JPS6161372B2 - - Google Patents
Info
- Publication number
- JPS6161372B2 JPS6161372B2 JP50096779A JP50096779A JPS6161372B2 JP S6161372 B2 JPS6161372 B2 JP S6161372B2 JP 50096779 A JP50096779 A JP 50096779A JP 50096779 A JP50096779 A JP 50096779A JP S6161372 B2 JPS6161372 B2 JP S6161372B2
- Authority
- JP
- Japan
- Prior art keywords
- emulsion
- compounds
- silver halide
- sensitivity
- direct positive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 description 65
- 150000002896 organic halogen compounds Chemical class 0.000 description 34
- -1 silver halide Chemical class 0.000 description 33
- 229910052709 silver Inorganic materials 0.000 description 29
- 239000004332 silver Substances 0.000 description 29
- 230000035945 sensitivity Effects 0.000 description 22
- 239000000975 dye Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 14
- 230000005070 ripening Effects 0.000 description 12
- UDYYQHILRSDDMP-UHFFFAOYSA-N 2-(tribromomethyl)quinoline Chemical compound C1=CC=CC2=NC(C(Br)(Br)Br)=CC=C21 UDYYQHILRSDDMP-UHFFFAOYSA-N 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000000523 sample Substances 0.000 description 9
- 238000007792 addition Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- YTSFUCJYOKYMDE-UHFFFAOYSA-N 2-(dibromomethyl)quinoline Chemical compound C1=CC=CC2=NC(C(Br)Br)=CC=C21 YTSFUCJYOKYMDE-UHFFFAOYSA-N 0.000 description 3
- VCCOPRMZNNMFLI-UHFFFAOYSA-N 2-(tribromomethyl)quinoxaline Chemical compound C1=CC=CC2=NC(C(Br)(Br)Br)=CN=C21 VCCOPRMZNNMFLI-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 3
- 206010070834 Sensitisation Diseases 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 229910052792 caesium Inorganic materials 0.000 description 3
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 230000008313 sensitization Effects 0.000 description 3
- WVJRAJZMOVQFEC-UHFFFAOYSA-N 1,2,3,4-tetrabromo-5,6-dimethylbenzene Chemical group CC1=C(C)C(Br)=C(Br)C(Br)=C1Br WVJRAJZMOVQFEC-UHFFFAOYSA-N 0.000 description 2
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 2
- WYECURVXVYPVAT-UHFFFAOYSA-N 1-(4-bromophenyl)ethanone Chemical compound CC(=O)C1=CC=C(Br)C=C1 WYECURVXVYPVAT-UHFFFAOYSA-N 0.000 description 2
- APGGSERFJKEWFG-UHFFFAOYSA-N 1-(chloromethyl)-3-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC(CCl)=C1 APGGSERFJKEWFG-UHFFFAOYSA-N 0.000 description 2
- INOGLHRUEYDAHX-UHFFFAOYSA-N 1-chlorobenzotriazole Chemical compound C1=CC=C2N(Cl)N=NC2=C1 INOGLHRUEYDAHX-UHFFFAOYSA-N 0.000 description 2
- DMESYGCAHWHFCS-UHFFFAOYSA-N 2,2,3,4-tetrachloronaphthalen-1-one Chemical compound C1=CC=C2C(Cl)=C(Cl)C(Cl)(Cl)C(=O)C2=C1 DMESYGCAHWHFCS-UHFFFAOYSA-N 0.000 description 2
- YOYAIZYFCNQIRF-UHFFFAOYSA-N 2,6-dichlorobenzonitrile Chemical compound ClC1=CC=CC(Cl)=C1C#N YOYAIZYFCNQIRF-UHFFFAOYSA-N 0.000 description 2
- BFLBZZSGIIUGIX-UHFFFAOYSA-N 2-(trichloromethyl)-1h-quinazolin-4-one Chemical compound C1=CC=C2NC(C(Cl)(Cl)Cl)=NC(=O)C2=C1 BFLBZZSGIIUGIX-UHFFFAOYSA-N 0.000 description 2
- OFZJESMXFWZEAW-UHFFFAOYSA-N 2-chloro-1-(chloromethyl)-4-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=C(CCl)C(Cl)=C1 OFZJESMXFWZEAW-UHFFFAOYSA-N 0.000 description 2
- SEXXECWFJRNWMX-UHFFFAOYSA-N 2-methyl-2-(tribromomethyl)-1h-quinoline Chemical compound C1=CC=C2C=CC(C)(C(Br)(Br)Br)NC2=C1 SEXXECWFJRNWMX-UHFFFAOYSA-N 0.000 description 2
- HLHNOIAOWQFNGW-UHFFFAOYSA-N 3-bromo-4-hydroxybenzonitrile Chemical compound OC1=CC=C(C#N)C=C1Br HLHNOIAOWQFNGW-UHFFFAOYSA-N 0.000 description 2
- CQQSQBRPAJSTFB-UHFFFAOYSA-N 4-(bromomethyl)benzoic acid Chemical compound OC(=O)C1=CC=C(CBr)C=C1 CQQSQBRPAJSTFB-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- VRLDVERQJMEPIF-UHFFFAOYSA-N dbdmh Chemical compound CC1(C)N(Br)C(=O)N(Br)C1=O VRLDVERQJMEPIF-UHFFFAOYSA-N 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- MHQOURYMHSSLDM-UHFFFAOYSA-M 1,1'-diethyl-2,2'-cyanine chloride Chemical compound [Cl-].C1=CC2=CC=CC=C2N(CC)C1=CC1=CC=C(C=CC=C2)C2=[N+]1CC MHQOURYMHSSLDM-UHFFFAOYSA-M 0.000 description 1
- TYIOVYZMKITKRO-UHFFFAOYSA-N 2-[hexadecyl(dimethyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O TYIOVYZMKITKRO-UHFFFAOYSA-N 0.000 description 1
- RTESDSDXFLYAKZ-UHFFFAOYSA-N 2-bromo-2,3-dihydro-1h-inden-1-ol Chemical compound C1=CC=C2C(O)C(Br)CC2=C1 RTESDSDXFLYAKZ-UHFFFAOYSA-N 0.000 description 1
- LDLCZOVUSADOIV-UHFFFAOYSA-N 2-bromoethanol Chemical compound OCCBr LDLCZOVUSADOIV-UHFFFAOYSA-N 0.000 description 1
- VRGCYEIGVVTZCC-UHFFFAOYSA-N 3,4,5,6-tetrachlorocyclohexa-3,5-diene-1,2-dione Chemical compound ClC1=C(Cl)C(=O)C(=O)C(Cl)=C1Cl VRGCYEIGVVTZCC-UHFFFAOYSA-N 0.000 description 1
- ZGIKWINFUGEQEO-UHFFFAOYSA-N 3-bromoquinoline Chemical compound C1=CC=CC2=CC(Br)=CN=C21 ZGIKWINFUGEQEO-UHFFFAOYSA-N 0.000 description 1
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
- VOLRSQPSJGXRNJ-UHFFFAOYSA-N 4-nitrobenzyl bromide Chemical compound [O-][N+](=O)C1=CC=C(CBr)C=C1 VOLRSQPSJGXRNJ-UHFFFAOYSA-N 0.000 description 1
- WGOLHUGPTDEKCF-UHFFFAOYSA-N 5-bromopyridin-2-amine Chemical compound NC1=CC=C(Br)C=N1 WGOLHUGPTDEKCF-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229940090898 Desensitizer Drugs 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 206010034960 Photophobia Diseases 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 description 1
