C=C/C(C=CC(Cl)=C1)=C1Cl)=O BIIBYWQGRFWQKM-JVVROLKMSA-N 0.000 description 1
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ALYNCZNDIQEVRV-PZFLKRBQSA-N 4-amino-3,5-ditritiobenzoic acid Chemical compound [3H]c1cc(cc([3H])c1N)C(O)=O ALYNCZNDIQEVRV-PZFLKRBQSA-N 0.000 description 1
- MVXMNHYVCLMLDD-UHFFFAOYSA-N 4-methoxynaphthalene-1-carbaldehyde Chemical compound C1=CC=C2C(OC)=CC=C(C=O)C2=C1 MVXMNHYVCLMLDD-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 241000974482 Aricia saepiolus Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- BQRPKHOZMDAQPG-UHFFFAOYSA-J Cl[Ni](Cl)(Cl)Cl Chemical compound Cl[Ni](Cl)(Cl)Cl BQRPKHOZMDAQPG-UHFFFAOYSA-J 0.000 description 1
- 241000208202 Linaceae Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- FFNKZSVHHUBFHT-UHFFFAOYSA-N cyanamide;sodium Chemical compound [Na].[Na].NC#N FFNKZSVHHUBFHT-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 1
- 238000009967 direct dyeing Methods 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- RIWRFSMVIUAEBX-UHFFFAOYSA-N n-methyl-1-phenylmethanamine Chemical compound CNCC1=CC=CC=C1 RIWRFSMVIUAEBX-UHFFFAOYSA-N 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000007530 organic bases Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical compound OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- KZVLNAGYSAKYMG-UHFFFAOYSA-N pyridine-2-sulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=N1 KZVLNAGYSAKYMG-UHFFFAOYSA-N 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
- C09B47/24—Obtaining compounds having âCOOH or âSO3H radicals, or derivatives thereof, directly bound to the phthalocyanine radical
- C09B47/26—Amide radicals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/917—Wool or silk
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/919—Paper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/924—Polyamide fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
äŸãã°ãã€ãç¹èš±æ现æžç¬¬696591å·ããããã¿
ãã·ã¢ãã³ã¹ã«ãã¯ããªããšã¢ã³ã¢ãã¢ã第äžçŽ
åã¯ç¬¬äºçŽèèªæåã¯è³éŠæã¢ãã³ãšãåå¿ãã
ãããšã«ãã€ãŠè£œé ããããšãåºæ¥ããã¹ã«ãã³
ã¢ããåºå«æã®ãã¿ãã·ã¢ãã³ææãå ¬ç¥ã§ã
ãããã¿ãã·ã¢ãã³ã¹ã«ãã¯ããªããšè€çŽ ç°ã¢ã
ã³ãšãåå¿ãããããšã«ãã€ãŠè£œé ãããè€çŽ ç°
æ®åºãæãã察å¿ããèªå°äœãåãããã§ã«èšèŒ
ãããŠãããïŒç±³åœç¹èš±ç¬¬2459771å·åç §ïŒããã®
ãã¿ãã·ã¢ãã³ã¹ã«ãã³ã¢ããã¯ãå šéšã®ã¹ã«ã
ã¯ããªãåºãã¹ã«ãã³ã¢ããåºã«å€æãããå Žå
ã«ã¯ãäžæ§ã§ã¯æ°Žã«æº¶è§£ãããã¢ã³ã¢ãã¢åã¯ç¬¬
äžçŽã¢ãã³ããèªå°ãããå Žåã¯ã¢ã«ã«ãªã®æ·»å
äžã§ã®ã¿æ°Žã«æº¶è§£ãããåŸã€ãŠããã¯ææãšããŠ
匷ã¢ã«ã«ãªæ§æµŽããã®ã¿é©çšãããã
ãã·ã¢ãã³ã¹ã«ãã¯ããªããšã¢ã³ã¢ãã¢ã第äžçŽ
åã¯ç¬¬äºçŽèèªæåã¯è³éŠæã¢ãã³ãšãåå¿ãã
ãããšã«ãã€ãŠè£œé ããããšãåºæ¥ããã¹ã«ãã³
ã¢ããåºå«æã®ãã¿ãã·ã¢ãã³ææãå ¬ç¥ã§ã
ãããã¿ãã·ã¢ãã³ã¹ã«ãã¯ããªããšè€çŽ ç°ã¢ã
ã³ãšãåå¿ãããããšã«ãã€ãŠè£œé ãããè€çŽ ç°
æ®åºãæãã察å¿ããèªå°äœãåãããã§ã«èšèŒ
ãããŠãããïŒç±³åœç¹èš±ç¬¬2459771å·åç §ïŒããã®
ãã¿ãã·ã¢ãã³ã¹ã«ãã³ã¢ããã¯ãå šéšã®ã¹ã«ã
ã¯ããªãåºãã¹ã«ãã³ã¢ããåºã«å€æãããå Žå
ã«ã¯ãäžæ§ã§ã¯æ°Žã«æº¶è§£ãããã¢ã³ã¢ãã¢åã¯ç¬¬
äžçŽã¢ãã³ããèªå°ãããå Žåã¯ã¢ã«ã«ãªã®æ·»å
äžã§ã®ã¿æ°Žã«æº¶è§£ãããåŸã€ãŠããã¯ææãšããŠ
匷ã¢ã«ã«ãªæ§æµŽããã®ã¿é©çšãããã
æŽã«ãã€ãç¹èš±æ现æžç¬¬868035å·ãè±åœç¹èš±ç¬¬
1046520å·ããã€ãç¹èš±å ¬éæ现æžç¬¬1928677å·äžŠ
ã³ã«ç±³åœâç¹èš±æ现æžç¬¬2459773å·ãããã»ã«ã
ãŒãºå«æææã®çŽæ¥æè²ã«é©ããŠãããå€ããå°
ãã氎溶æ§ã®ãã¿ãã·ã¢ãã³ã¹ã«ãã³ã¢ãããå ¬
ç¥ã§ãããããã¯ãã¿ãã·ã¢ãã³ã¹ã«ãã¯ããªã
ãšã¢ã³ã¢ãã¢åã³ïŒåã¯èèªæã¢ãã³ãšã®éšåç
åå¿ã«ãã€ãŠè£œé ããããšãåºæ¥ããã®éåå¿ã
ãªãã¹ã«ãã¯ããªãåºã¯åæã«åã¯ç¶ããŠå æ°Žå
解ãããããã®ãã¿ãã·ã¢ãã³ã¹ã«ãã³ã¢ããã®
氎溶æ§ã¯ãå®éã«ã¯å€ãã®å Žåååã§ã¯ãããã
å¯æº¶æ§ã«ããã¹ã«ãåºã®æ°ã¯åœç¶éãããŠããã®
ã§ãæ¹åããå¿ èŠãããã
1046520å·ããã€ãç¹èš±å ¬éæ现æžç¬¬1928677å·äžŠ
ã³ã«ç±³åœâç¹èš±æ现æžç¬¬2459773å·ãããã»ã«ã
ãŒãºå«æææã®çŽæ¥æè²ã«é©ããŠãããå€ããå°
ãã氎溶æ§ã®ãã¿ãã·ã¢ãã³ã¹ã«ãã³ã¢ãããå ¬
ç¥ã§ãããããã¯ãã¿ãã·ã¢ãã³ã¹ã«ãã¯ããªã
ãšã¢ã³ã¢ãã¢åã³ïŒåã¯èèªæã¢ãã³ãšã®éšåç
åå¿ã«ãã€ãŠè£œé ããããšãåºæ¥ããã®éåå¿ã
ãªãã¹ã«ãã¯ããªãåºã¯åæã«åã¯ç¶ããŠå æ°Žå
解ãããããã®ãã¿ãã·ã¢ãã³ã¹ã«ãã³ã¢ããã®
氎溶æ§ã¯ãå®éã«ã¯å€ãã®å Žåååã§ã¯ãããã
å¯æº¶æ§ã«ããã¹ã«ãåºã®æ°ã¯åœç¶éãããŠããã®
ã§ãæ¹åããå¿ èŠãããã
æ¬çºæè
ã¯ãäžèšã®æ¬ ç¹ãæããããã®æ°Žæº¶æ§
ãã¹ã«ãåºã®ååšã«å·Šå³ãããªããèå³ããæ°èŠ
ãªã¹ã«ãã³ã¢ããåºå«æã®ãéåžžã«è¯å¥œãªæ°Žæº¶æ§
ãæãããé«ãå質ã®ææãšããŠäœ¿çšããããã¿
ãã·ã¢ãã³ååç©ãèŠåºããã
ãã¹ã«ãåºã®ååšã«å·Šå³ãããªããèå³ããæ°èŠ
ãªã¹ã«ãã³ã¢ããåºå«æã®ãéåžžã«è¯å¥œãªæ°Žæº¶æ§
ãæãããé«ãå質ã®ææãšããŠäœ¿çšããããã¿
ãã·ã¢ãã³ååç©ãèŠåºããã
ãã®æ°èŠãã¿ãã·ã¢ãã³ååç©ã¯é
žæ§ã®åœ¢åã³
ãã®å¡©ã®åœ¢ã§äžèšäžè¬åŒ(1)ã«çžåœããïŒ ãåŒäžã Pcã¯é âãããã±ã«âåã¯ã³ãã«ãâãã¿ã
ã·ã¢ãã³æ®åºã§ããããã®éãã®åŒ(1)ã«ç€ºããã
ã¹ã«ããã«ã¢ãããâãã¹ã«ãã³ã¢ããâåã³
ïŒåã¯ïŒã¹ã«ãã³é žåºã¯ãã¿ãã·ã¢ãã³ã®ççŽ ç°
ç¶è³éŠæç°ã®ïŒâåã³ïŒåã¯ïŒïŒâäœã«çµåããŠ
