JPS59157319A - 高弾性率の全芳香族ポリイミド成型物の製造法 - Google Patents
高弾性率の全芳香族ポリイミド成型物の製造法Info
- Publication number
- JPS59157319A JPS59157319A JP2706883A JP2706883A JPS59157319A JP S59157319 A JPS59157319 A JP S59157319A JP 2706883 A JP2706883 A JP 2706883A JP 2706883 A JP2706883 A JP 2706883A JP S59157319 A JPS59157319 A JP S59157319A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- solution
- yarn
- elastic modulus
- formed article
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004642 Polyimide Substances 0.000 title claims description 10
- 229920001721 polyimide Polymers 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 125000003118 aryl group Chemical group 0.000 title description 3
- 239000002253 acid Substances 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 11
- 230000015271 coagulation Effects 0.000 claims abstract description 8
- 238000005345 coagulation Methods 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 8
- 150000004984 aromatic diamines Chemical class 0.000 claims abstract description 6
- 125000005462 imide group Chemical group 0.000 claims abstract description 6
- 229920005575 poly(amic acid) Polymers 0.000 claims description 9
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 claims 2
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 abstract description 7
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 abstract description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 3
- MGLZGLAFFOMWPB-UHFFFAOYSA-N 2-chloro-1,4-phenylenediamine Chemical compound NC1=CC=C(N)C(Cl)=C1 MGLZGLAFFOMWPB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 25
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 150000004985 diamines Chemical class 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- 150000008065 acid anhydrides Chemical class 0.000 description 7
- 238000009987 spinning Methods 0.000 description 7
- 238000007363 ring formation reaction Methods 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 4
- -1 2-chloro- p-phenylene Chemical group 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- ITQTTZVARXURQS-UHFFFAOYSA-N 3-methylpyridine Chemical compound CC1=CC=CN=C1 ITQTTZVARXURQS-UHFFFAOYSA-N 0.000 description 2
- XKXPBJBODVHDAW-UHFFFAOYSA-N 4-(4-amino-2-chlorophenyl)-3-chloroaniline Chemical compound ClC1=CC(N)=CC=C1C1=CC=C(N)C=C1Cl XKXPBJBODVHDAW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- HUWXDEQWWKGHRV-UHFFFAOYSA-N 3,3'-Dichlorobenzidine Chemical compound C1=C(Cl)C(N)=CC=C1C1=CC=C(N)C(Cl)=C1 HUWXDEQWWKGHRV-UHFFFAOYSA-N 0.000 description 1
- LPDSNGAFAJYVKH-UHFFFAOYSA-N 4-(4-aminophenyl)-2,3-dichloroaniline Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C(Cl)=C1Cl LPDSNGAFAJYVKH-UHFFFAOYSA-N 0.000 description 1
- 241001137307 Cyprinodon variegatus Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 244000088415 Raphanus sativus Species 0.000 description 1
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 1
- 102000016941 Rho Guanine Nucleotide Exchange Factors Human genes 0.000 description 1
- 108010053823 Rho Guanine Nucleotide Exchange Factors Proteins 0.000 description 1
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- KQSABULTKYLFEV-UHFFFAOYSA-N naphthalene-1,5-diamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1N KQSABULTKYLFEV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Moulding By Coating Moulds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2706883A JPS59157319A (ja) | 1983-02-22 | 1983-02-22 | 高弾性率の全芳香族ポリイミド成型物の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2706883A JPS59157319A (ja) | 1983-02-22 | 1983-02-22 | 高弾性率の全芳香族ポリイミド成型物の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59157319A true JPS59157319A (ja) | 1984-09-06 |
