JPS62257000A - 卑金属基材からの金属コ−テイングの選択的電解剥離 - Google Patents
卑金属基材からの金属コ−テイングの選択的電解剥離Info
- Publication number
- JPS62257000A JPS62257000A JP62096383A JP9638387A JPS62257000A JP S62257000 A JPS62257000 A JP S62257000A JP 62096383 A JP62096383 A JP 62096383A JP 9638387 A JP9638387 A JP 9638387A JP S62257000 A JPS62257000 A JP S62257000A
- Authority
- JP
- Japan
- Prior art keywords
- metal
- anode
- tin
- coating
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 33
- 239000002184 metal Substances 0.000 title claims abstract description 33
- 238000000576 coating method Methods 0.000 title claims abstract description 30
- 239000010953 base metal Substances 0.000 title claims abstract description 17
- 239000011248 coating agent Substances 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 title description 4
- 239000000758 substrate Substances 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000003792 electrolyte Substances 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 11
- 230000007423 decrease Effects 0.000 claims abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 22
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 14
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 10
- 239000011135 tin Substances 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 239000011651 chromium Substances 0.000 claims description 8
- 229910052718 tin Inorganic materials 0.000 claims description 8
- 229910000978 Pb alloy Inorganic materials 0.000 claims description 6
- 229940098779 methanesulfonic acid Drugs 0.000 claims description 6
- 239000011133 lead Substances 0.000 claims description 5
- 229910001128 Sn alloy Inorganic materials 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052793 cadmium Inorganic materials 0.000 claims description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000000243 solution Substances 0.000 abstract description 9
- 239000007864 aqueous solution Substances 0.000 abstract description 2
- 239000010405 anode material Substances 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 14
- 229910052802 copper Inorganic materials 0.000 description 14
- 239000010949 copper Substances 0.000 description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 10
- 229910052725 zinc Inorganic materials 0.000 description 10
- 239000011701 zinc Substances 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910000679 solder Inorganic materials 0.000 description 5
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 238000009428 plumbing Methods 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- FKOZPUORKCHONH-UHFFFAOYSA-N 2-methylpropane-1-sulfonic acid Chemical compound CC(C)CS(O)(=O)=O FKOZPUORKCHONH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000016496 Panda oleosa Nutrition 0.000 description 1
- 240000000220 Panda oleosa Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- QDHFHIQKOVNCNC-UHFFFAOYSA-N butane-1-sulfonic acid Chemical compound CCCCS(O)(=O)=O QDHFHIQKOVNCNC-UHFFFAOYSA-N 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- -1 lead alloys Chemical compound 0.000 description 1
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- HNDXKIMMSFCCFW-UHFFFAOYSA-N propane-2-sulphonic acid Chemical compound CC(C)S(O)(=O)=O HNDXKIMMSFCCFW-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F5/00—Electrolytic stripping of metallic layers or coatings
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/06—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process
- H05K3/067—Etchants
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Electroplating Methods And Accessories (AREA)
- Manufacturing Of Printed Circuit Boards (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- ing And Chemical Polishing (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/855,043 US4678552A (en) | 1986-04-22 | 1986-04-22 | Selective electrolytic stripping of metal coatings from base metal substrates |
| US855043 | 1986-04-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62257000A true JPS62257000A (ja) | 1987-11-09 |
Family
ID=25320193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62096383A Pending JPS62257000A (ja) | 1986-04-22 | 1987-04-21 | 卑金属基材からの金属コ−テイングの選択的電解剥離 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4678552A (enExample) |
| EP (1) | EP0242583B1 (enExample) |
| JP (1) | JPS62257000A (enExample) |
| AT (1) | ATE54186T1 (enExample) |
| AU (1) | AU592630B2 (enExample) |