ããã ã¯æ°ŽçŽ ååãã¢ã«ã«ãªéå±åã¯ã¢ã³ã¢ããŠã
åºã§ããã R1åã³R2ã¯åæ¹ãšãæ°ŽçŽ ååã瀺ãã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ãã®å ŽåïœïŒïœåã³ïœã¯çžäºã«åäžåã¯ç°ãªã€
ãŠããããäœãïŒïœïŒïœïŒïœïŒã®åèšã¯ïŒãïŒã§
ãããã åŒ(1)ã«ãããŠïŒžãæ°ŽçŽ ååã§ããæ°èŠååç©
ã¯ããïŒã®å Žåã«ãé žæ§ååç©ã§ããããšãã
ã®ã¯ã¹ã«ããã«ã·ã¢ãããåºäžã®ã¢ããæ®åºã匷
ã極æ§åãããŠãããã¢ããåºã®æ°ŽçŽ ååã¯ãã
ãã³ãšããŠåå¿ããä»ã®å¡©åœ¢æã«ããªã³ãäŸãã°
ãããªãŠã âãã«ãªãŠã âåã³ã¢ã³ã¢ããŠã ã€ãª
ã³ã«ãã€ãŠå®¹æã«äº€æãããããã§ããã
ãã®å¡©ã®åœ¢ã§äžèšäžè¬åŒ(1)ã«çžåœããïŒ ãåŒäžã Pcã¯é âãããã±ã«âåã¯ã³ãã«ãâãã¿ã
ã·ã¢ãã³æ®åºã§ããããã®éãã®åŒ(1)ã«ç€ºããã
ã¹ã«ããã«ã¢ãããâãã¹ã«ãã³ã¢ããâåã³
ïŒåã¯ïŒã¹ã«ãã³é žåºã¯ãã¿ãã·ã¢ãã³ã®ççŽ ç°
ç¶è³éŠæç°ã®ïŒâåã³ïŒåã¯ïŒïŒâäœã«çµåããŠ
ããã ã¯æ°ŽçŽ ååãã¢ã«ã«ãªéå±åã¯ã¢ã³ã¢ããŠã
åºã§ããã R1åã³R2ã¯åæ¹ãšãæ°ŽçŽ ååã瀺ãã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ãã®å ŽåïœïŒïœåã³ïœã¯çžäºã«åäžåã¯ç°ãªã€
ãŠããããäœãïŒïœïŒïœïŒïœïŒã®åèšã¯ïŒãïŒã§
ãããã åŒ(1)ã«ãããŠïŒžãæ°ŽçŽ ååã§ããæ°èŠååç©
ã¯ããïŒã®å Žåã«ãé žæ§ååç©ã§ããããšãã
ã®ã¯ã¹ã«ããã«ã·ã¢ãããåºäžã®ã¢ããæ®åºã匷
ã極æ§åãããŠãããã¢ããåºã®æ°ŽçŽ ååã¯ãã
ãã³ãšããŠåå¿ããä»ã®å¡©åœ¢æã«ããªã³ãäŸãã°
ãããªãŠã âãã«ãªãŠã âåã³ã¢ã³ã¢ããŠã ã€ãª
ã³ã«ãã€ãŠå®¹æã«äº€æãããããã§ããã
äžè¬åŒ(1)ã®ååç©ã¯éåžžåŒ(1)ã®åã
ã®ååç©ã®
æ··åç©ã®åœ¢ã§åŸããããã®éãã®åã ã®ååç©ã¯
ææ°ïœïŒïœåã³ïœã§è¡šããããæ®åºã®çœ®æ床ã«ã
ã€ãŠç°ãªããåŸã€ãŠåŸãããåŒ(1)ã®ç®ççæç©ã®
åŒãçµç«ãŠãéãææ°ïœïŒïœåã³ïœã¯éåžžåæ°ã§
ããã
æ··åç©ã®åœ¢ã§åŸããããã®éãã®åã ã®ååç©ã¯
ææ°ïœïŒïœåã³ïœã§è¡šããããæ®åºã®çœ®æ床ã«ã
ã€ãŠç°ãªããåŸã€ãŠåŸãããåŒ(1)ã®ç®ççæç©ã®
åŒãçµç«ãŠãéãææ°ïœïŒïœåã³ïœã¯éåžžåæ°ã§
ããã
äžè¬åŒ(1)ã®æ°èŠååç©ã¯æ¬çºæã«ãã次ã®ãã
ã«è£œé ãããïŒ äžèšäžè¬åŒ(2) ãåŒäžPcã¯åèšã®æå³ãæããã¹ã«ãã¯ããª
ãâåã³ã¹ã«ãåºã¯ãã¿ãã·ã¢ãã³ã®ççŽ ç°ç¶è³
éŠæç°ã®ïŒâåã³ïŒåã¯ïŒäœã«çµåããŠãããïœ
ã¯ïŒãïŒã®æ°ãïœã¯ãŒããïŒã®æ°ã§ãããïŒïœïŒ
ïœïŒã®åã¯ïŒãïŒã§ãããã ãªããã¿ãã·ã¢ãã³ã¹ã«ãã³é žã¯ããªããã·ã¢ã
ãããšãåã¯ãã®å¡©ãšãããã¯ã·ã¢ãããåã¯ã
ã®å¡©åã³ã¢ã³ã¢ãã¢ãšãšåæã«åã¯ä»»æã®é åºã§
æ°Žæ§åªè³ªäžåã¯å¥œãŸããã¯æ°Žãšæ··åãããææ©æº¶
å€äžãåã¯ãããã®æ··åç©äžïŒã14ã®PHå€ã奜ãŸ
ããïŒã14ã®PHå€ã§ãâ10âãïŒ110âã奜ãŸãã
ã¯ïŒâã40âã®æž©åºŠã§ãé žçµåå€ã®ååšäžã«ãå
å¿ããããã®éå Žåã«ããåæã«åã¯åŸããã¹ã«
ãã¯ããªãåºãéšåçã«å æ°Žå解ããŠã¹ã«ãåºãš
ãªããã·ã¢ãããã¯ãã®éå Žåã«ããäŸãã°ã¢ã
ãŒåã¯ãžãããªãŠã ã·ã¢ãããã®åŠãå¡©ã®åœ¢ã§ã
䜿çšãããã
ã«è£œé ãããïŒ äžèšäžè¬åŒ(2) ãåŒäžPcã¯åèšã®æå³ãæããã¹ã«ãã¯ããª
ãâåã³ã¹ã«ãåºã¯ãã¿ãã·ã¢ãã³ã®ççŽ ç°ç¶è³
éŠæç°ã®ïŒâåã³ïŒåã¯ïŒäœã«çµåããŠãããïœ
ã¯ïŒãïŒã®æ°ãïœã¯ãŒããïŒã®æ°ã§ãããïŒïœïŒ
ïœïŒã®åã¯ïŒãïŒã§ãããã ãªããã¿ãã·ã¢ãã³ã¹ã«ãã³é žã¯ããªããã·ã¢ã
ãããšãåã¯ãã®å¡©ãšãããã¯ã·ã¢ãããåã¯ã
ã®å¡©åã³ã¢ã³ã¢ãã¢ãšãšåæã«åã¯ä»»æã®é åºã§
æ°Žæ§åªè³ªäžåã¯å¥œãŸããã¯æ°Žãšæ··åãããææ©æº¶
å€äžãåã¯ãããã®æ··åç©äžïŒã14ã®PHå€ã奜ãŸ
ããïŒã14ã®PHå€ã§ãâ10âãïŒ110âã奜ãŸãã
ã¯ïŒâã40âã®æž©åºŠã§ãé žçµåå€ã®ååšäžã«ãå
å¿ããããã®éå Žåã«ããåæã«åã¯åŸããã¹ã«
ãã¯ããªãåºãéšåçã«å æ°Žå解ããŠã¹ã«ãåºãš
ãªããã·ã¢ãããã¯ãã®éå Žåã«ããäŸãã°ã¢ã
ãŒåã¯ãžãããªãŠã ã·ã¢ãããã®åŠãå¡©ã®åœ¢ã§ã
䜿çšãããã
äžè¬åŒ(1)ã«ãããŠææ°ïŒ£ããŒãã§ãªãååç©ã¯
äžèšã®æ¬çºæã®æ¹æ³ã«ãã€ãŠæ¬¡ã®ããã«è£œé ãã
ããšãåºæ¥ããããªãã¡æ¬çºæã«ããããããåŒ
(2)ã®ååç©ãšã·ã¢ãããåã¯ãã®å¡©ãšãããã¯ã·
ã¢ãããåã¯ãã®å¡©åã³ã¢ã³ã¢ãã¢ãšã®çž®ååå¿
ã®åã«ãåæã«åã¯åŸã«ãåŒ(2)ã®åºçºååç©ã®ã¹
ã«ãã³é žã¯ããªãåºã®äžéšãå æ°Žå解ã«ãã€ãŠã¹
ã«ãã³é žåºã«å°ãããšã«ããå€æãããåŸã€ãŠçž®
åãäŸãã°æ¬¡ã®ããã«è¡ãããšãåºæ¥ããã·ã¢ã
ããåã¯ãã®å¡©ãšãããã¯ã·ã¢ãããåã¯ãã®å¡©
åã³ã¢ã³ã¢ãã¢ãšã®åå¿ãšåæã«ãã¹ã«ãã³é žã¯
ããªãåºã®äžéšãå æ°Žå解ããããæãã¯å ãã¹
ã«ãã³é žã¯ããªãåºå šéšãå®å šã«åå¿ãããã®ã«
ååã§ãªãéã®ã·ã¢ãããåã¯ãã®å¡©ãšãããã¯
ã·ã¢ãããåã¯ãã®å¡©åã³ã¢ã³ã¢ãã¢ãšåå¿ã
ããç¶ããŠæ®ãã®ã¹ã«ãã³é žã¯ããªãåºãå¥ã®å
å¿æ®µéã§é žæ§åã¯ã¢ã«ã«ãªæ§ã®åªè³ªäžãããªãã¡
PHå€ïŒãïŒåã¯ïŒã12ã«ãŠãå Žåã«ããç±æãã
ãªãã¡20ã60âã®æž©åºŠã§å æ°Žå解ããã
äžèšã®æ¬çºæã®æ¹æ³ã«ãã€ãŠæ¬¡ã®ããã«è£œé ãã
ããšãåºæ¥ããããªãã¡æ¬çºæã«ããããããåŒ
(2)ã®ååç©ãšã·ã¢ãããåã¯ãã®å¡©ãšãããã¯ã·
ã¢ãããåã¯ãã®å¡©åã³ã¢ã³ã¢ãã¢ãšã®çž®ååå¿
ã®åã«ãåæã«åã¯åŸã«ãåŒ(2)ã®åºçºååç©ã®ã¹
ã«ãã³é žã¯ããªãåºã®äžéšãå æ°Žå解ã«ãã€ãŠã¹
ã«ãã³é žåºã«å°ãããšã«ããå€æãããåŸã€ãŠçž®
åãäŸãã°æ¬¡ã®ããã«è¡ãããšãåºæ¥ããã·ã¢ã
ããåã¯ãã®å¡©ãšãããã¯ã·ã¢ãããåã¯ãã®å¡©
åã³ã¢ã³ã¢ãã¢ãšã®åå¿ãšåæã«ãã¹ã«ãã³é žã¯
ããªãåºã®äžéšãå æ°Žå解ããããæãã¯å ãã¹
ã«ãã³é žã¯ããªãåºå šéšãå®å šã«åå¿ãããã®ã«
ååã§ãªãéã®ã·ã¢ãããåã¯ãã®å¡©ãšãããã¯
ã·ã¢ãããåã¯ãã®å¡©åã³ã¢ã³ã¢ãã¢ãšåå¿ã
ããç¶ããŠæ®ãã®ã¹ã«ãã³é žã¯ããªãåºãå¥ã®å
å¿æ®µéã§é žæ§åã¯ã¢ã«ã«ãªæ§ã®åªè³ªäžãããªãã¡
PHå€ïŒãïŒåã¯ïŒã12ã«ãŠãå Žåã«ããç±æãã
ãªãã¡20ã60âã®æž©åºŠã§å æ°Žå解ããã
åŒ(1)ã®ååç©ã¯éåžžãã®å¡©ã®åœ¢ã§ã奜ãŸããã¯
ã¢ã«ã«ãªéå±å¡©ãäŸãã°ãããªãŠã âåã³ã«ãªãŠ
ã å¡©ãåã¯ã¢ã³ã¢ããŠã å¡©ã®åœ¢ã§åŸããåã¯è£œé
ããããŸããã®ãããªåœ¢ã§ç¹ç¶ææã®æè²ã«äœ¿çš
ãããã
ã¢ã«ã«ãªéå±å¡©ãäŸãã°ãããªãŠã âåã³ã«ãªãŠ
ã å¡©ãåã¯ã¢ã³ã¢ããŠã å¡©ã®åœ¢ã§åŸããåã¯è£œé
ããããŸããã®ãããªåœ¢ã§ç¹ç¶ææã®æè²ã«äœ¿çš
ãããã
äžè¬åŒ(2)ã®ãã¿ãã·ã¢ãã³ã¹ã«ãã¯ããªãã¯ã·