- 229960001748 allylthiourea Drugs 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- FPOIHTHYDSFYCY-UHFFFAOYSA-N cesium;[[[[[[($l^{1}-boranyl-$l^{2}-boranyl)-$l^{2}-boranyl]-$l^{2}-boranyl]sulfanyl-$l^{2}-boranyl]-$l^{2}-boranyl]-$l^{2}-boranyl]-$l^{2}-boranyl]boron(1-) Chemical compound [Cs+].[B][B][B][B]S[B][B][B][B][B-] FPOIHTHYDSFYCY-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002473 indoazoles Chemical class 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 150000002497 iodine compounds Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 208000013469 light sensitivity Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002483 medication Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- KGCNHWXDPDPSBV-UHFFFAOYSA-N p-nitrobenzyl chloride Chemical compound [O-][N+](=O)C1=CC=C(CCl)C=C1 KGCNHWXDPDPSBV-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 150000003252 quinoxalines Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000004043 responsiveness Effects 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- YFDSDPIBEUFTMI-UHFFFAOYSA-N tribromoethanol Chemical compound OCC(Br)(Br)Br YFDSDPIBEUFTMI-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/485—Direct positive emulsions
- G03C1/48515—Direct positive emulsions prefogged
- G03C1/48523—Direct positive emulsions prefogged characterised by the desensitiser
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
è«æ±ã®ç¯å²
ïŒ æ¬è³ªçã«(1)ã³ãã€ãçµåå€äžã§ããã²ã³åé
ã®æ²æŸ±ãçæãããããšã(2)åŸãããä¹³å€ããã¶
ãããããšã(3)ææ©ããã²ã³ååç©ãæ·»å ããã
ãšããããŠ(4)æ¯æäœäžã«ãã®ä¹³å€ãã³ãŒãã€ã³ã°
ããããšã®å段éãããªããããã(3)ã®æ®µéåŸã§
ãããŠ(4)ã®æ®µéã®åã«ä¹³å€ãçæãããŠãã¶ãäž
å¿ãšã®ææ©ããã²ã³ååç©ã®ç±åå¿ãä¿é²ããã
ããã«ãã€ãŠææ©ããã²ã³ååç©ãéå ãããã
ãŠãã¶ãäžå¿ãéšåçã«é žåãããŠåªããé床ã
ãã³å®å®æ§ã®ä¹³å€ãçæãããããšãç¹åŸŽãšã
ããçŽæ¥éœç»ããã²ã³åéåçä¹³å€ã®è£œé æ¹æ³ã ïŒ ææ©ããã²ã³ååç©ãèçŽ ãŸãã¯å¡©çŽ å«æå
åç©ã§ãããåèšç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ ææ©ããã²ã³ååç©ãïŒâã¯ããâïŒâãã
ããã³ãžã«ã¯ããªããïŒã»ïŒã»ïŒã»ïŒâããã©ã¯
ãããããâïŒâãªã³ãïŒã»ïŒâãã¹ïŒããªã¯ã
ãã¡ãã«ïŒâãã³ãŒã³ãããªããã¢é ¢é žãããã©
ã¯ãã«âãªã«ããã³ãŸããã³ãïŒã»ïŒâãžããã¢
âïŒã»ïŒâãžã¡ãã«ããã³ãã€ã³ãïŒâã¯ããã
ã³ãŸããªã¢ãŸãŒã«ãαâããã¢âïœâãã«ã€ã«
é žãïŒâããªã¯ããã¡ãã«âïŒïŒ3HïŒâãããŸãª
ãã³ãïœâããã¢ã¢ã»ãããšãã³ãïœâãããã
ã³ãžã«ã¯ããªããïŒâããªããã¢ã¡ãã«ããã«ãž
ã³ãïŒã»ïŒâãžã¯ãããã³ãŸãããªã«ãïŒâããª
ããã¢ã¡ãã«ãããªã³ãïŒâãžããã¢ã¡ãã«ãã
ãªã³ãïŒâããªããã¢ã¡ãã«ããããµãªã³ããã³
αã»Î±ã»Î±â²ã»Î±â²âããã©ããã¢ãã·ã¬ã³ãããª
ã矀ããéžã°ãããã®ã§ãããåèšç¬¬ïŒé èšèŒã®
æ¹æ³ã ïŒ ææ©ããã²ã³ååç©ãä¹³å€äžã®ããã²ã³åé
ïŒã¢ã«åœãã0.015ã0.50ïœã®éã§ãã¶ãä¹³å€ã«
å ãããããåèšç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ çæãææ©ããã²ã³ååç©ãå«æãããã¶ã
ä¹³å€ã45ã65âã®æž©åºŠã«10ã120åå ç±ããããš
ã«ããå®æœããããåèšç¬¬ïŒé èšèŒã®æ¹æ³ã æè¡åé æ¬çºæã¯åçæè¡ã®åéã«é¢ãããããŠæŽã«è©³
ããã¯çŽæ¥éœç»ïŒããžãã€ãïŒããã²ã³åéä¹³å€
æè¡ã«é¢ããã èæ¯æè¡ åŸæ¥æè¡ã¯ããç®çã«å¯ŸããŠã¯å ç»å圢ææ³ã
ãã³çµæç©äžã§ææ©ããã²ã³ååç©ãæçšã§ãã
ããšãæ瀺ããŠãããäŸãã°ç±³åœç¹èš±ç¬¬3632340
å·æ现æžã¯ãçŽæ¥éœç»ä¹³å€äžã«ãããã»ã³ã·ãã¡
ããªãŒã®äžæã®ããã«ããã¢ãµã¯ã·ã³ã€ãããã
ã³ïŒã»1â²âãžãšãã«âïŒã»2â²âã·ã¢ãã³ã¯ããªã
ææãæ··åããããšãæ瀺ããŠãããæŸå°æåæ§
ååç©ã«ããéå§ãããå Žåã®éé¢ã©ãžã«ã«çæ
ã®ããã«å éåæ§çæç©äžã§æçšã§ãããã®ãšã
ãŠãããã¢ãµã¯ã·ã³ã€ãã以å€ã®ä»ã®ææ©ããã²
ã³ååç©ãç±³åœç¹èš±ç¬¬3495987å·æ现æžäžã«é瀺
ãããŠãããæ¥æ¬ç¹èš±ç¬¬919049å·æ现æžã«ã¯ãæ
æ©ããã²ã³ååç©ãå ã«é²å ããããšããã²ã³ã
éé¢ããŠçŽæ¥éœç»ä¹³å€ã®æ床ãäžæãããããšã
é瀺ããŠããã æ¬çºæã¯åŸæ¥æè¡ãè¶ããé²æ©ã§ããããããŠ
ããã¯çŽæ¥éœç»ããã²ã³åéåçãšã¬ã¡ã³ãã«ã
ãçš®ã®ææ©ããã²ã³ååç©ãæ·»å ããããšãããª
ãããããã®æ·»å 段éãçæïŒdigestionïŒæ®µé
ã®åã«ããããšãç¹åŸŽãšããæ¹æ³ã«é¢ãããæ¬æ
现æžäžã§ã¯ããçæãã®è¡šçŸã¯ãåè¿°ãããããª
ææ©ããã²ã³ååç©ã®äžã€ãå«æããçŽæ¥éœç»ã
ãã²ã³åéä¹³å€ããã®ææ©ããã²ã³ååç©ãããŠ
ä¹³å€äžã®éãã¶ãäžå¿ãéžæçã«é žåããããã«
å åãªæéããã³å åãªæž©åºŠã«å ç±ããããããª
æ¹æ³ãæå³ããããã«äœ¿çšãããŠããããã®çµæ
ãšããŠå®å®æ§ã«æªåœ±é¿ãäžããããšãªãã«ä¹³å€ã®
å æåæ§ãå¢å€§ããããããã çºæã®æŠèŠ åªããæ床ããã³å®å®æ§ã®çŽæ¥éœç»ããã²ã³å
éåçä¹³å€ããæ¬è³ªçã«(1)ã³ãã€ãçµåå€äžã§ã
ãã²ã³åéã®æ²æŸ±ãçæãããããšã(2)åŸããã
ä¹³å€ããã¶ãããããšã(3)ææ©ããã²ã³ååç©ã
æ·»å ããããšããããŠ(4)æ¯æäœäžã«ãã®ä¹³å€ãã³
ãŒãã€ã³ã°ããããšã®å段éãããªãããããŠ(3)
ã®æ®µéã§ããã(4)ã®æ®µéã®åã«ä¹³å€ãçæãããŠ
ãã¶ãäžå¿ãšã®ææ©ããã²ã³ååç©ã®ç±åå¿ãä¿
é²ãããããã«ãã€ãŠææ©ããã²ã³ååç©ãéå
ãããããŠãã¶ãäžå¿ãéšåçã«é žåãããããš
ãç¹åŸŽãšããæ¹æ³ã«ãã€ãŠè£œé ãããã çºæã®è©³çŽ°ãªèšè¿° åçç§åŠã®åéã«ãããŠã¯ãããé«ãæ床ã«å¯Ÿ
ããç 究ã¯çµ¶ããããšãªãã€ã¥ããã®ã§ãããçŽ
æ¥éœç»ä¹³å€ã¯åçã®åéã«ãããŠã¯ãããäžè¬ç
ãªé°ç»çã«åãä¹³å€ãããæ°ãããã®ã§ããã
ãããã®ãããªä¹³å€ã®å¢æã¯ãã»ã©äºèŠå¯èœã§ã¯
ãªãããŸããé°ç»çã«åãåéããã®çºèŠã¯çŽæ¥
éœç»åéã«ã¯å¿ ãããé©çšãããªãããšãèŠåºã
ããŠãããäŸãã°ãã³ãã€ãçµåå€ãååºå€ãã
ã³ç²åçé·å€ã®ãããªèŠçŽ ã¯äž¡åéã«çããé©çš
ã§ããããã©ããäžè¬çå¢æå€ãã¹ãã¯ãã«å¢æ
å€ïŒäŸãã°ææïŒããã³ãã¶ãé²æ¢å€ã®ãããªã
ã®ãèæ ®ããå Žåã«ã¯åŸåŸã«ããŠå察ã®å¹æãå
åšãããæ¬çºæã¯ãæ¿åºŠåŸé ããããæ¿åºŠããã³
解åæ§ãäžåœã«ç æ§ã«ããããšãªããããŠåŠæ¹å€
æŽã®å¿ èŠãªãã«ãçŽæ¥éœç»ããã²ã³åéå æåæ§
ãšã¬ã¡ã³ãã®ã»ã³ã·ãã¡ããªãŒæ床å¿çæ§ãäžæ
ãããæ段ãæäŸããã®ã§ãããDmaxãŸãã¯ã³
ã³ãã©ã¹ãã«åœ±é¿ãäžããããšãªãã«æ床ãïŒã®
ãã¢ã¯ã¿ãŒã ãäžæãããããšãã§ããããã®æ
床äžæ床ã¯ãããã²ã³åéç²åçé·ã®å€åãç²å
ã®éå±ããŒãã³ã°ãããã³æ°ããå¢æããã³æžæ
æææ§é äœããã³ææçµåãã®äœ¿çšãå å«ããã
ã®ä»ã®æ床äžææ段ã«æ¯ã¹ãŠé©ãã¹ããã®ã§ã
ãã æãæå¹ã§ããããšã®èŠåºãããŠããããã²ã³
