JPS59136326A - ポリエ−テルスルホンの製造方法 - Google Patents
ポリエ−テルスルホンの製造方法Info
- Publication number
- JPS59136326A JPS59136326A JP942583A JP942583A JPS59136326A JP S59136326 A JPS59136326 A JP S59136326A JP 942583 A JP942583 A JP 942583A JP 942583 A JP942583 A JP 942583A JP S59136326 A JPS59136326 A JP S59136326A
- Authority
- JP
- Japan
- Prior art keywords
- amount
- potassium carbonate
- polymer
- sulfone
- sodium hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004695 Polyether sulfone Substances 0.000 title claims abstract description 8
- 229920006393 polyether sulfone Polymers 0.000 title claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 60
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 54
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 27
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 7
- 125000005843 halogen group Chemical group 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000011734 sodium Substances 0.000 claims abstract description 3
- 238000010438 heat treatment Methods 0.000 claims abstract 2
- 150000002989 phenols Chemical class 0.000 claims abstract 2
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- 239000002904 solvent Substances 0.000 abstract description 10
- 239000011541 reaction mixture Substances 0.000 abstract description 4
- 150000003457 sulfones Chemical class 0.000 abstract description 4
- 235000015320 potassium carbonate Nutrition 0.000 abstract 2
- 235000011181 potassium carbonates Nutrition 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 29
- 238000006116 polymerization reaction Methods 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 238000004040 coloring Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- GPAPPPVRLPGFEQ-UHFFFAOYSA-N 4,4'-dichlorodiphenyl sulfone Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC=C(Cl)C=C1 GPAPPPVRLPGFEQ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 3
- 150000008041 alkali metal carbonates Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000007086 side reaction Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000001339 alkali metal compounds Chemical class 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- -1 aromatic sulfone Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- AZMMUMQYPBKXHS-UHFFFAOYSA-N gold sodium Chemical compound [Na].[Au] AZMMUMQYPBKXHS-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000033444 hydroxylation Effects 0.000 description 1
- 238000005805 hydroxylation reaction Methods 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Polyethers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP942583A JPS59136326A (ja) | 1983-01-25 | 1983-01-25 | ポリエ−テルスルホンの製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP942583A JPS59136326A (ja) | 1983-01-25 | 1983-01-25 | ポリエ−テルスルホンの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59136326A true JPS59136326A (ja) | 1984-08-04 |
| JPH0340733B2 JPH0340733B2 (enrdf_load_stackoverflow) | 1991-06-19 |
Family
ID=11719985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP942583A Granted JPS59136326A (ja) | 1983-01-25 | 1983-01-25 | ポリエ−テルスルホンの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59136326A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62179527A (ja) * | 1986-01-30 | 1987-08-06 | ハ−キュルス インコ−ポレ−テッド | ポリアリ−レンポリエ−テルの製造方法 |