| JPH0140125B2 JPH0140125B2 (enrdf_load_stackoverflow) | 1989-08-25 |
Family
ID=12210750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2706883A Granted JPS59157319A (ja) | 1983-02-22 | 1983-02-22 | 高弾性率の全芳香族ポリイミド成型物の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59157319A (enrdf_load_stackoverflow) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61138629A (ja) * | 1984-12-10 | 1986-06-26 | Sumitomo Bakelite Co Ltd | 耐熱性樹脂の製造方法 |
| JPS61250031A (ja) * | 1985-04-29 | 1986-11-07 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | 熔融可能なポリイミド共重合体 |
| JPS6420238A (en) * | 1987-07-15 | 1989-01-24 | Kanegafuchi Chemical Ind | Production of aromatic polyimide polymer molding |
| JPH01306609A (ja) * | 1988-05-30 | 1989-12-11 | Asahi Chem Ind Co Ltd | ナイロン６６繊維の製造法 |
| WO2001081456A1 (en) * | 2000-04-20 | 2001-11-01 | Teijin Limited | Polyimide film and process for producing the same |
| CN113795536A (zh) * | 2019-01-02 | 2021-12-14 | (株) 大林公司 | 聚酰胺酸组合物及其制备方法、聚酰亚胺膜的制备方法及由此制备的聚酰亚胺膜 |
-
1983
- 1983-02-22 JP JP2706883A patent/JPS59157319A/ja active Granted
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61138629A (ja) * | 1984-12-10 | 1986-06-26 | Sumitomo Bakelite Co Ltd | 耐熱性樹脂の製造方法 |
| JPS61250031A (ja) * | 1985-04-29 | 1986-11-07 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | 熔融可能なポリイミド共重合体 |
| JPS6420238A (en) * | 1987-07-15 | 1989-01-24 | Kanegafuchi Chemical Ind | Production of aromatic polyimide polymer molding |
| JPH01306609A (ja) * | 1988-05-30 | 1989-12-11 | Asahi Chem Ind Co Ltd | ナイロン６６繊維の製造法 |
| WO2001081456A1 (en) * | 2000-04-20 | 2001-11-01 | Teijin Limited | Polyimide film and process for producing the same |
| US6797801B2 (en) | 2000-04-20 | 2004-09-28 | Teijin Limited | Polyimide film and process for producing the same |
| CN113795536A (zh) * | 2019-01-02 | 2021-12-14 | (株) 大林公司 | 聚酰胺酸组合物及其制备方法、聚酰亚胺膜的制备方法及由此制备的聚酰亚胺膜 |
| JP2022516281A (ja) * | 2019-01-02 | 2022-02-25 | デリム カンパニー リミテッド | ポリアミド酸組成物の製造方法、ポリアミド酸組成物、これを用いたポリイミドフィルムの製造方法及びその製造方法によって製造されたポリイミドフィルム |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0140125B2 (enrdf_load_stackoverflow) | 1989-08-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3242136A (en) | Ammonium salts of aromatic polyamideacids and process for preparing polyimides therefrom | |
| CN107779975B (zh) | 含氯高性能杂环芳香族聚酰胺纤维的制备方法 | |
| JPS59157319A (ja) | 高弾性率の全芳香族ポリイミド成型物の製造法 | |
| JPS5910894B2 (ja) | ホウコウゾクポリアミドハクマクノブツリテキセイシツノ カイリヨウホウ | |
| JPS6277921A (ja) | 全芳香族コポリイミド一軸配向品 | |
| JPH0418115A (ja) | ポリイミド繊維の製造法 | |
| JPS6257916A (ja) | コポリイミド繊維 | |
| JPH07310232A (ja) | バグフィルター用ポリアミドイミド繊維 | |
| JPS636028A (ja) | ポリイミド成形体の製造方法 | |
| JPH036174B2 (enrdf_load_stackoverflow) | ||
| JPS59163416A (ja) | ポリイミド繊維の製造法 | |
| JPH01315428A (ja) | ポリイミドフィルムの製造方法 | |
| JPH01260015A (ja) | 高弾性率繊維の製造法 | |
| RU2062276C1 (ru) | Способ получения полиамидокислотного раствора для формования волокон | |
| Preston et al. | Thermally stable amide–bithiazole ordered copolymers | |
| JPS63315211A (ja) | ポリイミドフィルムの製造方法 | |
| JPH0455613B2 (enrdf_load_stackoverflow) | ||
| JPH01292120A (ja) | 化学環化ポリイミド繊維の製造方法 | |
| JPH03287815A (ja) | ポリイミド繊維の製造法 | |
| JPS6279227A (ja) | 全芳香族コポリピロメリトイミド | |
| JPS60204309A (ja) | 優れた機械的性質を有する皮膜又は繊維の製法 | |
| JPH0450404B2 (enrdf_load_stackoverflow) | ||
| JPS63230738A (ja) | ポリエステルイミド繊維 | |
| JPS63211319A (ja) | ポリイミド繊維 | |
| JPH0742611B2 (ja) | ポリイミド繊維 |