眮æäœã¯èçŽ ããã³å¡©çŽ ã§ãããæ²çŽ ååç©ã¯æ
å¹ã§ãããšã¯ç€ºãããŠããªãããããŠåŒçŽ ååç©
ã¯éåå¿æ§ååç©çŸ€ãè¡šãããŠãããèçŽ ãŸãã¯
å¡©çŽ ãçµåããŠããææ©ååã¯é©åœãªæ äœãšããŠ
åããªããŠã¯ãªããããããŠææå°æ©ã®éé¢ãå
解ãŸãã¯æ°åãå¯èœãªããããŠã¯ãªããªããäœæ
ãªãã°ãããã®ããšã¯åçæ床ã®ææã®å¢åŒ·ãç¡
å¹ã«ããããã§ãããäŸãã°ãé«åºŠã«æ®çºæ§ã®å
åç©ã®äœ¿çšã«éããŠã¯æ°ããå¶åŸ¡ãŸãã¯ç°å¢ä¿è·
è£ çœ®ãåŸã ã«ããŠå¿ èŠãšãªãããããæ¬çºæã®å
åç©ã¯ãã®ãããªäžå©ç¹ã¯æããŠããªãããã®ä»£
ãã«åŒ±é žæ§å€ãšããŠç¹æ§ã¥ããããšã®ã§ãããã
ãææ©ããã²ã³ååç©ã®ãã®æçšæ§ã¯ãç±åŠçã
ãªãã¡çæã®éã«ä¹³å€ãšåå¿ããŠåŒ±é žåæ§æåã
éå ããããšããç±æ¥ãããã®ã§ãããããŠåŸã€
ãŠçæã®éã«ãã以äžã®æ§è³ªã®å€åã¯çããªãã å®éçéå®ã®çµæãšããŠãçŽæ¥éœç»åçç³»ã«ã
ã€ãŠç¹ã«æå¹ãªææ©ããã²ã³ååç©ã®æŽ»æ§ã¯å®éš
çã«æ±ºå®ãããªããŠã¯ãªããªããšããããšã課ã
ãããŠãããæ¬çºæã®ç¹ã«æå¹ãªååç©ã¯äžèšã
ãªãã¡ ïŒâã¯ããâïŒâããããã³ãžã«ã¯ããªãã ïŒã»ïŒã»ïŒã»ïŒâããã©ã¯ãããããâïŒâãª
ã³ã ïŒã»ïŒâãã¹ïŒããªã¯ããã¡ãã«ïŒâãã³ãŒ
ã³ã ããªããã¢é ¢é žã ãã©ã¯ãã«âãªã«ããã³ãŸããã³ã ïŒã»ïŒâãžããã¢âïŒã»ïŒâãžã¡ãã«ããã³ã
ã€ã³ã ïŒâã¯ãããã³ãŸããªã¢ãŸãŒã«ã αâããã¢âïœâãã«ã€ã«é žã ïŒâããªã¯ããã¡ãã«âïŒïŒ3HïŒâãããŸãªã
ã³ã ïœâããã¢ã¢ã»ãããšãã³ã ïœâããããã³ãžã«ã¯ããªãã ïŒâããªããã¢ã¡ãã«ããã«ãžã³ã ïŒã»ïŒâãžã¯ãããã³ãŸãããªã«ã ïŒâããªããã¢ã¡ãã«ãããªã³ã ïŒâãžããã¢ã¡ãã«ãããªã³ã ïŒâããªããã¢ã¡ãã«ãããã¶ãªã³ããã㳠αã»Î±ã»Î±â²ã»Î±â²âããã©ããã¢ãã·ã¬ã³ ã§ãããããã«å¯Ÿç §çã«ãããã¢ãµã¯ã·ã³é žã€ã
ããïœâããããã³ãžã«ãããããïŒâããã¢â
ïŒâã€ã³ãããŒã«ãïŒâããã¢ãããªã³ãïœâã
ãããã³ãžã«ã¯ããªããïŒâã¢ããâïŒâããã¢
âããªãžã³ãããã³ïŒâããã¢ãšã¿ããŒã«ã¯ãã
ãååç©ãå«æããªãå¯Ÿç §ã«æ¯ã¹ãŠå©ç¹ã瀺ããª
ãã€ãã æ¬çºæã«ããäžããããçŽæ¥éœç»å æåæ§ã®å¢
倧ã¯ãä¹³å€äžã«ææ©ããã²ã³ååç©ãå ããããŠ
ãããçæããããšããç°¡åãªæ®µéããåŸãã
ãããã®çŽæ¥çã¢ãããŒãã®çµæãšããŠããã®æ
è¡ã䜿çšããŠæ¢åã®çŽæ¥éœç»ä¹³å€åŠæ¹ããã以äž
ä¿®æ£ããå¿ èŠãªãã«ææã®æ床äžæãåŸãããšã
å¯èœã§ãããããã«å¯Ÿç §çã«ãæ床äžæã®ããã®
ãã®ä»ã®æè¡ã¯éåžžæ床äžææ段ã«äŒŽãªããã®ä»
ã®å€åããã³ä¿®æ£ãå¿ èŠãšãããäŸãã°æ°ããç²
åã®æäŸã®ããã«ã¯ãä¹³å€ã®çæïŒripeningïŒã
ä¹³å€ã®æŽæµãå¢æããã³å®å®å段éã®å€åãä¹³å€
ã®ã³ãŒãã€ã³ã°ããã³ä¹Ÿç¥ãå¯èœãªãããããã
ã®è£å©æ·»å å€ã®äœ¿çšãã®ä»ãå¿ èŠãšããããæ°èŠ
ãªãŸãã¯æ¹åãããææã¯ä»¥åã«äœ¿çšãããŠãã
å¢ææè¡ãšã¯éå ±åæ§ã§ãããããããªãã æ¬çºæã¯åäžãžãšããããã³äºéãžãšããæ²æŸ±
æè¡ã®äž¡æ¹ã«ããçæãããããã²ã³åéç²åã«
é¢ããŠäœ¿çšå¯èœã§ãã€ãŠããããåæ£ããã³åäž
åæ£ç²åãµã€ãºååžãçæãããããã®ãããªæ¢
ç¥ã®æè¡ã«ãã補é ãããç²åäžã«éå±ã€ãªã³ã
å°å ¥ããŠãåçå¿çæ§ãä¿®æ£ãããããŠïŒãŸãã¯
ãã¶ãå€ãšããŠäœçšãããããšãã§ãããééå±
ããã³ãã®ååç©ããŸã䜿çšããŠãç©çççæ
ïŒripeningïŒã®éã«ç²åããã¶ããããããŠäºå
調æŽãããããšãã§ããããŸãã¯ããã«ä»£ããã¶
ãæ©æ§ãšããŠç²åã掻æ§ç·ç §å°ã«é²å ãããããš
ãã§ãããããå Žåã«ã¯ãååŠçã«å€æ§ãããç²
åãæŽæµãããããŠæåã®ç²åäžã«ããã²ã³åé
ã®å±€ãæ²æŸ±ãããããšã«ãã€ãŠç²åãµã€ãºãæŽã«
å¢å€§ãããããšãæãŸãããããããªãããã³ã¢
âã·ãšã«ãç²åãªãèªã¯ãã®ãããªå±€ç¶ç²åã«é©
çšãããŠããã æ¬çºæã«ãããŠã¯ãåŸæ¥æè¡ã«ãããããã«ã
䜿çšããããã¶ãå€ã®ã¿ã€ãããã³ãã¶ãçšåºŠã®
äž¡æ¹ãæ¿åºŠãPHãpAgã枩床ããã³åŠçæéã«äŸ
åããŠãããè¡šé¢ããã³å éšäž¡æ¹ã®ãã¶ãäžå¿ã
çŽæ¥éœç»ä¹³å€ã«å¯ŸããŠæ©èœçã§ããããšãèªãã
ããŠããããã¶ãã«é©åœãªéå±ãšããŠã¯éãé«ã
éããã©ãžãŠã ããã³ã€ãªãžãŠã ããããããã
é©åœãªééå±ååç©ãšããŠã¯ã¢ãã³ããã©ã³ãã
ãã©ãžã³ãããªå°¿çŽ ãžãªããµã€ãããã«ã ã¢ã«ã
ããããã³ã¢ãªã«ããªå°¿çŽ ããããããã ãã¶ãåå¿ãå®äºããããææ©ããã²ã³ååç©
ããã®ä¹³å€ã«å ããããšãã§ãããããŠãã®ç³»ã
é«æž©ã«ä¿æããŠé žåâéå åå¿ãå®æœããŠããã
å®äºã«åãããã æ¬çºæã®ææ©ããã²ã³ååç©ã¯äŸãã°ç±³åœç¹èš±
第3615643å·ãå第3583870å·ãå第3867149å·ã
å第3898216å·ããã³å第3747986å·æ现æžã«é瀺
ããããã®ãå«ããŠçŽæ¥éœç»ä¹³å€ã«æçšã§ããã
ãšãç¥ãããŠããææã®ååšäžã«æ©èœããããã
ãææã¯çŽæ¥éœç»ããã²ã³åéä¹³å€ã®å¿çæ§ãäž
æãããæžæå€ãšããŠæçšã§ããããããæžææ
æãšå ±ã«äœ¿çšããå Žåã«æçšã§ã¯ããããã©ãã
æ¬çºæã¯ãŸããããã®äžååšäžã§ãæ©èœãããç¹
ã«ãé»åå容æ§ã§ã¯ãªãå¢æææäŸãã°åäžãã
ã³è€åã·ã¢ãã³ãã¡ãã·ã¢ãã³ãã¹ããªã«ããã³
ããã·ã¢ãã³é¡ããŸãä¹³å€äžã«ååšãããããšã
ã§ããã æ¬çºææžã«èšèŒã®çŽæ¥éœç»ããã²ã³åéä¹³å€ã®
ããã²ã³åéæåã¯çŽç²ã§ããããŸãã¯æ··åãã
ãéå¡©åç©ãèåç©ãŸãã¯æ²åç©ããæ§æããã
ãã®ã§ããããããããŠãã®ç²åã¯ãã®åœ¢ç¶ãèŠ
åçãŸãã¯äžèŠåãªãã®ã§ããããšãã§ããäŸã
ã°ç«æ¹äœãå «é¢äœãææ¹å é¢äœãã®ä»ã§ããã
ããç±³åœç¹èš±åºé¡ç¬¬972972å·æ现æžèšèŒã®æ°èŠãª
ä¹³å€ããŸãæ¬çºæã®å®æœã«æçšã§ããããããä¹³
å€ã«å¯Ÿããçµåå€ããã³ããã¿ã€ã¶ãŒåªäœãšããŠ
ã¯ãŒã©ãã³ã䜿çšããããšãäžè¬çã§ããããã
ããã®ãŒã©ãã³ãäžéšãŸãã¯å šäœçã«åœæè¡åé
ã§ã¯æ¢ç¥ã®ãã®ä»ã®å€©ç¶ãŸãã¯åæä¿è·ã³ãã€ã
ã§çœ®æããããšãã§ãããä»ã®æçšãªæ·»å å€ãšã
ãŠã¯ãäŸãã°ããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã®ãããª
æ床å¢å€§äœçšååç©ã³ãŒãã€ã³ã°å©å€ãšããŠæçš
ãªè¡šé¢æŽ»æ§å€ããã¶ãé²æ¢å€ãããã³ã€ã³ããŸãŒ
ã«ãã€ãããŸãŒã«ãã¢ã¶ã€ã³ãã³ãæ°Žéããã³ã
ãªããããã·ãã³ãŒã³ååç©ãå«ãå®å®å€ããã
ãããã çŽæ¥éœç»ä¹³å€ã«å¯Ÿãããã®ä»ã®æçšãªæåãšã
ãŠã¯ã硬èå€ã垯é»é²æ¢å€ãè¶æ¶å€ãå¯å¡å€ãæ
è²åå€ããã³å€©ç¶ããã³åæã®æ¹¿æœ€å€ããããã
ããããããã¹ãŠã®æçšãªæåãçµåããŠãé©åœ
ãªæ¯æäœäŸãã°ã»ã«ããŒã¹ãã€ãã¬ãŒããã€ã«
ã ãã»ã«ããŒã¹ãšã¹ãã«ãã€ã«ã ãããªããã«ã¢
ã»ã¿ãŒã«ãã€ã«ã ãããªã¹ãã¬ã³ãã€ã«ã ãããª
ïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒãã€ã«ã ããã³é¢ä¿
ãããã€ã«ã ãŸãã¯æš¹èç©è³ªäŸãã°ã¬ã©ã¹ãçŽã
éå±ãã®ä»ã«ã³ãŒãã€ã³ã°ããããšã®ã§ããåŠæ¹
ãçæãããããšãã§ããã æ¬çºæã次ã®å®æœäŸã«ãã説æããã äŸ ïŒ 1.0ïŒ ãšãŒãã€ãããã³0.01ïŒ ããžãŠã ãå«æ
ããããžãŠã ããŒããããååæ£ç«æ¹äœç¶Ag
ïŒïŒBrä¹³å€ãã8.2ã®pAgãä¿ã¡ã€ã€ããã©ã³ã¹
ããã«ãžãšããæ²æŸ±æè¡ã«ãã補é ãããç©çç
çæã®å®äºåŸããã®ä¹³å€ãããªããã«ã¢ã«ã³ãŒã«
ïœâã¹ã«ããã³ãºã¢ã«ãããã¢ã»ã¿ãŒã«ã§ååºã
ãããããŠéå°ã®ãã©ã€ãå¡©ãåŸçããé€å»ã
ããæŽã€ãä¹³å€ããŒã©ãã³äžã§ååæ£ããããPH
ã7.5ã«èª¿æŽããããŠpAgã8.0ã«èª¿æŽããããã
ã²ã³åéïŒã¢ã«åœã2.4Ã10-7ã¢ã«ã®ã»ã·ãŠã ã
ãªãã«ãã©ã³ããã³3.1Ã10-6ã¢ã«ã®å¡©é žå®å®å
ãããå¡©åéãå ããããšã«ãããã®ä¹³å€ããã¶
ãããã72âã«ãããŠïŒæéçæãããåŸãä¹³å€
ã35âã«å·åŽããããŠã»ã«ããã¿ã€ã³ãã³ãŒãã€
ã³ã°å©å€ãšããŠå ããã ä¹³å€ãããã€ãã®åºåéã«åå²ããããŠæ¬¡ã®è¡š
ïŒã®ãããªæ·»å ãå®æœããã
