JPS6178806A - 被覆用熱硬化性アクリル樹脂組成物の製造法 - Google Patents
被覆用熱硬化性アクリル樹脂組成物の製造法Info
- Publication number
- JPS6178806A JPS6178806A JP59199776A JP19977684A JPS6178806A JP S6178806 A JPS6178806 A JP S6178806A JP 59199776 A JP59199776 A JP 59199776A JP 19977684 A JP19977684 A JP 19977684A JP S6178806 A JPS6178806 A JP S6178806A
- Authority
- JP
- Japan
- Prior art keywords
- group
- weight
- groups
- formulas
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 42
- 239000011248 coating agent Substances 0.000 title claims description 22
- 238000000576 coating method Methods 0.000 title claims description 22
- 239000004925 Acrylic resin Substances 0.000 title claims description 16
- 229920000178 Acrylic resin Polymers 0.000 title claims description 16
- 229920001187 thermosetting polymer Polymers 0.000 title claims description 7
- -1 polysiloxane Polymers 0.000 claims abstract description 37
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 27
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 16
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 9
- 229910000077 silane Inorganic materials 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims description 23
- 239000000178 monomer Substances 0.000 claims description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- 238000007334 copolymerization reaction Methods 0.000 claims description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 150000007524 organic acids Chemical class 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 125000004185 ester group Chemical group 0.000 claims description 6
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000002904 solvent Substances 0.000 abstract description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 5
- 239000008096 xylene Substances 0.000 abstract description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 abstract description 3
- 229920002554 vinyl polymer Polymers 0.000 abstract description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 4
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 abstract 1
- 239000011342 resin composition Substances 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910010272 inorganic material Inorganic materials 0.000 description 5
- 239000011147 inorganic material Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Chemical class 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 150000004756 silanes Chemical class 0.000 description 3
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical group OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- ZYAASQNKCWTPKI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propan-1-amine Chemical compound CO[Si](C)(OC)CCCN ZYAASQNKCWTPKI-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- MPFUOCVWJGGDQN-UHFFFAOYSA-N butan-1-ol;1,2-xylene Chemical compound CCCCO.CC1=CC=CC=C1C MPFUOCVWJGGDQN-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- GYLXWHLPLTVIOP-UHFFFAOYSA-N ethenyl(2,2,2-trimethoxyethoxy)silane Chemical compound COC(OC)(OC)CO[SiH2]C=C GYLXWHLPLTVIOP-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- ZLNAFSPCNATQPQ-UHFFFAOYSA-N ethenyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C=C ZLNAFSPCNATQPQ-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000013035 low temperature curing Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59199776A JPS6178806A (ja) | 1984-09-25 | 1984-09-25 | 被覆用熱硬化性アクリル樹脂組成物の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59199776A JPS6178806A (ja) | 1984-09-25 | 1984-09-25 | 被覆用熱硬化性アクリル樹脂組成物の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6178806A true JPS6178806A (ja) | 1986-04-22 |
| JPH0446306B2 JPH0446306B2 (enrdf_load_stackoverflow) | 1992-07-29 |
Family
ID=16413421
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59199776A Granted JPS6178806A (ja) | 1984-09-25 | 1984-09-25 | 被覆用熱硬化性アクリル樹脂組成物の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6178806A (enrdf_load_stackoverflow) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01131254A (ja) * | 1987-08-14 | 1989-05-24 | Mitsubishi Kasei Vinyl Co | 塩化ビニル系樹脂成形品 |
