JPS59217712A - 耐衝撃性スチレン系樹脂 - Google Patents
耐衝撃性スチレン系樹脂Info
- Publication number
- JPS59217712A JPS59217712A JP9317283A JP9317283A JPS59217712A JP S59217712 A JPS59217712 A JP S59217712A JP 9317283 A JP9317283 A JP 9317283A JP 9317283 A JP9317283 A JP 9317283A JP S59217712 A JPS59217712 A JP S59217712A
- Authority
- JP
- Japan
- Prior art keywords
- impact
- weight
- styrene
- rubber
- polybutadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 229920005989 resin Polymers 0.000 title claims abstract description 14
- 239000011347 resin Substances 0.000 title claims abstract description 14
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 45
- 229920001971 elastomer Polymers 0.000 claims abstract description 38
- 239000005060 rubber Substances 0.000 claims abstract description 38
- 239000002245 particle Substances 0.000 claims abstract description 32
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 12
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 8
- 229920001890 Novodur Polymers 0.000 claims description 27
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 abstract description 16
- 238000012662 bulk polymerization Methods 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 238000010557 suspension polymerization reaction Methods 0.000 abstract description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract description 2
- 239000002932 luster Substances 0.000 abstract description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 23
- 238000000034 method Methods 0.000 description 20
- 238000006116 polymerization reaction Methods 0.000 description 20
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 101100208721 Mus musculus Usp5 gene Proteins 0.000 description 10
- 238000003756 stirring Methods 0.000 description 9
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000007822 coupling agent Substances 0.000 description 6
- 239000005049 silicon tetrachloride Substances 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 239000000178 monomer Substances 0.000 description 5
- -1 notertrichlorosilane Chemical compound 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 125000001979 organolithium group Chemical group 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 101001015940 Oryza sativa subsp. japonica Protein terminal ear1 homolog Proteins 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 2
- SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical compound [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920006216 polyvinyl aromatic Polymers 0.000 description 2
- 238000010092 rubber production Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- VIZORQUEIQEFRT-UHFFFAOYSA-N Diethyl adipate Chemical compound CCOC(=O)CCCCC(=O)OCC VIZORQUEIQEFRT-UHFFFAOYSA-N 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- PBGVMIDTGGTBFS-UHFFFAOYSA-N but-3-enylbenzene Chemical compound C=CCCC1=CC=CC=C1 PBGVMIDTGGTBFS-UHFFFAOYSA-N 0.000 description 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- DAZXVJBJRMWXJP-UHFFFAOYSA-N n,n-dimethylethylamine Chemical compound CCN(C)C DAZXVJBJRMWXJP-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002900 organolithium compounds Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Landscapes
- Graft Or Block Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9317283A JPS59217712A (ja) | 1983-05-26 | 1983-05-26 | 耐衝撃性スチレン系樹脂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9317283A JPS59217712A (ja) | 1983-05-26 | 1983-05-26 | 耐衝撃性スチレン系樹脂 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59217712A true JPS59217712A (ja) | 1984-12-07 |
| JPH0357925B2 JPH0357925B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-09-03 |
Family
ID=14075148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9317283A Granted JPS59217712A (ja) | 1983-05-26 | 1983-05-26 | 耐衝撃性スチレン系樹脂 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59217712A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61266422A (ja) * | 1985-05-20 | 1986-11-26 | Denki Kagaku Kogyo Kk | ゴム変性スチレン系樹脂 |
| JPS638410A (ja) * | 1986-06-30 | 1988-01-14 | Nippon Erasutomaa Kk | 耐衝撃性スチレン系樹脂組成物 |
| JPS6372711A (ja) * | 1986-09-17 | 1988-04-02 | Nippon Erasutomaa Kk | ゴム変性されたスチレン系樹脂組成物 |
| JPS63122720A (ja) * | 1986-11-12 | 1988-05-26 | Asahi Chem Ind Co Ltd | 外観良好なゴム変性熱可塑性樹脂組成物 |
| JPS63241052A (ja) * | 1987-03-28 | 1988-10-06 | Mitsui Toatsu Chem Inc | アニオン重合ゴム変性スチレン系共重合体 |
| JPS63248809A (ja) * | 1987-01-28 | 1988-10-17 | ザ ダウ ケミカル カンパニー | ゴム強化モノビニリデン芳香族ポリマー樹脂およびその製造法 |
| JPH02229818A (ja) * | 1989-03-03 | 1990-09-12 | Nippon Erasutomaa Kk | 物性バランスの優れた耐衝撃性スチレン系樹脂及びその製造方法 |
| JPH02229809A (ja) * | 1989-03-03 | 1990-09-12 | Nippon Erasutomaa Kk | 改良されたポリブタジエンゴム |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5575413A (en) * | 1978-12-05 | 1980-06-06 | Nippon Erasutomaa Kk | Preraration of high rubber content impact resistant polystyrene |
| JPS5672010A (en) * | 1979-11-15 | 1981-06-16 | Mitsui Toatsu Chem Inc | Styrene type resin composition having excellent appearance |
-
1983
- 1983-05-26 JP JP9317283A patent/JPS59217712A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5575413A (en) * | 1978-12-05 | 1980-06-06 | Nippon Erasutomaa Kk | Preraration of high rubber content impact resistant polystyrene |
| JPS5672010A (en) * | 1979-11-15 | 1981-06-16 | Mitsui Toatsu Chem Inc | Styrene type resin composition having excellent appearance |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61266422A (ja) * | 1985-05-20 | 1986-11-26 | Denki Kagaku Kogyo Kk | ゴム変性スチレン系樹脂 |
| JPS638410A (ja) * | 1986-06-30 | 1988-01-14 | Nippon Erasutomaa Kk | 耐衝撃性スチレン系樹脂組成物 |
| JPS6372711A (ja) * | 1986-09-17 | 1988-04-02 | Nippon Erasutomaa Kk | ゴム変性されたスチレン系樹脂組成物 |
| JPS63122720A (ja) * | 1986-11-12 | 1988-05-26 | Asahi Chem Ind Co Ltd | 外観良好なゴム変性熱可塑性樹脂組成物 |
| JPS63248809A (ja) * | 1987-01-28 | 1988-10-17 | ザ ダウ ケミカル カンパニー | ゴム強化モノビニリデン芳香族ポリマー樹脂およびその製造法 |
| JPS63241052A (ja) * | 1987-03-28 | 1988-10-06 | Mitsui Toatsu Chem Inc | アニオン重合ゴム変性スチレン系共重合体 |
| JPH02229818A (ja) * | 1989-03-03 | 1990-09-12 | Nippon Erasutomaa Kk | 物性バランスの優れた耐衝撃性スチレン系樹脂及びその製造方法 |
| JPH02229809A (ja) * | 1989-03-03 | 1990-09-12 | Nippon Erasutomaa Kk | 改良されたポリブタジエンゴム |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0357925B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-09-03 |
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