ã®æ²æŸ±ãçæãããããšã(2)åŸãããä¹³å€ããã¶
ãããããšã(3)ææ©ããã²ã³ååç©ãæ·»å ããã
ãšããããŠ(4)æ¯æäœäžã«ãã®ä¹³å€ãã³ãŒãã€ã³ã°
ããããšã®å段éãããªããããã(3)ã®æ®µéåŸã§
ãããŠ(4)ã®æ®µéã®åã«ä¹³å€ãçæãããŠãã¶ãäž
å¿ãšã®ææ©ããã²ã³ååç©ã®ç±åå¿ãä¿é²ããã
ããã«ãã€ãŠææ©ããã²ã³ååç©ãéå ãããã
ãŠãã¶ãäžå¿ãéšåçã«é žåãããŠåªããé床ã
ãã³å®å®æ§ã®ä¹³å€ãçæãããããšãç¹åŸŽãšã
ããçŽæ¥éœç»ããã²ã³åéåçä¹³å€ã®è£œé æ¹æ³ã ïŒ ææ©ããã²ã³ååç©ãèçŽ ãŸãã¯å¡©çŽ å«æå
åç©ã§ãããåèšç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ ææ©ããã²ã³ååç©ãïŒâã¯ããâïŒâãã
ããã³ãžã«ã¯ããªããïŒã»ïŒã»ïŒã»ïŒâããã©ã¯
ãããããâïŒâãªã³ãïŒã»ïŒâãã¹ïŒããªã¯ã
ãã¡ãã«ïŒâãã³ãŒã³ãããªããã¢é ¢é žãããã©
ã¯ãã«âãªã«ããã³ãŸããã³ãïŒã»ïŒâãžããã¢
âïŒã»ïŒâãžã¡ãã«ããã³ãã€ã³ãïŒâã¯ããã
ã³ãŸããªã¢ãŸãŒã«ãαâããã¢âïœâãã«ã€ã«
é žãïŒâããªã¯ããã¡ãã«âïŒïŒ3HïŒâãããŸãª
ãã³ãïœâããã¢ã¢ã»ãããšãã³ãïœâãããã
ã³ãžã«ã¯ããªããïŒâããªããã¢ã¡ãã«ããã«ãž
ã³ãïŒã»ïŒâãžã¯ãããã³ãŸãããªã«ãïŒâããª
ããã¢ã¡ãã«ãããªã³ãïŒâãžããã¢ã¡ãã«ãã
ãªã³ãïŒâããªããã¢ã¡ãã«ããããµãªã³ããã³
αã»Î±ã»Î±â²ã»Î±â²âããã©ããã¢ãã·ã¬ã³ãããª
ã矀ããéžã°ãããã®ã§ãããåèšç¬¬ïŒé èšèŒã®
æ¹æ³ã ïŒ ææ©ããã²ã³ååç©ãä¹³å€äžã®ããã²ã³åé
ïŒã¢ã«åœãã0.015ã0.50ïœã®éã§ãã¶ãä¹³å€ã«
å ãããããåèšç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ çæãææ©ããã²ã³ååç©ãå«æãããã¶ã
ä¹³å€ã45ã65âã®æž©åºŠã«10ã120åå ç±ããããš
ã«ããå®æœããããåèšç¬¬ïŒé èšèŒã®æ¹æ³ã æè¡åé æ¬çºæã¯åçæè¡ã®åéã«é¢ãããããŠæŽã«è©³
ããã¯çŽæ¥éœç»ïŒããžãã€ãïŒããã²ã³åéä¹³å€
æè¡ã«é¢ããã èæ¯æè¡ åŸæ¥æè¡ã¯ããç®çã«å¯ŸããŠã¯å ç»å圢ææ³ã
ãã³çµæç©äžã§ææ©ããã²ã³ååç©ãæçšã§ãã
ããšãæ瀺ããŠãããäŸãã°ç±³åœç¹èš±ç¬¬3632340
å·æ现æžã¯ãçŽæ¥éœç»ä¹³å€äžã«ãããã»ã³ã·ãã¡
ããªãŒã®äžæã®ããã«ããã¢ãµã¯ã·ã³ã€ãããã
ã³ïŒã»1â²âãžãšãã«âïŒã»2â²âã·ã¢ãã³ã¯ããªã
ææãæ··åããããšãæ瀺ããŠãããæŸå°æåæ§
ååç©ã«ããéå§ãããå Žåã®éé¢ã©ãžã«ã«çæ
ã®ããã«å éåæ§çæç©äžã§æçšã§ãããã®ãšã
ãŠãããã¢ãµã¯ã·ã³ã€ãã以å€ã®ä»ã®ææ©ããã²
ã³ååç©ãç±³åœç¹èš±ç¬¬3495987å·æ现æžäžã«é瀺
ãããŠãããæ¥æ¬ç¹èš±ç¬¬919049å·æ现æžã«ã¯ãæ
æ©ããã²ã³ååç©ãå ã«é²å ããããšããã²ã³ã
éé¢ããŠçŽæ¥éœç»ä¹³å€ã®æ床ãäžæãããããšã
é瀺ããŠããã æ¬çºæã¯åŸæ¥æè¡ãè¶ããé²æ©ã§ããããããŠ
ããã¯çŽæ¥éœç»ããã²ã³åéåçãšã¬ã¡ã³ãã«ã
ãçš®ã®ææ©ããã²ã³ååç©ãæ·»å ããããšãããª
ãããããã®æ·»å 段éãçæïŒdigestionïŒæ®µé
ã®åã«ããããšãç¹åŸŽãšããæ¹æ³ã«é¢ãããæ¬æ
现æžäžã§ã¯ããçæãã®è¡šçŸã¯ãåè¿°ãããããª
ææ©ããã²ã³ååç©ã®äžã€ãå«æããçŽæ¥éœç»ã
ãã²ã³åéä¹³å€ããã®ææ©ããã²ã³ååç©ãããŠ
ä¹³å€äžã®éãã¶ãäžå¿ãéžæçã«é žåããããã«
å åãªæéããã³å åãªæž©åºŠã«å ç±ããããããª
æ¹æ³ãæå³ããããã«äœ¿çšãããŠããããã®çµæ
ãšããŠå®å®æ§ã«æªåœ±é¿ãäžããããšãªãã«ä¹³å€ã®
å æåæ§ãå¢å€§ããããããã çºæã®æŠèŠ åªããæ床ããã³å®å®æ§ã®çŽæ¥éœç»ããã²ã³å
éåçä¹³å€ããæ¬è³ªçã«(1)ã³ãã€ãçµåå€äžã§ã
ãã²ã³åéã®æ²æŸ±ãçæãããããšã(2)åŸããã
ä¹³å€ããã¶ãããããšã(3)ææ©ããã²ã³ååç©ã
æ·»å ããããšããããŠ(4)æ¯æäœäžã«ãã®ä¹³å€ãã³
ãŒãã€ã³ã°ããããšã®å段éãããªãããããŠ(3)
ã®æ®µéã§ããã(4)ã®æ®µéã®åã«ä¹³å€ãçæãããŠ
ãã¶ãäžå¿ãšã®ææ©ããã²ã³ååç©ã®ç±åå¿ãä¿
é²ãããããã«ãã€ãŠææ©ããã²ã³ååç©ãéå
ãããããŠãã¶ãäžå¿ãéšåçã«é žåãããããš
ãç¹åŸŽãšããæ¹æ³ã«ãã€ãŠè£œé ãããã çºæã®è©³çŽ°ãªèšè¿° åçç§åŠã®åéã«ãããŠã¯ãããé«ãæ床ã«å¯Ÿ
ããç 究ã¯çµ¶ããããšãªãã€ã¥ããã®ã§ãããçŽ
æ¥éœç»ä¹³å€ã¯åçã®åéã«ãããŠã¯ãããäžè¬ç
ãªé°ç»çã«åãä¹³å€ãããæ°ãããã®ã§ããã
ãããã®ãããªä¹³å€ã®å¢æã¯ãã»ã©äºèŠå¯èœã§ã¯
ãªãããŸããé°ç»çã«åãåéããã®çºèŠã¯çŽæ¥
éœç»åéã«ã¯å¿ ãããé©çšãããªãããšãèŠåºã
ããŠãããäŸãã°ãã³ãã€ãçµåå€ãååºå€ãã
ã³ç²åçé·å€ã®ãããªèŠçŽ ã¯äž¡åéã«çããé©çš
ã§ããããã©ããäžè¬çå¢æå€ãã¹ãã¯ãã«å¢æ
å€ïŒäŸãã°ææïŒããã³ãã¶ãé²æ¢å€ã®ãããªã
ã®ãèæ ®ããå Žåã«ã¯åŸåŸã«ããŠå察ã®å¹æãå
åšãããæ¬çºæã¯ãæ¿åºŠåŸé ããããæ¿åºŠããã³
解åæ§ãäžåœã«ç æ§ã«ããããšãªããããŠåŠæ¹å€
æŽã®å¿ èŠãªãã«ãçŽæ¥éœç»ããã²ã³åéå æåæ§
ãšã¬ã¡ã³ãã®ã»ã³ã·ãã¡ããªãŒæ床å¿çæ§ãäžæ
ãããæ段ãæäŸããã®ã§ãããDmaxãŸãã¯ã³
ã³ãã©ã¹ãã«åœ±é¿ãäžããããšãªãã«æ床ãïŒã®
ãã¢ã¯ã¿ãŒã ãäžæãããããšãã§ããããã®æ
床äžæ床ã¯ãããã²ã³åéç²åçé·ã®å€åãç²å
ã®éå±ããŒãã³ã°ãããã³æ°ããå¢æããã³æžæ
æææ§é äœããã³ææçµåãã®äœ¿çšãå å«ããã
ã®ä»ã®æ床äžææ段ã«æ¯ã¹ãŠé©ãã¹ããã®ã§ã
ãã æãæå¹ã§ããããšã®èŠåºãããŠããããã²ã³
眮æäœã¯èçŽ ããã³å¡©çŽ ã§ãããæ²çŽ ååç©ã¯æ
å¹ã§ãããšã¯ç€ºãããŠããªãããããŠåŒçŽ ååç©
ã¯éåå¿æ§ååç©çŸ€ãè¡šãããŠãããèçŽ ãŸãã¯
å¡©çŽ ãçµåããŠããææ©ååã¯é©åœãªæ äœãšããŠ
åããªããŠã¯ãªããããããŠææå°æ©ã®éé¢ãå
解ãŸãã¯æ°åãå¯èœãªããããŠã¯ãªããªããäœæ
ãªãã°ãããã®ããšã¯åçæ床ã®ææã®å¢åŒ·ãç¡
å¹ã«ããããã§ãããäŸãã°ãé«åºŠã«æ®çºæ§ã®å
åç©ã®äœ¿çšã«éããŠã¯æ°ããå¶åŸ¡ãŸãã¯ç°å¢ä¿è·
è£ çœ®ãåŸã ã«ããŠå¿ èŠãšãªãããããæ¬çºæã®å
åç©ã¯ãã®ãããªäžå©ç¹ã¯æããŠããªãããã®ä»£
ãã«åŒ±é žæ§å€ãšããŠç¹æ§ã¥ããããšã®ã§ãããã
ãææ©ããã²ã³ååç©ã®ãã®æçšæ§ã¯ãç±åŠçã
ãªãã¡çæã®éã«ä¹³å€ãšåå¿ããŠåŒ±é žåæ§æåã
éå ããããšããç±æ¥ãããã®ã§ãããããŠåŸã€
ãŠçæã®éã«ãã以äžã®æ§è³ªã®å€åã¯çããªãã å®éçéå®ã®çµæãšããŠãçŽæ¥éœç»åçç³»ã«ã
ã€ãŠç¹ã«æå¹ãªææ©ããã²ã³ååç©ã®æŽ»æ§ã¯å®éš
çã«æ±ºå®ãããªããŠã¯ãªããªããšããããšã課ã
ãããŠãããæ¬çºæã®ç¹ã«æå¹ãªååç©ã¯äžèšã
ãªãã¡ ïŒâã¯ããâïŒâããããã³ãžã«ã¯ããªãã ïŒã»ïŒã»ïŒã»ïŒâããã©ã¯ãããããâïŒâãª
ã³ã ïŒã»ïŒâãã¹ïŒããªã¯ããã¡ãã«ïŒâãã³ãŒ
ã³ã ããªããã¢é ¢é žã ãã©ã¯ãã«âãªã«ããã³ãŸããã³ã ïŒã»ïŒâãžããã¢âïŒã»ïŒâãžã¡ãã«ããã³ã
ã€ã³ã ïŒâã¯ãããã³ãŸããªã¢ãŸãŒã«ã αâããã¢âïœâãã«ã€ã«é žã ïŒâããªã¯ããã¡ãã«âïŒïŒ3HïŒâãããŸãªã
ã³ã ïœâããã¢ã¢ã»ãããšãã³ã ïœâããããã³ãžã«ã¯ããªãã ïŒâããªããã¢ã¡ãã«ããã«ãžã³ã ïŒã»ïŒâãžã¯ãããã³ãŸãããªã«ã ïŒâããªããã¢ã¡ãã«ãããªã³ã ïŒâãžããã¢ã¡ãã«ãããªã³ã ïŒâããªããã¢ã¡ãã«ãããã¶ãªã³ããã㳠αã»Î±ã»Î±â²ã»Î±â²âããã©ããã¢ãã·ã¬ã³ ã§ãããããã«å¯Ÿç §çã«ãããã¢ãµã¯ã·ã³é žã€ã
ããïœâããããã³ãžã«ãããããïŒâããã¢â
ïŒâã€ã³ãããŒã«ãïŒâããã¢ãããªã³ãïœâã
ãããã³ãžã«ã¯ããªããïŒâã¢ããâïŒâããã¢
âããªãžã³ãããã³ïŒâããã¢ãšã¿ããŒã«ã¯ãã
ãååç©ãå«æããªãå¯Ÿç §ã«æ¯ã¹ãŠå©ç¹ã瀺ããª
ãã€ãã æ¬çºæã«ããäžããããçŽæ¥éœç»å æåæ§ã®å¢
倧ã¯ãä¹³å€äžã«ææ©ããã²ã³ååç©ãå ããããŠ
ãããçæããããšããç°¡åãªæ®µéããåŸãã
ãããã®çŽæ¥çã¢ãããŒãã®çµæãšããŠããã®æ
è¡ã䜿çšããŠæ¢åã®çŽæ¥éœç»ä¹³å€åŠæ¹ããã以äž
ä¿®æ£ããå¿ èŠãªãã«ææã®æ床äžæãåŸãããšã