| JP2020050747A (ja) * | 2018-09-26 | 2020-04-02 | 住友化学株式会社 | ポリビフェニルエーテルスルホン樹脂及びその製造方法並びに溶融成形品 |
| WO2020066888A1 (ja) * | 2018-09-26 | 2020-04-02 | 住友化学株式会社 | ポリビフェニルエーテルスルホン樹脂及び成形品 |
-
1983
- 1983-01-25 JP JP942583A patent/JPS59136326A/ja active Granted
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62179527A (ja) * | 1986-01-30 | 1987-08-06 | ハ−キュルス インコ−ポレ−テッド | ポリアリ−レンポリエ−テルの製造方法 |
| JP2020050747A (ja) * | 2018-09-26 | 2020-04-02 | 住友化学株式会社 | ポリビフェニルエーテルスルホン樹脂及びその製造方法並びに溶融成形品 |
| WO2020066888A1 (ja) * | 2018-09-26 | 2020-04-02 | 住友化学株式会社 | ポリビフェニルエーテルスルホン樹脂及び成形品 |
| WO2020066875A1 (ja) * | 2018-09-26 | 2020-04-02 | 住友化学株式会社 | ポリビフェニルエーテルスルホン樹脂及びその製造方法並びに溶融成形品 |
| CN112739745A (zh) * | 2018-09-26 | 2021-04-30 | 住友化学株式会社 | 聚联苯醚砜树脂及成型品 |
| CN112739746A (zh) * | 2018-09-26 | 2021-04-30 | 住友化学株式会社 | 聚联苯醚砜树脂及其制造方法以及熔融成型品 |
| JPWO2020066888A1 (ja) * | 2018-09-26 | 2021-08-30 | 住友化学株式会社 | ポリビフェニルエーテルスルホン樹脂及び成形品 |
| EP3858892A4 (en) * | 2018-09-26 | 2022-06-22 | Sumitomo Chemical Company Limited | Poly(biphenyl ether sulfone) resin, production method therefor, and melt-molded article |
| EP3858891A4 (en) * | 2018-09-26 | 2022-06-22 | Sumitomo Chemical Company Limited | Poly(biphenyl ether sulfone) resin and molded article |
| CN112739746B (zh) * | 2018-09-26 | 2023-02-17 | 住友化学株式会社 | 聚联苯醚砜树脂及其制造方法以及熔融成型品 |
| CN112739745B (zh) * | 2018-09-26 | 2023-08-08 | 住友化学株式会社 | 聚联苯醚砜树脂及成型品 |
| US11807723B2 (en) | 2018-09-26 | 2023-11-07 | Sumitomo Chemical Compnay, Limited | Poly(biphenyl ether sulfone) resin and molded article |
| US12116457B2 (en) | 2018-09-26 | 2024-10-15 | Sumitomo Chemical Company, Limited | Poly(biphenyl ether sulfone) resin, production method therefor, and melt-molded article |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0340733B2 (enrdf_load_stackoverflow) | 1991-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4200728A (en) | Manufacture of polyethers from bis-(4-hydroxyphenyl)-sulfone and bis-(4-chlorophenyl)-sulfone in N-methylpyrrolidone using an alkali metal carbonate as catalysts | |
| JPS59136326A (ja) | ポリエ−テルスルホンの製造方法 | |
| JPS627730A (ja) | 結晶性芳香族ポリエ−テルケトンの製造方法 | |
| JPH02308814A (ja) | 芳香族ポリエーテルケトンの製造方法 | |
| JPS5930822A (ja) | 芳香族ポリエ−テルの製造法 | |
| JPS5974123A (ja) | ポリアリ−レンエ−テルの製造法 | |
| JPS58101113A (ja) | ポリエ−テル系重合体の製造方法 | |
| JPH0323570B2 (enrdf_load_stackoverflow) | ||
| WO1991013929A1 (fr) | Polymeres non cristallins et leur production | |
| JPH01245018A (ja) | 着色度の改善されたポリスルホンの製造方法 | |
| JPH0216122A (ja) | 熱安定性の優れた芳香族ポリエーテル | |
| JPS6379868A (ja) | オリゴマ−の精製分離法 | |
| JPS59164326A (ja) | 芳香族ポリエ−テルケトン系共重合体 | |
| JPS61159420A (ja) | 芳香族ポリエ−テル系共重合体 | |
| JPH0269527A (ja) | 新規の芳香剤ポリエーテルスルホン、その製造方法およびその使用 | |
| JPH01315421A (ja) | 芳香族ポリスルホン | |
| JPS6071635A (ja) | 芳香族系ポリエ−テル及びその製造法 | |
| JPH01141912A (ja) | 芳香族ポリエーテルスホンの製造方法 | |
| JPH0533934B2 (enrdf_load_stackoverflow) | ||
| JPH0277426A (ja) | 結晶性新規芳香族ポリスルホン及びその製造方法 | |
| JPH01311126A (ja) | 芳香族ポリエーテルスルホン | |
| JPS61231026A (ja) | ポリシアノアリ−ルエ−テルの製造方法 | |
| GB1569602A (en) | Production of aromatic polymers | |
| JPH0352924A (ja) | 芳香族ポリエーテル重合体の製造方法 | |
| JPH03153737A (ja) | ポリエーテルスルホンの製造法 |