| BR (1) | BR8701888A (enExample) |
| CA (1) | CA1294238C (enExample) |
| DE (1) | DE3763431D1 (enExample) |
| DK (1) | DK167776B1 (enExample) |
| ES (1) | ES2015906B3 (enExample) |
| GR (1) | GR3000587T3 (enExample) |
| IN (1) | IN164856B (enExample) |
| MX (1) | MX165328B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06272098A (ja) * | 1993-03-19 | 1994-09-27 | Ebara Yuujiraito Kk | 錫または錫合金からなる皮膜のための電解剥離液および剥離法 |
| JP2002212800A (ja) * | 2001-01-10 | 2002-07-31 | Ebara Udylite Kk | スズ合金めっき皮膜の電解剥離方法 |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6045686A (en) * | 1997-03-18 | 2000-04-04 | The University Of Connecticut | Method and apparatus for electrochemical delacquering and detinning |
| DE19809487A1 (de) * | 1998-03-06 | 1999-09-09 | Greising | Verfahren und Vorrichtung zur Aufbringung einer räumlich begrenzten metallischen Deckschicht auf einer elektrisch leitenden Materialoberfläche |
| US6494960B1 (en) * | 1998-04-27 | 2002-12-17 | General Electric Company | Method for removing an aluminide coating from a substrate |
| US6176999B1 (en) | 1998-12-18 | 2001-01-23 | United Technologies Corporation | Feedback controlled stripping of airfoils |
| GB9901586D0 (en) * | 1999-01-25 | 1999-03-17 | Alpha Fry Ltd | Process for the recovery of lead and/or tin or alloys thereof from substrate surfaces |
| US6599416B2 (en) | 2001-09-28 | 2003-07-29 | General Electric Company | Method and apparatus for selectively removing coatings from substrates |
| EP1302569A3 (en) * | 2001-10-11 | 2004-03-03 | Shipley Co. L.L.C. | Stripping solution |
| US6758914B2 (en) | 2001-10-25 | 2004-07-06 | General Electric Company | Process for partial stripping of diffusion aluminide coatings from metal substrates, and related compositions |
| US6969457B2 (en) * | 2002-10-21 | 2005-11-29 | General Electric Company | Method for partially stripping a coating from the surface of a substrate, and related articles and compositions |
| EP1473387A1 (de) * | 2003-05-02 | 2004-11-03 | Siemens Aktiengesellschaft | Verfahren zur Entschichtung eines Bauteils |
| DE102004045297A1 (de) * | 2004-09-16 | 2006-03-23 | Basf Ag | Verfahren zum Behandeln von metallischen Oberflächen unter Verwendung von Formulierungen auf Basis von wasserarmer Methansulfonsäure |
| EP2381015B1 (en) | 2005-08-12 | 2019-01-16 | Modumetal, Inc. | Compositionally modulated composite materials |
| DE102006045221B3 (de) * | 2006-09-25 | 2008-04-03 | Poligrat Gmbh | Elektropolierverfahren für Kobalt und Kobaltlegierungen und Elektrolyt |
| EP3009532A1 (en) | 2009-06-08 | 2016-04-20 | Modumetal, Inc. | Electrodeposited nanolaminate coatings and claddings for corrosion protection |
| WO2011044340A1 (en) * | 2009-10-08 | 2011-04-14 | First Solar, Inc. | Electrochemical method and apparatus for removing coating from a substrate |
| EP2558605A1 (en) | 2010-04-15 | 2013-02-20 | Advanced Technology Materials, Inc. | Method for recycling of obsolete printed circuit boards |
| CN103088399B (zh) * | 2011-10-31 | 2016-01-06 | 通用电气公司 | 多步骤电化学去金属涂层方法 |
| KR20140139131A (ko) | 2011-12-15 | 2014-12-04 | 어드밴스드 테크놀러지 머티리얼즈, 인코포레이티드 | 폐 전기 및 전자 장비의 재활용 동안 땜납 금속의 스트리핑을 위한 장치 및 방법 |
| DE102013102331B3 (de) * | 2013-03-08 | 2014-07-03 | Horst-Otto Bertholdt | Verfahren zum Abbau einer Oxidschicht |
| CA2905575C (en) | 2013-03-15 | 2022-07-12 | Modumetal, Inc. | A method and apparatus for continuously applying nanolaminate metal coatings |
| EP2971265A4 (en) | 2013-03-15 | 2016-12-14 | Modumetal Inc | NICKEL CHROME NANOLAMINE COATING WITH HIGH HARDNESS |
| CA2905536C (en) | 2013-03-15 | 2023-03-07 | Modumetal, Inc. | Electrodeposited compositions and nanolaminated alloys for articles prepared by additive manufacturing processes |
| WO2016044720A1 (en) | 2014-09-18 | 2016-03-24 | Modumetal, Inc. | A method and apparatus for continuously applying nanolaminate metal coatings |
| HK1220741A1 (zh) | 2013-03-15 | 2017-05-12 | Modumetal, Inc. | 纳米层压涂层 |
| US20160319444A1 (en) | 2013-12-20 | 2016-11-03 | Greene Lyon Group, Inc. | Method and apparatus for recovery of noble metals, including recovery of noble metals from plated and/or filled scrap |
| BR112017005534A2 (pt) | 2014-09-18 | 2017-12-05 | Modumetal Inc | métodos de preparação de artigos por processos de eletrodeposição e fabricação aditiva |
| CN107922992B (zh) | 2015-06-24 | 2021-03-02 | 格林里昂集团有限公司 | 使用包括含有硝酸根离子的流体的酸性流体的贵金属的选择性移出 |