å¯èœã§ãããããã«å¯Ÿç §çã«ãæ床äžæã®ããã®
ãã®ä»ã®æè¡ã¯éåžžæ床äžææ段ã«äŒŽãªããã®ä»
ã®å€åããã³ä¿®æ£ãå¿ èŠãšãããäŸãã°æ°ããç²
åã®æäŸã®ããã«ã¯ãä¹³å€ã®çæïŒripeningïŒã
ä¹³å€ã®æŽæµãå¢æããã³å®å®å段éã®å€åãä¹³å€
ã®ã³ãŒãã€ã³ã°ããã³ä¹Ÿç¥ãå¯èœãªãããããã
ã®è£å©æ·»å å€ã®äœ¿çšãã®ä»ãå¿ èŠãšããããæ°èŠ
ãªãŸãã¯æ¹åãããææã¯ä»¥åã«äœ¿çšãããŠãã
å¢ææè¡ãšã¯éå ±åæ§ã§ãããããããªãã æ¬çºæã¯åäžãžãšããããã³äºéãžãšããæ²æŸ±
æè¡ã®äž¡æ¹ã«ããçæãããããã²ã³åéç²åã«
é¢ããŠäœ¿çšå¯èœã§ãã€ãŠããããåæ£ããã³åäž
åæ£ç²åãµã€ãºååžãçæãããããã®ãããªæ¢
ç¥ã®æè¡ã«ãã補é ãããç²åäžã«éå±ã€ãªã³ã
å°å ¥ããŠãåçå¿çæ§ãä¿®æ£ãããããŠïŒãŸãã¯
ãã¶ãå€ãšããŠäœçšãããããšãã§ãããééå±
ããã³ãã®ååç©ããŸã䜿çšããŠãç©çççæ
ïŒripeningïŒã®éã«ç²åããã¶ããããããŠäºå
調æŽãããããšãã§ããããŸãã¯ããã«ä»£ããã¶
ãæ©æ§ãšããŠç²åã掻æ§ç·ç §å°ã«é²å ãããããš
ãã§ãããããå Žåã«ã¯ãååŠçã«å€æ§ãããç²
åãæŽæµãããããŠæåã®ç²åäžã«ããã²ã³åé
ã®å±€ãæ²æŸ±ãããããšã«ãã€ãŠç²åãµã€ãºãæŽã«
å¢å€§ãããããšãæãŸãããããããªãããã³ã¢
âã·ãšã«ãç²åãªãèªã¯ãã®ãããªå±€ç¶ç²åã«é©
çšãããŠããã æ¬çºæã«ãããŠã¯ãåŸæ¥æè¡ã«ãããããã«ã
䜿çšããããã¶ãå€ã®ã¿ã€ãããã³ãã¶ãçšåºŠã®
äž¡æ¹ãæ¿åºŠãPHãpAgã枩床ããã³åŠçæéã«äŸ
åããŠãããè¡šé¢ããã³å éšäž¡æ¹ã®ãã¶ãäžå¿ã
çŽæ¥éœç»ä¹³å€ã«å¯ŸããŠæ©èœçã§ããããšãèªãã
ããŠããããã¶ãã«é©åœãªéå±ãšããŠã¯éãé«ã
éããã©ãžãŠã ããã³ã€ãªãžãŠã ããããããã
é©åœãªééå±ååç©ãšããŠã¯ã¢ãã³ããã©ã³ãã
ãã©ãžã³ãããªå°¿çŽ ãžãªããµã€ãããã«ã ã¢ã«ã
ããããã³ã¢ãªã«ããªå°¿çŽ ããããããã ãã¶ãåå¿ãå®äºããããææ©ããã²ã³ååç©
ããã®ä¹³å€ã«å ããããšãã§ãããããŠãã®ç³»ã
é«æž©ã«ä¿æããŠé žåâéå åå¿ãå®æœããŠããã
å®äºã«åãããã æ¬çºæã®ææ©ããã²ã³ååç©ã¯äŸãã°ç±³åœç¹èš±
第3615643å·ãå第3583870å·ãå第3867149å·ã
å第3898216å·ããã³å第3747986å·æ现æžã«é瀺
ããããã®ãå«ããŠçŽæ¥éœç»ä¹³å€ã«æçšã§ããã
ãšãç¥ãããŠããææã®ååšäžã«æ©èœããããã
ãææã¯çŽæ¥éœç»ããã²ã³åéä¹³å€ã®å¿çæ§ãäž
æãããæžæå€ãšããŠæçšã§ããããããæžææ
æãšå ±ã«äœ¿çšããå Žåã«æçšã§ã¯ããããã©ãã
æ¬çºæã¯ãŸããããã®äžååšäžã§ãæ©èœãããç¹
ã«ãé»åå容æ§ã§ã¯ãªãå¢æææäŸãã°åäžãã
ã³è€åã·ã¢ãã³ãã¡ãã·ã¢ãã³ãã¹ããªã«ããã³
ããã·ã¢ãã³é¡ããŸãä¹³å€äžã«ååšãããããšã
ã§ããã æ¬çºææžã«èšèŒã®çŽæ¥éœç»ããã²ã³åéä¹³å€ã®
ããã²ã³åéæåã¯çŽç²ã§ããããŸãã¯æ··åãã
ãéå¡©åç©ãèåç©ãŸãã¯æ²åç©ããæ§æããã
ãã®ã§ããããããããŠãã®ç²åã¯ãã®åœ¢ç¶ãèŠ
åçãŸãã¯äžèŠåãªãã®ã§ããããšãã§ããäŸã
ã°ç«æ¹äœãå «é¢äœãææ¹å é¢äœãã®ä»ã§ããã
ããç±³åœç¹èš±åºé¡ç¬¬972972å·æ现æžèšèŒã®æ°èŠãª
ä¹³å€ããŸãæ¬çºæã®å®æœã«æçšã§ããããããä¹³
å€ã«å¯Ÿããçµåå€ããã³ããã¿ã€ã¶ãŒåªäœãšããŠ
ã¯ãŒã©ãã³ã䜿çšããããšãäžè¬çã§ããããã
ããã®ãŒã©ãã³ãäžéšãŸãã¯å šäœçã«åœæè¡åé
ã§ã¯æ¢ç¥ã®ãã®ä»ã®å€©ç¶ãŸãã¯åæä¿è·ã³ãã€ã
ã§çœ®æããããšãã§ãããä»ã®æçšãªæ·»å å€ãšã
ãŠã¯ãäŸãã°ããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã®ãããª
æ床å¢å€§äœçšååç©ã³ãŒãã€ã³ã°å©å€ãšããŠæçš
ãªè¡šé¢æŽ»æ§å€ããã¶ãé²æ¢å€ãããã³ã€ã³ããŸãŒ
ã«ãã€ãããŸãŒã«ãã¢ã¶ã€ã³ãã³ãæ°Žéããã³ã
ãªããããã·ãã³ãŒã³ååç©ãå«ãå®å®å€ããã
ãããã çŽæ¥éœç»ä¹³å€ã«å¯Ÿãããã®ä»ã®æçšãªæåãšã
ãŠã¯ã硬èå€ã垯é»é²æ¢å€ãè¶æ¶å€ãå¯å¡å€ãæ
è²åå€ããã³å€©ç¶ããã³åæã®æ¹¿æœ€å€ããããã
ããããããã¹ãŠã®æçšãªæåãçµåããŠãé©åœ
ãªæ¯æäœäŸãã°ã»ã«ããŒã¹ãã€ãã¬ãŒããã€ã«
ã ãã»ã«ããŒã¹ãšã¹ãã«ãã€ã«ã ãããªããã«ã¢
ã»ã¿ãŒã«ãã€ã«ã ãããªã¹ãã¬ã³ãã€ã«ã ãããª
ïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒãã€ã«ã ããã³é¢ä¿
ãããã€ã«ã ãŸãã¯æš¹èç©è³ªäŸãã°ã¬ã©ã¹ãçŽã
éå±ãã®ä»ã«ã³ãŒãã€ã³ã°ããããšã®ã§ããåŠæ¹
ãçæãããããšãã§ããã æ¬çºæã次ã®å®æœäŸã«ãã説æããã äŸ ïŒ 1.0ïŒ ãšãŒãã€ãããã³0.01ïŒ ããžãŠã ãå«æ
ããããžãŠã ããŒããããååæ£ç«æ¹äœç¶Ag
ïŒïŒBrä¹³å€ãã8.2ã®pAgãä¿ã¡ã€ã€ããã©ã³ã¹
ããã«ãžãšããæ²æŸ±æè¡ã«ãã補é ãããç©çç
çæã®å®äºåŸããã®ä¹³å€ãããªããã«ã¢ã«ã³ãŒã«
ïœâã¹ã«ããã³ãºã¢ã«ãããã¢ã»ã¿ãŒã«ã§ååºã
ãããããŠéå°ã®ãã©ã€ãå¡©ãåŸçããé€å»ã
ããæŽã€ãä¹³å€ããŒã©ãã³äžã§ååæ£ããããPH
ã7.5ã«èª¿æŽããããŠpAgã8.0ã«èª¿æŽããããã
ã²ã³åéïŒã¢ã«åœã2.4Ã10-7ã¢ã«ã®ã»ã·ãŠã ã
ãªãã«ãã©ã³ããã³3.1Ã10-6ã¢ã«ã®å¡©é žå®å®å
ãããå¡©åéãå ããããšã«ãããã®ä¹³å€ããã¶
ãããã72âã«ãããŠïŒæéçæãããåŸãä¹³å€
ã35âã«å·åŽããããŠã»ã«ããã¿ã€ã³ãã³ãŒãã€
ã³ã°å©å€ãšããŠå ããã ä¹³å€ãããã€ãã®åºåéã«åå²ããããŠæ¬¡ã®è¡š
ïŒã®ãããªæ·»å ãå®æœããã
ãè¡šã
35mgïŒïœm2éã®èåéã§åççŽããªãšã¹ã«ããŒ
ã¹äžã«ãã®è©Šæãã³ãŒãã€ã³ã°ãããææå«æè©Š
æããªãã¡è©Šæãããã³ã10-3ç§éâïŒãŠ
ãšããžãéããŠEGGã»ã³ã·ãã¡ãŒã¿ãŒã§19æ¬ã®
ç·ã®ã³ã³ãã³ã»ãŒã¿ãŒã䜿çšããŠé²å ããããæ
æç¡æ·»å è©Šæããªãã¡è©Šæããã³ã35ãã«ã
ã§äœåãããã¿ã³ã°ã¹ãã³ã©ã³ãïŒGE2Fåçã
ã©ãã750ã¯ããïŒã䜿çšããŠ15ç§éé²å ãã
ãããã¹ãŠã®é²å è©Šæãæšæºçã¡ãŒãã«âããã
ããã³çŸå液äžã§å®€æž©ã§ïŒåéçŸåããé ¢é žåæ¢
济ã«30ç§æµžããæšæºããªç¡«é žå®ç液äžã§ïŒåéå®
çããããŠä¹Ÿç¥ããããçŸå液ã®è©Šæã®å段éã«
ãããå åŠæ¿åºŠãæ¿åºŠèšãçšããŠæž¬å®ããããŠé²
å ã«å¯ŸããŠãããããããè©Šæã¯ä»¥äžã®è¡šïŒã«ç€º
ããããªã»ã³ã·ãã¡ããªãŒå¿çæ§ã瀺ãããè¡š
äžãæ床ã¯0.1å åŠæ¿åºŠïŒïŒ€nioã§æž¬å®ãããŠãã
ãããŠã°ã©ãã€ãšã³ãïŒé調床ïŒã¯æ²ç·ã®çŽç·éš
åã«ã€ããŠæž¬å®ãããã次ã«æž¬å®ãããæ床ãè¡š
ïŒã«ç€ºããããã«çžå¯Ÿæ床ã«æç®ãããnaxã¯
çŸååŸã®ãã€ã«ã çã«ã€ããŠæž¬å®ãããæ倧æ¿åºŠ
ã§ããã
ã¹äžã«ãã®è©Šæãã³ãŒãã€ã³ã°ãããææå«æè©Š
æããªãã¡è©Šæãããã³ã10-3ç§éâïŒãŠ
ãšããžãéããŠEGGã»ã³ã·ãã¡ãŒã¿ãŒã§19æ¬ã®
ç·ã®ã³ã³ãã³ã»ãŒã¿ãŒã䜿çšããŠé²å ããããæ
æç¡æ·»å è©Šæããªãã¡è©Šæããã³ã35ãã«ã
ã§äœåãããã¿ã³ã°ã¹ãã³ã©ã³ãïŒGE2Fåçã
ã©ãã750ã¯ããïŒã䜿çšããŠ15ç§éé²å ãã
ãããã¹ãŠã®é²å è©Šæãæšæºçã¡ãŒãã«âããã
ããã³çŸå液äžã§å®€æž©ã§ïŒåéçŸåããé ¢é žåæ¢
济ã«30ç§æµžããæšæºããªç¡«é žå®ç液äžã§ïŒåéå®
çããããŠä¹Ÿç¥ããããçŸå液ã®è©Šæã®å段éã«
ãããå åŠæ¿åºŠãæ¿åºŠèšãçšããŠæž¬å®ããããŠé²
å ã«å¯ŸããŠãããããããè©Šæã¯ä»¥äžã®è¡šïŒã«ç€º
ããããªã»ã³ã·ãã¡ããªãŒå¿çæ§ã瀺ãããè¡š
äžãæ床ã¯0.1å åŠæ¿åºŠïŒïŒ€nioã§æž¬å®ãããŠãã
ãããŠã°ã©ãã€ãšã³ãïŒé調床ïŒã¯æ²ç·ã®çŽç·éš
åã«ã€ããŠæž¬å®ãããã次ã«æž¬å®ãããæ床ãè¡š
ïŒã«ç€ºããããã«çžå¯Ÿæ床ã«æç®ãããnaxã¯
çŸååŸã®ãã€ã«ã çã«ã€ããŠæž¬å®ãããæ倧æ¿åºŠ
ã§ããã
ãè¡šã
è¡šïŒã¯çŽæ¥éœç»ææã®ååšäžããŸãã¯ãããªã
ã§åæ§ã®æ床äžæãåŸãããšãã§ãããšããããš
ã瀺ããŠããããçµæã¯ãŸããææããã³ããã²
ã³äŸäžååç©ã®å¹æãçžå çã§ããããšã瀺ããŠ
ããã äŸ ïŒ äŸïŒãšåæ§ã«ããŠè£œé ããããŠãã¶ãããä¹³å€
ãïŒåã®çéã«åå²ããã第éšåã«ã¯48.5mgã®