ã¢ããããšãåã¯ã·ã¢ãããåã¯ãã®å¡©ãšããã
ã¯ã·ã¢ãããåã¯ãã®å¡©åã³ã¢ã³ã¢ãã¢ãšã奜ãŸ
ããã¯åå¿åªè³ªãšããŠã®æ°Žã®äžã§ãåå¿ãããã
ããããããã®åå¿ã¯ææ©æº¶å€äžã§è¡ãããšãåº
æ¥ããã®éæ°Žãšæ··åããã溶å€ãäŸãã°äœçŽã¢ã«
ã«ããŒã«ãäŸãã°ã¡ã¿ããŒã«åã³ãšã¿ããŒã«ã
âã¡ãã«âãããªãã³ããžã¡ãã«ãã«ã ã¢ããå
ã³ãžã¡ãã«ã¹ã«ããã·ãã奜ãŸãããåã¯ãã®ã
ããªæº¶å€ãšæ°Žã®æ··åç©äžã§è¡ãããšãã§ããã
ã¢ããããšãåã¯ã·ã¢ãããåã¯ãã®å¡©ãšããã
ã¯ã·ã¢ãããåã¯ãã®å¡©åã³ã¢ã³ã¢ãã¢ãšã奜ãŸ
ããã¯åå¿åªè³ªãšããŠã®æ°Žã®äžã§ãåå¿ãããã
ããããããã®åå¿ã¯ææ©æº¶å€äžã§è¡ãããšãåº
æ¥ããã®éæ°Žãšæ··åããã溶å€ãäŸãã°äœçŽã¢ã«
ã«ããŒã«ãäŸãã°ã¡ã¿ããŒã«åã³ãšã¿ããŒã«ã
âã¡ãã«âãããªãã³ããžã¡ãã«ãã«ã ã¢ããå
ã³ãžã¡ãã«ã¹ã«ããã·ãã奜ãŸãããåã¯ãã®ã
ããªæº¶å€ãšæ°Žã®æ··åç©äžã§è¡ãããšãã§ããã
äžè¬åŒ(2)ã®ååç©ãšã·ã¢ãããåã¯ãã®å¡©ãšã
ããã¯ã·ã¢ãããåã¯ãã®å¡©åã³ã¢ã³ã¢ãã¢ãšã®
åå¿ã¯â10âãïŒ110âã®æž©åºŠã§è¡ããããã®é
åå¿ãäœã枩床ã§ãäŸãã°â10âãïŒ20âãç¹ã«
ïŒâãïŒ10âã®æž©åºŠã§éå§ããäžéšåå¿ãè¡ãã
ãåŸæž©åºŠã20ã50âã«ãå¿ èŠãªå Žåã«ã¯110âãŸ
ã§ã奜ãŸããã¯çŽ100âã«é«ããããšã«ãã€ãŠå
å¿ãå®äºããããã®ãæå©ã§ããã
ããã¯ã·ã¢ãããåã¯ãã®å¡©åã³ã¢ã³ã¢ãã¢ãšã®
åå¿ã¯â10âãïŒ110âã®æž©åºŠã§è¡ããããã®é
åå¿ãäœã枩床ã§ãäŸãã°â10âãïŒ20âãç¹ã«
ïŒâãïŒ10âã®æž©åºŠã§éå§ããäžéšåå¿ãè¡ãã
ãåŸæž©åºŠã20ã50âã«ãå¿ èŠãªå Žåã«ã¯110âãŸ
ã§ã奜ãŸããã¯çŽ100âã«é«ããããšã«ãã€ãŠå
å¿ãå®äºããããã®ãæå©ã§ããã
äžè¬åŒ(1)ã®ååç©ã補é ããããã®æ¬çºæã«ã
ãçž®ååå¿ã®éã«äœ¿çšãããé žçµåå€ã¯å¥œãŸãã
ã¯ã¢ã«ã«ãªâåã³ã¢ã«ã«ãªåé¡âæ°Žé žåç©ã䞊ã³
ã«ã¢ã«ã«ãªâåã³ã¢ã«ã«ãªåé¡éå±ãšç¡æ©åã¯æ
æ©é žãšã®å¡©åºæ§ã«åå¿ããå¡©ãåã¯ç¬¬äžææ©å¡©åº
ã§ãããã¢ã«ã«ãªéå±ãšã¯å¥œãŸããã¯ãããªãŠã
åã³ã«ãªãŠã ããã¢ã«ã«ãªåé¡éå±ãšã¯å¥œãŸãã
ã¯ã«ã«ã·ãŠã ãæå³ãããå¡©åºæ§ã«åå¿ããå¡©ã¯
çé žããªã³é žåã³é ¢é žã®ã¢ã«ã«ãªéå±å¡©ãç¹ã«é ¢
é žãããªãŠã åã³âã«ãªãŠã ãéçé žãããªãŠã
åã³âã«ãªãŠã ãçé žãããªãŠã åã³âã«ãªãŠ
ã ããªã³é žäºæ°ŽçŽ ãããªãŠã ããªã³é žæ°ŽçŽ äºãã
ãªãŠã ããªã³é žäžãããªãŠã åã¯ãããã®å¯Ÿå¿ã
ãã«ãªãŠã å¡©ã奜ãŸããã
ãçž®ååå¿ã®éã«äœ¿çšãããé žçµåå€ã¯å¥œãŸãã
ã¯ã¢ã«ã«ãªâåã³ã¢ã«ã«ãªåé¡âæ°Žé žåç©ã䞊ã³
ã«ã¢ã«ã«ãªâåã³ã¢ã«ã«ãªåé¡éå±ãšç¡æ©åã¯æ
æ©é žãšã®å¡©åºæ§ã«åå¿ããå¡©ãåã¯ç¬¬äžææ©å¡©åº
ã§ãããã¢ã«ã«ãªéå±ãšã¯å¥œãŸããã¯ãããªãŠã
åã³ã«ãªãŠã ããã¢ã«ã«ãªåé¡éå±ãšã¯å¥œãŸãã
ã¯ã«ã«ã·ãŠã ãæå³ãããå¡©åºæ§ã«åå¿ããå¡©ã¯
çé žããªã³é žåã³é ¢é žã®ã¢ã«ã«ãªéå±å¡©ãç¹ã«é ¢
é žãããªãŠã åã³âã«ãªãŠã ãéçé žãããªãŠã
åã³âã«ãªãŠã ãçé žãããªãŠã åã³âã«ãªãŠ
ã ããªã³é žäºæ°ŽçŽ ãããªãŠã ããªã³é žæ°ŽçŽ äºãã
ãªãŠã ããªã³é žäžãããªãŠã åã¯ãããã®å¯Ÿå¿ã
ãã«ãªãŠã å¡©ã奜ãŸããã
第äžçŽææ©ã¢ãã³ã¯äŸãã°ããªãžã³ãããªãšã¿
ããŒã«ã¢ãã³åã¯ãžã¡ãã«ã¢ããªã³åã¯ç¹ã«ããª
ãžã³ã¹ã«ãã³é žåã¯ããªãžã³ã«ã«ãã³é žã奜ãŸã
ãã¯ãã³ãã³é žã§ããã
ããŒã«ã¢ãã³åã¯ãžã¡ãã«ã¢ããªã³åã¯ç¹ã«ããª
ãžã³ã¹ã«ãã³é žåã¯ããªãžã³ã«ã«ãã³é žã奜ãŸã
ãã¯ãã³ãã³é žã§ããã
åŒ(2)ã®åºçºååç©ãšããŠã¯é
ãã¿ãã·ã¢ãã³ã
ã³ãã«ããã¿ãã·ã¢ãã³åã¯ããã±ã«ãã¿ãã·ã¢
ãã³ã®ãžâãããªâåã¯ããã©ã¹ã«ãã³é žã¯ããª
ããäŸãã°é ãã¿ãã·ã¢ãã³â(3)âãžã¹ã«ãã³é ž
ã¯ããªããé ãã¿ãã·ã¢ãã³â(3)âããªã¹ã«ãã³
é žã¯ããªããé âåã¯ããã±ã«ãã¿ãã·ã¢ãã³â
(3)âããã©ã¹ã«ãã³é žã¯ããªããã³ãã«ããã¿ã
ã·ã¢ãã³â(3)âããªã¹ã«ãã³é žã¯ããªããé ãã¿
ãã·ã¢ãã³â(4)âãžã¹ã«ãã³é žã¯ããªãåã¯é ã
ã¿ãã·ã¢ãã³â(4)âããã©ã¹ã«ãã³é žã¯ããªãã
é ãã¿ãã·ã¢ãã³â(3)âãžã¹ã«ãã³é žã¯ããªãâ
ãžã¹ã«ãã³é žãé ãã¿ãã·ã¢ãã³â(3)âããªã¹ã«
ãã³é žã¯ããªãâã¢ãã¹ã«ãã³é žãæŽã«ãã¿ãã·
ã¢ãã³æ žã«ä»å çã«ä»ã®çœ®æåºãäŸãã°ããšãã«
æ®åºåã³ããã²ã³ååãå«æããé¡äŒŒã®ã¹ã«ãã³
é žã¯ããªããäŸãã°ããã©ããšãã«âé ãã¿ãã·
ã¢ãã³åã¯ããã©ã¯ãã«âããã±ã«ãã¿ãã·ã¢ã
ã³ã®ã¹ã«ãã³é žã¯ããªãã§ãããåŒ(2)ã®ã¹ã«ãã³
é žã¯ããªãã¯å ¬ç¥ã®æ¹æ³ã«ãããäŸãã°ãã€ãç¹
èš±æ现æžç¬¬891121å·ã®æ¹æ³ã«ãã€ãŠè£œé ãããã
ã³ãã«ããã¿ãã·ã¢ãã³åã¯ããã±ã«ãã¿ãã·ã¢
ãã³ã®ãžâãããªâåã¯ããã©ã¹ã«ãã³é žã¯ããª
ããäŸãã°é ãã¿ãã·ã¢ãã³â(3)âãžã¹ã«ãã³é ž
ã¯ããªããé ãã¿ãã·ã¢ãã³â(3)âããªã¹ã«ãã³
é žã¯ããªããé âåã¯ããã±ã«ãã¿ãã·ã¢ãã³â
(3)âããã©ã¹ã«ãã³é žã¯ããªããã³ãã«ããã¿ã
ã·ã¢ãã³â(3)âããªã¹ã«ãã³é žã¯ããªããé ãã¿
ãã·ã¢ãã³â(4)âãžã¹ã«ãã³é žã¯ããªãåã¯é ã
ã¿ãã·ã¢ãã³â(4)âããã©ã¹ã«ãã³é žã¯ããªãã
é ãã¿ãã·ã¢ãã³â(3)âãžã¹ã«ãã³é žã¯ããªãâ
ãžã¹ã«ãã³é žãé ãã¿ãã·ã¢ãã³â(3)âããªã¹ã«
ãã³é žã¯ããªãâã¢ãã¹ã«ãã³é žãæŽã«ãã¿ãã·
ã¢ãã³æ žã«ä»å çã«ä»ã®çœ®æåºãäŸãã°ããšãã«
æ®åºåã³ããã²ã³ååãå«æããé¡äŒŒã®ã¹ã«ãã³
é žã¯ããªããäŸãã°ããã©ããšãã«âé ãã¿ãã·
ã¢ãã³åã¯ããã©ã¯ãã«âããã±ã«ãã¿ãã·ã¢ã
ã³ã®ã¹ã«ãã³é žã¯ããªãã§ãããåŒ(2)ã®ã¹ã«ãã³
é žã¯ããªãã¯å ¬ç¥ã®æ¹æ³ã«ãããäŸãã°ãã€ãç¹
èš±æ现æžç¬¬891121å·ã®æ¹æ³ã«ãã€ãŠè£œé ãããã
åè¿°ã®æ¹æ³ã§åŸããããã¿ãã·ã¢ãã³ååç©ã®
åé¢ã¯åžžæ³ã«ãããäŸãã°å¡©åãããªãŠã ãâã«
ãªãŠã åã¯âã¢ã³ã¢ããŠã ã«ããå¡©æãåã³ïŒå
ã¯é±é žã«ããé žæ§åã«ãããåã¯ãã®äžæ§åã¯åŒ±
é žæ§æ°Žæ§æº¶æ¶²ã奜ãŸããã¯ããé«ãã枩床åã³æž
å§ã§èžçºæ¿çž®ããããšã«ãã€ãŠè¡ããããæ¬çºæ
ã«ãããã¿ãã·ã¢ãã³ååç©ã¯åŸã€ãŠãã®ãããª
ãŠã âãã«ãªãŠã âåã¯ã¢ã³ã¢ããŠã å¡©ã®åœ¢ã§å
ã¯é žã®åœ¢ã§ãæãã¯ãããã®åœ¢ã®æ··åç©ãšããŠåŸ
ãããã
åé¢ã¯åžžæ³ã«ãããäŸãã°å¡©åãããªãŠã ãâã«
ãªãŠã åã¯âã¢ã³ã¢ããŠã ã«ããå¡©æãåã³ïŒå
ã¯é±é žã«ããé žæ§åã«ãããåã¯ãã®äžæ§åã¯åŒ±
é žæ§æ°Žæ§æº¶æ¶²ã奜ãŸããã¯ããé«ãã枩床åã³æž
å§ã§èžçºæ¿çž®ããããšã«ãã€ãŠè¡ããããæ¬çºæ
