JPS62184458A

JPS62184458A - ハロゲン化銀写真感光材料

ハロゲン化銀写真感光材料

Info

Publication number: JPS62184458A
Authority: JP; Japan
Prior art keywords: group; groups; general formula; represented; silver halide
Prior art date: 1986-02-08
Legal status : Granted

Application number

JP2643886A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0569416B2 (enrdf_load_stackoverflow

Inventor

Toyoki Nishijima

豊喜西嶋

Kaoru Onodera

薫小野寺

Current Assignee

Konica Minolta Inc

Original Assignee

Konica Minolta Inc

Priority date

1986-02-08

Filing date

1986-02-08

Publication date

1987-08-12

1986-02-08 Application filed by Konica Minolta Inc filed Critical Konica Minolta Inc

1986-02-08 Priority to JP2643886A priority Critical patent/JPS62184458A/ja

1987-08-12 Publication of JPS62184458A publication Critical patent/JPS62184458A/ja

1993-10-01 Publication of JPH0569416B2 publication Critical patent/JPH0569416B2/ja

Status Granted legal-status Critical Current

Links

-1 Silver halide Chemical class 0.000 title claims abstract description 430
229910052709 silver Inorganic materials 0.000 title claims abstract description 100
239000004332 silver Substances 0.000 title claims abstract description 100
239000000463 material Substances 0.000 title claims abstract description 56
125000003118 aryl group Chemical group 0.000 claims abstract description 155
125000001424 substituent group Chemical group 0.000 claims abstract description 155
150000001875 compounds Chemical class 0.000 claims abstract description 101
239000000839 emulsion Substances 0.000 claims abstract description 62
125000001931 aliphatic group Chemical group 0.000 claims abstract description 29
239000003795 chemical substances by application Substances 0.000 claims abstract description 18
238000006243 chemical reaction Methods 0.000 claims abstract description 15
125000005647 linker group Chemical group 0.000 claims abstract description 15
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 96
239000003960 organic solvent Substances 0.000 claims description 15
239000000126 substance Substances 0.000 claims description 15
150000004696 coordination complex Chemical class 0.000 claims description 12
238000009835 boiling Methods 0.000 claims description 10
238000003860 storage Methods 0.000 abstract description 9
125000004122 cyclic group Chemical group 0.000 abstract description 2
230000003647 oxidation Effects 0.000 abstract 1
238000007254 oxidation reaction Methods 0.000 abstract 1
125000000217 alkyl group Chemical group 0.000 description 200
125000000623 heterocyclic group Chemical group 0.000 description 87
125000003545 alkoxy group Chemical group 0.000 description 81
239000010410 layer Substances 0.000 description 78
125000000753 cycloalkyl group Chemical group 0.000 description 72
125000003342 alkenyl group Chemical group 0.000 description 69
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 67
125000002887 hydroxy group Chemical group [H]O* 0.000 description 60
125000005843 halogen group Chemical group 0.000 description 58
125000004104 aryloxy group Chemical group 0.000 description 41
125000004453 alkoxycarbonyl group Chemical group 0.000 description 40
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 35
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 34
125000004432 carbon atom Chemical group C* 0.000 description 33
238000000034 method Methods 0.000 description 29
125000001624 naphthyl group Chemical group 0.000 description 27
125000004429 atom Chemical group 0.000 description 26
125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 25
125000000565 sulfonamide group Chemical group 0.000 description 25
125000002252 acyl group Chemical group 0.000 description 24
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 24
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 22
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 21
150000002430 hydrocarbons Chemical group 0.000 description 21
229910052801 chlorine Inorganic materials 0.000 description 20
125000004442 acylamino group Chemical group 0.000 description 19
238000000576 coating method Methods 0.000 description 19
125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 18
239000011248 coating agent Substances 0.000 description 18
239000000975 dye Substances 0.000 description 18
239000000243 solution Substances 0.000 description 18
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 18
125000004423 acyloxy group Chemical group 0.000 description 17
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 17
125000005161 aryl oxy carbonyl group Chemical group 0.000 description 16
229910052799 carbon Inorganic materials 0.000 description 16
229910052731 fluorine Inorganic materials 0.000 description 16
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 16
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 15
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 14
229910052757 nitrogen Inorganic materials 0.000 description 14
108010010803 Gelatin Proteins 0.000 description 13
125000004093 cyano group Chemical group *C#N 0.000 description 13
239000011737 fluorine Substances 0.000 description 13
229920000159 gelatin Polymers 0.000 description 13
239000008273 gelatin Substances 0.000 description 13
235000019322 gelatine Nutrition 0.000 description 13
235000011852 gelatine desserts Nutrition 0.000 description 13
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 13
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 13
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 12
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 12
125000004391 aryl sulfonyl group Chemical group 0.000 description 12
150000001721 carbon Chemical group 0.000 description 12
239000000460 chlorine Substances 0.000 description 12
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 12
229910052751 metal Inorganic materials 0.000 description 12
239000002184 metal Substances 0.000 description 12
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 12
238000012545 processing Methods 0.000 description 12
150000003839 salts Chemical class 0.000 description 12
229910052717 sulfur Inorganic materials 0.000 description 12
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 11
125000003302 alkenyloxy group Chemical group 0.000 description 11
125000005153 alkyl sulfamoyl group Chemical group 0.000 description 11
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 11
229910052794 bromium Inorganic materials 0.000 description 11
239000000084 colloidal system Substances 0.000 description 11
239000013078 crystal Substances 0.000 description 11
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 11
125000004433 nitrogen atom Chemical group N* 0.000 description 11
125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 11
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 11
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 10
239000002253 acid Substances 0.000 description 10
125000004390 alkyl sulfonyl group Chemical group 0.000 description 10
125000005110 aryl thio group Chemical group 0.000 description 10
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 10