ïŒâããªããã¢ã¡ãã«ãããªã³ããã³ïŒïœã®ã·ã¢
ãã³ææïŒäŸïŒã«èšèŒïŒãããã²ã³åéïŒã¢ã«åœ
ãã«å ããã第éšåã«ã¯ãããã²ã³åéïŒã¢ã«
åœã18.7mgã®ïŒâããªããã¢ã¡ãã«ãããªã³ãå
ããããããä¹³å€ã54âã«30åå ç±ãããå·åŽ
åŸã0.97ïœïŒã¢ã«ã®äŸïŒã§çšãããšåãçŽæ¥éœç»
ææãå ãããè©Šæã35mgAgBrïŒïœm2ã§ã³ãŒã
ã€ã³ã°ãããäž¡è©ŠæããªãŒãã³äžã§ïŒé±é50âïŒ
50ïŒ çžå¯Ÿæ¹¿åºŠã§çµæããããè©Šæã10-3ç§é19æ¬
ã®ç·ã®ã³ã³ãã³ã»ãŒã¿ãŒã䜿çšããŠEGGã»ã³ã·
ãã¡ãŒã¿ãŒã§é²å ãããããŠåèšã®ããã«åŠçã
ãã次ã®çµæãåŸãããã
ã§åæ§ã®æ床äžæãåŸãããšãã§ãããšããããš
ã瀺ããŠããããçµæã¯ãŸããææããã³ããã²
ã³äŸäžååç©ã®å¹æãçžå çã§ããããšã瀺ããŠ
ããã äŸ ïŒ äŸïŒãšåæ§ã«ããŠè£œé ããããŠãã¶ãããä¹³å€
ãïŒåã®çéã«åå²ããã第éšåã«ã¯48.5mgã®
ïŒâããªããã¢ã¡ãã«ãããªã³ããã³ïŒïœã®ã·ã¢
ãã³ææïŒäŸïŒã«èšèŒïŒãããã²ã³åéïŒã¢ã«åœ
ãã«å ããã第éšåã«ã¯ãããã²ã³åéïŒã¢ã«
åœã18.7mgã®ïŒâããªããã¢ã¡ãã«ãããªã³ãå
ããããããä¹³å€ã54âã«30åå ç±ãããå·åŽ
åŸã0.97ïœïŒã¢ã«ã®äŸïŒã§çšãããšåãçŽæ¥éœç»
ææãå ãããè©Šæã35mgAgBrïŒïœm2ã§ã³ãŒã
ã€ã³ã°ãããäž¡è©ŠæããªãŒãã³äžã§ïŒé±é50âïŒ
50ïŒ çžå¯Ÿæ¹¿åºŠã§çµæããããè©Šæã10-3ç§é19æ¬
ã®ç·ã®ã³ã³ãã³ã»ãŒã¿ãŒã䜿çšããŠEGGã»ã³ã·
ãã¡ãŒã¿ãŒã§é²å ãããããŠåèšã®ããã«åŠçã
ãã次ã®çµæãåŸãããã
ãè¡šã
è¡šïŒã®çµæã«ããã°ãææ©ããã²ã³ååç©ã®æ·»
å åŸå ç±ãããªãè©Šæã¯ããã²ã³ååç©ã®æ·»å
åŸå ç±ããè©Šæã«æ¯ããŠããå°éã®äœ¿çšãå¯èœ
ãªãããäžã€å®å®æ§ãå¢å€§ãããããšããããã
è©Šæã«ã€ããŠã®ïŒ€naxã®äœäžã¯ãŸãæ床äžæã
䌎ãªã€ãŠã»ã³ã·ãã¡ããªãŒã®åçŸæ§ãæªãã€ãã äŸ ïŒ äŸïŒã®ããã«ããŠè£œé ãããä¹³å€ãïŒåã®çå
éã«åå²ããã第éšåã«ã¯ããã²ã³åéïŒã¢ã«
åœã1.1ïœã®ïŒâãžããã¢ã¡ãã«ãããªã³ãå ã
ãã第éšåã«ã¯ããã²ã³åéïŒã¢ã«åœã0.12ïœ
ã®ïŒâããªããã¢ã¡ãã«ãããªã³ãå ããã第
éšåã¯å¯Ÿç §ãšããŠä¿åãããçŽæ¥éœç»ææãå
ãããããŠè©Šæ40mgAgBrïŒïœm2ã®ã³ãŒãã€ã³ã°
ééã§ã³ãŒãã€ã³ã°ãããè©ŠæãçŽïŒåéâïŒãŠ
ãšããžãéããŠå¯çæ§åŒã§ïŒ«ïŒïŒ¥ã¿ã³ã°ã¹ãã³å
æºã䜿çšããŠ0.6ããŠãŒãã©ã«æ¿åºŠãã€ã«ã¿ãŒã
䜿çšããŠæ倧åºåã§é²å ãããã次ãã§ãããã
æšæºã¡ãŒãã«âãããããã³çŸåå€äžã§åŠçãã
30ç§éé žåæ¢æµŽã«å ¥ããããããŠïŒåéããªç¡«é ž
å¡©å®ç液äžã§å®çãããããã®çµæã¯è¡šïŒã«ç€ºã
ããŠããã
å åŸå ç±ãããªãè©Šæã¯ããã²ã³ååç©ã®æ·»å
åŸå ç±ããè©Šæã«æ¯ããŠããå°éã®äœ¿çšãå¯èœ
ãªãããäžã€å®å®æ§ãå¢å€§ãããããšããããã
è©Šæã«ã€ããŠã®ïŒ€naxã®äœäžã¯ãŸãæ床äžæã
䌎ãªã€ãŠã»ã³ã·ãã¡ããªãŒã®åçŸæ§ãæªãã€ãã äŸ ïŒ äŸïŒã®ããã«ããŠè£œé ãããä¹³å€ãïŒåã®çå
éã«åå²ããã第éšåã«ã¯ããã²ã³åéïŒã¢ã«
åœã1.1ïœã®ïŒâãžããã¢ã¡ãã«ãããªã³ãå ã
ãã第éšåã«ã¯ããã²ã³åéïŒã¢ã«åœã0.12ïœ
ã®ïŒâããªããã¢ã¡ãã«ãããªã³ãå ããã第
éšåã¯å¯Ÿç §ãšããŠä¿åãããçŽæ¥éœç»ææãå
ãããããŠè©Šæ40mgAgBrïŒïœm2ã®ã³ãŒãã€ã³ã°
ééã§ã³ãŒãã€ã³ã°ãããè©ŠæãçŽïŒåéâïŒãŠ
ãšããžãéããŠå¯çæ§åŒã§ïŒ«ïŒïŒ¥ã¿ã³ã°ã¹ãã³å
æºã䜿çšããŠ0.6ããŠãŒãã©ã«æ¿åºŠãã€ã«ã¿ãŒã
䜿çšããŠæ倧åºåã§é²å ãããã次ãã§ãããã
æšæºã¡ãŒãã«âãããããã³çŸåå€äžã§åŠçãã
30ç§éé žåæ¢æµŽã«å ¥ããããããŠïŒåéããªç¡«é ž
å¡©å®ç液äžã§å®çãããããã®çµæã¯è¡šïŒã«ç€ºã
ããŠããã
ãè¡šã
ãã®çµæã¯ãããªããã¢ã®ãã®ã«æ¯ããŠãžãã
ã¢ååç©ãåæ§ã®çµæãäžããããšãããããã®
çµæãäžããããã«ã¯10å以äžãå¿ èŠãšããããš
ã瀺ããŠããã äŸ ïŒ äŸïŒã®ããã«ããŠä¹³å€ã補é ããããŠãããïŒ
åã®çåéã«åå²ããã第XIã®è©Šæã«ã¯ããã²ã³
åéïŒã¢ã«åœã0.122mgã®ïŒâããªããã¢ã¡ãã«
ãããµãªã³ãå ãã第XIIã®è©Šæã«ã¯ããã²ã³åé
ïŒã¢ã«åœã0.122mgã®ïŒâããªããã¢ã¡ãã«ãã
ãªã³ãå ãããããŠç¬¬ã®è©Šæã¯å¯Ÿç §ã§ãã€
ããçŽæ¥éœç»ææã®æ·»å ãªãã«è©Šæãã³ãŒãã€ã³
ã°ããããŠäŸïŒã®ããã«åŠçããããã®çµæã¯è¡š
ïŒã«èšèŒãããŠããããããã¯åæ§ã®åŠçæ¡ä»¶äž
ã«ã¯ãïŒâããªããã¢ã¡ãã«ãããªã³ãšïŒâããª
ããã¢ã¡ãã«âããããµãªã³ååç©ãšãåäžã®æ
åãããããšã瀺ããŠããã
ã¢ååç©ãåæ§ã®çµæãäžããããšãããããã®
çµæãäžããããã«ã¯10å以äžãå¿ èŠãšããããš
ã瀺ããŠããã äŸ ïŒ äŸïŒã®ããã«ããŠä¹³å€ã補é ããããŠãããïŒ
åã®çåéã«åå²ããã第XIã®è©Šæã«ã¯ããã²ã³
åéïŒã¢ã«åœã0.122mgã®ïŒâããªããã¢ã¡ãã«
ãããµãªã³ãå ãã第XIIã®è©Šæã«ã¯ããã²ã³åé
ïŒã¢ã«åœã0.122mgã®ïŒâããªããã¢ã¡ãã«ãã
ãªã³ãå ãããããŠç¬¬ã®è©Šæã¯å¯Ÿç §ã§ãã€
ããçŽæ¥éœç»ææã®æ·»å ãªãã«è©Šæãã³ãŒãã€ã³
ã°ããããŠäŸïŒã®ããã«åŠçããããã®çµæã¯è¡š
ïŒã«èšèŒãããŠããããããã¯åæ§ã®åŠçæ¡ä»¶äž
ã«ã¯ãïŒâããªããã¢ã¡ãã«ãããªã³ãšïŒâããª
ããã¢ã¡ãã«âããããµãªã³ååç©ãšãåäžã®æ
åãããããšã瀺ããŠããã
ãè¡šã
äŸ ïŒ
ïŒçš®ã®ææ©ããã²ã³ååç©ãçŽæ¥éœç»æ床äžæ
ã®ããã®é žåå€ãšããŠè©äŸ¡ããããããã¯äŸïŒã®
ä¹³å€äžã§ïŒâããªããã¢ã¡ãã«ãããªã³ã«æ¯èŒã
ãŠè©Šéšããããåå®éšæ®µéã¯ãããã²ã³åéïŒã¢
ã«åœã0.97ïœã®äŸïŒããã³ïŒã§çšãããšåãçŽæ¥
éœç»ææãå«æããŠããããããŠããã¯ææ©ãã
ã²ã³ååç©ã®æ·»å åŸ10åé54âã«ä¿æãããŠã
ããå¯Ÿç §è©Šæã¯ããã²ã³åéïŒã¢ã«åœã0.97
ïœã®çŽæ¥éœç»ææã®ã¿ãå«æããŠããããããã
ãããŸã54âã§10åéçæãããŠæ¬çºæã®ããåª
ããçµæã¯ææ©ããã²ã³ååç©ã®ååšãå¿ èŠãšã
ãããšã確蚌ãããã
ã®ããã®é žåå€ãšããŠè©äŸ¡ããããããã¯äŸïŒã®
ä¹³å€äžã§ïŒâããªããã¢ã¡ãã«ãããªã³ã«æ¯èŒã
ãŠè©Šéšããããåå®éšæ®µéã¯ãããã²ã³åéïŒã¢
ã«åœã0.97ïœã®äŸïŒããã³ïŒã§çšãããšåãçŽæ¥
éœç»ææãå«æããŠããããããŠããã¯ææ©ãã
ã²ã³ååç©ã®æ·»å åŸ10åé54âã«ä¿æãããŠã
ããå¯Ÿç §è©Šæã¯ããã²ã³åéïŒã¢ã«åœã0.97
ïœã®çŽæ¥éœç»ææã®ã¿ãå«æããŠããããããã
ãããŸã54âã§10åéçæãããŠæ¬çºæã®ããåª
ããçµæã¯ææ©ããã²ã³ååç©ã®ååšãå¿ èŠãšã
ãããšã確蚌ãããã
ãè¡šã
ãããã®çµæã¯ãäŸïŒã«çžå¯Ÿçã«ïŒâããªãã
ã¢ã¡ãã«ãããªã³ã®éãäžæãããããšã«ãã€
ãŠããããŠäŸïŒãããçãå ç±åŠçã®äœ¿çšã«ãã€
ãŠãå¯Ÿç §ä¹³å€ã«ïŒåã®æ床äžæãåŸãããããšã
瀺ãããããããªãããã®ç¹å®ã®è©Šéšã«ãããŠ
ã¯ãææ©ããã²ã³ååç©ã®ïŒçš®ïŒïŒã»ïŒã»ïŒâã
ãªããã¢ãšã¿ããŒã«ïŒã®ã¿ãæ床äžæã®æ§çžã瀺
ãããããã¯æ¬çºæãèªæã§ãªãããšã®äŸç€ºã§ã
ããããªãã¡ã©ã®ååç©ããã®æ¹æ³ã«ãããŠå®é
ã«äœçšããããã©ããã¯å®éšçã«æ±ºå®ããããšã
å¿ èŠãªã®ã§ãããè©Šæã¯æ¬çºæã®å®æœã«å¯Ÿã
ãŠæå³ãããŠããæè¯ã®æ§åŒã代衚ããŠããã äŸ ïŒ ãã®ä»ã®æ¯èŒã®ããã«ãäŸïŒã®ãã®ãšåæ§ã§ã
ãããããããã²ã³åéïŒã¢ã«åœã2.3Ã10-7ã¢
ã«ã®ã»ã·ãŠã ããªãã«ãã©ã³ããã³1.9Ã10-6ã¢
ã«ã®å¡©åéã§ãã¶ãããä¹³å€ã䜿çšãããã»ãã«
ãã¿ã€ã³ã®ä»£ãã«ã³ãŒãã€ã³ã°å©å€ãšããŠãµãã
ã³ã䜿çšãããè¡šïŒã¯æ¯èŒçµæãäžããŠããã
ã¢ã¡ãã«ãããªã³ã®éãäžæãããããšã«ãã€
ãŠããããŠäŸïŒãããçãå ç±åŠçã®äœ¿çšã«ãã€
ãŠãå¯Ÿç §ä¹³å€ã«ïŒåã®æ床äžæãåŸãããããšã
瀺ãããããããªãããã®ç¹å®ã®è©Šéšã«ãããŠ
ã¯ãææ©ããã²ã³ååç©ã®ïŒçš®ïŒïŒã»ïŒã»ïŒâã
ãªããã¢ãšã¿ããŒã«ïŒã®ã¿ãæ床äžæã®æ§çžã瀺
ãããããã¯æ¬çºæãèªæã§ãªãããšã®äŸç€ºã§ã