ã«ãããã¿ãã·ã¢ãã³ååç©ã¯åŸã€ãŠãã®ãããª
ãŠã âãã«ãªãŠã âåã¯ã¢ã³ã¢ããŠã å¡©ã®åœ¢ã§å
ã¯é žã®åœ¢ã§ãæãã¯ãããã®åœ¢ã®æ··åç©ãšããŠåŸ
ãããã
æ¬çºæã«ãããã¿ãã·ã¢ãã³ååç©ã¯ãçŸæ¯ã
çµ¹ãç·ç¶ããªã¢ãããã ãç¹ã«ã»ã«ããŒãºã®åŠã
ããããã·åºå«æææãäŸãã°äºéº»ãåçã»ã«ã
ãŒãºåã³ç¹ã«æšç¶¿ããæãç¹ç¶ææã䞊ã³ã«çŽã
æŽã«ç®é©ãæè²åã³æºæããããã®ææãšããŠé©
ããŠãããç¹ã«ã¢ã³ã¢ããŠã å¡©ã®åœ¢ã§ææãšããŠ
䜿çšãããã
çµ¹ãç·ç¶ããªã¢ãããã ãç¹ã«ã»ã«ããŒãºã®åŠã
ããããã·åºå«æææãäŸãã°äºéº»ãåçã»ã«ã
ãŒãºåã³ç¹ã«æšç¶¿ããæãç¹ç¶ææã䞊ã³ã«çŽã
æŽã«ç®é©ãæè²åã³æºæããããã®ææãšããŠé©
ããŠãããç¹ã«ã¢ã³ã¢ããŠã å¡©ã®åœ¢ã§ææãšããŠ
䜿çšãããã
æè²ã®è£œé ã¯åžžæ³ã«ããç±ãåºçåªè³ªãšããŠäžŠ
ã³ã«äžæ§åã¯é žæ§PHåã§è¡ããããäŸãã°å Žåã«
ããäžæ§ç¡æ©å¡©ãäŸãã°å¡©åã¢ã«ã«ãªåã¯ç¡«é žã¢
ã«ã«ãªãå«æããæ济ããã宀枩åã¯é«ãããã
枩床ãäŸãã°çŽ40ãçŽ100âã«ãŠçŽæ¥æè²ããå Ž
åã«ããäžé也ç¥ããåŸãç¶ããŠ95â以äžã®æž©åºŠ
ã§åºçããããšã«ãã€ãŠè¡ãããã
ã³ã«äžæ§åã¯é žæ§PHåã§è¡ããããäŸãã°å Žåã«
ããäžæ§ç¡æ©å¡©ãäŸãã°å¡©åã¢ã«ã«ãªåã¯ç¡«é žã¢
ã«ã«ãªãå«æããæ济ããã宀枩åã¯é«ãããã
枩床ãäŸãã°çŽ40ãçŽ100âã«ãŠçŽæ¥æè²ããå Ž
åã«ããäžé也ç¥ããåŸãç¶ããŠ95â以äžã®æž©åºŠ
ã§åºçããããšã«ãã€ãŠè¡ãããã
äžè¬åŒ(1)ã®ååç©â以äžææãšåŒã¶âã¯ç¹ç¶ã«
察ãã芪åæ§ãå°ããã®ã§ãå Žåã«ããäžæ§ç¡æ©
å¡©ãå«æããæ¬çºæã«ããææã®æ°Žæ§æº¶æ¶²ã«ãã
ç¹ç¶ææãå·æåã¯ããé«ãã枩床ã§å«æµžããå§
æŸããããããŠä»äžãããææããå Žåã«ããäž
é也ç¥åŸãåºçããããšã«ãã€ãŠé©çšããã®ãæ
å©ã§ããã
察ãã芪åæ§ãå°ããã®ã§ãå Žåã«ããäžæ§ç¡æ©
å¡©ãå«æããæ¬çºæã«ããææã®æ°Žæ§æº¶æ¶²ã«ãã
ç¹ç¶ææãå·æåã¯ããé«ãã枩床ã§å«æµžããå§
æŸããããããŠä»äžãããææããå Žåã«ããäž
é也ç¥åŸãåºçããããšã«ãã€ãŠé©çšããã®ãæ
å©ã§ããã
åºçã¯95ã220âã®æž©åºŠã§è¡ããããã®é枩床
ã¯ãç¹ç¶ææãéåžžã«é«ã枩床åã¯ä¹Ÿç±ç©ºæ°ã«å¯Ÿ
ããŠææã§ããå Žåãç¹ç¶ææãããã«ãã€ãŠéž
æããããã奜ãŸããã¯åçã¯100ã160âã®æž©åºŠ
ã®æ°Žèžæ°ã«ããåã¯ä¹Ÿç¥ç©ºæ°ïŒç±åºçïŒã«ãã
150ã220âã§è¡ããããã®éç±åºçã¯ã»ã«ããŒã¹
ç¹ç¶ææã®å Žåã«é©çšããã®ã奜ãŸããã
ã¯ãç¹ç¶ææãéåžžã«é«ã枩床åã¯ä¹Ÿç±ç©ºæ°ã«å¯Ÿ
ããŠææã§ããå Žåãç¹ç¶ææãããã«ãã€ãŠéž
æããããã奜ãŸããã¯åçã¯100ã160âã®æž©åºŠ
ã®æ°Žèžæ°ã«ããåã¯ä¹Ÿç¥ç©ºæ°ïŒç±åºçïŒã«ãã
150ã220âã§è¡ããããã®éç±åºçã¯ã»ã«ããŒã¹
ç¹ç¶ææã®å Žåã«é©çšããã®ã奜ãŸããã
ç¹ç©é¡ãæºæããå Žåããæ¬çºæã«ããææã¯ã
å Žåã«ããæ £çšã®å©å€ãäŸãã°å°¿çŽ åã¯åæ£å€ã®
æ·»å äžã«æ°Žã«æº¶è§£ããç³å€äŸãã°ã¡ãã«ã»ã«ããŒ
ãºåã¯ã¢ã«ã®ããŒãç³å€ãšäžç·ã«æ¹æããããã®
ããã«ããŠåŸãããããŒã¹ããçšããŠè£œåãåžžæ³
ã«ããæºæããã次ã«åºçã¯äžèšã®å ¬ç¥ã®æ¹æ³ã§
ã¹ããŒãã³ã°åã¯ç±åºçã«ãã€ãŠè¡ãããã
å Žåã«ããæ £çšã®å©å€ãäŸãã°å°¿çŽ åã¯åæ£å€ã®
æ·»å äžã«æ°Žã«æº¶è§£ããç³å€äŸãã°ã¡ãã«ã»ã«ããŒ
ãºåã¯ã¢ã«ã®ããŒãç³å€ãšäžç·ã«æ¹æããããã®
ããã«ããŠåŸãããããŒã¹ããçšããŠè£œåãåžžæ³
ã«ããæºæããã次ã«åºçã¯äžèšã®å ¬ç¥ã®æ¹æ³ã§
ã¹ããŒãã³ã°åã¯ç±åºçã«ãã€ãŠè¡ãããã
æ¬çºæã«ããææã¯åèšã®ç¹ç¶ææäžã«éåžžã«
䟡å€ããæ¿åãªæè²åã³æºæãçããããã¯éåžž
ã«è¯å¥œãªæ¹¿æœ€å ç¢æ§åã³åè¶ããå å ç¢æ§ãæã
ãç¹ã§åªããŠããã
䟡å€ããæ¿åãªæè²åã³æºæãçããããã¯éåžž
ã«è¯å¥œãªæ¹¿æœ€å ç¢æ§åã³åè¶ããå å ç¢æ§ãæã
ãç¹ã§åªããŠããã
äžèšã®äŸã¯æ¬çºæã説æããããã®ãã®ã§ã
ããå¥ã«èšèŒããªãéãéšã¯éééšãããŒã»ãã®
èšèŒã¯ééïŒ ã§ãããéééšãšå®¹ééšã®é¢ä¿ã¯Kg
ãšã®é¢ä¿ã§ãããæ®åºCuPcïŒNiPcåã³CoPc
ã¯é眮æã®é âãããã±ã«âåã¯ã³ãã«ããã¿ã
ã·ã¢ãã³éªšæ Œãæå³ããã
ããå¥ã«èšèŒããªãéãéšã¯éééšãããŒã»ãã®
èšèŒã¯ééïŒ ã§ãããéééšãšå®¹ééšã®é¢ä¿ã¯Kg
ãšã®é¢ä¿ã§ãããæ®åºCuPcïŒNiPcåã³CoPc
ã¯é眮æã®é âãããã±ã«âåã¯ã³ãã«ããã¿ã
ã·ã¢ãã³éªšæ Œãæå³ããã
äŸ ïŒ
ã·ã¢ããã21éšåã³æ°Žé
žåãããªãŠã 20éšãæ°Ž
700éšäžã«å«ã溶液ã«ãè¯ãæ¹æããªããé ãã¿
ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ããªã97éšã湿
最éã±ãŒãã®åœ¢ã§å ãããåå¿ã¯åŒ±ãç±çºçã®
äžã«éå§ããåå¿æ··åç©ã®æž©åºŠã¯çŽ30âãŸã§äžæ
ããã2nâèæ§ãœãŒã溶液çŽ155容ééšãé£ç¶ç
ã«æ»Žå ããããšã«ãã€ãŠãåå¿æ··åç©ã®PHå€ã10
ã«ä¿ã€ãåå¿ã¯çŽïŒæéåŸã«çµäºããŠããããã
ã¯èæ§ãœãŒã溶液ãæ¶è²»ãããªããªãããšã§ç€ºã
ãããæŸæ溶液ãçæããŠãããå¡©é žã§æº¶æ¶²ãäž
æ§ã«ããæžå§ã§èžçºä¹Ÿåºãããå¡©å«æã®ãã«ã³ã
ã«ãŒã®ææç²æ«143éšãåŸãããããã¯ææãšã
ãŠæ¬¡åŒ CuPcâïŒSO2âNHâCNïŒ4 ã®ååç©ã®ãããªãŠã å¡©ã75ïŒ å«æããã
700éšäžã«å«ã溶液ã«ãè¯ãæ¹æããªããé ãã¿
ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ããªã97éšã湿
最éã±ãŒãã®åœ¢ã§å ãããåå¿ã¯åŒ±ãç±çºçã®
äžã«éå§ããåå¿æ··åç©ã®æž©åºŠã¯çŽ30âãŸã§äžæ
ããã2nâèæ§ãœãŒã溶液çŽ155容ééšãé£ç¶ç
ã«æ»Žå ããããšã«ãã€ãŠãåå¿æ··åç©ã®PHå€ã10
ã«ä¿ã€ãåå¿ã¯çŽïŒæéåŸã«çµäºããŠããããã
ã¯èæ§ãœãŒã溶液ãæ¶è²»ãããªããªãããšã§ç€ºã
ãããæŸæ溶液ãçæããŠãããå¡©é žã§æº¶æ¶²ãäž
æ§ã«ããæžå§ã§èžçºä¹Ÿåºãããå¡©å«æã®ãã«ã³ã
ã«ãŒã®ææç²æ«143éšãåŸãããããã¯ææãšã
ãŠæ¬¡åŒ CuPcâïŒSO2âNHâCNïŒ4 ã®ååç©ã®ãããªãŠã å¡©ã75ïŒ å«æããã
ãã®ãããªãŠã å¡©ã¯å¯èŠç¯å²ã§æ倧åžå
ïŒÎ»maxïŒ659nmïŒæ°Žæ§æº¶æ¶²äžã§æž¬å®ïŒãæããã
ïŒÎ»maxïŒ659nmïŒæ°Žæ§æº¶æ¶²äžã§æž¬å®ïŒãæããã
åŒCuPcâïŒSO2âNHâCNïŒ4ã®ååç©ã¯ãäž
ã§åŸããããããªãŠã å¡©ã®æ°Žæ§æº¶æ¶²ãå¡©é žã§é žæ§
åããæåºããææé žãåããçšæ°Žæ§å¡©é žã§ã
ãæŽæµããæžå§äžã«ä¹Ÿç¥ããããšã«ãã€ãŠãé žã®
圢ã§åŸãããããã®ããã«ããŠåŸãããææé žã
äžæ§åå¿ã瀺ããŸã§æ°Žæ§ã¢ã³ã¢ãã¢æº¶æ¶²ã®æ·»å äž
ã«ãæ°Žã«æº¶è§£ãããã®æº¶æ¶²ãæžå§äžã«èžçºä¹Ÿæ¶žã
ããããšã«ãã€ãŠãã¢ã³ã¢ããŠã å¡©ã補é ããã
ãšãåºæ¥ãã
ã§åŸããããããªãŠã å¡©ã®æ°Žæ§æº¶æ¶²ãå¡©é žã§é žæ§