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 10
HBEDSQVIWPRPAY-UHFFFAOYSA-N 2,3-dihydrobenzofuran Chemical compound C1=CC=C2OCCC2=C1 HBEDSQVIWPRPAY-UHFFFAOYSA-N 0.000 description 9
KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical group NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 9
VZWXIQHBIQLMPN-UHFFFAOYSA-N chromane Chemical compound C1=CC=C2CCCOC2=C1 VZWXIQHBIQLMPN-UHFFFAOYSA-N 0.000 description 9
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 9
125000004430 oxygen atom Chemical group O* 0.000 description 9
239000002245 particle Substances 0.000 description 9
125000004434 sulfur atom Chemical group 0.000 description 9
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 8
125000004414 alkyl thio group Chemical group 0.000 description 8
125000003277 amino group Chemical group 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 8
125000001309 chloro group Chemical group Cl* 0.000 description 8
125000005842 heteroatom Chemical group 0.000 description 8
239000000203 mixture Substances 0.000 description 8
YYMBJDOZVAITBP-UHFFFAOYSA-N rubrene Chemical compound C1=CC=CC=C1C(C1=C(C=2C=CC=CC=2)C2=CC=CC=C2C(C=2C=CC=CC=2)=C11)=C(C=CC=C2)C2=C1C1=CC=CC=C1 YYMBJDOZVAITBP-UHFFFAOYSA-N 0.000 description 8
238000003786 synthesis reaction Methods 0.000 description 8
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 7
SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 7
125000003282 alkyl amino group Chemical group 0.000 description 7
125000002947 alkylene group Chemical group 0.000 description 7
125000004421 aryl sulphonamide group Chemical group 0.000 description 7
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 7
125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 description 7
125000000392 cycloalkenyl group Chemical group 0.000 description 7
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
238000011161 development Methods 0.000 description 7
125000006038 hexenyl group Chemical group 0.000 description 7
125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 7
230000001235 sensitizing effect Effects 0.000 description 7
125000003003 spiro group Chemical group 0.000 description 7
239000003381 stabilizer Substances 0.000 description 7
125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 7
125000004149 thio group Chemical group *S* 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
101001047650 Rhyparobia maderae Leucokinin-3 Proteins 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
125000004422 alkyl sulphonamide group Chemical group 0.000 description 6
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 6
125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 6
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 6
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
229910052737 gold Inorganic materials 0.000 description 6
239000010931 gold Substances 0.000 description 6
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical compound CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 6
125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 6
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 6
125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 6
229910000027 potassium carbonate Inorganic materials 0.000 description 6
235000011181 potassium carbonates Nutrition 0.000 description 6
229920006395 saturated elastomer Polymers 0.000 description 6
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
238000011282 treatment Methods 0.000 description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
125000005115 alkyl carbamoyl group Chemical group 0.000 description 5
125000004448 alkyl carbonyl group Chemical group 0.000 description 5
125000000304 alkynyl group Chemical group 0.000 description 5
125000005129 aryl carbonyl group Chemical group 0.000 description 5
230000000694 effects Effects 0.000 description 5
229910052740 iodine Inorganic materials 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
QWOKKHXWFDAJCZ-UHFFFAOYSA-N octane-1-sulfonamide Chemical group CCCCCCCCS(N)(=O)=O QWOKKHXWFDAJCZ-UHFFFAOYSA-N 0.000 description 5
125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
125000006678 phenoxycarbonyl group Chemical group 0.000 description 5
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
230000008569 process Effects 0.000 description 5
125000004076 pyridyl group Chemical group 0.000 description 5
150000003413 spiro compounds Chemical group 0.000 description 5
125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
150000003457 sulfones Chemical class 0.000 description 5
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
125000004417 unsaturated alkyl group Chemical group 0.000 description 5
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 4
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 4
ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 4
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
206010070834 Sensitisation Diseases 0.000 description 4
125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 4
125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
150000003973 alkyl amines Chemical class 0.000 description 4
125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 4
125000001769 aryl amino group Chemical group 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
125000000043 benzamido group Chemical group [H]N([*])C(=O)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 4
239000012964 benzotriazole Substances 0.000 description 4
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 4
238000004061 bleaching Methods 0.000 description 4
239000007844 bleaching agent Substances 0.000 description 4
230000006866 deterioration Effects 0.000 description 4
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
238000005562 fading Methods 0.000 description 4
125000001153 fluoro group Chemical group F* 0.000 description 4
125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
125000003392 indanyl group Chemical group C1(CCC2=CC=CC=C12)* 0.000 description 4
229910052742 iron Inorganic materials 0.000 description 4
239000003446 ligand Substances 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
125000005064 octadecenyl group Chemical group C(=CCCCCCCCCCCCCCCCC)* 0.000 description 4
150000007524 organic acids Chemical class 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 4
125000005499 phosphonyl group Chemical group 0.000 description 4
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 4
238000010791 quenching Methods 0.000 description 4
230000000171 quenching effect Effects 0.000 description 4
230000008313 sensitization Effects 0.000 description 4
125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 4
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 4
125000003944 tolyl group Chemical group 0.000 description 4
125000002088 tosyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])S(*)(=O)=O 0.000 description 4
125000003774 valeryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
229910052727 yttrium Inorganic materials 0.000 description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
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