ããããªãã¡ã©ã®ååç©ããã®æ¹æ³ã«ãããŠå®é
ã«äœçšããããã©ããã¯å®éšçã«æ±ºå®ããããšã
å¿ èŠãªã®ã§ãããè©Šæã¯æ¬çºæã®å®æœã«å¯Ÿã
ãŠæå³ãããŠããæè¯ã®æ§åŒã代衚ããŠããã äŸ ïŒ ãã®ä»ã®æ¯èŒã®ããã«ãäŸïŒã®ãã®ãšåæ§ã§ã
ãããããããã²ã³åéïŒã¢ã«åœã2.3Ã10-7ã¢
ã«ã®ã»ã·ãŠã ããªãã«ãã©ã³ããã³1.9Ã10-6ã¢
ã«ã®å¡©åéã§ãã¶ãããä¹³å€ã䜿çšãããã»ãã«
ãã¿ã€ã³ã®ä»£ãã«ã³ãŒãã€ã³ã°å©å€ãšããŠãµãã
ã³ã䜿çšãããè¡šïŒã¯æ¯èŒçµæãäžããŠããã
ãè¡šã
ããããµãªã³
α,α,αâ²ãαâ²ããã 0.122 130
ã©ããã¢ãã·ã¬ã³
ãããã®çµæã¯ããªããã åãããåºãæãã
ãããªã³ããã³ãããã¶ãªã³ååç©ãäŸïŒã«ãã
ãããã«Î±ã»Î±ã»Î±â²ã»Î±â²âããã©ããã¢ãã·ã¬
ã³ã«æ¯ã¹ãŠå©ç¹ãä¿æãã€ã€äŸïŒã®ãã®ãšåæ§ã®
æ床äžæãäžããããšããããšã瀺ãã äŸ ïŒ æ¥æ¬ç¹èš±ç¬¬1191127å·æ现æžã®äŸïŒã«èšèŒã®ã
ãã«ããŠãã©ã³ã¹ããã«ãžãšããæ²æŸ±ã«ãã€ãŠã
åäžåæ£ç«æ¹äœç¶ããªãã©ã€ãä¹³å€ïŒBr90ïŒCl
9.5ïŒI0.5ïŒã補é ãããäŸïŒã®æ²èåéä¹³å€ãš
ã¯ç°ã€ãŠãæ²æŸ±ã®éã«ããžãŠã ã¯å å«ãããªãã€
ããä¹³å€ãäŸïŒã«ãããããã«ããŠæŽããããŠå
åæ£ããããããã«ããã²ã³åéïŒã¢ã«åœã7.3
Ã10-8ã¢ã«ã®ã»ã·ãŠã ãã¢ãã«ãã©ã³ããã³1.6
Ã10-4ã¢ã«ã®å¡©åéãå ããããšã«ããä¹³å€ãã
ã¶ãããHClã§å®å®åããã次ãã§72âã§100å
éçæããããä¹³å€ã35âã§å·åŽãããããŠäŸïŒ
ã®çŽæ¥éœç»ææããã³ã³ãŒãã€ã³ã°å©å€ãå ã
ããä¹³å€ã次ãã§ïŒåºåã«åå²ããããããã®ã
ã¡ïŒåºåã«ææ©ããã²ã³ååç©ãå ãããããŠç¬¬
ïŒã®ãã®ã¯å¯Ÿç §ãšããŠãšã€ãŠããããè¡šïŒã¯æ¬çº
æã®çæ段éãæããå Žåããã³ãããé€å€ãã
å Žåã«ä¹³å€ã«é¢ããŠåŸãããæ¯èŒçµæã瀺ããŠã
ããè©Šæã35mgïŒïœm2ã§ã³ãŒãã€ã³ã°ããããŠäŸ
ïŒã®ããã«ããŠé²å ããããããŠåŠçããã
α,α,αâ²ãαâ²ããã 0.122 130
ã©ããã¢ãã·ã¬ã³
ãããã®çµæã¯ããªããã åãããåºãæãã
ãããªã³ããã³ãããã¶ãªã³ååç©ãäŸïŒã«ãã
ãããã«Î±ã»Î±ã»Î±â²ã»Î±â²âããã©ããã¢ãã·ã¬
ã³ã«æ¯ã¹ãŠå©ç¹ãä¿æãã€ã€äŸïŒã®ãã®ãšåæ§ã®
æ床äžæãäžããããšããããšã瀺ãã äŸ ïŒ æ¥æ¬ç¹èš±ç¬¬1191127å·æ现æžã®äŸïŒã«èšèŒã®ã
ãã«ããŠãã©ã³ã¹ããã«ãžãšããæ²æŸ±ã«ãã€ãŠã
åäžåæ£ç«æ¹äœç¶ããªãã©ã€ãä¹³å€ïŒBr90ïŒCl
9.5ïŒI0.5ïŒã補é ãããäŸïŒã®æ²èåéä¹³å€ãš
ã¯ç°ã€ãŠãæ²æŸ±ã®éã«ããžãŠã ã¯å å«ãããªãã€
ããä¹³å€ãäŸïŒã«ãããããã«ããŠæŽããããŠå
åæ£ããããããã«ããã²ã³åéïŒã¢ã«åœã7.3
Ã10-8ã¢ã«ã®ã»ã·ãŠã ãã¢ãã«ãã©ã³ããã³1.6
Ã10-4ã¢ã«ã®å¡©åéãå ããããšã«ããä¹³å€ãã
ã¶ãããHClã§å®å®åããã次ãã§72âã§100å
éçæããããä¹³å€ã35âã§å·åŽãããããŠäŸïŒ
ã®çŽæ¥éœç»ææããã³ã³ãŒãã€ã³ã°å©å€ãå ã
ããä¹³å€ã次ãã§ïŒåºåã«åå²ããããããã®ã
ã¡ïŒåºåã«ææ©ããã²ã³ååç©ãå ãããããŠç¬¬
ïŒã®ãã®ã¯å¯Ÿç §ãšããŠãšã€ãŠããããè¡šïŒã¯æ¬çº
æã®çæ段éãæããå Žåããã³ãããé€å€ãã
å Žåã«ä¹³å€ã«é¢ããŠåŸãããæ¯èŒçµæã瀺ããŠã
ããè©Šæã35mgïŒïœm2ã§ã³ãŒãã€ã³ã°ããããŠäŸ
ïŒã®ããã«ããŠé²å ããããããŠåŠçããã
ãè¡šã
ïŒã±æã®æ£åžžçµæåŸã«ãããè©Šæã³ãŒãã€ã³ã°
ãè©Šéšããå Žåãå¯Ÿç §ããã³ïŒçš®ã®çæä¹³
å€ïŒããã³ïŒã®ã¿ãè¡šïŒã®ãã®ã®
10ïŒ ä»¥å ã®é床å€ã瀺ãããšã枬å®ãããã10ïŒ
å€åã¯å®éšèª€å·®å ã§ããããããã®ããšã¯ãã®ç
æè©Šæãé¡èã«ä¿åå®å®æ§ã§ããããšã瀺ããŠã
ãã äŸ ïŒ äŸïŒã§çšãããã®ãšåãä¹³å€ã調補ããããŠäŸ
ïŒã®ããã«ããŠãã¶ããããè¡šïŒã¯çæ段éã䜿
çšããå Žåããã³ãããé€å€ããå Žåã«çš®ã ã®é
ã®ææ©ããã²ã³ååç©ãå ããŠåŸãããæ¯èŒçµæ
ãäžããã
ãè©Šéšããå Žåãå¯Ÿç §ããã³ïŒçš®ã®çæä¹³
å€ïŒããã³ïŒã®ã¿ãè¡šïŒã®ãã®ã®
10ïŒ ä»¥å ã®é床å€ã瀺ãããšã枬å®ãããã10ïŒ
å€åã¯å®éšèª€å·®å ã§ããããããã®ããšã¯ãã®ç
æè©Šæãé¡èã«ä¿åå®å®æ§ã§ããããšã瀺ããŠã
ãã äŸ ïŒ äŸïŒã§çšãããã®ãšåãä¹³å€ã調補ããããŠäŸ
ïŒã®ããã«ããŠãã¶ããããè¡šïŒã¯çæ段éã䜿
çšããå Žåããã³ãããé€å€ããå Žåã«çš®ã ã®é
ã®ææ©ããã²ã³ååç©ãå ããŠåŸãããæ¯èŒçµæ
ãäžããã
ãè¡šã
çæãªãã®å Žåã§ãããæ床ã«åœ±é¿ã瀺ãä»ã®
ææ©ããã²ã³ååç©ãšã¯ç°ã€ãŠãæ¬ååç©ã¯åã®
å®æœäŸäžã«äœ¿çšãããŠããäžå±€æŽ»æ§ãªããã²ã³é ž
åå€ãããããé·ãçææéãå¿ èŠãšããã äŸ ïŒ ãã¶ãåå¿ãããã²ã³åéïŒã¢ã«åœã2.9Ã
10-7ã¢ã«ã®ã»ã·ãŠã ããªãã«ãã©ã³ããã³4.6Ã
10-6ã¢ã«ã®å¡©åéã䜿çšããŠå®æœããã以å€ã¯äŸ
ïŒã®ããã«ããŠä¹³å€ã補é ãããè¡š10ã¯æ·»å ç©ã
å«æããªãå¯Ÿç §ãšã®æ¯èŒã«ãããŠåäžéã®ææ©ã
ãã²ã³ååç©ãç°ã€ãæéæéçæãããå Žåã«
åŸãããçžå¯Ÿççµæã瀺ããŠããã
ææ©ããã²ã³ååç©ãšã¯ç°ã€ãŠãæ¬ååç©ã¯åã®
å®æœäŸäžã«äœ¿çšãããŠããäžå±€æŽ»æ§ãªããã²ã³é ž
åå€ãããããé·ãçææéãå¿ èŠãšããã äŸ ïŒ ãã¶ãåå¿ãããã²ã³åéïŒã¢ã«åœã2.9Ã
10-7ã¢ã«ã®ã»ã·ãŠã ããªãã«ãã©ã³ããã³4.6Ã
10-6ã¢ã«ã®å¡©åéã䜿çšããŠå®æœããã以å€ã¯äŸ
ïŒã®ããã«ããŠä¹³å€ã補é ãããè¡š10ã¯æ·»å ç©ã
å«æããªãå¯Ÿç §ãšã®æ¯èŒã«ãããŠåäžéã®ææ©ã
ãã²ã³ååç©ãç°ã€ãæéæéçæãããå Žåã«
åŸãããçžå¯Ÿççµæã瀺ããŠããã
ãè¡šã
ãã®è¡šã¯ã30ååŸã«ã¯ãã以äžã®çæã¯æ床å€
åãçããããªãããšã瀺ããŠããããã®ããšã¯
é žåæåãæ¶è²»ãããŠããŸã€ãããšãæå³ããã
ã®ã§ããã ææ©ããã²ã³ååç©ã®æ·»å åŸã«é«æž©ã§ä¹³å€ãç
æãããããšãéèŠã§ãããšããããšã¯æ¬çºæã®
æ瀺ã§ããããã®ä¹³å€ã54âã«äŸïŒã§ã¯30åãã
ããŠäŸïŒã§ã¯10åéä¿æããããããããªããã
ããã¯éå®ãšèããããã¹ãã§ã¯ãªããäœæ ãªã
ã°ãããã¯æäœæ¡ä»¶ã®äŸ¿å©ãã®ããã®å®éšççµæ
ãšããŠãããŠäœ¿çšãããä¹³å€ã«æªåœ±é¿ã®ãªãé©åœ
ãªãã®ãšããŠéžã°ããã«ãããªãã䜿çšãããæ
æ©ããã²ã³ååç©ãæ·»å éããã³æ·»å ã®ãªããã
ä¹³å€ã®ç¬ç¹ã®ç¹æ§ã®å€åã®æ ã«ãçææéã®æé
ããã³æž©åºŠãå€åãããŠæé©çµæãåŸãããšã¯åœ
æ¥è ã«ã¯æçœã§ããçã§ãããããã«é¢ããŠã¯æ¬¡
ã®æ å ±ãæçšã§ãããšèããããã 40âã80âã®æž©åºŠãä¹³å€ã«æªåœ±é¿ãåãŒãããš
ãªãã«çæåå¿ããªãã«æçšã§ãããç¹å®ã®äœ¿çš
ãããŠããææ©ããã²ã³ååç©ã®åå¿æ§ã«é å¿ã
ããŠïŒåçšåºŠã®çæéããæ°æéçšåºŠã®é·æéã
䜿çšããŠãã¶ãäžå¿ãšåå¿ãããããšãã§ããã
ããã²ã³åéä¹³å€ïŒã¢ã«åœãã®ææ©ããã²ã³åå
ç©ã®æå¹éã¯0.01ïœçšåºŠã®å°éãã1.00ïœçšåºŠã®
倧éãŸã§å€åãããããšãã§ããã0.015ïœã
0.50ïœã®ææ©ããã²ã³ååç©ã䜿çšããŠ45âã65
âã®æž©åºŠã§10ã120åéãæäœããã®ã䟿å©ã§ã
ãããšãèŠåºãããŠããã
åãçããããªãããšã瀺ããŠããããã®ããšã¯
é žåæåãæ¶è²»ãããŠããŸã€ãããšãæå³ããã
ã®ã§ããã ææ©ããã²ã³ååç©ã®æ·»å åŸã«é«æž©ã§ä¹³å€ãç
æãããããšãéèŠã§ãããšããããšã¯æ¬çºæã®
æ瀺ã§ããããã®ä¹³å€ã54âã«äŸïŒã§ã¯30åãã
ããŠäŸïŒã§ã¯10åéä¿æããããããããªããã
ããã¯éå®ãšèããããã¹ãã§ã¯ãªããäœæ ãªã
ã°ãããã¯æäœæ¡ä»¶ã®äŸ¿å©ãã®ããã®å®éšççµæ
ãšããŠãããŠäœ¿çšãããä¹³å€ã«æªåœ±é¿ã®ãªãé©åœ
ãªãã®ãšããŠéžã°ããã«ãããªãã䜿çšãããæ
æ©ããã²ã³ååç©ãæ·»å éããã³æ·»å ã®ãªããã
ä¹³å€ã®ç¬ç¹ã®ç¹æ§ã®å€åã®æ ã«ãçææéã®æé
ããã³æž©åºŠãå€åãããŠæé©çµæãåŸãããšã¯åœ
æ¥è ã«ã¯æçœã§ããçã§ãããããã«é¢ããŠã¯æ¬¡
ã®æ å ±ãæçšã§ãããšèããããã 40âã80âã®æž©åºŠãä¹³å€ã«æªåœ±é¿ãåãŒãããš
ãªãã«çæåå¿ããªãã«æçšã§ãããç¹å®ã®äœ¿çš