åããæåºããææé žãåããçšæ°Žæ§å¡©é žã§ã
ãæŽæµããæžå§äžã«ä¹Ÿç¥ããããšã«ãã€ãŠãé žã®
圢ã§åŸãããããã®ããã«ããŠåŸãããææé žã
äžæ§åå¿ã瀺ããŸã§æ°Žæ§ã¢ã³ã¢ãã¢æº¶æ¶²ã®æ·»å äž
ã«ãæ°Žã«æº¶è§£ãããã®æº¶æ¶²ãæžå§äžã«èžçºä¹Ÿæ¶žã
ããããšã«ãã€ãŠãã¢ã³ã¢ããŠã å¡©ã補é ããã
ãšãåºæ¥ãã
䜿çšäŸ
åŒCuPcâïŒSO2âNHâCNïŒ4ã®ååç©ã®ã¢ã³
ã¢ããŠã å¡©30éšãæ°Ž1000éšã«æº¶è§£ãããæè²æµŽã
å®å šã«ããããã«ãæŽã«æšç¶¿æè²æ¥çšã«åžè²©ãã
ãŠãã湿最å€ãæ·»å ããããã®æè²æµŽäžã§æšç¶¿ç¹
ç©ã济æ¯ïŒïŒ20ã«ãŠ95âã§ïŒæéåŠçããã
ã¢ããŠã å¡©30éšãæ°Ž1000éšã«æº¶è§£ãããæè²æµŽã
å®å šã«ããããã«ãæŽã«æšç¶¿æè²æ¥çšã«åžè²©ãã
ãŠãã湿最å€ãæ·»å ããããã®æè²æµŽäžã§æšç¶¿ç¹
ç©ã济æ¯ïŒïŒ20ã«ãŠ95âã§ïŒæéåŠçããã
ãã®ç¹ç©ã济ããåãåºããå§æŸè±æ°Žãã也ç¥
ãã210âã§ïŒåç±åºçãããç¶ããŠå·æ°Žåã³ç±
æ°Žã§ããããæåŸã«æ²žéš°çšç³ãã溶液ã§ãããã
è¯å¥œãªæŽæ¿¯å ç¢æ§åã³éåžžã«è¯å¥œãªå å ç¢æ§ãæ
ãããã«ã³ãã«ãŒã®æè²ãåŸãããã
ãã210âã§ïŒåç±åºçãããç¶ããŠå·æ°Žåã³ç±
æ°Žã§ããããæåŸã«æ²žéš°çšç³ãã溶液ã§ãããã
è¯å¥œãªæŽæ¿¯å ç¢æ§åã³éåžžã«è¯å¥œãªå å ç¢æ§ãæ
ãããã«ã³ãã«ãŒã®æè²ãåŸãããã
äŸ 1a
æ¬çºæã«ããææã補é ããããã«äŸïŒã«èšèŒ
ã®åŠãè¡ããäœãé ãã¿ãã·ã¢ãã³â(3)âããã©
ã¹ã«ãã¯ããªãã®ä»£ãã«ãä»ã®éå±äžå«ã®åã¯é
å±å«æã®ãã¿ãã·ã¢ãã³ã¹ã«ãã¯ããªããäŸãã°
é ãã¿ãã·ã¢ãã³â(4)âããã©ã¹ã«ãã¯ããªãã
ããã±ã«ãã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ã
ãªããã³ãã«ããã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«
ãã¯ããªããé ãã¿ãã·ã¢ãã³â(3)âããªã¹ã«ã
ã¯ããªããé ãã¿ãã·ã¢ãã³â(3)âãžã¹ã«ãã¯ã
ãªãåã¯ãã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ã
ãªãã䜿çšãããåæ§ã«ææãåŸãããããã¯äŸ
ïŒã®æäœæ³ã«åŸã€ãŠã»ã«ããŒãºç¹ç¶äžã«ä»äžã
ããç±åºçãããè¯å¥œãªå ç¢æ§ãæãããã«ã³ã
ã«ãŒã®æè²ãäžããã
ã®åŠãè¡ããäœãé ãã¿ãã·ã¢ãã³â(3)âããã©
ã¹ã«ãã¯ããªãã®ä»£ãã«ãä»ã®éå±äžå«ã®åã¯é
å±å«æã®ãã¿ãã·ã¢ãã³ã¹ã«ãã¯ããªããäŸãã°
é ãã¿ãã·ã¢ãã³â(4)âããã©ã¹ã«ãã¯ããªãã
ããã±ã«ãã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ã
ãªããã³ãã«ããã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«
ãã¯ããªããé ãã¿ãã·ã¢ãã³â(3)âããªã¹ã«ã
ã¯ããªããé ãã¿ãã·ã¢ãã³â(3)âãžã¹ã«ãã¯ã
ãªãåã¯ãã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ã
ãªãã䜿çšãããåæ§ã«ææãåŸãããããã¯äŸ
ïŒã®æäœæ³ã«åŸã€ãŠã»ã«ããŒãºç¹ç¶äžã«ä»äžã
ããç±åºçãããè¯å¥œãªå ç¢æ§ãæãããã«ã³ã
ã«ãŒã®æè²ãäžããã
äŸ ïŒ
ã·ã¢ããã8.4éšåã³æ°Žé
žåãããªãŠã 8.0éšã
æ°Ž300éšäžã«å«ã溶液äžã«ãããæ¹æããªããé
ãã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ããªã97éš
ã湿最éã±ãŒãã®åœ¢ã§å ãããåå¿ãè¡ããã
ããšã«ãã€ãŠåå¿æ··åç©ã®PHå€ã¯éäžããã2n
âèæ§ãœãŒã溶液ãç¶ããŠæ·»å ããããšã«ãã€ãŠ
PHå€ã10ã«ä¿ã¡ãæ°Žé žåã¢ã«ã«ãªããã¯ãæ¶è²»ã
ããªããªããŸã§åå¿æ··åç©ãæ¹æããããã®ãã
ã«2nâèæ§ãœãŒãçŽ310容ééšãå¿ èŠã§ãããæ¿
éè²æº¶æ¶²ãçæããŠããã圢æãããææãåé¢
ããããã«æ¿å¡©é ž70éšã§é žæ§åããå¡©åã¢ã³ã¢ã
ãŠã 200éšã§å¡©æãããæ²æŸ±ãåãããããçš
å¡©é žã§ããæŽããæžå§äžã§ä¹Ÿç¥ãããææå«é98
ïŒ ã®ææç²æ«96éšãåŸããããåŸãããææåå
ç©ã¯éé¢é žã®åœ¢ã§æžããšãäžèšã®æ§é ãæã
ããïŒ åŸãããååç©ãã25ïŒ æ°Žæ§ã¢ã³ã¢ãã¢æº¶æ¶²27
éšã®æ·»å äžã«æ°Ž1200éšäžã«æº¶è§£ããåŸãããææ
溶液ãæžå§äžã§èžçºä¹Ÿåºããããã次åŒã«çžåœã
ãäžèšãã¿ãã·ã¢ãã³ååç©ã®ã¢ã³ã¢ããŠã å¡©
102éšãåŸãããïŒ ãã®ã¢ã³ã¢ããŠã å¡©ã¯å¯èŠç¯å²ã§æ倧åžå
ïŒÎ»maxïŒ661nmïŒæ°Žæ§æº¶æ¶²äžã§æž¬å®ïŒãæããã
æ°Ž300éšäžã«å«ã溶液äžã«ãããæ¹æããªããé
ãã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ããªã97éš
ã湿最éã±ãŒãã®åœ¢ã§å ãããåå¿ãè¡ããã
ããšã«ãã€ãŠåå¿æ··åç©ã®PHå€ã¯éäžããã2n
âèæ§ãœãŒã溶液ãç¶ããŠæ·»å ããããšã«ãã€ãŠ
PHå€ã10ã«ä¿ã¡ãæ°Žé žåã¢ã«ã«ãªããã¯ãæ¶è²»ã
ããªããªããŸã§åå¿æ··åç©ãæ¹æããããã®ãã
ã«2nâèæ§ãœãŒãçŽ310容ééšãå¿ èŠã§ãããæ¿
éè²æº¶æ¶²ãçæããŠããã圢æãããææãåé¢
ããããã«æ¿å¡©é ž70éšã§é žæ§åããå¡©åã¢ã³ã¢ã
ãŠã 200éšã§å¡©æãããæ²æŸ±ãåãããããçš
å¡©é žã§ããæŽããæžå§äžã§ä¹Ÿç¥ãããææå«é98
ïŒ ã®ææç²æ«96éšãåŸããããåŸãããææåå
ç©ã¯éé¢é žã®åœ¢ã§æžããšãäžèšã®æ§é ãæã
ããïŒ åŸãããååç©ãã25ïŒ æ°Žæ§ã¢ã³ã¢ãã¢æº¶æ¶²27
éšã®æ·»å äžã«æ°Ž1200éšäžã«æº¶è§£ããåŸãããææ
溶液ãæžå§äžã§èžçºä¹Ÿåºããããã次åŒã«çžåœã
ãäžèšãã¿ãã·ã¢ãã³ååç©ã®ã¢ã³ã¢ããŠã å¡©
102éšãåŸãããïŒ ãã®ã¢ã³ã¢ããŠã å¡©ã¯å¯èŠç¯å²ã§æ倧åžå
ïŒÎ»maxïŒ661nmïŒæ°Žæ§æº¶æ¶²äžã§æž¬å®ïŒãæããã
䜿çšäŸ
ãã®ã¢ã³ã¢ããŠã å¡©15éšãå°¿çŽ 20éšãšå
±ã«ç±æ°Ž
200éšäžã«æº¶è§£ããã匷ããã«ã³ãã«ãŒã«çè²ã
ã溶液ã«ãïŒïŒ æ°Žæ§ã¢ã«ã®ã³é žãããªãŠã ç³å€
400éšãæ¹æäžã«æ·»å ããããã®ããã«ããŠåŸã
ããããŒã¹ãã«æ°Žåã³ç³å€ãå ããŠ1000éšãšãª
ãã
200éšäžã«æº¶è§£ããã匷ããã«ã³ãã«ãŒã«çè²ã
ã溶液ã«ãïŒïŒ æ°Žæ§ã¢ã«ã®ã³é žãããªãŠã ç³å€
400éšãæ¹æäžã«æ·»å ããããã®ããã«ããŠåŸã
ããããŒã¹ãã«æ°Žåã³ç³å€ãå ããŠ1000éšãšãª
ãã
ãã®ããã«ããŠè£œé ãããæºæããŒã¹ããçšã
ãŠæšç¶¿ç¹ç©ãæºæãã也ç¥ãã次ã«ïŒå210âã§
ç±åºçããç¶ããŠå·æ°Žåã³ç±æ°Žã§ããããç ®æ²žãœ
ãŒãã³ã°ããåã³æ°Žã§æŽæµãã也ç¥ãããæ¿ãã
ã«ã³ãã«ãŒã®æºææš¡æ§ãåŸãããããã¯è¯å¥œãªå
å ç¢æ§ãæããæŽæ¿¯åŠçã«å¯Ÿãéåžžã«è¯å¥œãªå®å®
æ§ã瀺ãã
ãŠæšç¶¿ç¹ç©ãæºæãã也ç¥ãã次ã«ïŒå210âã§
ç±åºçããç¶ããŠå·æ°Žåã³ç±æ°Žã§ããããç ®æ²žãœ
ãŒãã³ã°ããåã³æ°Žã§æŽæµãã也ç¥ãããæ¿ãã
ã«ã³ãã«ãŒã®æºææš¡æ§ãåŸãããããã¯è¯å¥œãªå
å ç¢æ§ãæããæŽæ¿¯åŠçã«å¯Ÿãéåžžã«è¯å¥œãªå®å®
æ§ã瀺ãã
äŸ ïŒ
ã·ã¢ããã8.4éšåã³æ°Žé
žåãããªãŠã 8.0éšã
æ°Ž500éšäžã«å«ã溶液ã«ãé ãã¿ãã·ã¢ãã³â(3)