| US10514242B1 (en) | 2015-10-14 | 2019-12-24 | The University Of Massachusetts | Method and apparatus for electrochemical ammunition disposal and material recovery |
| EP3510185A1 (en) | 2016-09-08 | 2019-07-17 | Modumetal, Inc. | Processes for providing laminated coatings on workpieces, and articles made therefrom |
| EP3509812B1 (en) | 2016-09-09 | 2025-04-09 | Modumetal, Inc. | Manufacturing of molds by deposition of material layers on a workpiece, molds and articles obtained by said process |
| CN109963966B (zh) | 2016-09-14 | 2022-10-11 | 莫杜美拓有限公司 | 用于可靠、高通量、复杂电场生成的系统以及由其生产涂层的方法 |
| CN110114210B (zh) | 2016-11-02 | 2022-03-04 | 莫杜美拓有限公司 | 拓扑优化的高界面填充结构 |
| US11293272B2 (en) | 2017-03-24 | 2022-04-05 | Modumetal, Inc. | Lift plungers with electrodeposited coatings, and systems and methods for producing the same |
| US11286575B2 (en) | 2017-04-21 | 2022-03-29 | Modumetal, Inc. | Tubular articles with electrodeposited coatings, and systems and methods for producing the same |
| WO2019210264A1 (en) | 2018-04-27 | 2019-10-31 | Modumetal, Inc. | Apparatuses, systems, and methods for producing a plurality of articles with nanolaminated coatings using rotation |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2525942A (en) * | 1945-06-29 | 1950-10-17 | Standard Oil Co | Electrodepositing bath and process |
| US2706171A (en) * | 1953-03-09 | 1955-04-12 | Enthone | Stripping chromium plating from zinc electrolytically |
| DE1926228C3 (de) * | 1969-05-22 | 1974-02-21 | Bergische Metallwarenfabrik Dillenberg & Co Kg, 5601 Gruiten | Bad zum elektrolytischen Ablösen von Metallüberzügen aus Nickel oder Chrom von Grundkörpern aus Buntmetall |
| US4356069A (en) * | 1981-03-09 | 1982-10-26 | Ross Cunningham | Stripping composition and method for preparing and using same |
| US4400248A (en) * | 1982-03-08 | 1983-08-23 | Occidental Chemical Corporation | Electrolytic stripping process |
| HU186150B (en) * | 1982-10-29 | 1985-06-28 | Latszereszeti Eszkoezoek Gyara | Process for the removal electrolitically of nickel, chrome ot gold layers from the surface of copper or cupric alloys and equipemnt for carrying out the process |
| ATE30344T1 (de) * | 1983-10-26 | 1987-11-15 | Schloetter Fa Dr Ing Max | Entmetallisierungsbad und verfahren zum elektrolytischen abziehen von metallen von titan als grundmetall. |
| DE3415364A1 (de) * | 1984-04-25 | 1985-10-31 | Hoechst Ag, 6230 Frankfurt | Verfahren zur elektrochemischen aufrauhung von aluminium fuer druckplattentraeger in einem waessrigen mischelektrolyten |
| US4664763A (en) * | 1985-05-08 | 1987-05-12 | M&T Chemicals Inc. | Process for stripping nickel or nickel-alloy plating in a chromic acid solution |
-
1986
- 1986-04-22 US US06/855,043 patent/US4678552A/en not_active Expired - Fee Related
-
1987
- 1987-03-12 CA CA000531903A patent/CA1294238C/en not_active Expired - Lifetime
- 1987-03-16 DE DE8787103767T patent/DE3763431D1/de not_active Expired - Fee Related
- 1987-03-16 ES ES87103767T patent/ES2015906B3/es not_active Expired - Lifetime
- 1987-03-16 AT AT87103767T patent/ATE54186T1/de active
- 1987-03-16 EP EP87103767A patent/EP0242583B1/en not_active Expired - Lifetime
- 1987-04-02 AU AU70988/87A patent/AU592630B2/en not_active Ceased
- 1987-04-03 IN IN273/CAL/87A patent/IN164856B/en unknown
- 1987-04-21 BR BR8701888A patent/BR8701888A/pt not_active Application Discontinuation
- 1987-04-21 DK DK202387A patent/DK167776B1/da active
- 1987-04-21 JP JP62096383A patent/JPS62257000A/ja active Pending
- 1987-04-21 MX MX006126A patent/MX165328B/es unknown
-
1990
- 1990-06-28 GR GR90400205T patent/GR3000587T3/el unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06272098A (ja) * | 1993-03-19 | 1994-09-27 | Ebara Yuujiraito Kk | 錫または錫合金からなる皮膜のための電解剥離液および剥離法 |
| JP2002212800A (ja) * | 2001-01-10 | 2002-07-31 | Ebara Udylite Kk | スズ合金めっき皮膜の電解剥離方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US4678552A (en) | 1987-07-07 |
| DK167776B1 (da) | 1993-12-13 |
| ES2015906B3 (es) | 1990-09-16 |
| AU592630B2 (en) | 1990-01-18 |
| DK202387D0 (da) | 1987-04-21 |
| ATE54186T1 (de) | 1990-07-15 |
| DK202387A (da) | 1987-10-23 |
| IN164856B (enExample) | 1989-06-17 |
| BR8701888A (pt) | 1988-02-02 |
| AU7098887A (en) | 1987-10-29 |
| GR3000587T3 (en) | 1991-07-31 |
| DE3763431D1 (de) | 1990-08-02 |
| EP0242583A1 (en) | 1987-10-28 |
| CA1294238C (en) | 1992-01-14 |
| EP0242583B1 (en) | 1990-06-27 |
| MX165328B (es) | 1992-11-05 |
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