| JPH01184130A (ja) * | 1988-01-18 | 1989-07-21 | Mitsubishi Kasei Vinyl Co | 農業用塩化ビニル系樹脂フィルム |
| JPH01206040A (ja) * | 1987-10-08 | 1989-08-18 | Mitsubishi Kasei Vinyl Co | 農業用塩化ビニル系樹脂フィルム |
| JPH02108536A (ja) * | 1988-10-18 | 1990-04-20 | Mitsubishi Kasei Vinyl Co | 農業用塩化ビニル系樹脂フィルム |
| JPH02113939A (ja) * | 1988-10-24 | 1990-04-26 | Mitsubishi Kasei Vinyl Co | 農業用軟質塩化ビニル系樹脂フィルム |
| JPH02233752A (ja) * | 1989-03-08 | 1990-09-17 | Kansai Paint Co Ltd | 硬化性組成物 |
| GB2247461A (en) * | 1990-08-29 | 1992-03-04 | Kansai Paint Co Ltd | Polysiloxane and resin coating composition |
| WO2005032814A1 (en) * | 2003-10-06 | 2005-04-14 | Fuji Photo Film Co., Ltd. | Hard coating article, curing composition, and information recording media |
| JP2005314606A (ja) * | 2004-04-30 | 2005-11-10 | Kuraray Co Ltd | ケイ素含有重合体の製造方法およびケイ素含有重合体 |
| WO2012091178A1 (en) | 2010-12-28 | 2012-07-05 | Dow Corning Toray Co., Ltd. | Additive for a coating agent and coating agent containing same |
| CN102898578A (zh) * | 2012-07-16 | 2013-01-30 | 杭州师范大学 | 一种自交联硅丙聚合物乳液及其制备方法 |
| CN107075122A (zh) * | 2014-12-16 | 2017-08-18 | 湛新奥地利有限公司 | 用于涂料组合物的流动改性剂 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4831252A (enrdf_load_stackoverflow) * | 1971-08-26 | 1973-04-24 | ||
| JPS5142752A (ja) * | 1974-10-09 | 1976-04-12 | Japan Atomic Energy Res Inst | Kokaseijushisoseibutsu |
| JPS5462299A (en) * | 1977-10-26 | 1979-05-19 | Japan Atom Energy Res Inst | Curable resin composition |
| JPS5947216A (ja) * | 1982-09-13 | 1984-03-16 | Shin Etsu Chem Co Ltd | プライマ−組成物 |
-
1984
- 1984-09-25 JP JP59199776A patent/JPS6178806A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4831252A (enrdf_load_stackoverflow) * | 1971-08-26 | 1973-04-24 | ||
| JPS5142752A (ja) * | 1974-10-09 | 1976-04-12 | Japan Atomic Energy Res Inst | Kokaseijushisoseibutsu |
| JPS5462299A (en) * | 1977-10-26 | 1979-05-19 | Japan Atom Energy Res Inst | Curable resin composition |
| JPS5947216A (ja) * | 1982-09-13 | 1984-03-16 | Shin Etsu Chem Co Ltd | プライマ−組成物 |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01131254A (ja) * | 1987-08-14 | 1989-05-24 | Mitsubishi Kasei Vinyl Co | 塩化ビニル系樹脂成形品 |
| JPH01206040A (ja) * | 1987-10-08 | 1989-08-18 | Mitsubishi Kasei Vinyl Co | 農業用塩化ビニル系樹脂フィルム |
| JPH01184130A (ja) * | 1988-01-18 | 1989-07-21 | Mitsubishi Kasei Vinyl Co | 農業用塩化ビニル系樹脂フィルム |
| JPH02108536A (ja) * | 1988-10-18 | 1990-04-20 | Mitsubishi Kasei Vinyl Co | 農業用塩化ビニル系樹脂フィルム |
| JPH02113939A (ja) * | 1988-10-24 | 1990-04-26 | Mitsubishi Kasei Vinyl Co | 農業用軟質塩化ビニル系樹脂フィルム |
| JPH02233752A (ja) * | 1989-03-08 | 1990-09-17 | Kansai Paint Co Ltd | 硬化性組成物 |
| GB2247461A (en) * | 1990-08-29 | 1992-03-04 | Kansai Paint Co Ltd | Polysiloxane and resin coating composition |
| GB2247461B (en) * | 1990-08-29 | 1994-07-06 | Kansai Paint Co Ltd | Curable resin composition and curing method |
| WO2005032814A1 (en) * | 2003-10-06 | 2005-04-14 | Fuji Photo Film Co., Ltd. | Hard coating article, curing composition, and information recording media |
| JP2005314606A (ja) * | 2004-04-30 | 2005-11-10 | Kuraray Co Ltd | ケイ素含有重合体の製造方法およびケイ素含有重合体 |
| WO2012091178A1 (en) | 2010-12-28 | 2012-07-05 | Dow Corning Toray Co., Ltd. | Additive for a coating agent and coating agent containing same |
| CN102898578A (zh) * | 2012-07-16 | 2013-01-30 | 杭州师范大学 | 一种自交联硅丙聚合物乳液及其制备方法 |
| CN102898578B (zh) * | 2012-07-16 | 2015-01-07 | 杭州师范大学 | 一种自交联硅丙聚合物乳液及其制备方法 |
| CN107075122A (zh) * | 2014-12-16 | 2017-08-18 | 湛新奥地利有限公司 | 用于涂料组合物的流动改性剂 |
| JP2018505233A (ja) * | 2014-12-16 | 2018-02-22 | オールネックス オーストリア ゲーエムベーハー | コーティング組成物のための流動性改良剤 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0446306B2 (enrdf_load_stackoverflow) | 1992-07-29 |
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