âããã©ã¹ã«ãã¯ããªã97éšã湿最éã±ãŒãã®
圢ã§ããæ¹æããªããå ãããåå¿ã®çµéäžåå¿
æ··åç©ã®PHå€ã¯éäžããã®ã§ã2nèæ§ãœãŒã溶
液ã®æ»Žå ã«ãã€ãŠPHå€ã10ã«ä¿ã€ãèæ§ãœãŒã溶
液100容ééšãæ¶è²»ãããããèæ§ãœãŒãæ·»å ã
æ¢ããæŽã«æ°Žæ§2nã¢ã³ã¢ãã¢æº¶æ¶²ã®æ»Žå ã«ãã€
ãŠPHå€ã10ã«ä¿ã€ãåå¿çµäºåŸã圢æãããææ
ãå¡©é žã§é žæ§ã«ããããšã«ãã€ãŠæåºããããã
ãåããçšå¡©é žã§ããæŽããæžå§äžã§ä¹Ÿç¥ã
ããæéè²ã®ææç²æ«90éšãåŸãããããã¯100
ééïŒ ã次åŒïŒéé¢é žã®åœ¢ã§èšèŒïŒã®ååç©ã§ã
ãïŒ ãã®ææã¯äŸïŒã«èšèŒåŠãã¢ã³ã¢ããŠã å¡©ã«å°
ãããããã®ã¢ã³ã¢ããŠã å¡©ã¯æ°Žæ§æº¶æ¶²äžã§æž¬å®
ããŠãå¯èŠç¯å²ã§æ倧åžåïŒÎ»maxïŒ610nmãæ
ããããã®ææãçšããäŸïŒã®æäœæ³ã«ãããè¯
奜ãªå å ç¢æ§åã³è¯å¥œãªæŽæ¿¯å®å®æ§ãæããåã
ããã«ã³ãã«ãŒã®æšç¶¿æºæãåŸãããã
æ°Ž500éšäžã«å«ã溶液ã«ãé ãã¿ãã·ã¢ãã³â(3)
âããã©ã¹ã«ãã¯ããªã97éšã湿最éã±ãŒãã®
圢ã§ããæ¹æããªããå ãããåå¿ã®çµéäžåå¿
æ··åç©ã®PHå€ã¯éäžããã®ã§ã2nèæ§ãœãŒã溶
液ã®æ»Žå ã«ãã€ãŠPHå€ã10ã«ä¿ã€ãèæ§ãœãŒã溶
液100容ééšãæ¶è²»ãããããèæ§ãœãŒãæ·»å ã
æ¢ããæŽã«æ°Žæ§2nã¢ã³ã¢ãã¢æº¶æ¶²ã®æ»Žå ã«ãã€
ãŠPHå€ã10ã«ä¿ã€ãåå¿çµäºåŸã圢æãããææ
ãå¡©é žã§é žæ§ã«ããããšã«ãã€ãŠæåºããããã
ãåããçšå¡©é žã§ããæŽããæžå§äžã§ä¹Ÿç¥ã
ããæéè²ã®ææç²æ«90éšãåŸãããããã¯100
ééïŒ ã次åŒïŒéé¢é žã®åœ¢ã§èšèŒïŒã®ååç©ã§ã
ãïŒ ãã®ææã¯äŸïŒã«èšèŒåŠãã¢ã³ã¢ããŠã å¡©ã«å°
ãããããã®ã¢ã³ã¢ããŠã å¡©ã¯æ°Žæ§æº¶æ¶²äžã§æž¬å®
ããŠãå¯èŠç¯å²ã§æ倧åžåïŒÎ»maxïŒ610nmãæ
ããããã®ææãçšããäŸïŒã®æäœæ³ã«ãããè¯
奜ãªå å ç¢æ§åã³è¯å¥œãªæŽæ¿¯å®å®æ§ãæããåã
ããã«ã³ãã«ãŒã®æšç¶¿æºæãåŸãããã
äŸ 3a
äŸïŒã®æäœæ³ã«åŸã€ãŠæ¬çºæã«ããææã補é
ããããã«ãæ°Žæ§ã¢ã³ã¢ãã¢ã®ä»£ãã«ãåœéã®ä»
ã®ç¬¬äžçŽåã¯ç¬¬äºçŽèèªæåã¯è³éŠææã¢ãã³ã
äŸãã°ã¡ãã«ã¢ãã³ããšãã«ã¢ãã³ãïœâããã«
ã¢ãã³ããã³ãžã«ã¢ãã³ãã¢ããªã³ããšã¿ããŒã«
ã¢ãã³ããžã¡ãã«ã¢ãã³ããžãšãã«ã¢ãã³ããžâ
ã€ãœãããã«ã¢ãã³ãâã¡ãã«ãã³ãžã«ã¢ã
ã³ãâã¡ãã«ã¢ããªã³ããããªãžã³ãã¢ã«ããª
ã³ãïŒâã¢ãããšã¿ã³âïŒâã«ã«ãã³é žãïŒâã¢
ãããšã¿ã³âïŒâã¹ã«ãã³é žãïŒâã¢ããå®æ¯éŠ
é žãïŒâã¢ããâãã³ãŸãŒã«ã¹ã«ãã³é žåã¯ïŒâ
ã¢ããâãã³ãŸãŒã«ã¹ã«ãã³é žãå«ãæ°Žæ§æº¶æ¶²ã
çšããŠæäœããçšããããã¢ãã³ã®å¡©åºæ§ããã
ã«ããçž®ååå¿ãPHå€ïŒã8.5ã§è¡ããããããŠ
äžè¬åŒ(1)ã«çžåœããææãåŸããããããçšããŠ
ã»ã«ããŒãºç¹ç¶ææäžã«è¯å¥œãªæŽæ¿¯âåã³å å ç¢
æ§ãæãã垯ç·éè²ããã«ã³ãã«ãŒã®æè²ã補é
ããããšãåºæ¥ãã
ããããã«ãæ°Žæ§ã¢ã³ã¢ãã¢ã®ä»£ãã«ãåœéã®ä»
ã®ç¬¬äžçŽåã¯ç¬¬äºçŽèèªæåã¯è³éŠææã¢ãã³ã
äŸãã°ã¡ãã«ã¢ãã³ããšãã«ã¢ãã³ãïœâããã«
ã¢ãã³ããã³ãžã«ã¢ãã³ãã¢ããªã³ããšã¿ããŒã«
ã¢ãã³ããžã¡ãã«ã¢ãã³ããžãšãã«ã¢ãã³ããžâ
ã€ãœãããã«ã¢ãã³ãâã¡ãã«ãã³ãžã«ã¢ã
ã³ãâã¡ãã«ã¢ããªã³ããããªãžã³ãã¢ã«ããª
ã³ãïŒâã¢ãããšã¿ã³âïŒâã«ã«ãã³é žãïŒâã¢
ãããšã¿ã³âïŒâã¹ã«ãã³é žãïŒâã¢ããå®æ¯éŠ
é žãïŒâã¢ããâãã³ãŸãŒã«ã¹ã«ãã³é žåã¯ïŒâ
ã¢ããâãã³ãŸãŒã«ã¹ã«ãã³é žãå«ãæ°Žæ§æº¶æ¶²ã
çšããŠæäœããçšããããã¢ãã³ã®å¡©åºæ§ããã
ã«ããçž®ååå¿ãPHå€ïŒã8.5ã§è¡ããããããŠ
äžè¬åŒ(1)ã«çžåœããææãåŸããããããçšããŠ
ã»ã«ããŒãºç¹ç¶ææäžã«è¯å¥œãªæŽæ¿¯âåã³å å ç¢
æ§ãæãã垯ç·éè²ããã«ã³ãã«ãŒã®æè²ã補é
ããããšãåºæ¥ãã
äŸ ïŒ
æ¬çºæã«ããææã補é ãããããäŸïŒã®æ¹æ³
ã«åŸã€ãŠæäœãããäœãçž®ååå¿ã®éèæ§ãœãŒã
溶液ã®ä»£ãã«é žçµåå€ãšããŠãåå¿éå§æããæ°Ž
æ§ã¢ã³ã¢ãã¢æº¶æ¶²ã滎å ãããã®éãPHå€ã10ã«
ä¿ã€ãéé¢é žã®åœ¢ã§èšèŒãããšæ¬¡åŒ ïŒïœã¯ïŒããå°ãããïœã¯ïŒãã倧ãããïœïŒ
ïœã¯ïŒã§ãããïŒ ãæããææãåŸãããããã¯äŸïŒã®ææããã
ãåé£æº¶æ§ã§ããããããäŸïŒã«åŸã€ãŠæšç¶¿ç¹ç¶
ææäžã«ä»äžããåºçãããšãéåžžã«è¯å¥œãªå ç¢
æ§ãæãããã«ã³ãã«ãŒã®æè²ãåŸãããã
ã«åŸã€ãŠæäœãããäœãçž®ååå¿ã®éèæ§ãœãŒã
溶液ã®ä»£ãã«é žçµåå€ãšããŠãåå¿éå§æããæ°Ž
æ§ã¢ã³ã¢ãã¢æº¶æ¶²ã滎å ãããã®éãPHå€ã10ã«
ä¿ã€ãéé¢é žã®åœ¢ã§èšèŒãããšæ¬¡åŒ ïŒïœã¯ïŒããå°ãããïœã¯ïŒãã倧ãããïœïŒ
ïœã¯ïŒã§ãããïŒ ãæããææãåŸãããããã¯äŸïŒã®ææããã
ãåé£æº¶æ§ã§ããããããäŸïŒã«åŸã€ãŠæšç¶¿ç¹ç¶
ææäžã«ä»äžããåºçãããšãéåžžã«è¯å¥œãªå ç¢
æ§ãæãããã«ã³ãã«ãŒã®æè²ãåŸãããã
äŸ ïŒ
ã·ã¢ããã42éšåã³æ°Žé
žåãããªãŠã 80éšãæ°Ž
1000éšäžã«å«ã溶液ã«å®€æž©ã§åŒ·ãæ¹æããªããé
ãã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ããªã97éš
ãå ããã枩床ã¯çæéã«çŽ30âã«äžæãããæ·±
éè²æº¶æ¶²ãçæãããåå¿çµäºåŸçæããææã
å¡©é žåã¯æ°Žæ§ç¡«é žã®æ·»å ã«ãã€ãŠæåºããããã
ãåããçšå¡©é žã§ããæŽããæžå§äžã§ä¹Ÿç¥ã
ãã
1000éšäžã«å«ã溶液ã«å®€æž©ã§åŒ·ãæ¹æããªããé
ãã¿ãã·ã¢ãã³â(3)âããã©ã¹ã«ãã¯ããªã97éš
ãå ããã枩床ã¯çæéã«çŽ30âã«äžæãããæ·±
éè²æº¶æ¶²ãçæãããåå¿çµäºåŸçæããææã
å¡©é žåã¯æ°Žæ§ç¡«é žã®æ·»å ã«ãã€ãŠæåºããããã
ãåããçšå¡©é žã§ããæŽããæžå§äžã§ä¹Ÿç¥ã
ãã
åŒCuPcïŒSO2âNHâCNïŒ4ã®ååç©92éšãåŸã
ãããããã®æè²ç¹æ§ã¯åŒïŒã®ææã«çžåœããã
ãããããã®æè²ç¹æ§ã¯åŒïŒã®ææã«çžåœããã
äŸ ïŒ
ã·ã¢ããã25.8éšãâã¡ãã«âãããªãã³
250容ééšäžã«å«ã溶液ã«ãéçé žãããªãŠã 50
éšãå ããå šäœãïŒâã«å·åŽãããã®åŸããæ¹æ
ããªããçŽïŒæéãèŠããŠé ãã¿ãã·ã¢ãã³â(3)
âããã©ã¹ã«ãã¯ããªã97éšã湿最æŒéã±ãŒã
ã®åœ¢ã§å ããããã®é枩床ã¯10âãè¶ããªãã10
âã§æ°æéãç¶ããŠå®€æž©ã§12æéæ¹æãããçæ
ããææå¡©ãïœâãã¿ããŒã«ã®æ·»å ã«ãã€ãŠå®å š
ã«æåºãããåãããã¿ããŒã«åã³ãšã¿ããŒã«
ã§æŽæµãããåŸãããååç©ãé žã®åœ¢ã«å°ããä»
çããå¡©ãé€å»ããããã«ãææçæç©ãçšå¡©é ž
ãšå ±ã«æ¹æããåããçšå¡©é žã§ããæŽããæžå§
äžã§ä¹Ÿç¥ãããåŒCuPcïŒSO2âNHâCNïŒ4ã®åå
ç©ã®åéã¯94éšã§ããããã®ææã®æ§è³ªã¯ç¹ã«ã¢
ã«ã«ãªéå±å¡©ã®åœ¢ã§ã奜ãŸããã¯ã¢ã³ã¢ããŠã å¡©
ã®åœ¢ã§ãåŒïŒã«ãã補é ããææã«çžåœããã
250容ééšäžã«å«ã溶液ã«ãéçé žãããªãŠã 50