ãããŠããææ©ããã²ã³ååç©ã®åå¿æ§ã«é å¿ã
ããŠïŒåçšåºŠã®çæéããæ°æéçšåºŠã®é·æéã
䜿çšããŠãã¶ãäžå¿ãšåå¿ãããããšãã§ããã
ããã²ã³åéä¹³å€ïŒã¢ã«åœãã®ææ©ããã²ã³åå
ç©ã®æå¹éã¯0.01ïœçšåºŠã®å°éãã1.00ïœçšåºŠã®
倧éãŸã§å€åãããããšãã§ããã0.015ïœã
0.50ïœã®ææ©ããã²ã³ååç©ã䜿çšããŠ45âã65
âã®æž©åºŠã§10ã120åéãæäœããã®ã䟿å©ã§ã
ãããšãèŠåºãããŠããã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US91201678A | 1978-06-02 | 1978-06-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55500380A JPS55500380A (ja) | 1980-06-26 |
| JPS6161372B2 true JPS6161372B2 (ja) | 1986-12-25 |
Family
ID=25431258
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50096779A Expired JPS6161372B2 (ja) | 1978-06-02 | 1979-06-01 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0016061B1 (ja) |
| JP (1) | JPS6161372B2 (ja) |
| BE (1) | BE876734A (ja) |
| CA (1) | CA1142788A (ja) |
| DE (1) | DE2967425D1 (ja) |
| WO (1) | WO1980000040A1 (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0271172U (ja) * | 1988-11-16 | 1990-05-30 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4845011A (en) * | 1987-10-23 | 1989-07-04 | Hoechst Celanese Corporation | Visible light photoinitiation compositions |
| US4945027A (en) * | 1987-10-23 | 1990-07-31 | Hoechst Celanese Corporation | 1,4 or 9,10 dimethoxyanthracene triggers for 2-tri(chloro or bromo)methyl-4(1H)-quinazolimone polymerization initiators |
| JPH06100795B2 (ja) * | 1988-05-13 | 1994-12-12 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
| GB9221383D0 (en) * | 1992-10-12 | 1992-11-25 | Minnesota Mining & Mfg | Photothermographic imaging materials and antifoggants therefor |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH378283A (de) * | 1959-10-15 | 1964-07-31 | Agfa Ag | Verfahren zur Herstellung von farbigen photographischen Bildern auf Textilmaterial |
| US3495987A (en) * | 1965-09-03 | 1970-02-17 | Du Pont | Photopolymerizable products |
| US3510348A (en) * | 1966-03-11 | 1970-05-05 | Eastman Kodak Co | Direct positive recording film |
| DE1597598A1 (de) * | 1966-11-16 | 1970-06-25 | Gaf Corp | Gelatine fuer photographische Zwecke |
| US3637387A (en) * | 1967-10-24 | 1972-01-25 | Agfa Gevaert Nv | Direct positive emulsion containing a halide releasing compound developed in the presence of an unsubstituted hydrazine |
| US3632340A (en) * | 1968-09-09 | 1972-01-04 | Eastman Kodak Co | Cored direct positive silver halide emulsion developed with polyhydroxybenzene |
| BE757145A (nl) * | 1969-10-09 | 1971-04-07 | Agfa Gevaert Nv | Fotografische opnametechniek |
| GB1427525A (en) * | 1972-07-13 | 1976-03-10 | Agfa Gevaert | Directpositive silver halide emulsions |
-
1979
- 1979-06-01 WO PCT/US1979/000378 patent/WO1980000040A1/en unknown
- 1979-06-01 DE DE7979900704T patent/DE2967425D1/de not_active Expired
- 1979-06-01 CA CA000328961A patent/CA1142788A/en not_active Expired
- 1979-06-01 JP JP50096779A patent/JPS6161372B2/ja not_active Expired
- 1979-06-01 BE BE0/195536A patent/BE876734A/xx not_active IP Right Cessation
-
1980
- 1980-01-14 EP EP79900704A patent/EP0016061B1/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0271172U (ja) * | 1988-11-16 | 1990-05-30 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1980000040A1 (en) | 1980-01-10 |
| EP0016061A1 (en) | 1980-10-01 |
| BE876734A (fr) | 1979-12-03 |
| JPS55500380A (ja) | 1980-06-26 |
| CA1142788A (en) | 1983-03-15 |
| DE2967425D1 (en) | 1985-05-15 |
| EP0016061A4 (en) | 1981-08-27 |
| EP0016061B1 (en) | 1985-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3317322A (en) | Photographic emulsions having high internal sensitivity | |
| US3761266A (en) | Silver halide emulsions predominantly chloride containing silver halide grains with surfaces chemically sensitized and interiors free fromchemical sensitization and the use thereof in reversal processes | |
| JPS6330616B2 (ja) | ||
| US4349622A (en) | Photographic silver halide emulsion comprising epitaxial composite silver halide crystals, silver iodobromide emulsion and process for preparing the same | |
| JPS5943730B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH0259968B2 (ja) | ||
| JPS6230414B2 (ja) | ||
| JPS6161372B2 (ja) | ||
| JPS581414B2 (ja) | ããšã¯ã»ãããžããã²ã³ã«ã®ã³ããŠãŠã¶ã€ã ã»ã€ãŸãŠã㊠| |
| US5240828A (en) | Direct reversal emulsions | |
| JPH07199390A (ja) | åçèŠçŽ åã³åçæ¹æ³ | |
| GB2053499A (en) | Photographic silver halide emulsion and process for preparing same | |
| JPS584333B2 (ja) | ããšã¯ã»ãããžããã²ã³ã«ã®ã³ããŠãŠã¶ã€ | |
| JPS62194248A (ja) | å éšæœååããã²ã³åéä¹³å€ | |
| US5141845A (en) | Process for the spectral sensitization of photographic silver halide emulsions and products thereof | |
| JP2841220B2 (ja) | ããã²ã³åéãšãã«ãžã§ã³ã®å¢ææ³ | |
| JPS6217216B2 (ja) | ||
| JPS62222243A (ja) | ããã²ã³åéåçæå ææ | |
| JPH0764231A (ja) | ãŒã©ãã³å«æå±€ã®ç¡¬èå€ | |
| JPS6024457B2 (ja) | åçä¹³å€ã®å¢ææ³ | |
| JPH0627577A (ja) | ééå±ååç©ãšããªå°¿çŽ ååç©ã«ãã£ãŠå¢æããããã²ã³åéä¹³å€ | |
| US4097285A (en) | Direct-positive photographic silver halide emulsion containing novel dye | |
| JPS5948372B2 (ja) | é°ç»å圢ææ¹æ³ | |
| JPH1078629A (ja) | æ宀åæ±å¯èœãªçŽæ¥å転ããã²ã³åéä¹³å€ | |
| JPS6120026A (ja) | ããã²ã³åéåçæå ææ |