JPS58167623A - 耐衝撃性ブロツクコポリアミドの製造法 - Google Patents
耐衝撃性ブロツクコポリアミドの製造法Info
- Publication number
- JPS58167623A JPS58167623A JP57049326A JP4932682A JPS58167623A JP S58167623 A JPS58167623 A JP S58167623A JP 57049326 A JP57049326 A JP 57049326A JP 4932682 A JP4932682 A JP 4932682A JP S58167623 A JPS58167623 A JP S58167623A
- Authority
- JP
- Japan
- Prior art keywords
- lactam
- polymerization
- impact
- butadiene
- polyamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 22
- 239000012190 activator Substances 0.000 claims abstract description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 12
- 239000012948 isocyanate Substances 0.000 claims abstract description 10
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 9
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 8
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 7
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims abstract description 7
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims abstract description 3
- -1 polymethylene Polymers 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229920000265 Polyparaphenylene Polymers 0.000 claims 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract description 18
- 239000004952 Polyamide Substances 0.000 abstract description 16
- 229920002647 polyamide Polymers 0.000 abstract description 16
- 238000010539 anionic addition polymerization reaction Methods 0.000 abstract description 6
- 239000002685 polymerization catalyst Substances 0.000 abstract description 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract description 2
- 150000001340 alkali metals Chemical class 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 22
- 239000005062 Polybutadiene Substances 0.000 description 10
- 229920002857 polybutadiene Polymers 0.000 description 10
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 6
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 240000006108 Allium ampeloprasum Species 0.000 description 1
- 235000005254 Allium ampeloprasum Nutrition 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- CJYXCQLOZNIMFP-UHFFFAOYSA-N azocan-2-one Chemical compound O=C1CCCCCCN1 CJYXCQLOZNIMFP-UHFFFAOYSA-N 0.000 description 1
- YDLSUFFXJYEVHW-UHFFFAOYSA-N azonan-2-one Chemical compound O=C1CCCCCCCN1 YDLSUFFXJYEVHW-UHFFFAOYSA-N 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000012693 lactam polymerization Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/69—Polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57049326A JPS58167623A (ja) | 1982-03-27 | 1982-03-27 | 耐衝撃性ブロツクコポリアミドの製造法 |
| DE8383301707T DE3372628D1 (en) | 1982-03-27 | 1983-03-25 | Production of block copolyamide from omega-lactam |
| EP83301707A EP0091250B1 (en) | 1982-03-27 | 1983-03-25 | Production of block copolyamide from omega-lactam |
| US06/479,237 US4485213A (en) | 1982-03-27 | 1983-03-28 | Process for the production of high impact block copolyamide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57049326A JPS58167623A (ja) | 1982-03-27 | 1982-03-27 | 耐衝撃性ブロツクコポリアミドの製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58167623A true JPS58167623A (ja) | 1983-10-03 |
| JPH0362728B2 JPH0362728B2 (enExample) | 1991-09-26 |
Family
ID=12827854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57049326A Granted JPS58167623A (ja) | 1982-03-27 | 1982-03-27 | 耐衝撃性ブロツクコポリアミドの製造法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4485213A (enExample) |
| EP (1) | EP0091250B1 (enExample) |
| JP (1) | JPS58167623A (enExample) |
| DE (1) | DE3372628D1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60208328A (ja) * | 1984-03-29 | 1985-10-19 | ザ・フアイヤ−スト−ン・タイヤ・アンド・ラバ−・カンパニ− | ポリブタジエン／ナイロン−６ブロツク共重合体の迅速重合方法 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4810753A (en) * | 1985-10-29 | 1989-03-07 | Mitsubishi Chemical Industries Limited | Process for producing polyamide |
| US4694039A (en) * | 1986-03-26 | 1987-09-15 | Dsm Rim Nylon V.O.F. | Stabilized lactam polymerization solutions |
| EP0243177B1 (en) * | 1986-04-23 | 1993-07-07 | Sumitomo Chemical Company, Limited | Catalytic production of polyamide block copolymers |
| CA2016189C (en) * | 1989-11-30 | 1999-05-25 | Gerd M. Lenke | Abrasion resistant polyurethane blend compositions |