éšãå ããå šäœãïŒâã«å·åŽãããã®åŸããæ¹æ
ããªããçŽïŒæéãèŠããŠé ãã¿ãã·ã¢ãã³â(3)
âããã©ã¹ã«ãã¯ããªã97éšã湿最æŒéã±ãŒã
ã®åœ¢ã§å ããããã®é枩床ã¯10âãè¶ããªãã10
âã§æ°æéãç¶ããŠå®€æž©ã§12æéæ¹æãããçæ
ããææå¡©ãïœâãã¿ããŒã«ã®æ·»å ã«ãã€ãŠå®å š
ã«æåºãããåãããã¿ããŒã«åã³ãšã¿ããŒã«
ã§æŽæµãããåŸãããååç©ãé žã®åœ¢ã«å°ããä»
çããå¡©ãé€å»ããããã«ãææçæç©ãçšå¡©é ž
ãšå ±ã«æ¹æããåããçšå¡©é žã§ããæŽããæžå§
äžã§ä¹Ÿç¥ãããåŒCuPcïŒSO2âNHâCNïŒ4ã®åå
ç©ã®åéã¯94éšã§ããããã®ææã®æ§è³ªã¯ç¹ã«ã¢
ã«ã«ãªéå±å¡©ã®åœ¢ã§ã奜ãŸããã¯ã¢ã³ã¢ããŠã å¡©
ã®åœ¢ã§ãåŒïŒã«ãã補é ããææã«çžåœããã
äŸ ïŒ
ã«ã«ã·ãŠã ã·ã¢ãããïŒã·ã¢ãããã«é¢ã33
ïŒ ãååé42ïŒ63.5éšãæ°Ž450éšã§çšéãããåŸ
ãããæžæ¿æ¶²äžã«é ãã¿ãã·ã¢ãã³â(3)âããã©
ã¹ã«ãã¯ããªã97éšã湿最éã±ãŒãã®åœ¢ã§å ã
ããåå¿ã¯åŒ±ãç±çºçã®äžã«éå§ããåå¿æ··åç©
ã®æž©åºŠã¯å·åŽã«ãã€ãŠ30以äžã«ä¿ã€ãçŽïŒæéåŸ
åå¿ã¯çµäºããŠãããå°éã®äžæº¶æ§å¯çæç©ãå«
æããæ·±éè²æº¶æ¶²ãçæããŠãããçé žã¢ã³ã¢ã
ãŠã 90éšãæ°Ž400éšäžã«å«ã溶液ãæ·»å ããçæ
éæ¹æåŸãæåºããçé žã«ã«ã·ãŠã ãå»ãã
液ãæžå§äžã§èžçºä¹Ÿæ¶žãããã
ïŒ ãååé42ïŒ63.5éšãæ°Ž450éšã§çšéãããåŸ
ãããæžæ¿æ¶²äžã«é ãã¿ãã·ã¢ãã³â(3)âããã©
ã¹ã«ãã¯ããªã97éšã湿最éã±ãŒãã®åœ¢ã§å ã
ããåå¿ã¯åŒ±ãç±çºçã®äžã«éå§ããåå¿æ··åç©
ã®æž©åºŠã¯å·åŽã«ãã€ãŠ30以äžã«ä¿ã€ãçŽïŒæéåŸ
åå¿ã¯çµäºããŠãããå°éã®äžæº¶æ§å¯çæç©ãå«
æããæ·±éè²æº¶æ¶²ãçæããŠãããçé žã¢ã³ã¢ã
ãŠã 90éšãæ°Ž400éšäžã«å«ã溶液ãæ·»å ããçæ
éæ¹æåŸãæåºããçé žã«ã«ã·ãŠã ãå»ãã
液ãæžå§äžã§èžçºä¹Ÿæ¶žãããã
åŒCuPcâïŒSO2âNHâCNïŒ4ã®ååç©ã®ã¢ã³
ã¢ããŠã å¡©83ïŒ ãå«æããå¡©å«æã®éè²ææç²æ«
128éšãåŸãããã
ã¢ããŠã å¡©83ïŒ ãå«æããå¡©å«æã®éè²ææç²æ«
128éšãåŸãããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžè¬åŒ(1) ãåŒäžã Pcã¯é âãããã±ã«âåã¯ã³ãã«ãâãã¿ã
ã·ã¢ãã³æ®åºã§ããããã®éãã®åŒ(1)ã«ç€ºããã
ã¹ã«ããã«ã·ã¢ãããâãã¹ã«ãã³ã¢ããâåã³
ïŒåã¯ïŒã¹ã«ãã³é žåºã¯ãã¿ãã·ã¢ãã³ã®ççŽ ç°
ç¶è³éŠæç°ã®ïŒâåã³ïŒåã¯ïŒïŒâäœã«çµåããŠ
ããã ã¯æ°ŽçŽ ååãã¢ã«ã«ãªéå±åã¯ã¢ã³ã¢ããŠã
åºã§ããã R1åã³R2ã¯åæ¹ãšãæ°ŽçŽ ååã瀺ãã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ãã®å ŽåïœïŒïœåã³ïœã¯çžäºã«åäžåã¯ç°ãªã€
ãŠããããäœãïŒïœïŒïœïŒïœïŒã®åèšã¯ïŒãïŒã§
ãããã ã§è¡šããããã¿ãã·ã¢ãã³ååç©ã ïŒ ïŒžã¯ãããªãŠã ãã«ãªãŠã åã¯ã¢ã³ã¢ããŠã
ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ãã¿ãã·ã¢ã
ã³ååç©ã ïŒ äžè¬åŒ(1) ãåŒäžã Pcã¯é âãããã±ã«âåã¯ã³ãã«ãâãã¿ã
ã·ã¢ãã³æ®åºã§ããããã®éãã®åŒ(1)ã«ç€ºããã
ã¹ã«ããã«ã·ã¢ãããâãã¹ã«ãã³ã¢ããâåã³
ïŒåã¯ïŒã¹ã«ãã³é žåºã¯ãã¿ãã·ã¢ãã³ã®ççŽ ç°
ç¶è³éŠæç°ã®ïŒâåã³ïŒåã¯ïŒïŒâäœã«çµåããŠ
ããã ã¯æ°ŽçŽ ååãã¢ã«ã«ãªéå±åã¯ã¢ã³ã¢ããŠã
åºã§ããã R1åã³R2ã¯åæ¹ãšãæ°ŽçŽ ååã瀺ãã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ãã®å ŽåïœïŒïœåã³ïœã¯çžäºã«åäžåã¯ç°ãªã€
ãŠããããäœãïŒïœïŒïœïŒïœïŒã®åèšã¯ïŒãïŒã§
ãããã ã§è¡šããããã¿ãã·ã¢ãã³ååç©ã補é ããã«ã
ãããäžèšäžè¬åŒ(2) ãåŒäžPcã¯äžèšã®æå³ãæããïœã¯ïŒãïŒã®
æ°ãïœã¯ïŒãïŒã®æŽæ°ã§ããããã®éïŒïœïŒïœïŒ
ã®åã¯ïŒãïŒã§ãããã ã®ãã¿ãã·ã¢ãã³ã¹ã«ãã³é žã¯ããªããã·ã¢ãã
ãåã¯ãã®å¡©ãšãããã¯ã·ã¢ãããåã¯ãã®å¡©å
ã³ã¢ã³ã¢ãã¢ãšåæã«åã¯ä»»æã®é åºã§æ°Žæ§åªäœ
äžåã¯ææ©æº¶å€äžåã¯ãããã®æ··åç©äžã§ãïŒã
14ã®PHå€åã³â10âã110âã®æž©åºŠã§é žçµåå€ã®
ååšäžã«åå¿ããããã®éå Žåã«ããåæã«åã¯
åŸããã¹ã«ãã³é žã¯ããªãåºãéšåçã«å æ°Žå解
ããŠã¹ã«ãåºãšãªãããšãç¹åŸŽãšãããäžèšäžè¬
åŒ(1)ãªããã¿ãã·ã¢ãã³ååç©ã®è£œé æ³ã ïŒ äžè¬åŒ(1) ãåŒäžã Pcã¯é âãããã±ã«âåã¯ã³ãã«ãâãã¿ã
ã·ã¢ãã³æ®åºã§ããããã®éãã®åŒ(1)ã«ç€ºããã
ã¹ã«ããã«ã·ã¢ãããâãã¹ã«ãã³ã¢ããâåã³
ïŒåã¯ïŒã¹ã«ãã³é žåºã¯ãã¿ãã·ã¢ãã³ã®ççŽ ç°
ç¶è³éŠæç°ã®ïŒâåã³ïŒåã¯ïŒïŒâäœã«çµåããŠ
ããã ã¯æ°ŽçŽ ååãã¢ã«ã«ãªéå±åã¯ã¢ã³ã¢ããŠã
åºã§ããã R1åã³R2ã¯åæ¹ãšãæ°ŽçŽ ååã瀺ãã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°åã¯åæ°ã§ããã ãã®å ŽåïœïŒïœåã³ïœã¯çžäºã«åäžåã¯ç°ãªã€
ãŠããããäœãïŒïœïŒïœïŒïœïŒã®åèšã¯ïŒãïŒã§
ãããã ã§è¡šããããã¿ãã·ã¢ãã³ååç©ãææãšããŠäœ¿
çšããæ¹æ³ã ïŒ çŸæ¯ãçµ¹ãç·ç¶ããªã¢ãããç®é©åã¯ããã
ãã·ã«åºå«æææããæãç¹ç¶ææã®æè²åã¯æº
æã«äœ¿çšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19792934248 DE2934248A1 (de) | 1979-08-24 | 1979-08-24 | Wasserloesliche phthalocyaninverbindungen, verfahren zu ihrer herstellung und ihre verwendung als farbstoffe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5632546A JPS5632546A (en) | 1981-04-02 |
| JPS6324545B2 true JPS6324545B2 (ja) | 1988-05-20 |
Family
ID=6079197
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11488380A Granted JPS5632546A (en) | 1979-08-24 | 1980-08-22 | Water soluble phthalocianine compound and production and use as dyestuff |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4397649A (ja) |
| EP (1) | EP0024677B1 (ja) |
| JP (1) | JPS5632546A (ja) |
| DE (2) | DE2934248A1 (ja) |
| IN (1) | IN154643B (ja) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3025790A1 (de) * | 1980-07-08 | 1982-02-04 | Hoechst Ag, 6000 Frankfurt | Wasserloesliche phthalocyaninverbindungen, verfahren zu ihrer herstellung und ihre verwendung als farbstoffe |
