JPS5818326A - ２，４，５−トリフルオロ−〔４′−（トランス−４″−アルキルシクロヘキシル）シクロヘキセン−１′−イル〕ベンゼン - Google Patents
２，４，５−トリフルオロ−〔４′−（トランス−４″−アルキルシクロヘキシル）シクロヘキセン−１′−イル〕ベンゼンInfo
- Publication number
- JPS5818326A JPS5818326A JP11731481A JP11731481A JPS5818326A JP S5818326 A JPS5818326 A JP S5818326A JP 11731481 A JP11731481 A JP 11731481A JP 11731481 A JP11731481 A JP 11731481A JP S5818326 A JPS5818326 A JP S5818326A
- Authority
- JP
- Japan
- Prior art keywords
- liquid crystal
- benzene
- trans
- compound
- cyclohexen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract description 23
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 abstract description 14
- 239000000463 material Substances 0.000 abstract description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 4
- 239000011777 magnesium Substances 0.000 abstract description 3
- 229910052749 magnesium Inorganic materials 0.000 abstract description 3
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 abstract description 3
- 229910000343 potassium bisulfate Inorganic materials 0.000 abstract description 3
- XSMLLZPSNLQCQU-UHFFFAOYSA-N 1-bromo-2,3,5-trifluorobenzene Chemical compound FC1=CC(F)=C(F)C(Br)=C1 XSMLLZPSNLQCQU-UHFFFAOYSA-N 0.000 abstract 1
- JIWRAHHCDZUHKY-UHFFFAOYSA-M [Br-].FC1=CC(F)=C([Mg+])C=C1F Chemical compound [Br-].FC1=CC(F)=C([Mg+])C=C1F JIWRAHHCDZUHKY-UHFFFAOYSA-M 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004988 Nematic liquid crystal Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GPGGNNIMKOVSAG-UHFFFAOYSA-N 4-(4-octoxyphenyl)benzonitrile Chemical group C1=CC(OCCCCCCCC)=CC=C1C1=CC=C(C#N)C=C1 GPGGNNIMKOVSAG-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- PXLZHAOTBQULGW-UHFFFAOYSA-M Fc1ccc([Mg]Br)c(F)c1F Chemical compound Fc1ccc([Mg]Br)c(F)c1F PXLZHAOTBQULGW-UHFFFAOYSA-M 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 210000002858 crystal cell Anatomy 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- -1 propylcyclohexyl Chemical group 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Liquid Crystal Substances (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11731481A JPS5818326A (ja) | 1981-07-27 | 1981-07-27 | ２，４，５−トリフルオロ−〔４′−（トランス−４″−アルキルシクロヘキシル）シクロヘキセン−１′−イル〕ベンゼン |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11731481A JPS5818326A (ja) | 1981-07-27 | 1981-07-27 | ２，４，５−トリフルオロ−〔４′−（トランス−４″−アルキルシクロヘキシル）シクロヘキセン−１′−イル〕ベンゼン |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5818326A true JPS5818326A (ja) | 1983-02-02 |
| JPS644497B2 JPS644497B2 (en, 2012) | 1989-01-25 |
Family
ID=14708678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11731481A Granted JPS5818326A (ja) | 1981-07-27 | 1981-07-27 | ２，４，５−トリフルオロ−〔４′−（トランス−４″−アルキルシクロヘキシル）シクロヘキセン−１′−イル〕ベンゼン |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5818326A (en, 2012) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4551264A (en) * | 1982-03-13 | 1985-11-05 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Polyhalogenoaromatic compounds for liquid crystal compositions |
| US5032313A (en) * | 1989-03-07 | 1991-07-16 | Chisso Corporation | Trifluorobenzene derivative and liquid crystal composition containing the same |
| US5213710A (en) * | 1990-09-26 | 1993-05-25 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Benzene derivatives and a liquid-crystalline medium |
| US5308542A (en) * | 1990-03-13 | 1994-05-03 | Merck Patent Gesellschaft Mit Beschrankter Haftung | 4,4'-disubstituted 2',3-difluorobisphenyls and a liquid-crystalline medium |
| US5324449A (en) * | 1987-09-25 | 1994-06-28 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Substituted phenyl trifluoromethyl ethers |
| US5389292A (en) * | 1988-07-27 | 1995-02-14 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Difluoromethyl compounds |
| US5487845A (en) * | 1989-09-06 | 1996-01-30 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Fluorobenzene derivatives and liquid-crystalline medium |
| US5536442A (en) * | 1987-09-25 | 1996-07-16 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Fluorinated liquid crystal compounds and liquid crystal medium containing same |
| DE4035509C2 (de) * | 1990-11-08 | 1999-10-21 | Merck Patent Gmbh | Cyclohexylcyclohexene und flüssigkristallines Medium |
| CN107573212A (zh) * | 2017-10-13 | 2018-01-12 | 河北美星化工有限公司 | 反式4‑烷基环己基苯结构液晶中间体及单体的合成方法 |
-
1981
- 1981-07-27 JP JP11731481A patent/JPS5818326A/ja active Granted
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4551264A (en) * | 1982-03-13 | 1985-11-05 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Polyhalogenoaromatic compounds for liquid crystal compositions |
| US5324449A (en) * | 1987-09-25 | 1994-06-28 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Substituted phenyl trifluoromethyl ethers |
| US5536442A (en) * | 1987-09-25 | 1996-07-16 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Fluorinated liquid crystal compounds and liquid crystal medium containing same |
| US5389292A (en) * | 1988-07-27 | 1995-02-14 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Difluoromethyl compounds |
| US5032313A (en) * | 1989-03-07 | 1991-07-16 | Chisso Corporation | Trifluorobenzene derivative and liquid crystal composition containing the same |
| US5487845A (en) * | 1989-09-06 | 1996-01-30 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Fluorobenzene derivatives and liquid-crystalline medium |
| US5308542A (en) * | 1990-03-13 | 1994-05-03 | Merck Patent Gesellschaft Mit Beschrankter Haftung | 4,4'-disubstituted 2',3-difluorobisphenyls and a liquid-crystalline medium |
| US5213710A (en) * | 1990-09-26 | 1993-05-25 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Benzene derivatives and a liquid-crystalline medium |
| DE4035509C2 (de) * | 1990-11-08 | 1999-10-21 | Merck Patent Gmbh | Cyclohexylcyclohexene und flüssigkristallines Medium |
| CN107573212A (zh) * | 2017-10-13 | 2018-01-12 | 河北美星化工有限公司 | 反式4‑烷基环己基苯结构液晶中间体及单体的合成方法 |
| CN107573212B (zh) * | 2017-10-13 | 2020-08-04 | 宁夏中星显示材料有限公司 | 反式4-烷基环己基苯结构液晶中间体及单体的合成方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS644497B2 (en, 2012) | 1989-01-25 |
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