| EP1478679B1 (en) * | 2002-02-21 | 2008-05-14 | Stichting Dutch Polymer Institute | Copolymer containing one or more amide segments |
| CN104004346A (zh) * | 2014-05-22 | 2014-08-27 | 广州市南方尼龙制品有限公司 | 一种超韧耐磨mc尼龙复合材料及其制备方法 |
| US10633513B2 (en) * | 2018-03-26 | 2020-04-28 | Fina Technology, Inc. | Curable low sulfur liquid rubber compositions and methods of manufacturing the same |
| CN111057207A (zh) * | 2018-10-17 | 2020-04-24 | 上海浦加钻采技术有限公司 | 螺杆钻具用弹性体材料的预聚体及其制备方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2877212A (en) * | 1954-10-11 | 1959-03-10 | Du Pont | Polyurethanes from difunctional polymers of conjugated dienes |
| GB1099265A (en) * | 1964-05-11 | 1968-01-17 | British Celanese | Improvements relating to the polymerisation of caprolactam |
| GB1169737A (en) * | 1966-04-29 | 1969-11-05 | Internat Synthetic Rubber Comp | Thermoplastic Elastomer Block Polymers |
| US3511893A (en) * | 1967-07-31 | 1970-05-12 | Polymer Corp | Polyamides block copolymers with caprolactam and caprylactam |
| US3770849A (en) * | 1971-02-01 | 1973-11-06 | Union Carbide Corp | Lactam-vinyl block copolymers |
| US3887643A (en) * | 1971-06-07 | 1975-06-03 | Phillips Petroleum Co | Diene-lactam block copolymers |
| US3859382A (en) * | 1972-01-19 | 1975-01-07 | Firestone Tire & Rubber Co | Method of making nylon constituent block copolymers of predetermined pliability at low temperatures |
| US4151222A (en) * | 1975-05-05 | 1979-04-24 | The Firestone Tire & Rubber Company | Amine terminated polymers and the formation of block copolymers |
| US4070344A (en) * | 1975-05-05 | 1978-01-24 | The Firestone Tire And Rubber Company | Amine terminated polymers and the formation of block copolymers |
| DD139337A3 (de) * | 1975-05-06 | 1979-12-27 | Christoph Roth | Verfahren zur herstellung von mit blockierten isocyanaten abgeschlossenen homo-und copolymerisaten konjugierter diene und vinylaromatischer verbindungen |
| FR2322165A1 (fr) * | 1975-09-01 | 1977-03-25 | Inst Francais Du Petrole | Nouveaux copolymeres sequences a base de polyamide et leur preparation a partir de copolymeres butadiene-acrylonitrile a terminaisons acyllactames |
| JPS5757720A (en) * | 1980-09-25 | 1982-04-07 | Daicel Chem Ind Ltd | Roduction of copolyamide resin |
-
1982
- 1982-03-27 JP JP57049326A patent/JPS58167623A/ja active Granted
-
1983
- 1983-03-25 EP EP83301707A patent/EP0091250B1/en not_active Expired
- 1983-03-25 DE DE8383301707T patent/DE3372628D1/de not_active Expired
- 1983-03-28 US US06/479,237 patent/US4485213A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60208328A (ja) * | 1984-03-29 | 1985-10-19 | ザ・フアイヤ−スト−ン・タイヤ・アンド・ラバ−・カンパニ− | ポリブタジエン／ナイロン−６ブロツク共重合体の迅速重合方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3372628D1 (en) | 1987-08-27 |
| JPH0362728B2 (enExample) | 1991-09-26 |
| EP0091250B1 (en) | 1987-07-22 |
| US4485213A (en) | 1984-11-27 |
| EP0091250A1 (en) | 1983-10-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR880001142B1 (ko) | 폴리머 얼로이의 제조방법 및 반응 사출 성형 생성물 | |
| JPS5837022A (ja) | 長い貯蔵寿命を有するポリオ−ル／ジフエニルメタンウレトジオンジイソシアネ−トの不均一な一成分系、その製造方法およびそれの高分子量ポリウレタンの合成のための使用 | |
| JPH0715000B2 (ja) | ラクタム類の活性化アニオン性重合 | |
| JPS58167623A (ja) | 耐衝撃性ブロツクコポリアミドの製造法 | |
| JPH03124813A (ja) | 高弾性、高強度エラスタン繊維およびその製造法 | |
| US4939234A (en) | Polymerization of lactam polyisocyanate having the isocyanate groups blocked with lactam | |
| KR870001406B1 (ko) | N-치환된 카로바모일-락탐 화합물의 제조방법 | |
| KR860001553B1 (ko) | N-치환된 카르바모일-락탐 화합물의 제조방법 | |
| US4940773A (en) | Process for producing modified, impact-resistant polyamides with lactam-blocked diisocyanate/monoisocyanate | |
| EP0320070B1 (en) | Process for the preparation of a nylon block copolymer | |
| US4614615A (en) | Process for preparing an N-substituted carbamoyl-lactam compound | |
| JPS6119649B2 (enExample) | ||
| KR870001407B1 (ko) | N-치환된 카로바모일-락탐 화합물의 제조방법 | |
| JPS6153373B2 (enExample) | ||
| JP2906629B2 (ja) | ガラス転移温度の高いポリアミドの製造法 | |
| JPH0248017B2 (enExample) | ||
| JPS61152728A (ja) | Ｎ―置換アシルラクタム化合物および該化合物の製造法 | |
| JPS59170120A (ja) | 耐衝撃性ポリアミドの製造方法 | |
| JPS5996132A (ja) | 耐衝撃性ポリアミドの製造法 | |
| JPS60229924A (ja) | 耐衝撃性ポリアミドの製造法 | |
| JPS6053536A (ja) | 耐衝撃性ポリアミドの製法 | |
| JPS60243118A (ja) | ポリアミドブロツク共重合体の製法 | |
| JPS60120721A (ja) | ポリアミドブロック共重合体の製造方法 | |
| JPS634855B2 (enExample) | ||
| JPS5996131A (ja) | ポリアミドの製法 |