| US4497741A (en) * | 1981-12-09 | 1985-02-05 | Ciba-Geigy Corporation | Water-soluble zinc and aluminium phthalocyanines |
| JPS59179569A (ja) * | 1983-03-29 | 1984-10-12 | Canon Inc | èšé²æ¶² |
| DE3461940D1 (en) * | 1983-04-02 | 1987-02-12 | Hoechst Ag | Process for reoxidizing dyeings with sulphur dyes |
| DE19634354A1 (de) * | 1996-08-26 | 1998-03-05 | Clariant Gmbh | Wasserlösliche Kupferphtalocyanin-Farbstoffe, ihre Herstellung und Verwendung |
| DE19711445A1 (de) * | 1997-03-19 | 1998-09-24 | Basf Ag | Farbstoffsalze und ihre Anwendung beim FÀrben von polymerem Material |
| WO2002085988A1 (en) * | 2001-04-19 | 2002-10-31 | Ciba Specialty Chemicals Holding, Inc. | Water-soluble salt of sulfonamides as colorants for the pigmenting of porous materials and for use in inkjet printing |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2259721A (en) * | 1940-11-19 | 1941-10-21 | American Cyanamid Co | Sulphonyl cyanamides |
| US2463793A (en) * | 1944-11-24 | 1949-03-08 | Rhone Poulenc Sa | Production of n4-acetyl sulfguanidines |
| US2459771A (en) * | 1945-07-11 | 1949-01-18 | Gen Aniline & Film Corp | Phthalocyanine sulfonamidopyridines |
| US3461143A (en) * | 1968-06-27 | 1969-08-12 | American Cyanamid Co | Production of sulfaguanidine |
| GB1265842A (ja) * | 1969-05-20 | 1972-03-08 | ||
| DE1928677C3 (de) * | 1969-06-06 | 1978-11-09 | Bayer Ag, 5090 Leverkusen | Phthalocyaninfarbstoffe und deren Verwendung zum FÀrben und Bedrucken cellulosehaltiger Materialien |
| DE2030572A1 (de) * | 1970-04-30 | 1972-02-10 | Farbenfabriken Bayer Ag, 5090 Leverkusen | Disulfonylimide. Ausscheidung aus: 2021257 |
| JPS5331923B2 (ja) * | 1972-07-26 | 1978-09-05 | ||
| DE2636427C3 (de) * | 1976-08-13 | 1980-07-31 | Basf Ag, 6700 Ludwigshafen | Farbstoffzubereitungen fÃŒr Cellulose oder cellulosehaltiges Fasermaterial |
| DE3025790A1 (de) * | 1980-07-08 | 1982-02-04 | Hoechst Ag, 6000 Frankfurt | Wasserloesliche phthalocyaninverbindungen, verfahren zu ihrer herstellung und ihre verwendung als farbstoffe |
-
1979
- 1979-08-24 DE DE19792934248 patent/DE2934248A1/de not_active Withdrawn
-
1980
- 1980-08-19 EP EP80104926A patent/EP0024677B1/de not_active Expired
- 1980-08-19 DE DE8080104926T patent/DE3060629D1/de not_active Expired
- 1980-08-19 IN IN943/CAL/80A patent/IN154643B/en unknown
- 1980-08-22 JP JP11488380A patent/JPS5632546A/ja active Granted
-
1981
- 1981-08-26 US US06/296,442 patent/US4397649A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US4397649A (en) | 1983-08-09 |
| IN154643B (ja) | 1984-11-24 |
| EP0024677A1 (de) | 1981-03-11 |
| EP0024677B1 (de) | 1982-06-30 |
| JPS5632546A (en) | 1981-04-02 |
| DE3060629D1 (en) | 1982-08-19 |
| DE2934248A1 (de) | 1981-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3226395A (en) | Water-insoluble phthalocyanine dyestuffs and process for their manufacture | |
| KR920001489B1 (ko) | ë°ìì± êžì í¬ë¥Žë§ì íí©ë¬Œì ì ì¡°ë°©ë² | |
| JPS6221025B2 (ja) | ||
| US4952688A (en) | Water-soluble phthalocyanine compounds | |
| JPS6239179B2 (ja) | ||
| JPH0124826B2 (ja) | ||
| US4855411A (en) | Water-soluble, monoazo dyes containing a ureido group and two sulfonyl fiber-reactive groups | |
| CA1156223A (en) | Copper formazan compounds, processes for their preparation and their use as dyestuffs | |
| KR20020079999A (ko) | ì¬ì ë°ìì± ëì€ìì¡° íí©ë¬Œ | |
| JPS6324545B2 (ja) | ||
| JPS61247760A (ja) | ããããã·åºãå«æããç¹ç¶ææã®æè²åã¯æºææ³ | |
| KR960006671B1 (ko) | ìì©ì± ëííž ìì¡° íŒëŒì¡žë¡ íí©ë¬Œ, ìŽì ì ì¡°ë°©ë² ë° ìŒë£ë¡ìì ìŽì ì©ë | |
| JPH04268379A (ja) | åå¿æ§ææããã®è£œé æ¹æ³åã³ææã®æè²æ¹æ³ | |
| CS221843B2 (en) | Method of making the derivative of the phtalocyanine | |
| JPS6035948B2 (ja) | 氎溶æ§ææããã®è£œæ³åã³ã»ã«ããŒãºâåã³ããªã¢ããç¹ç¶ææã®æè²åã³æºæãžã®äœ¿çš | |
| JPH0798910B2 (ja) | 氎溶æ§ãžã¹ã¢ãŸååç©ããã®è£œæ³åã³è©²ååç©ãææãšããŠäœ¿çšããæ¹æ³ | |
| KR890002348B1 (ko) | ì-ì©ì± ëªšë žìì¡° íí©ë¬Œì ì ì¡°ë°©ë² | |
| JP2927568B2 (ja) | ã¢ãŸææããã®è£œé æ³ããã³äœ¿çšæ³ | |
| JPS63199768A (ja) | 氎溶æ§ã¢ãã¢ãŸâãã©ãŸãã³âååç©ããã®è£œæ³åã³è©²ååç©ãææãšããŠäœ¿çšããæ¹æ³ | |
| CA1120209A (en) | Process for the preparation of fiber-reactive dyestuffs | |
| CA1266046A (en) | Process for the preparation of copper complex disazo compounds | |
| JPH0811784B2 (ja) | å¡©åºæ§åºãå«æãããªããµãžã³ååç© | |
| CA2135555A1 (en) | Water-soluble phthalocyanine dyes, preparation thereof and use thereof | |
| JPS6214585B2 (ja) | ||
| JPH0772255B2 (ja) | 氎溶æ§ãã¿ãã·ã¢ãã³è²çŽ |